US803921A - Alloy. - Google Patents

Alloy. Download PDF

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Publication number
US803921A
US803921A US25736804A US1904257368A US803921A US 803921 A US803921 A US 803921A US 25736804 A US25736804 A US 25736804A US 1904257368 A US1904257368 A US 1904257368A US 803921 A US803921 A US 803921A
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United States
Prior art keywords
alloy
lead
sodium
per cent
metals
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Expired - Lifetime
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US25736804A
Inventor
Frederic W Moffett
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HOWARD M THOMAS
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HOWARD M THOMAS
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Priority to US25736804A priority Critical patent/US803921A/en
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Publication of US803921A publication Critical patent/US803921A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C11/00Alloys based on lead
    • C22C11/02Alloys based on lead with an alkali or an alkaline earth metal as the next major constituent

Definitions

  • the present invention relates to an alloy possessing the quality of a highdegree of toughness combined with a low temperature of fusion and the further advantage of being slippery to such. an extent that it is preeminently adapted for use asa bearing metal for journals and the like.
  • the essential ingredients of my new alloy are lead and sodium, and in its production I proceed as follows: A quantity of lead is melted in the usual manner and covered with a heavy flux-such, for example, as fluor-sparand the sodium in suitable amount, varying from one-half of one per cent. to four per cent. of the quantity of the lead, is plunged through the flux into the molten metal.
  • a heavy flux- such, for example, as fluor-sparand the sodium in suitable amount, varying from one-half of one per cent. to four per cent. of the quantity of the lead
  • the proportions of sodium may be varied considerably within the limits above given.
  • the product alloy is much harder than lead, but still too soft for practical service as a journal or bearing metal, affording, however, an excellent material for plumbers traps, thin piping, and other a-rti cles which are required to be both flexible and tough.
  • increase of the proportion of sodium results in a decrease in the melting-point of the alloy and renders it at the same time more readily oxidizable. The latter feature is so pronounced that with the maximum proportion stated of four per cent. the product alloy oxidizes so freely as to require close protection against moisture in order to be serviceable at all; but it is extremely hard and tenacious.
  • the sodium should be added in the proportions of from about one per cent. to two per cent. of the amount of lead, which Will result in an alloy having all the advantages of toughness and slipperiness hereinbefore mentioned and melting at a temperature well above that ever likely to occur in journal-bearings and at the same time not so high but that it can be melted in an ordinary ladle and safely poured into cast-iron journalseats.
  • the shrinkage on cooling will be found to be so slight as to be negligible, and the bearing when formed will require the minimum of lubrication, giving most satisfactory results.
  • the alloy is tough and hard and is sufiiciently elastic to have a decided metallic ring, and, furthermore, it is entirely free from the objections of flaking or mashing under heavy loads.
  • My experiments have indicated that the best results for general purposes can be secured by adding approximately one and one-half pounds of sodium to one hundred pounds of lead, the melting-point of this mixture being about 585 Fahrenheit.
  • metals may be added to the alloy, if desired, or mixed with it during its manufacture for special purposes; but metals, such as antimony and bismuth or other ingredients which haveahardening eii'ecton lead, will not be necessary and except in minute amounts will be injurious to the operation of the product as a bearing metal.
  • Aluminium and tin which are substantially indifferent in this respect, may be added in amounts up to about ten per cent. of the whole without seriously impairing the quality of the product; but these additions, while being objectionable on account of the extra expense, would not improve the efficiency of the alloy as a bearing metal or materially alter it otherwise except in weight and appearance.
  • IO alloy composed of lead and sodium and con- H. G. KIMBALL.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

FREDERIC W. MOFFETT, OF BLOOMFIELD, NEW
ONE-HALF TO HOWARD JERSEY, ASSIGNOR OF M. THOMAS, OF BLOOMFIELD, NEW JERSEY.
ALLOY.
Specification of Letters Patent.
Patented Nov. '7, 1905.
Application filed May 4, 1904. Renewed April 25, 1905. Serial No. 257,368-
To all whom, it may concern:
Be it known that I, FREDERIc W. MoFFETT, a citizen of the United States, residing at Bloomfield, county of Essex, State of New Jersey, have invented certain new and useful Improvements in Alloys, of which the following is a full, clear, and concise specification.
The present invention relates to an alloy possessing the quality of a highdegree of toughness combined with a low temperature of fusion and the further advantage of being slippery to such. an extent that it is preeminently adapted for use asa bearing metal for journals and the like.
The essential ingredients of my new alloy are lead and sodium, and in its production I proceed as follows: A quantity of lead is melted in the usual manner and covered with a heavy flux-such, for example, as fluor-sparand the sodium in suitable amount, varying from one-half of one per cent. to four per cent. of the quantity of the lead, is plunged through the flux into the molten metal. On account of the considerable difference between the specific gravities of the two metals 1 find it necessary to confine the sodium in a cage or other apertured receptacle, and I attach the latter to the end of the stirring-rod, so that the metal can be quickly introduced into the lead and at the same time be prevented from rising to the surface, where it might become exposed to free oxygen and be consumed. The process of mixing the two metals will be facilitated and the loss by oxidation reduced if the sodium is stirred vigorously into the lead at the moment of introduction, as described and claimed in a certain copending application filed by me on the 19th day of July, 1904, and numbered 217,238. Immediately upon the coalescing of the two metals the alloy may be poured and cooled and is then ready for use in the same manner as ordinary bearing or Babbitt metals.
The proportions of sodium may be varied considerably within the limits above given. When containing the lowest percentage of those mentioned, the product alloy is much harder than lead, but still too soft for practical service as a journal or bearing metal, affording, however, an excellent material for plumbers traps, thin piping, and other a-rti cles which are required to be both flexible and tough. I have observed that increase of the proportion of sodium results in a decrease in the melting-point of the alloy and renders it at the same time more readily oxidizable. The latter feature is so pronounced that with the maximum proportion stated of four per cent. the product alloy oxidizes so freely as to require close protection against moisture in order to be serviceable at all; but it is extremely hard and tenacious. For general and practical use as a journal-bearing metal, however, the sodium should be added in the proportions of from about one per cent. to two per cent. of the amount of lead, which Will result in an alloy having all the advantages of toughness and slipperiness hereinbefore mentioned and melting at a temperature well above that ever likely to occur in journal-bearings and at the same time not so high but that it can be melted in an ordinary ladle and safely poured into cast-iron journalseats. The shrinkage on cooling will be found to be so slight as to be negligible, and the bearing when formed will require the minimum of lubrication, giving most satisfactory results. The alloy is tough and hard and is sufiiciently elastic to have a decided metallic ring, and, furthermore, it is entirely free from the objections of flaking or mashing under heavy loads. My experiments have indicated that the best results for general purposes can be secured by adding approximately one and one-half pounds of sodium to one hundred pounds of lead, the melting-point of this mixture being about 585 Fahrenheit.
Other metals may be added to the alloy, if desired, or mixed with it during its manufacture for special purposes; but metals, such as antimony and bismuth or other ingredients which haveahardening eii'ecton lead, will not be necessary and except in minute amounts will be injurious to the operation of the product as a bearing metal. Aluminium and tin, which are substantially indifferent in this respect, may be added in amounts up to about ten per cent. of the whole without seriously impairing the quality of the product; but these additions, while being objectionable on account of the extra expense, would not improve the efficiency of the alloy as a bearing metal or materially alter it otherwise except in weight and appearance.
Having described my invention, what I taining sodium in the proportion of one and claim, and desire to secure by Letters Patent, one-half per cent. of the amount of lead, subis as follows: stantially as described.
1. 'As a new composition of matter, an alloy In testimony whereof I have signed my name 5 containing lead and sodium and containing to the specification in the presence of two sub- 5 sodium in the proportion of from one-half of scribing witnesses.
one per cent. to four per cent. of the amount FREDERIG W. MOFFETT. of lead, substantially as described. Witnesses:
2. As a new antifriction-bearing metal, an G. A. TAYLOR,
IO alloy composed of lead and sodium and con- H. G. KIMBALL.
US25736804A 1904-05-04 1904-05-04 Alloy. Expired - Lifetime US803921A (en)

Priority Applications (1)

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US25736804A US803921A (en) 1904-05-04 1904-05-04 Alloy.

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US25736804A US803921A (en) 1904-05-04 1904-05-04 Alloy.

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