US76031A - Improved compound of aniline colors - Google Patents
Improved compound of aniline colors Download PDFInfo
- Publication number
- US76031A US76031A US76031DA US76031A US 76031 A US76031 A US 76031A US 76031D A US76031D A US 76031DA US 76031 A US76031 A US 76031A
- Authority
- US
- United States
- Prior art keywords
- aniline
- colors
- glue
- water
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 title description 38
- 239000003086 colorant Substances 0.000 title description 36
- 150000001875 compounds Chemical class 0.000 title description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 36
- 239000003292 glue Substances 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 239000000463 material Substances 0.000 description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 229920000742 Cotton Polymers 0.000 description 8
- 238000004043 dyeing Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 6
- 210000002268 Wool Anatomy 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000001828 Gelatine Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 230000001476 alcoholic Effects 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- RFKJHQXSLBUONF-UHFFFAOYSA-N methyl blue free acid Chemical compound C1=CC(S(=O)(=O)O)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=NC=2C=CC(=CC=2)S(O)(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S(O)(=O)=O)=CC=2)C=C1 RFKJHQXSLBUONF-UHFFFAOYSA-N 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 244000215068 Acacia senegal Species 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- -1 Parme Chemical compound 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N Saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 240000003946 Saponaria officinalis Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000023298 conjugation with cellular fusion Effects 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000021037 unidirectional conjugation Effects 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/228—Indigo
Definitions
- g rh gram item @ffita EMIL ZINSSMANNOF NEW YORK, N. Y., ASSIGNOR TO HIMSELF AND CHARLES RUMPFF, OF SAME PLAQE.
- This invention consists in a compound, which is soluble in water, and made of aniline colors, which, in themselves, are not-soluble in Water, by treating said colors with glue or gelatinous materials, or'with different kinds of gums, such as gum-arabic or gum-tragacanth, or with starch, which is soluble in water, or with other equivalent materials, either alone or mixed together, in combination with either acetic acid, or glycerine, or saccharine solutions or decoctions of plants, or any other liquid vhich Illl produce the desired effect; said I materials being combined mechanically to a thick sirup-like homogeneous mass, and then mixed together with the aniline color, (which is to be rendered soluble in water,) andheated in such a manner that a product is obtained which retains all the coloring properties and qualities inherent to the aniline colors, and which is so perfectly soluble in water that it can he used with thebest success for dyeingand printing all fibrous materials, and consequently the expensive operation of dissolving the aniline
- I proceed, for instance, as follows I take a quantity of glue, (about from two to six poundsof glue to one pound of the color,) and dissolve the same in common acetic acid of seven or eight degrees, so as to form a thick, 'sirup-like mass. With this thick solution I mix the anilinev color previously reduced to a fine powder, and then I work the mass until it forms a. fine thick homogeneous pulp, either by means of suitable stones, or by passing the mass through a mill, or in any suitable manner.
- the pulp thus obtained is then placed into a suitableycssel, (best an enamelled kettle,) and heated'in a water-bath under constant agitution or kneading, it being desirable at the same time to provide the vessel containing the pulp with a tightlyclosing cover, so as to prevent the undue evaporation of the liquid parts of the mass.
- a suitableycssel (best an enamelled kettle,) and heated'in a water-bath under constant agitution or kneading, it being desirable at the same time to provide the vessel containing the pulp with a tightlyclosing cover, so as to prevent the undue evaporation of the liquid parts of the mass.
- the desired reaction or, in other words, the perfect dissolution of the aniline color in the glue, or the equivalent material, will take place only and best when the pulp in the waterbath forms a mass of such thickness and consistency that it just can be kneaded or stirred. If the pulp should, however, become so thick that it cannot be stirred or kneaded before the aniline color is perfectly dissolved in the glue or. equivalent material, the addition of a small quantity of'the corresponding liquid is suiiicient to reduce the pulp to the desired consistency.
- a compound which is soluble in water, and made from such aniline colors which in themselves are not soluble in water, by treating said colors with glue or equivalent substances, either alone or mixcd together, and with a liquid, such as acetic acid, or glycerine, or their equivalents, either-alone or mixed together, as herein set forth.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
g rh gram item: @ffita EMIL ZINSSMANNOF NEW YORK, N. Y., ASSIGNOR TO HIMSELF AND CHARLES RUMPFF, OF SAME PLAQE.
l Letters Patent No. 76,031, dated March 24, 1868.
IMPROVED COMPOUND OP ANILINE COLORS.
the fitlgttule nfetnt in in that items again no mating gain in tin time TO ALL WHOM IT MAY CONCERN:
Be it known that I, EMIL ZINSSMANN,'Of the city ofNew York, in the county and State of New York, have invented a new and improved Compound of Aniline Colors; and I do hereby declare the following to be a full, clear, and exact description thereof, enabling those skilled in the art to make and use the same.
This invention consists in a compound, which is soluble in water, and made of aniline colors, which, in themselves, are not-soluble in Water, by treating said colors with glue or gelatinous materials, or'with different kinds of gums, such as gum-arabic or gum-tragacanth, or with starch, which is soluble in water, or with other equivalent materials, either alone or mixed together, in combination with either acetic acid, or glycerine, or saccharine solutions or decoctions of plants, or any other liquid vhich Illl produce the desired effect; said I materials being combined mechanically to a thick sirup-like homogeneous mass, and then mixed together with the aniline color, (which is to be rendered soluble in water,) andheated in such a manner that a product is obtained which retains all the coloring properties and qualities inherent to the aniline colors, and which is so perfectly soluble in water that it can he used with thebest success for dyeingand printing all fibrous materials, and consequently the expensive operation of dissolving the aniline colors in alcohol, which, with aniline colors as now made, is indispensable, particularly for dyeing and printing wool or cotton, or fabrics made therefrom, can be dispensed with.
In carrying out my invention, I proceed, for instance, as follows I take a quantity of glue, (about from two to six poundsof glue to one pound of the color,) and dissolve the same in common acetic acid of seven or eight degrees, so as to form a thick, 'sirup-like mass. With this thick solution I mix the anilinev color previously reduced to a fine powder, and then I work the mass until it forms a. fine thick homogeneous pulp, either by means of suitable stones, or by passing the mass through a mill, or in any suitable manner. The pulp thus obtained is then placed into a suitableycssel, (best an enamelled kettle,) and heated'in a water-bath under constant agitution or kneading, it being desirable at the same time to provide the vessel containing the pulp with a tightlyclosing cover, so as to prevent the undue evaporation of the liquid parts of the mass.
It must be remarked, however, that the desired reaction, or, in other words, the perfect dissolution of the aniline color in the glue, or the equivalent material, will take place only and best when the pulp in the waterbath forms a mass of such thickness and consistency that it just can be kneaded or stirred. If the pulp should, however, become so thick that it cannot be stirred or kneaded before the aniline color is perfectly dissolved in the glue or. equivalent material, the addition of a small quantity of'the corresponding liquid is suiiicient to reduce the pulp to the desired consistency.
From time to time a small quantity of the pulp is taken out, dissolved in hot water, and while hot passed through a filter, and if no color remains on the filter, the process can be considered completed, and the product can be used immediately, or it can be dried and preserved for future use.
For purple aniline colors, with the exception of the bluish purple, such as Parme. or of the aniline blue, about two orthrce pounds of glue or gelatine to one pound of the color are sufiiicient, but for bluish aniline, such as Parme, or for aniline blue, it is better to use from four to sin pounds of glue or gelatine.
For blue aniline, or for 'Parmc, the use of glue and acetic acid is to be recommended, but for purple aniline I can use gums, or starch which is soluble in water, (dextrine,) and the acetic acid can be replaced by glycerine or dccoctions of plants, such as soa-pwort, (Radix saponicm) or materials of a similar efl'ect, and this change is to be recommended, because the acetic acid afi'ects and injures the hue of the purple aniline colors. If glycerine and glue are employed, it is necessary to soften the glue first in a small quantity of water, and the: to effect the combination of the glyeerine and glue by heating them together.
By this treatment I am enabled to produce from aniline colors, which in themselves are not soluble in water, a compound which is perfectly soluble in hot water, thus forming a solution which is applicable with great advantage in place of the expensive and, unreliable alcoholic solution of said colors. The great saving effected thereby is apparent from the fact that at present, for thepurpose of dissolving one pound of purple or blue aniline colors, (particularly for the purpose of dyeing or printing woollen and cotton materials,) from twenty to thirty pounds of the strongest alcohol, or astill larger quantity of methylene or wood spirit, are required, and even then the solution thus produced is not reliable or perfect. If the alcoholic solution remains standing a short time, a portion of the color is precipitated from the same, and if said solution is used for dyeing, the color of the dyed fabricis many times not uniform, and liable to come off.
By the use of my compound all these disadvantages are avoided, it dissolves perfectly; the coloring-matter is not liable to precipitate from the solution, however long said solution may remain standing, and wool, silk, cotton, also paper, and different other materials or. fabrics can be dyed or printed therewith with the greatest ease and perfection.
I am well aware that products soluble in water have been prepared by treating aniline colors with sulphuric acid, but such products are applicable more particularly fordyeing and printing leather or silk, but little or not at all for dyeing and printing of wool or cotton or fabrics made therefrom. I am also aware that some time ago, glycerine or decoctions of plants have been recommended for the purpose of dissolving aniline colors. But the extensive and common use of alcohol as a solvent of these colors,'sl1ows that said materials did not produce the desired result: I have never succeeded in producing, with these last-named materials alone, anything like a satisfactory result, and it is only possible to effect the solution, if at the same time a substance is used, such as glue or equivalent material, as above specified.
Having thus described my invention, what I claim as new, and desire to secure by Letters Patent, is
A compound, which is soluble in water, and made from such aniline colors which in themselves are not soluble in water, by treating said colors with glue or equivalent substances, either alone or mixcd together, and with a liquid, such as acetic acid, or glycerine, or their equivalents, either-alone or mixed together, as herein set forth.
This specification signed by me, this 23d day of January, 1868. A
EMIL ZINSSMANN.
Witnesses:
W. HAUFF, E. F. Kas'ruunusun.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US76031A true US76031A (en) | 1868-03-24 |
Family
ID=2145535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US76031D Expired - Lifetime US76031A (en) | Improved compound of aniline colors |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US76031A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050219892A1 (en) * | 2004-04-06 | 2005-10-06 | Macronix International Co., Ltd. | Method of multi-level cell FeRAM |
-
0
- US US76031D patent/US76031A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050219892A1 (en) * | 2004-04-06 | 2005-10-06 | Macronix International Co., Ltd. | Method of multi-level cell FeRAM |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US76031A (en) | Improved compound of aniline colors | |
| US120393A (en) | Improvement in dyeing and printing madder colors | |
| US1660167A (en) | Basic dye | |
| US1228089A (en) | Soluble color compound. | |
| US2263616A (en) | Composition comprising ice color coupling components | |
| US90417A (en) | Improved ink-powder and dye from aniline colors | |
| US1181202A (en) | Method of sizing and dyeing. | |
| DE606095C (en) | Process for the preparation of conversion products of chromium-containing azo dyes | |
| US29404A (en) | Improvement in preparation of aniline colors | |
| US192201A (en) | Improvement in processes of dyeing tissue and bonbon papers | |
| US110994A (en) | Alfred paraf | |
| US1193838A (en) | William somerville | |
| US2047919A (en) | Cellulose acetate compositions | |
| USRE1358E (en) | Improvement in treating aniline to produce a red coloring-matter or dye | |
| US1206189A (en) | Composition of matter for sizing and dyeing. | |
| US88102A (en) | Improvement in the manufacture of paper | |
| US120392A (en) | Improvement in compositions of madder for dyeing | |
| US671344A (en) | New form of indigo readily soluble in vats and method of making same. | |
| US2247351A (en) | Prolamine composition | |
| US692775A (en) | Cellulose lakes and process of making same. | |
| US69121A (en) | Alfred p a | |
| US194264A (en) | Improvement in processes of restoring crape, laces | |
| US647493A (en) | Process of mordanting. | |
| US1485790A (en) | Dye solution and process for making and utilizing same | |
| US298998A (en) | Peospbe moistlstet |