US741A - Improved process for gilding copper,, brass - Google Patents
Improved process for gilding copper,, brass Download PDFInfo
- Publication number
- US741A US741A US741DA US741A US 741 A US741 A US 741A US 741D A US741D A US 741DA US 741 A US741 A US 741A
- Authority
- US
- United States
- Prior art keywords
- brass
- articles
- gilding
- improved process
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 32
- 229910001369 Brass Inorganic materials 0.000 title description 12
- 239000010951 brass Substances 0.000 title description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title description 10
- 229910052802 copper Inorganic materials 0.000 title description 10
- 239000010949 copper Substances 0.000 title description 10
- 238000004140 cleaning Methods 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 14
- 150000002739 metals Chemical class 0.000 description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 10
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 10
- 229910052737 gold Inorganic materials 0.000 description 10
- 239000010931 gold Substances 0.000 description 10
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 10
- 229940072033 potash Drugs 0.000 description 10
- 235000015320 potassium carbonate Nutrition 0.000 description 10
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 10
- 229910052753 mercury Inorganic materials 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229910000497 Amalgam Inorganic materials 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 101700065560 andI Proteins 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 229910052572 stoneware Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
Definitions
- My invention consists in gildiu g copper, brass, and other metals or alloys of metals by means of potash or soda combined with carbonic acid and with a solution of gold, as hereinafter described and in order to myinvention being most fully understood, I will proceed to describe the process as performed by.
- dead appearance In case it is desired to produce what is called a dead appearance, it may be performed by several processes.
- the one I usually employ is to dead the articles-in the process of cleaning, as practiced by brass-founders and other trades, and it is produced by an acid prepared-for that purpose, sold by the makers under the term dca'ding aqua fortis, which is well understood.
- It may also be produced by a weak solution of nitrate of mercury applied to the articles previous to the gilding process, as is practiced in the process of gilding with mercury previous to spreading the amalgam, but generally a much weaker solution; or the articles having been gilded may be'dipped in a solution of nitrate of mercury and submitted to heat to expel the same, as is practiced in the usual process of gilding.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
UNITED STATES PATENT OFFICE;
GEORGE RICHARDS ELKINGTON, OF BIRMINGHAM, ENGLAND.
Specification forming part of Letters Patent No. 741, dated May 17', 1838.
To all whom it may concern:
Be it known that 1, GEORGE RICHARDS ELKINGTON, a subject of the Queen of Great Britain, and now residingat Birmingham, in the county of Warwick, in the said Kingdom of Great Britain, have invented or discovered a new and Improved Method of Gliding Oopper, Brass, and other Metals orAlloys of Metal; and I, thesaid GEORGERIGHARDS ELKINGTON, do hereby declare the nature of my invention and the manner in which the same is to be performed are fully described and ascertained in and by the following statement thereofthat is to say:
My invention consists in gildiu g copper, brass, and other metals or alloys of metals by means of potash or soda combined with carbonic acid and with a solution of gold, as hereinafter described and in order to myinvention being most fully understood, I will proceed to describe the process as performed by. me, and which has fully answered the purpose, the articles operated on having a very beautiful ap' pearance, and in most instances are considered to be gilded far better than when similar articles have been submitted to the gildin g process where quicksilver is used, the process of gildind by the aidot' quicksilver being well known and in general practice, and as it forms no part of my improved method, but is entirely difi'ereut from my invention, no description of such process will benecessaryin this my specifica'tion.
I will first describe the preparation of the materials and then explain the process of using the same.
Dissolve five ounces, troy weight, offine gold in fifty-two ounces, avoirdupois weight, of nitro-muriaticacid of the following proportions- .videlicet, twenty-one ounces of nitro-acid pure,
of potash of the best quality, let the whole boil moderately for two hours. The mixture will then be ready for use. The liquid being thus prepared, and as in practice it is difiicult to keep the liquid hot in stoneware vessels when many articles are being dipped, I have found it advantageous to transfer the liquid to a cast-iron vessel, which it is necessary to keep very clean. The articles to be gilded having? been first perfectly cleaned from scale or grease, they are to be suspendedon wires conveniently for a workman to dip them in the liquid, which is kept boiling. The time required for gilding any particular article willdepend on circumstances,'partly on the quantity of the gold remaining in theliquid and partly on the size and weight of the article; but alittle practice will readil y produce sufficient judgment to the workman. Supposing the articles desired to be gilded to be brass or copper buttons, or small articles for gilt toys, or ornaments'of dress, such as ear-rings or brace; lets, a considerable number of which may be strung on a hoop or bent piece of copper or brass wire, and dippedinto the vessel containing the boiling liquid above described and moved therein; and the requisite gilding will be generally obtained in from a few seconds to a minute. This is when the liquid is i nthecon-' dition above described, and depending on the quality of the gildin g desired; butif theliquid has been used some time the quantity of gold ed with clean water. They may then be submitted to the usual process of coloring.
It the articles be cast figures of animals or otherwise-a considerable weight compared with the articles above mentioned-the time required to perform the process will be greater.
In case it is desired to produce what is called a dead appearance, it may be performed by several processes. The one I usually employ is to dead the articles-in the process of cleaning, as practiced by brass-founders and other trades, and it is produced by an acid prepared-for that purpose, sold by the makers under the term dca'ding aqua fortis, which is well understood. It may also be produced by a weak solution of nitrate of mercury applied to the articles previous to the gilding process, as is practiced in the process of gilding with mercury previous to spreading the amalgam, but generally a much weaker solution; or the articles having been gilded may be'dipped in a solution of nitrate of mercury and submitted to heat to expel the same, as is practiced in the usual process of gilding.
It is desirable to remark that much of the beauty of the result depends on the wellcleauing of the articles, and it is better to clean them by the ordinary processes and atonce pass them into the liquid to be gilded.
I have always employed the usual means for cleaning the articles from scales and other impurities, which are commonly resorted to in workingof the metals for other purposes, where the surfaces are required to be freed from scales or other impurities,andI would remark that great care should be observed in par chasing the articles above described of the best description.
I have described only the using of bicarbonate of potash, which I believe to be the bestmaterial for the purpose, and I would remark that soda in a state of carbonate may be employed, as also some preparations ofpotash and soda,
, but, so far as my experience goes, not with such advantages as potash in a state of bicarbonate, as above described.
Having now described the nature of my in? vention and the manner of performing the same, I would have it understood that, although in order to give the best information in my power I have stated the exact quantities of the articles employed, I do not confine myself thereto nor do I claim any process for cleaning or (leading; but
WhatI claim as the improved process of gilding is- T-hegilding copper, brass,and other metals or alloys of metals by means of potash or soda, in the state of carbonate or otherwise,
and a solution of gold, as above described. GEORGE RICHARDS ELKINGTON.
Witnesses:
WM. ELKING'ION,
Attorney at Law, Birmingham. J OHN BULLIVAN'I, His- Clerk.
Publications (1)
Publication Number | Publication Date |
---|---|
US741A true US741A (en) | 1838-05-17 |
Family
ID=2061024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US741D Expired - Lifetime US741A (en) | Improved process for gilding copper,, brass |
Country Status (1)
Country | Link |
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US (1) | US741A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2726279A (en) * | 1951-08-23 | 1955-12-06 | Itt | Anode for primary cells and method for making same |
US2969295A (en) * | 1958-05-05 | 1961-01-24 | Pacific Semiconductors Inc | Chemical gold plating |
US20080165359A1 (en) * | 2007-01-09 | 2008-07-10 | Lockheed Martin Missiles And Fire Control - Orlando | Method for enhancing polarimeter systems that use micro-polarizers |
US20090136338A1 (en) * | 2007-11-26 | 2009-05-28 | Jochen Laubender | Turbocharger with at least one variable turbine geometry turbine |
-
0
- US US741D patent/US741A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2726279A (en) * | 1951-08-23 | 1955-12-06 | Itt | Anode for primary cells and method for making same |
US2969295A (en) * | 1958-05-05 | 1961-01-24 | Pacific Semiconductors Inc | Chemical gold plating |
US20080165359A1 (en) * | 2007-01-09 | 2008-07-10 | Lockheed Martin Missiles And Fire Control - Orlando | Method for enhancing polarimeter systems that use micro-polarizers |
US20090136338A1 (en) * | 2007-11-26 | 2009-05-28 | Jochen Laubender | Turbocharger with at least one variable turbine geometry turbine |
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