US789690A - Process of galvanizing, tinning, or otherwise plating wire or other metallic bodies. - Google Patents

Process of galvanizing, tinning, or otherwise plating wire or other metallic bodies. Download PDF

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US789690A
US789690A US211745A US1904211745A US789690A US 789690 A US789690 A US 789690A US 211745 A US211745 A US 211745A US 1904211745 A US1904211745 A US 1904211745A US 789690 A US789690 A US 789690A
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wire
plating
metal
molten
plating metal
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US211745A
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George A Goodson
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GOODSON ELECTRIC GALVANIZING Co
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GOODSON ELECTRIC GALVANIZING Co
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/12Aluminium or alloys based thereon

Definitions

  • My invention has for its object to provide an improved process of galvanizing, tinning, or otherwise plating wire and other metallic bodies; and to this end my invention or discovery consists of the novel process hereinafter described, and defined in the claims.
  • the old process which has hitherto been generally employed in galvanizing and tinning wire may be summarily stated as follows:
  • the zinc or tin used in plating the wire is kept in molten condition in large troughshaped kettles suitably mounted for the direct application thereto of flames from burning fuel, and the wire is drawn through the large body of molten plating metal contained in said kettles.
  • the molten metal must be kept substantially at a predetermined temperature, and the submerged portion of the wire being drawn therethrough must be brought to substantially the same temperature as the molten plating metal.
  • the wire of course is of hi her fusibility than the plating metal and will not be melted, but will remain intact. In carrying out said old process it has been found that considerable time is required to heat the wire to the temperature of the molten plating metal.
  • My improved process herein disclosed and claimed is a radical departure from the old process above summarized and overcomes many of the objections above noted, securing greatly-increased product per unit of time, a better quality of product, and a saving in the amount of plating metal consumed.
  • the numeral 1 represents a curved pipe or tube of relatively small caliber composed of iron or other suitable material.
  • the tube 1 is of approximately semicircular form and is supported with its open ends upward and supported by a pair of metallic pedestals 2, electrically connected therewith.
  • the pedestals 2 are shown as fixed to a base 3 of insulating material, such as a wooden sill or floor.
  • the said pipe or tube 1 affords an attenuated conduit open at its ends and through which the wire 4 may be drawn and is adapted to hold or maintain around that portion of the wire being drawn therethrough an attenuated or thinly-drawn-out body of molten plating metal 5.
  • Said molten plating metal 5 may be supplied to the plating-tube 1, so as to keep the tube filled to the proper height, in any suitable way.
  • a small melting pot or kettle 6 subject to the flames from a gas-burner 6 and connecting with the plating-tube 1 by a small supply-pipe 1
  • the melting-pot 6 should be insulated from the supporting-standard 2.
  • the numerals 7 represent conductors connecting standards 2, the plating-tube 1, the molten metal 5 within the tube 1, and the submerged portion of the wire 4 into an electric circuit supplied with current from any suitable source.
  • the tube 1 should be covered with a wrapping 8 of asbestos or other heat-insulating material.
  • the plating metal 5 and the wire 4, submerged therein, may be heated apparatus yidiich I have found to be to a common temperature by the current supplied thereto.
  • the current of course is properly regulated for maintaining the molten plating metal and the wire to be plated at the exact desired temperature for the best results.
  • the wire 4 may be drawn through the tube 1 by hand or by any suitable mechanical devices.
  • the attenuated body of molten plating metal is protected from the atmosphere, except only at the open ends of the tube 1, and this, if desired, can be reduced to an opening of substantially the same diameter as the wire itself or be fitted with a gland, so as to exclude the air entirely from the plating-tube 1, and hence it follows that the oxidation of the molten metal is reduced to a minimum and may be said to be almost entirely eliminated.
  • the process of electroplating which consists in submerging the metal to be plated in a bath of molten plating metal, and subject ing both to an electric current, with the metal to be plated, and the molten plating metal, connected up in multiple, in a common electric circuit.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Description

PATENTED MAY 9, 1905.
G. A. Goonsou. PROCESS OF GALVANIZING, TINNING, OR OTHERWISE PLATING WIRE OR OTHER METALLIC BODIES.
APPLICATION FILED JUNE 9. 1904.
,2 22 s JI/orngp.
NTTE STATES Patented May 9, 1905.
PATENT FFICE.
GEORGE A. GOODSON, OF PROVIDENCE, RHODE ISLAND, ASSIGNOR TO GOODSON ELECTRIC GALVANIZING COMPANY, OF MINNEAPOLIS, MINNESOTA, A CORPORATION OF MINNESOTA.
PROCESS OF GALVANIZING, TINNING, OR OTHERWISE PLATING WIRE OR OTHER METALLIC BODIES SPECIFICATION forming part of Letters Patent No. 789,690, dated Ma'9,
Original application filed March 31, 1904, Serial No. 200,918. Divided and this application filed June 9, 1904. Serial No. 211.7 15.
To all whom it may concern;
Be it known that I, GEORGE A. GooDsoN, a citizen of the Dominion of Canada, residing at Providence, in the county of Providence and State of Rhode Island, have invented certain new and useful Improvements in Processes of Galvanizing, Tinning, or Otherwise Plating Wire or other Metallic Bodies; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and use the same.
This application is filed as a division of my original application, Serial No. 200,913, filed by me March 31, 1904, entitled Process and apparatus for galvanizing, tinning, and otherwise plating wire and other metallic bodies.
My invention has for its object to provide an improved process of galvanizing, tinning, or otherwise plating wire and other metallic bodies; and to this end my invention or discovery consists of the novel process hereinafter described, and defined in the claims.
The old process which has hitherto been generally employed in galvanizing and tinning wire may be summarily stated as follows: The zinc or tin used in plating the wire is kept in molten condition in large troughshaped kettles suitably mounted for the direct application thereto of flames from burning fuel, and the wire is drawn through the large body of molten plating metal contained in said kettles. To effect good plating, the molten metal must be kept substantially at a predetermined temperature, and the submerged portion of the wire being drawn therethrough must be brought to substantially the same temperature as the molten plating metal. The wire of course is of hi her fusibility than the plating metal and will not be melted, but will remain intact. In carrying out said old process it has been found that considerable time is required to heat the wire to the temperature of the molten plating metal.
Hence the greater the length of the kettles containing the molten lating metal the more rapidly the wire may be drawn therethrough, and, conversely, the slower the movement of the wire the shorter the kettles may be. It is equally evident that the longer and more bulky the kettles the more space is required for the same and the greater is the amount of heat required to maintain such a large body of plating metal in molten condition at the proper temperature, and, on the other hand, a slow movement of the wire, as required when the kettles are short, is wasteful of time, making the product small for any given unit of time. As a compromise between the two plans above noted it has in practice been found advisable to employ kettles of about twelve feet in length and to draw the wire through the molten metal at the rate of about seventyfive feet per minute. This seems to be about the best result in point of capacity which can be secured. Under these conditions it will be seen that a large amount of space is taken up by the kettles, that a large quantity of fuel is required to keep the plating metal at the proper temperature, and that the wire can only be drawn through the molten plating metal at a comparatively slow rate of speed. Moreover, much labor and attention is required to maintain the fires and reliably to control the temperature of the molten plating metal so as to get the best results in the quality of the plating, for it is a wellknown fact that comparatively slight variation in the temperature of the molten plating metal either above or below the predetermined proper temperature will result in poor plating, or it may be, if the variation be considerable, that the wire will not be plated at all. Another serious'objeetion to the old process is the fact that such a large body of the molten plating metal must be exposed to the atmosphere, thereby producing a large waste from the resulting oxidation.
My improved process herein disclosed and claimed is a radical departure from the old process above summarized and overcomes many of the objections above noted, securing greatly-increased product per unit of time, a better quality of product, and a saving in the amount of plating metal consumed.
In my practice up to the date of this writing I have electrically excited contacting surfaces of the plating metal and the wire or other metal to be plated, securing thereby highly-satisfactory results, in respect to the quality of the plating, the product per unit of time, and the amount of plating metal consumed. So far I have got the best results by submerging the wire or other metal to be plated in an attenuated body of molten plating metal, with both thereof subject simultaneously to an electric current, or, otherwise stated, the molten metal has been held in tubes of small caliber, the wire has been drawn therethrough under a continuous movement, and a current of electricity has simultaneously been passed throughthe molten plating metal and through that portion of the wire which is submerged therein.
The accompanyim drawing illustrates one form of well adapted for carrying out my new proc ess above stated.
In the single view of said drawing the numeral 1 represents a curved pipe or tube of relatively small caliber composed of iron or other suitable material. As shown, the tube 1 is of approximately semicircular form and is supported with its open ends upward and supported by a pair of metallic pedestals 2, electrically connected therewith. The pedestals 2 are shown as fixed to a base 3 of insulating material, such as a wooden sill or floor. The said pipe or tube 1 affords an attenuated conduit open at its ends and through which the wire 4 may be drawn and is adapted to hold or maintain around that portion of the wire being drawn therethrough an attenuated or thinly-drawn-out body of molten plating metal 5. Said molten plating metal 5 may be supplied to the plating-tube 1, so as to keep the tube filled to the proper height, in any suitable way. I have shown for the purpose a small melting pot or kettle 6, subject to the flames from a gas-burner 6 and connecting with the plating-tube 1 by a small supply-pipe 1 The melting-pot 6 should be insulated from the supporting-standard 2.
The numerals 7 represent conductors connecting standards 2, the plating-tube 1, the molten metal 5 within the tube 1, and the submerged portion of the wire 4 into an electric circuit supplied with current from any suitable source. The tube 1 should be covered with a wrapping 8 of asbestos or other heat-insulating material.
With the apparatus above described it is obvious that the plating metal 5 and the wire 4, submerged therein, may be heated apparatus yidiich I have found to be to a common temperature by the current supplied thereto. The current of course is properly regulated for maintaining the molten plating metal and the wire to be plated at the exact desired temperature for the best results. The wire 4 may be drawn through the tube 1 by hand or by any suitable mechanical devices.
It will be seen that under this process and with the form of apparatus above described the amount of the plating metal which must be necessarily kept in a molten condition and at the required predetermined temperature for the best results in plating is reduced to a minimum, and hence it follows that by the application of the proper electric current this small attenuated body of plating metal may be quickly brought to the required temperature coincidentally with the corresponding heating of the wire and be there maintained while the wire is being drawn through under a continuous movement. It is further obvious that the attenuated body of molten plating metal is protected from the atmosphere, except only at the open ends of the tube 1, and this, if desired, can be reduced to an opening of substantially the same diameter as the wire itself or be fitted with a gland, so as to exclude the air entirely from the plating-tube 1, and hence it follows that the oxidation of the molten metal is reduced to a minimum and may be said to be almost entirely eliminated. Furthermore, from my experience in the practical application of my new process above disclosed I have been led to believe that when contacting surfaces of the metal to be plated and of the molten plating metal are electrically excited, as is the case under my process, a molecular action is set up in the said contacting surfaces which causes the plating metal more quickly and more firmly to adhere to the surface of the metal to be plated. I believe this to be an important discovery with possible far-reaching results.
Of course I do not limit myself to any spe cial form of apparatus for carrying my process into effect. Apparatus capable of doing the work may take a considerable range in diversity of forms and construction. For ex ample, I have disclosed in my pending application, Serial No. 209,993, filed April 7,1904, an apparatus within the principle of the apparatus herein disclosed in a broad point of view, but embodying numerous additional features better adapting the same for the commercial utilization of my new process herein disclosed and claimed.
In practice it has been found that this process gives highly-satisfactory results with the use of lead as the plating metal. This is a result which, so far as I know, has not been commercially practicable under any hithertoknown processes.
IIC
So far as I know the process herein disclosed is a pioneer invention or discovery of large practical utility and value, and I desire to claim the same herein in the broadest possible way.
What I claim, and desire to secure by Letters Patent of the United States, is as follows:
1. The process of plating wire or other metal, which consists in bringing the same into contact with molten plating metal, and in electrically exciting contacting surfaces of the molten plating metal and the metal to be plated.
2. The process of plating wire or other metallic bodies, which consists in submerging the same in a bath of molten plating metal, and in passing a current of electricity through the plating metal and the metal to be plated.
3. The process of plating wire or other metallic bodies, which consists in maintaining an attenuated body of plating metal around a portion of the metal to be plated, and in passing an electric current through said attenuated body of plating metal and the submerged portion of the metal to be plated, substantially as described.
4. The process of plating wire or other metallic bodies, which consists in drawing the same, under a continuous movement, through an attenuated body of plating metal, and in passing an electric current simultaneously through the plating metal and the metal to be plated, substantially as described.
5. The process of electroplating, which consists in submerging the metal to be plated in a bath of molten plating metal, and subject ing both to an electric current, with the metal to be plated, and the molten plating metal, connected up in multiple, in a common electric circuit.
In testimony whereof I ELfilX my signature in presence of two witnesses.
GEORGE A. GOODSON.
Witnesses:
JAs. F. WILLIAMSON, F. D. MERCHANT
US211745A 1904-03-31 1904-06-09 Process of galvanizing, tinning, or otherwise plating wire or other metallic bodies. Expired - Lifetime US789690A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2499191A (en) * 1948-09-22 1950-02-28 Gen Electric Vertical loop furnace
US3136709A (en) * 1959-07-14 1964-06-09 Nat Steel Corp Method of electroplating an aluminum containing coating
US3443996A (en) * 1966-04-29 1969-05-13 Svenska Ackumulator Ab Apparatus for continuous manufacture of electrodes for sintered plate accumulator cells
US4634609A (en) * 1985-06-18 1987-01-06 Hussey Copper, Ltd. Process and apparatus for coating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2499191A (en) * 1948-09-22 1950-02-28 Gen Electric Vertical loop furnace
US3136709A (en) * 1959-07-14 1964-06-09 Nat Steel Corp Method of electroplating an aluminum containing coating
US3443996A (en) * 1966-04-29 1969-05-13 Svenska Ackumulator Ab Apparatus for continuous manufacture of electrodes for sintered plate accumulator cells
US4634609A (en) * 1985-06-18 1987-01-06 Hussey Copper, Ltd. Process and apparatus for coating

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