US8278005B2 - Separator for fuel cell and solid polymer type fuel cell - Google Patents

Separator for fuel cell and solid polymer type fuel cell Download PDF

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US8278005B2
US8278005B2 US10/576,740 US57674004A US8278005B2 US 8278005 B2 US8278005 B2 US 8278005B2 US 57674004 A US57674004 A US 57674004A US 8278005 B2 US8278005 B2 US 8278005B2
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plate member
separator
fuel cell
gasket
main body
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US20070196716A1 (en
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Takashi Mashimo
Tomohiro Inoue
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Nok Corp
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Nok Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2483Details of groupings of fuel cells characterised by internal manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0286Processes for forming seals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to a fuel cell separator and a solid polymer electrolyte fuel cell that employs the fuel cell separator.
  • a fuel cell is formed with a power generating device that has an electrolyte film and electrode films (a fuel electrode and an air electrode) placed on both side of the electrolyte film, and separators that have fluid passages for supplying fuel gas (hydrogen) and oxide gas (oxygen, normally the atmosphere) to the electrode films.
  • a solid polymer electrolyte fuel cell has a fuel cell stack that is formed by stacking fuel cells of the above-described type.
  • FIG. 11 is a cross-sectional view of a conventional fuel cell 100 that has a power generating device 300 interposed between a separator 200 A and a separator 200 B. Since the volt age is too low in the single cell 100 , several cells of this type are stacked to form a fuel cell stack.
  • the power generating device 300 includes a fuel electrode 300 A that is located to face the separator 200 A for fuel gas supply, an air electrode 300 B that is located to face the separator 200 B for oxide gas supply, and an electrolyte film 300 C that is interposed between the fuel electrode 300 A and the air electrode 300 B.
  • FIG. 12 is a plan view of a conventional separator 200 .
  • the separator 200 has a gas channel 201 having a number of concave grooves formed in the center of the surface of a separator main body 205 . Also, manifolds 202 that penetrate the separator main body 205 in the stacking direction are provided on both sides of the gas channel on the surface of the separator main body 205 . Gas is supplied to the gas channel 201 via the manifolds 202 .
  • Connecting paths 203 that connect the concave grooves of the gas channel 201 to the manifolds 202 are formed between the gas channel 201 and the manifolds 202 .
  • Each of the connecting paths 203 is formed in a tunnel-like fashion with grooves 203 a that connects the gas channel 201 to the manifolds 202 , and a plate member 203 b that covers the openings of the grooves 203 a.
  • a gasket 204 a that is made of an elastic material, surrounds the gas channel 201 , and prevents gas leakage from the gas channel 201 to the outside, is formed on the surface of the separator main body 205 .
  • a gasket 204 b that is made of an elastic material is formed at the peripheral portion of the manifolds 202 , including the surface of the plate member 203 b that covers the grooves 203 a . Accordingly, the gas to be supplied from the manifolds 202 to the connecting paths 203 is prevented from leaking to another separator 200 stacked on the separator 200 or to the power generating device 300 interposed between the separators.
  • the plate member 203 b covers the grooves 203 a and the gasket 204 b is provided on the surface of the plate member 203 b , the plate member 203 b is pushed onto the grooves 203 a by virtue of the repulsive force of the gasket 204 b against the compression force applied from the other separator 200 stacked on the upper surface of the gasket.
  • the connecting paths can be hermetically sealed.
  • the plate member 203 b is engaged with the upper surface of the grooves 203 a without an adhesive agent, and the gaskets 204 a and 204 b made of an elastic material are integrally molded in a series at the entire peripheral portion of the manifolds 202 , including the surface of the plate member 203 b . In this manner, the plate member 203 b is secured to a predetermined position on the upper surface of the grooves of the separator 200 .
  • a fuel cell separator with this structure has been known (refer to Patent Document 1).
  • Patent Document 1 Japanese Unexamined Patent Publication No. 2002-50364
  • the fixing of the plate member 203 b to the separator main body 204 is performed only with the gasket 204 b molded on the surfaces of the separator 200 and the plate member 203 b .
  • the gasket 204 is thin, the plate member 203 b might move away from the predetermined fixing position, or the plate member 203 b might fall off while a fuel cell or a fuel cell stack is being assembled. Because of this, the plate member 203 b is not firmly secured.
  • the gasket 204 b formed on the surface of the plate member 203 b sticks to the mating separator. As a result, there is a problem that the plate member 203 b is lifted up, and the gasket 204 b breaks at the corresponding parts.
  • the object of the present invention is to provide fuel cell separators and a solid polymer electrolyte fuel cell in which the above problems of the related art are solved, the plate member can be firmly secured to the separator main body, and the gasket does not break when separators are disassembled.
  • the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
  • the fuel cell separator comprising:
  • separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
  • a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the surfaces of the separator main body and the plate member, the region surrounding the manifold, wherein
  • the plate member has notches or through holes
  • part of the elastic material fills the notches or the through holes, thereby increasing the fixing strength of the plate member to a predetermined position on the opening of the groove.
  • the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
  • the fuel cell separator comprising:
  • separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
  • a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the separator main body and the surface of the plate member, the region surrounding the manifold, wherein
  • the plate member has notches or through holes
  • the separator main body has guide protrusions that protrude from the separator main body
  • the guide protrusions have top ends inserted to the notches or the through holes formed in the plate member,
  • part of the elastic material fills gaps between the guide protrusions and the notches or the through holes, thereby increasing the fixing strength of the plate member to a predetermined position on the opening of the groove.
  • the separator main body has concave portions at the locations corresponding to the notches or the through holes formed in the plate member;
  • part of the elastic material when the gasket is being integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material also fills the concave portions, thereby increasing the fixing strength of the plate member to the predetermined position on the opening of the groove.
  • the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
  • the fuel cell separator comprising:
  • separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
  • a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the surfaces of the separator main body and the plate member, the region surrounding. the manifold, wherein
  • the plate member has notches or through holes
  • the separator main body has concave portions at the locations corresponding to the notches or the through holes formed in the plate member,
  • part of the elastic material that forms the gasket formed on the surface of the plate member protrudes from the back surface of the plate member through the notches or the through holes, thereby forming convex portions
  • the convex portions are engaged with the concave portions formed in the separator main body, thereby securing the plate member to a predetermined position on the opening of the groove in the separator main body.
  • a fuel cell separator wherein the gasket that is formed on the surface of the separator main body is formed separately from the gasket formed on the surface of the plate member.
  • a solid polymer electrolyte fuel cell comprising the fuel cell separator.
  • the plate member can be firmly secured to the separator main body.
  • the present invention provides fuel cell separators and the solid polymer electrolyte fuel cell in which the gaskets do not break when the separators are disassembled.
  • FIGS. 1A and 1B are plan views of a fuel cell separator (hereinafter referred to as a “separator”) in accordance with a first embodiment of the present invention.
  • FIG. 1A illustrates a separator 20 that has a plate member 23 b provided on grooves 23 a , and gaskets 24 a and 24 b formed on the surfaces of a separator main body 25 and the plate member 23 b .
  • the separator 20 has a gas channel 21 with a number of concave grooves.
  • the gas channel 21 is provided in the center of the surface of the plate-like separator main body 25 .
  • manifolds 22 that penetrate the separator main body 25 in the stacking direction are formed at both ends of the gas channel 21 on the separator main body 25 .
  • the manifolds 22 formed in each separator main body 25 forms a channel that penetrates the fuel cell.
  • a manifold is formed in the fuel cell stack.
  • the manifolds 22 are formed at six locations, with the gas channel 21 being flanked by the manifolds 22 .
  • gas is supplied to and discharged from the gas channel 21 through the two manifolds 22 that are located on a diagonal line of the gas channel 21 .
  • gas is supplied to other separators that form other fuel cells and are stacked on the separator 20 .
  • Connecting paths 23 that connect the concave grooves that form the gas channel 21 to the manifolds 22 is formed between the gas channel 21 and the manifolds 22 .
  • Each of the connecting paths 23 is formed in a tunnel-like fashion with the corresponding groove 23 a , which connects the gas channel 21 and the corresponding manifold 22 , and the plate member 23 b , which covers the opening of the grooves 23 a.
  • FIG. 1B illustrates the above separator, with the plate members 23 b being removed from the grooves 23 a to open the connecting paths 23 .
  • FIG. 2 is a cross-sectional view of the separator, taken along the line A-A of FIG. 1A .
  • the separator main body 25 has not only the grooves 23 a that form the gas channel, but also a housing concave portion 23 c that houses the plate member 23 b so that the surface of the plate member 23 b forms the same plane as the surface of the separator main body 25 . Accordingly, the grooves 23 a are formed through the bottom surface of the housing concave portion 23 c .
  • the plate member 23 b is engaged with the housing concave portion 23 c without an adhesive agent.
  • the separator 20 may preferably be formed with a metal plate such as SUS (steel use stainless), an aluminum plate and a titanium plate, a composite resin material such as FRP (fiber reinforced plastics) and CFRP (carbon fiber reinforced plastics), calcined carbon, a heat-resistant resin material such as PET (polyethylene terephthalate), PEN (polyethernitrile), PI (polyimide), PAI (polyamidimide), PPS (polyphenylene sulfide), PEEK (polyether ether ketone), or a conductive resin material.
  • a metal plate such as SUS (steel use stainless), an aluminum plate and a titanium plate
  • a composite resin material such as FRP (fiber reinforced plastics) and CFRP (carbon fiber reinforced plastics), calcined carbon
  • a heat-resistant resin material such as PET (polyethylene terephthalate), PEN (polyethernitrile), PI (polyimide), PAI (polyamidimide
  • the material for the plate member 23 b is not particularly limited, as long as it tolerates integral molding with the gaskets.
  • the plate member 23 b may preferably be formed with the same material for the separator 20 , and a heat-resistant resin material such as PEEK or PI.
  • the gaskets 24 a that surround the gas channel 21 to prevent gas leakage from the gas channel 21 to the outside, and are made of an elastic material are formed on the surface of the separator main body 25 .
  • the material for the gaskets 24 a is not particularly limited, as long as each gasket 24 a is made of an elastic material that is commonly used.
  • elastic materials such as fluorocarbon rubber, EPDM, or silicone rubber are preferable.
  • Each gasket 24 a can be molded beforehand, and be bonded to a predetermined location on the separator main body 25 . In such a case, however, an adhesive agent is used. In view of this, an elastic material should preferably be injection-molded at the predetermined location on the separator main body 25 , so that the gasket 24 a is integrally molded on the surface of the separator main body 25 .
  • each gasket 24 b is provided on the surface of the plate member 23 b and the surface of the separator main body 25 , which surround the openings of the manifolds 22 .
  • the gaskets 24 a and the gaskets 24 b are integrally molded at the same time through injection molding of elastic materials.
  • FIGS. 3A through 3D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25 , including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b .
  • FIG. 3A illustrates the state after the gasket molding.
  • FIG. 3B illustrates the state prior to the gasket molding.
  • the separator in accordance with the first embodiment has notches 23 e that are formed at the longitudinal-direction ends and the width-direction center of the plate member 23 b , and extend in the stacking direction, as shown in FIG. 3B .
  • FIG. 3C illustrates a state, with the plate member 23 b being removed.
  • the housing concave portion 23 c for housing the plate member 23 b is formed, and the grooves 23 a are formed through the bottom surface of the housing concave portion 23 c.
  • an elastic material is injection-molded to integrally mold the gasket 25 b in the region containing the separator main body 25 and the notches 23 e of the surface of the plate member 23 b , so that the gasket 25 b surrounds the manifold 22 .
  • part of the elastic material flows into the spaces between the plate member 23 b and the separator main body 25 , thereby securing the plate member 23 b to the predetermined location on the separator main body 25 .
  • FIG. 3D is a cross-sectional view of the structure, taken along the line A-A of FIG. 3A .
  • the notches 23 e are filled with part of the elastic material injection-molded in the region containing the notches 23 e , and the plate member 23 b is taken in with the notches 23 e by virtue of the repulsive force of the elastic material.
  • the plate member 23 b is secured.
  • the joined portion between the plate member 23 b and the gasket 24 b is enlarged. Accordingly, the gasket 24 b is firmly fixed to the surface of the plate member 23 b , and can be prevented from being lifted up from the plate member 23 b .
  • the plate member 23 b is firmly fixed to the separator main body 25 .
  • the notices 23 e may be replaced with through holes.
  • the joined portion between the plate member 23 b and the gasket 24 b is enlarged by the elastic material filling the through holes. Accordingly, the gasket 24 b is firmly fixed to the surface of the plate member 23 b , and can be prevented from being lifted up from the plate member 23 b.
  • FIGS. 4A through 5D illustrate separators in accordance with a second embodiment of the present invention.
  • FIGS. 4A through 5D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25 , including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b .
  • FIGS. 4A and 5A illustrate the states after the gasket molding.
  • FIGS. 4B and 5B illustrate the states prior to the gasket molding.
  • FIGS. 4C and 5C illustrate the states, with the plate member 23 b being removed.
  • the separator in accordance with the second embodiment has the notches 23 e formed in the plate member 23 b , as shown in FIG. 4B .
  • the housing concave portion 23 c for housing the plate member 23 b has guide protrusions 23 f that protrude therefrom. The top ends of the guide protrusions 23 f are inserted to the notches 23 e.
  • the guide protrusions 23 f are formed at the locations corresponding to the notches 23 e of the housing concave portion 23 c , so as to sandwich the notches 23 e formed at both ends of the plate member 23 b.
  • the plate member 23 b can be easily positioned onto the separator main body 25 .
  • FIG. 4D is a cross-sectional view of the structure, taken along the line B-B of FIG. 4A .
  • the notches 23 e outside the guide protrusions 23 f are filled with part of the elastic material that is injection-molded in the region containing the notches 23 e .
  • the plate member 23 b is secured.
  • FIGS. 5A through 5D illustrate a modification of the separator in accordance with the second embodiment.
  • through holes 23 g are formed in the plate member 23 b .
  • the guide protrusions 23 f are formed to protrude from the housing concave portion 23 c that is formed on the separator main body and houses the plate member 23 b .
  • the top ends of the guide protrusions 23 f are inserted to the through holes 23 g.
  • the guide protrusions 23 f are inserted to the through holes 23 g formed at both ends of the plate member 23 b , with small gaps being left.
  • FIG. 5D is a cross-sectional view of the structure, taken along the line C-C of FIG. 5A .
  • each guide protrusion 23 f and the inner peripheral surface of each through hole 23 g is filled with part of the elastic material that is injection-molded in the region containing the through holes 23 g .
  • the plate member 23 b is secured.
  • FIGS. 6A through 6D illustrate a separator in accordance with a third embodiment of the present invention.
  • FIGS. 6A through 6D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25 , including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b .
  • FIG. 6A illustrates the state after the gasket molding.
  • FIG. 6B illustrates the state prior to the gasket molding.
  • FIG. 6C illustrates the state, with the plate member 23 b being removed.
  • the separator in accordance with the third embodiment has the through holes 23 g formed in the plate member 23 b , as shown in FIG. 6B .
  • each of the concave portions 23 h is a circular hole that is concentric with each corresponding through hole 23 g and has a bottom with a greater diameter than the diameter of each corresponding through hole 23 g.
  • FIG. 6D is a cross-sectional view of the structure, taken along the-line D-D of FIG. 6A .
  • an elastic material is injection-molded in the region that surrounds the manifold 22 and contains the through holes 23 g formed through the surfaces of the separator main body 25 and the plate member 23 b , and the through holes 23 g and the concave portions 23 h are filled with the elastic material.
  • the gasket 24 b is secured to the separator main body 25 .
  • each of the concave portions 23 h has a greater diameter than the diameter of each through hole 23 g , the elastic material filling the concave portions 23 h more firmly secures the gasket 24 b onto the surface of the plate member 23 b . Accordingly, the bonding force between the plate member 23 b and the gasket 24 b is increased. Thus, the gasket 24 b can be prevented from being lifted up from the plate member 23 b.
  • the through holes 23 g may be replaced with the same notches as the notches 23 e of the first embodiment.
  • the housing concave portion 23 c that houses the plate member 23 b has the concave portions 23 h formed at the locations corresponding to the notches, so that the same effects as above can be achieved.
  • FIG. 7 is a plan view of a separator in accordance with a fourth embodiment of the present invention.
  • the separator in accordance with the fourth embodiment has the gasket 24 a in the region on the surface of the separator main body 25 that surround the gas channel 21 . Further, a gasket that surrounds each corresponding manifold 22 is formed with the gasket 24 b that is formed at the outer peripheral portions of the opening of the manifold 22 and is located outside the surface of the plate member 23 b , and a gasket 24 c that is formed separately from the gasket 24 b and is located on the surface of the plate member 23 b.
  • the gasket 24 a and the gasket 24 b outside the surface of the plate member 23 b are integrally molded at the same time on the surface of the separator main body 25 through injection molding.
  • the gasket 24 c is separately formed on the surface of the plate member 23 b .
  • a gap is formed between the gasket 24 b and the gasket 24 c .
  • the gap is located in the position corresponding to the region other than the concave grooves of the gas channel 21 , so that gas leakage can be prevented.
  • the gasket 24 c is formed separately from the gasket 24 b , part of the elastic material enters the gap formed between the separator main body 25 and the plate member 23 b at the time of the integral molding of the gasket, thereby preventing burrs. Accordingly, the entered elastic material prevents the plate member 23 b from lifting. Thus, gas leakage can be avoided.
  • FIG. 8 is a cross-sectional view of the structure, taken along the line E-E of FIG. 7 .
  • FIG. 9A is a plan view of the plate member 23 b in accordance with this embodiment.
  • FIG. 9B is a plan view illustrating the state in which the gasket 24 c is formed on the surface of the plate member 23 b.
  • a through hole 23 i that penetrates the plate member 23 b in the stacking direction is formed at the center of the surface of the plate member 23 b .
  • the gasket 24 c is then formed in the region on the surface of the plate member 23 b including the through hole 23 i.
  • a convex portion 24 d that protrudes from the through hole 23 i is integrally formed with the gasket 24 c on the back surface of the plate member 23 b.
  • the gasket 24 c formed on the surface of the plate member 23 b may be bonded to a predetermined position on the plate member 23 b after the convex portion 24 d is molded on the back surface of the gasket 24 c .
  • an adhesive agent is required. Therefore, it is preferable to set the plate member 23 b in a mold, injection-mold the elastic material in the region containing the through hole 23 i , and then integrally mold the gasket 24 c and the convex portion 24 d.
  • a concave portion 23 j is provided at the location corresponding to the through hole 23 i formed in the plate member 23 b.
  • the plate member 23 b is then engaged with the housing concave portion 23 c , so that the convex portion 24 d protruding from the back surface of the plate member 23 b is engaged with the concave portion 23 j .
  • the plate member 23 b can be certainly fixed to a predetermined location on the separator main body 25 .
  • the fixed position of the plate member 23 b can be prevented from moving, and the plate member 23 b can be prevented from falling off.
  • the gasket 24 c formed on the surface of the plate member 23 b can be prevented from sticking to the mating separator, and the plate member 23 c can be prevented from being lifted up.
  • the gasket 24 c can be prevented from breaking.
  • FIG. 10 is a modification of the separator in accordance with the fourth embodiment.
  • two through holes 23 i are formed in the vicinities of both ends of the plate member 23 b in the longitudinal direction.
  • the convex portion 24 d protruding from each of the through holes 23 i is integrally formed with the gasket 24 c.
  • the plate member 23 b is fixed to a predetermined position on the separator main body 25 by virtue of the two convex portions 24 d protruding from the vicinities of the end portions of the plate member 23 b in the longitudinal direction. Accordingly, more accurate fixing of the plate member 23 b can be performed, and the plate member 23 b can be prevented from moving or falling off at the time of stack assembling.
  • a power generating device that has an electrolyte film and electrode films (a fuel electrode and an air electrode) placed on both sides of the electrolyte film may be interposed between separators 20 of any of the above embodiments, thereby forming a fuel cell.
  • Such fuel cells are stacked on one another to form a fuel cell stack.
  • the plate member 23 b can be prevented from moving away from the predetermined attachment position or falling off at the time of assembling of the stack. Also, while the stack is being disassembled, the plate member 23 b can be prevented from being lifted up from the attachment position on each separator main body 25 and thus the gaskets can be prevented from breaking.
  • FIGS. 1A and 1B are plan views of a separator in accordance with a first embodiment
  • FIG. 2 is a cross-sectional view of the separator, taken along the line A-A of FIG. 1A ;
  • FIGS. 3A through 3D are partially enlarged views of the separator in accordance with the first embodiment
  • FIGS. 4A through 4D are partially enlarged views of a separator in accordance with a second embodiment
  • FIGS. 5A through 5D are partially enlarged views of a modification of the separator in accordance with the second embodiment
  • FIGS. 6A through 6D are partially enlarged views of a separator in accordance with a third embodiment
  • FIG. 7 is a plan view of a separator in accordance with a fourth embodiment.
  • FIG. 8 is a partially enlarged view of the separator in accordance with the fourth embodiment.
  • FIGS. 9A and 9B are plan views of the plate member of the separator in accordance with the fourth embodiment.
  • FIG. 10 is a partially enlarged view of a modification of the separator in accordance with the fourth embodiment.
  • FIG. 11 is a cross-sectional view of a conventional fuel cell.
  • FIG. 12 is a plan view of a conventional separator 200 .

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Abstract

Notches 23 e are filled with part of an elastic material that is injection-molded in a region containing the notches 23 e, so that a plate member 23 b is taken in by the notches 23 e through the repulsive force of the elastic material. Thus, the plate member 23 b is secured. Further, the elastic material filling the notches 23 e enlarges the joined portion between the plate member 23 b and the gasket 24 b. Accordingly, the gasket 24 b is firmly joined to the surface of the plate member 23 b, and can be prevented from being lifted up from the plate member 23 b. Thus, the plate member 23 b is firmly secured to the separator main body 25.

Description

This is a nationalization of PCT/JP2004/015709 filed 22 Oct. 2004 and published in Japanese.
TECHNICAL FIELD
The present invention relates to a fuel cell separator and a solid polymer electrolyte fuel cell that employs the fuel cell separator.
BACKGROUND ART
In general, a fuel cell is formed with a power generating device that has an electrolyte film and electrode films (a fuel electrode and an air electrode) placed on both side of the electrolyte film, and separators that have fluid passages for supplying fuel gas (hydrogen) and oxide gas (oxygen, normally the atmosphere) to the electrode films. A solid polymer electrolyte fuel cell has a fuel cell stack that is formed by stacking fuel cells of the above-described type.
FIG. 11 is a cross-sectional view of a conventional fuel cell 100 that has a power generating device 300 interposed between a separator 200A and a separator 200B. Since the volt age is too low in the single cell 100, several cells of this type are stacked to form a fuel cell stack.
The power generating device 300 includes a fuel electrode 300A that is located to face the separator 200A for fuel gas supply, an air electrode 300B that is located to face the separator 200B for oxide gas supply, and an electrolyte film 300C that is interposed between the fuel electrode 300A and the air electrode 300B.
FIG. 12 is a plan view of a conventional separator 200.
The separator 200 has a gas channel 201 having a number of concave grooves formed in the center of the surface of a separator main body 205. Also, manifolds 202 that penetrate the separator main body 205 in the stacking direction are provided on both sides of the gas channel on the surface of the separator main body 205. Gas is supplied to the gas channel 201 via the manifolds 202.
Connecting paths 203 that connect the concave grooves of the gas channel 201 to the manifolds 202 are formed between the gas channel 201 and the manifolds 202.
Each of the connecting paths 203 is formed in a tunnel-like fashion with grooves 203 a that connects the gas channel 201 to the manifolds 202, and a plate member 203 b that covers the openings of the grooves 203 a.
A gasket 204 a that is made of an elastic material, surrounds the gas channel 201, and prevents gas leakage from the gas channel 201 to the outside, is formed on the surface of the separator main body 205.
Also, a gasket 204 b that is made of an elastic material is formed at the peripheral portion of the manifolds 202, including the surface of the plate member 203 b that covers the grooves 203 a. Accordingly, the gas to be supplied from the manifolds 202 to the connecting paths 203 is prevented from leaking to another separator 200 stacked on the separator 200 or to the power generating device 300 interposed between the separators.
As the plate member 203 b covers the grooves 203 a and the gasket 204 b is provided on the surface of the plate member 203 b, the plate member 203 b is pushed onto the grooves 203 a by virtue of the repulsive force of the gasket 204 b against the compression force applied from the other separator 200 stacked on the upper surface of the gasket. Thus, the connecting paths can be hermetically sealed.
If an adhesive agent is used to secure the plate member 203 b to a predetermined position on the upper surface of the grooves 203 a of the separator 200, the adhesive agent might stick out to the grooves 203 a, and defective bonding is caused, resulting in a deterioration in quality. Therefore, the plate member 203 b is engaged with the upper surface of the grooves 203 a without an adhesive agent, and the gaskets 204 a and 204 b made of an elastic material are integrally molded in a series at the entire peripheral portion of the manifolds 202, including the surface of the plate member 203 b. In this manner, the plate member 203 b is secured to a predetermined position on the upper surface of the grooves of the separator 200. A fuel cell separator with this structure has been known (refer to Patent Document 1).
[Patent Document 1] Japanese Unexamined Patent Publication No. 2002-50364
DISCLOSURE OF THE INVENTION
Problems to be Solved by the Invention
In the above conventional separator, however, the fixing of the plate member 203 b to the separator main body 204 is performed only with the gasket 204 b molded on the surfaces of the separator 200 and the plate member 203 b. Thus, for example, if the gasket 204 is thin, the plate member 203 b might move away from the predetermined fixing position, or the plate member 203 b might fall off while a fuel cell or a fuel cell stack is being assembled. Because of this, the plate member 203 b is not firmly secured.
Furthermore, when the once-stacked separators 200 are disassembled, the gasket 204 b formed on the surface of the plate member 203 b sticks to the mating separator. As a result, there is a problem that the plate member 203 b is lifted up, and the gasket 204 b breaks at the corresponding parts.
Therefore, the object of the present invention is to provide fuel cell separators and a solid polymer electrolyte fuel cell in which the above problems of the related art are solved, the plate member can be firmly secured to the separator main body, and the gasket does not break when separators are disassembled.
Means to Solve the Problems
To achieve above-described object, the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
the fuel cell separator comprising:
a separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
a plate member that covers an opening of the groove; and
a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the surfaces of the separator main body and the plate member, the region surrounding the manifold, wherein
the plate member has notches or through holes,
when the gasket is being integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material fills the notches or the through holes, thereby increasing the fixing strength of the plate member to a predetermined position on the opening of the groove.
To achieve above-described object, the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
the fuel cell separator comprising:
a separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
a plate member that covers an opening of the groove; and
a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the separator main body and the surface of the plate member, the region surrounding the manifold, wherein
the plate member has notches or through holes,
the separator main body has guide protrusions that protrude from the separator main body,
the guide protrusions have top ends inserted to the notches or the through holes formed in the plate member,
when the gasket is being integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material fills gaps between the guide protrusions and the notches or the through holes, thereby increasing the fixing strength of the plate member to a predetermined position on the opening of the groove.
According to the preferred aspect of the present invention, there is provided a fuel cell separator, wherein:
the separator main body has concave portions at the locations corresponding to the notches or the through holes formed in the plate member; and
when the gasket is being integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material also fills the concave portions, thereby increasing the fixing strength of the plate member to the predetermined position on the opening of the groove.
To achieve above-described object, the present invention provides a fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
the fuel cell separator comprising:
a separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
a plate member that covers an opening of the groove; and
a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the surfaces of the separator main body and the plate member, the region surrounding. the manifold, wherein
the plate member has notches or through holes,
the separator main body has concave portions at the locations corresponding to the notches or the through holes formed in the plate member,
part of the elastic material that forms the gasket formed on the surface of the plate member, protrudes from the back surface of the plate member through the notches or the through holes, thereby forming convex portions,
the convex portions are engaged with the concave portions formed in the separator main body, thereby securing the plate member to a predetermined position on the opening of the groove in the separator main body.
According to the preferred aspect of the present invention, there is provided a fuel cell separator, wherein the gasket that is formed on the surface of the separator main body is formed separately from the gasket formed on the surface of the plate member.
To achieve above-described object, there is provided a solid polymer electrolyte fuel cell comprising the fuel cell separator.
Effects of the Invention
As described above, with the fuel cell separators and the solid polymer electrolyte fuel cell of the present invention, the plate member can be firmly secured to the separator main body. Also, the present invention provides fuel cell separators and the solid polymer electrolyte fuel cell in which the gaskets do not break when the separators are disassembled.
BEST MODE FOR CARRYING OUT THE INVENTION
The following is a detailed description of preferred embodiments of the present invention, with reference to the accompanying drawings. However, the sizes, materials, shapes, and relative locations of the components described in the following embodiments do not limit the scope of the present invention, unless otherwise specified.
(First Embodiment)
FIGS. 1A and 1B are plan views of a fuel cell separator (hereinafter referred to as a “separator”) in accordance with a first embodiment of the present invention.
FIG. 1A illustrates a separator 20 that has a plate member 23 b provided on grooves 23 a, and gaskets 24 a and 24 b formed on the surfaces of a separator main body 25 and the plate member 23 b. As shown in FIG. 1A, the separator 20 has a gas channel 21 with a number of concave grooves. The gas channel 21 is provided in the center of the surface of the plate-like separator main body 25. Also, manifolds 22 that penetrate the separator main body 25 in the stacking direction are formed at both ends of the gas channel 21 on the separator main body 25. As separators 20 are stacked on one another, the manifolds 22 formed in each separator main body 25 forms a channel that penetrates the fuel cell. As a result, a manifold is formed in the fuel cell stack. In this embodiment, the manifolds 22 are formed at six locations, with the gas channel 21 being flanked by the manifolds 22. However, gas is supplied to and discharged from the gas channel 21 through the two manifolds 22 that are located on a diagonal line of the gas channel 21. Through the other manifolds, gas is supplied to other separators that form other fuel cells and are stacked on the separator 20.
Connecting paths 23 that connect the concave grooves that form the gas channel 21 to the manifolds 22 is formed between the gas channel 21 and the manifolds 22.
Each of the connecting paths 23 is formed in a tunnel-like fashion with the corresponding groove 23 a, which connects the gas channel 21 and the corresponding manifold 22, and the plate member 23 b, which covers the opening of the grooves 23 a.
FIG. 1B illustrates the above separator, with the plate members 23 b being removed from the grooves 23 a to open the connecting paths 23.
FIG. 2 is a cross-sectional view of the separator, taken along the line A-A of FIG. 1A.
As shown in FIG. 2, the separator main body 25 has not only the grooves 23 a that form the gas channel, but also a housing concave portion 23 c that houses the plate member 23 b so that the surface of the plate member 23 b forms the same plane as the surface of the separator main body 25. Accordingly, the grooves 23 a are formed through the bottom surface of the housing concave portion 23 c. The plate member 23 b is engaged with the housing concave portion 23 c without an adhesive agent.
The separator 20 may preferably be formed with a metal plate such as SUS (steel use stainless), an aluminum plate and a titanium plate, a composite resin material such as FRP (fiber reinforced plastics) and CFRP (carbon fiber reinforced plastics), calcined carbon, a heat-resistant resin material such as PET (polyethylene terephthalate), PEN (polyethernitrile), PI (polyimide), PAI (polyamidimide), PPS (polyphenylene sulfide), PEEK (polyether ether ketone), or a conductive resin material.
The material for the plate member 23 b is not particularly limited, as long as it tolerates integral molding with the gaskets. The plate member 23 b may preferably be formed with the same material for the separator 20, and a heat-resistant resin material such as PEEK or PI.
The gaskets 24 a that surround the gas channel 21 to prevent gas leakage from the gas channel 21 to the outside, and are made of an elastic material are formed on the surface of the separator main body 25.
The material for the gaskets 24 a is not particularly limited, as long as each gasket 24 a is made of an elastic material that is commonly used. For example, elastic materials such as fluorocarbon rubber, EPDM, or silicone rubber are preferable.
Each gasket 24 a can be molded beforehand, and be bonded to a predetermined location on the separator main body 25. In such a case, however, an adhesive agent is used. In view of this, an elastic material should preferably be injection-molded at the predetermined location on the separator main body 25, so that the gasket 24 a is integrally molded on the surface of the separator main body 25.
Also, each gasket 24 b is provided on the surface of the plate member 23 b and the surface of the separator main body 25, which surround the openings of the manifolds 22. In the separator of this embodiment, the gaskets 24 a and the gaskets 24 b are integrally molded at the same time through injection molding of elastic materials.
FIGS. 3A through 3D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25, including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b. FIG. 3A illustrates the state after the gasket molding. FIG. 3B illustrates the state prior to the gasket molding.
The separator in accordance with the first embodiment has notches 23 e that are formed at the longitudinal-direction ends and the width-direction center of the plate member 23 b, and extend in the stacking direction, as shown in FIG. 3B.
FIG. 3C illustrates a state, with the plate member 23 b being removed. In the separator main body 25, the housing concave portion 23 c for housing the plate member 23 b is formed, and the grooves 23 a are formed through the bottom surface of the housing concave portion 23 c.
As shown in FIG. 3A, with the plate member 23 b being engaged with the housing concave portion 23 c, an elastic material is injection-molded to integrally mold the gasket 25 b in the region containing the separator main body 25 and the notches 23 e of the surface of the plate member 23 b, so that the gasket 25 b surrounds the manifold 22. In this manner, part of the elastic material flows into the spaces between the plate member 23 b and the separator main body 25, thereby securing the plate member 23 b to the predetermined location on the separator main body 25.
FIG. 3D is a cross-sectional view of the structure, taken along the line A-A of FIG. 3A.
As shown in FIG. 3D, the notches 23 e are filled with part of the elastic material injection-molded in the region containing the notches 23 e, and the plate member 23 b is taken in with the notches 23 e by virtue of the repulsive force of the elastic material. Thus, the plate member 23 b is secured. Further, with the elastic material filling the notches 23 e, the joined portion between the plate member 23 b and the gasket 24 b is enlarged. Accordingly, the gasket 24 b is firmly fixed to the surface of the plate member 23 b, and can be prevented from being lifted up from the plate member 23 b. Thus, the plate member 23 b is firmly fixed to the separator main body 25.
In the separator in accordance with the first embodiment, the notices 23 e may be replaced with through holes. In such a case, the joined portion between the plate member 23 b and the gasket 24 b is enlarged by the elastic material filling the through holes. Accordingly, the gasket 24 b is firmly fixed to the surface of the plate member 23 b, and can be prevented from being lifted up from the plate member 23 b.
(Second Embodiment)
FIGS. 4A through 5D illustrate separators in accordance with a second embodiment of the present invention.
FIGS. 4A through 5D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25, including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b. FIGS. 4A and 5A illustrate the states after the gasket molding. FIGS. 4B and 5B illustrate the states prior to the gasket molding. FIGS. 4C and 5C illustrate the states, with the plate member 23 b being removed.
The separator in accordance with the second embodiment has the notches 23 e formed in the plate member 23 b, as shown in FIG. 4B. Also, the housing concave portion 23 c for housing the plate member 23 b has guide protrusions 23 f that protrude therefrom. The top ends of the guide protrusions 23 f are inserted to the notches 23 e.
The guide protrusions 23 f are formed at the locations corresponding to the notches 23 e of the housing concave portion 23 c, so as to sandwich the notches 23 e formed at both ends of the plate member 23 b.
Accordingly, the plate member 23 b can be easily positioned onto the separator main body 25.
FIG. 4D is a cross-sectional view of the structure, taken along the line B-B of FIG. 4A.
As shown in FIG. 4D, the notches 23 e outside the guide protrusions 23 f are filled with part of the elastic material that is injection-molded in the region containing the notches 23 e. Thus, the plate member 23 b is secured.
FIGS. 5A through 5D illustrate a modification of the separator in accordance with the second embodiment.
As shown in FIG. 5B, through holes 23 g are formed in the plate member 23 b. Also, the guide protrusions 23 f are formed to protrude from the housing concave portion 23 c that is formed on the separator main body and houses the plate member 23 b. The top ends of the guide protrusions 23 f are inserted to the through holes 23 g.
The guide protrusions 23 f are inserted to the through holes 23 g formed at both ends of the plate member 23 b, with small gaps being left.
FIG. 5D is a cross-sectional view of the structure, taken along the line C-C of FIG. 5A.
As shown in FIG. 5D, the gap between the outer peripheral surface of each guide protrusion 23 f and the inner peripheral surface of each through hole 23 g is filled with part of the elastic material that is injection-molded in the region containing the through holes 23 g. Thus, the plate member 23 b is secured.
The other aspects of the structure are the same as those of the separator in accordance with the first embodiment, and therefore, explanation of them is not repeated here.
(Third Embodiment)
FIGS. 6A through 6D illustrate a separator in accordance with a third embodiment of the present invention.
FIGS. 6A through 6D are partially enlarged views illustrating the vicinity of one of the manifolds 22 of the separator main body 25, including the plate member 23 b and the gasket 24 b formed on the surface of the plate member 23 b. FIG. 6A illustrates the state after the gasket molding. FIG. 6B illustrates the state prior to the gasket molding. FIG. 6C illustrates the state, with the plate member 23 b being removed.
The separator in accordance with the third embodiment has the through holes 23 g formed in the plate member 23 b, as shown in FIG. 6B.
Also, the housing concave portion 23 c that is formed in the separator main body 25 and houses the plate member 23 b has concave portions 23 h formed at the locations corresponding to the through holes 23 g, as shown in FIGS. 6C and 6D. In this embodiment, each of the concave portions 23 h is a circular hole that is concentric with each corresponding through hole 23 g and has a bottom with a greater diameter than the diameter of each corresponding through hole 23 g.
FIG. 6D is a cross-sectional view of the structure, taken along the-line D-D of FIG. 6A.
As shown in FIG. 6D, an elastic material is injection-molded in the region that surrounds the manifold 22 and contains the through holes 23 g formed through the surfaces of the separator main body 25 and the plate member 23 b, and the through holes 23 g and the concave portions 23 h are filled with the elastic material. Thus, the gasket 24 b is secured to the separator main body 25.
As shown in FIG. 6D, since each of the concave portions 23 h has a greater diameter than the diameter of each through hole 23 g, the elastic material filling the concave portions 23 h more firmly secures the gasket 24 bonto the surface of the plate member 23 b. Accordingly, the bonding force between the plate member 23 b and the gasket 24 b is increased. Thus, the gasket 24 b can be prevented from being lifted up from the plate member 23 b.
In the separator in accordance with the third embodiment, the through holes 23 g may be replaced with the same notches as the notches 23 e of the first embodiment. In such a case, the housing concave portion 23 c that houses the plate member 23 b has the concave portions 23 h formed at the locations corresponding to the notches, so that the same effects as above can be achieved.
The other aspects of this structure are the same as those of the separator in accordance with the first embodiment, and therefore, explanation of them is not repeated here.
(Fourth Embodiment)
FIG. 7 is a plan view of a separator in accordance with a fourth embodiment of the present invention.
Like any of the foregoing embodiments, the separator in accordance with the fourth embodiment has the gasket 24 a in the region on the surface of the separator main body 25 that surround the gas channel 21. Further, a gasket that surrounds each corresponding manifold 22 is formed with the gasket 24 b that is formed at the outer peripheral portions of the opening of the manifold 22 and is located outside the surface of the plate member 23 b, and a gasket 24 c that is formed separately from the gasket 24 b and is located on the surface of the plate member 23 b.
In the separator in accordance with the fourth embodiment, the gasket 24 a and the gasket 24 b outside the surface of the plate member 23 b are integrally molded at the same time on the surface of the separator main body 25 through injection molding.
Further, the gasket 24 c is separately formed on the surface of the plate member 23 b. In this case, a gap is formed between the gasket 24 b and the gasket 24 c. However, the gap is located in the position corresponding to the region other than the concave grooves of the gas channel 21, so that gas leakage can be prevented.
Since the gasket 24 c is formed separately from the gasket 24 b, part of the elastic material enters the gap formed between the separator main body 25 and the plate member 23 b at the time of the integral molding of the gasket, thereby preventing burrs. Accordingly, the entered elastic material prevents the plate member 23 b from lifting. Thus, gas leakage can be avoided.
FIG. 8 is a cross-sectional view of the structure, taken along the line E-E of FIG. 7. FIG. 9A is a plan view of the plate member 23 b in accordance with this embodiment. FIG. 9B is a plan view illustrating the state in which the gasket 24 c is formed on the surface of the plate member 23 b.
As shown in FIGS. 8 and 9A, in this embodiment, a through hole 23 i that penetrates the plate member 23 b in the stacking direction is formed at the center of the surface of the plate member 23 b. As shown in FIG. 9B, the gasket 24 c is then formed in the region on the surface of the plate member 23 b including the through hole 23 i.
Further, a convex portion 24 d that protrudes from the through hole 23 i is integrally formed with the gasket 24 c on the back surface of the plate member 23 b.
The gasket 24 c formed on the surface of the plate member 23 b may be bonded to a predetermined position on the plate member 23 b after the convex portion 24 d is molded on the back surface of the gasket 24 c. In such a case, however, an adhesive agent is required. Therefore, it is preferable to set the plate member 23 b in a mold, injection-mold the elastic material in the region containing the through hole 23 i, and then integrally mold the gasket 24 c and the convex portion 24 d.
In the housing concave portion 23 c that is formed in the separator main body 25 and houses the plate member 23 b, a concave portion 23 j is provided at the location corresponding to the through hole 23 i formed in the plate member 23 b.
The plate member 23 b is then engaged with the housing concave portion 23 c, so that the convex portion 24 d protruding from the back surface of the plate member 23 b is engaged with the concave portion 23 j. Thus, the plate member 23 b can be certainly fixed to a predetermined location on the separator main body 25.
In this manner, at the time of assembling a fuel cell or a fuel cell stack, the fixed position of the plate member 23 b can be prevented from moving, and the plate member 23 b can be prevented from falling off.
Further, when a once-stacked separator is disassembled, the gasket 24 c formed on the surface of the plate member 23 b can be prevented from sticking to the mating separator, and the plate member 23 c can be prevented from being lifted up. Thus, the gasket 24 c can be prevented from breaking.
FIG. 10 is a modification of the separator in accordance with the fourth embodiment.
As shown in FIG. 10, two through holes 23 i are formed in the vicinities of both ends of the plate member 23 b in the longitudinal direction. The convex portion 24 d protruding from each of the through holes 23 i is integrally formed with the gasket 24 c.
In this modification, the plate member 23 b is fixed to a predetermined position on the separator main body 25 by virtue of the two convex portions 24 d protruding from the vicinities of the end portions of the plate member 23 b in the longitudinal direction. Accordingly, more accurate fixing of the plate member 23 b can be performed, and the plate member 23 b can be prevented from moving or falling off at the time of stack assembling.
The other aspects of this structure are the same as those of the separator of the first embodiment, and therefore, explanation of them is not repeated here.
A power generating device that has an electrolyte film and electrode films (a fuel electrode and an air electrode) placed on both sides of the electrolyte film may be interposed between separators 20 of any of the above embodiments, thereby forming a fuel cell. Such fuel cells are stacked on one another to form a fuel cell stack.
In such a fuel cell stack, the plate member 23 b can be prevented from moving away from the predetermined attachment position or falling off at the time of assembling of the stack. Also, while the stack is being disassembled, the plate member 23 b can be prevented from being lifted up from the attachment position on each separator main body 25 and thus the gaskets can be prevented from breaking.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. 1A and 1B are plan views of a separator in accordance with a first embodiment;
FIG. 2 is a cross-sectional view of the separator, taken along the line A-A of FIG. 1A;
FIGS. 3A through 3D are partially enlarged views of the separator in accordance with the first embodiment;
FIGS. 4A through 4D are partially enlarged views of a separator in accordance with a second embodiment;
FIGS. 5A through 5D are partially enlarged views of a modification of the separator in accordance with the second embodiment;
FIGS. 6A through 6D are partially enlarged views of a separator in accordance with a third embodiment;
FIG. 7 is a plan view of a separator in accordance with a fourth embodiment;
FIG. 8 is a partially enlarged view of the separator in accordance with the fourth embodiment;
FIGS. 9A and 9B are plan views of the plate member of the separator in accordance with the fourth embodiment;
FIG. 10 is a partially enlarged view of a modification of the separator in accordance with the fourth embodiment;
FIG. 11 is a cross-sectional view of a conventional fuel cell; and
FIG. 12 is a plan view of a conventional separator 200.
DESCRIPTION OF REFERENCE NUMERALS
  • 20 Fuel cell separator
  • 21 Gas channel
  • 22 Manifold
  • 23 Communication channel
  • 23 a Groove
  • 23 b Plate member
  • 23 e Notch
  • 23 f Guide protrusion
  • 23 g Through hole
  • 23 h Concave portion
  • 23 i Through hole
  • 23 j Concave portion
  • 24 a, 24 b, 24 c Gasket
  • 24 d Convex portion
  • 25 Separator main body

Claims (2)

1. A fuel cell separator that has a power generating device interposed between the fuel cell separator and another fuel cell separator, the power generating device having an electrolyte film and electrode films,
the fuel cell separator comprising:
a separator main body that includes a gas channel, a manifold that penetrates the separator main body in a fuel cell stacking direction, and a groove that connects the gas channel to the manifold;
a plate member that covers an opening of the groove; and
a gasket that is made of an elastic material, prevents gas leakage from the manifold to the outside, and is formed in a region on the surfaces of the separator main body and the plate member, the region surrounding the manifold,
wherein the plate member has notches or through holes, when the gasket is being integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material fills the notches or the through holes, thereby increasing the fixing strength of the plate member to a predetermined position on the opening of the groove, and
wherein the separator main body has guide protrusions protruding from a housing concave portion for housing the plate member at the locations corresponding to the notches or the through holes formed in the plate member, top ends of the guide protrusions are inserted to the notches or the through holes; and
wherein the gasket is integrally molded with the region on the surface of the plate member containing the notches or the through holes, part of the elastic material also fills between the guide protrusions and the notches or the through holes, thereby increasing the fixing strength of the plate member to the predetermined position on the opening of the groove.
2. The fuel cell separator of claim 1, wherein the plate member contains the through hole in the middle of the plate member.
US10/576,740 2003-10-22 2004-10-22 Separator for fuel cell and solid polymer type fuel cell Active 2028-03-19 US8278005B2 (en)

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JP2003362340A JP4474897B2 (en) 2003-10-22 2003-10-22 Fuel cell separator and polymer electrolyte fuel cell
PCT/JP2004/015709 WO2005038970A1 (en) 2003-10-22 2004-10-22 Separator for fuel cell and solid polymer type fuel cell

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CN1871732A (en) 2006-11-29
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JP4474897B2 (en) 2010-06-09
US20070196716A1 (en) 2007-08-23

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