US7033873B1 - Methods of controlling gate electrode doping, and systems for accomplishing same - Google Patents
Methods of controlling gate electrode doping, and systems for accomplishing same Download PDFInfo
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- US7033873B1 US7033873B1 US10/246,572 US24657202A US7033873B1 US 7033873 B1 US7033873 B1 US 7033873B1 US 24657202 A US24657202 A US 24657202A US 7033873 B1 US7033873 B1 US 7033873B1
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L22/00—Testing or measuring during manufacture or treatment; Reliability measurements, i.e. testing of parts without further processing to modify the parts as such; Structural arrangements therefor
- H01L22/20—Sequence of activities consisting of a plurality of measurements, corrections, marking or sorting steps
Definitions
- This invention relates generally to semiconductor fabrication technology, and, more particularly, to various methods of controlling gate electrode doping, and systems for accomplishing same.
- an illustrative field effect transistor is typically formed above a surface of a semiconducting substrate or wafer comprised of doped silicon.
- the substrate may be doped with either N-type or P-type dopant materials.
- the transistor typically has a doped polycrystalline silicon (polysilicon) gate electrode formed above a gate insulation layer comprised of, for example, silicon dioxide.
- the gate electrode and the gate insulation layer may be separated from doped source/drain regions of the transistor by a dielectric sidewall spacer.
- the source/drain regions of the transistor may be formed by performing one or more ion implantation processes to introduce dopant atoms, e.g., arsenic or phosphorous for NMOS devices, boron for PMOS devices, into the substrate. Shallow trench isolation regions may be provided to isolate the transistor electrically from neighboring semiconductor devices, such as other transistors.
- a typical integrated circuit device is comprised of a plurality of conductive interconnections, such as conductive lines and conductive contacts or vias, positioned in multiple layers of insulating material formed above the substrate. These conductive interconnections allow electrical signals to propagate between the transistors formed above the substrate.
- the present invention is directed to overcoming, or at least reducing the effects of, one or more of the problems described above.
- the present invention is generally directed to various methods of controlling gate electrode doping.
- the method disclosed herein comprises performing at least one process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of at least one process if the measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one diffusion process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one diffusion process if said measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one ion implant process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one ion implant process if said measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one deposition process in a deposition chamber while introducing dopant material therein to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one deposition process if the measured sheet resistance does not fall within acceptable limits.
- the present invention is also directed to various systems that may be used to perform the methods described herein.
- the system is comprised of a process tool for performing at least one process operation to form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of at least one process operation if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises a furnace for performing at least one heating process to introduce dopant atoms into a doped layer of gate electrode material by a diffusion process, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the at least one heating process if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises an ion implant tool for performing at least one ion implant process operation to form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the at least one ion implant process operation if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises a deposition tool adapted to perform a deposition process while dopant atoms are introduced into the deposition tool to thereby form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the deposition process if said measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- FIG. 1 is a cross-sectional view of an illustrative layer of gate electrode material formed above a semiconducting substrate
- FIG. 2 is one illustrative embodiment of a system that may be employed in one aspect of the present invention
- FIG. 3 is another illustrative embodiment of a system that may be employed with another aspect of the present invention.
- FIG. 4 is yet another illustrative embodiment of another illustrative system that may be employed with the present invention.
- the present invention is directed to various methods of controlling gate electrode doping, and various systems for accomplishing same.
- the present methods and systems are applicable to a variety of technologies, e.g., NMOS, PMOS, CMOS, etc., and they are readily applicable to the formation of a variety of devices, including, but not limited to, logic devices, memory devices, etc.
- FIG. 1 is a cross-sectional view of an illustrative substrate 10 having a layer of gate electrode material 12 formed thereabove.
- a layer of insulating material 14 is positioned between the gate electrode material 12 and the substrate 10 .
- the gate electrode material 12 and the layer of insulating material 14 may be comprised of a variety of different materials, and they may be formed using a variety of different techniques.
- the layer of gate electrode material 12 may be comprised of polysilicon, it may have a thickness ranging from approximately 85–300 nm, and it may be formed by a variety of different processes, e.g., chemical vapor deposition (CVD), low pressure chemical vapor deposition (LPCVD), etc.
- CVD chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- the layer of insulating material 14 may be comprised of, for example, silicon dioxide, it may have a thickness ranging from approximately 2–5 nm, and it may be formed by a thermal growth process or by a deposition process.
- the substrate 10 may be comprised of a variety of semiconducting materials, such as silicon or germanium, and it is also intended to be representative of structures such as silicon-on-insulator (SOI) structures, etc.
- SOI silicon-on-insulator
- the layer of gate electrode material 12 will be patterned using known photolithography and etching techniques to define a plurality of gate electrode structures for a plurality of transistors to be formed above the substrate 10 .
- additional process operations will be performed for a variety of purposes, e.g., to form source/drain regions for the device, to form metal silicide regions on the gate electrode and source/drain regions, to form sidewall spacers adjacent the gate electrode structures, etc.
- Dopant materials are introduced into the layer of gate electrode material 12 to, among other things, increase the conductivity of the resulting gate electrode structures on the finished transistor devices. This is important in that the increased conductivity of the gate electrode structures allows the transistors to operate at faster switching speeds.
- One parameter of interest with respect to the gate electrode material 12 and the resulting gate electrode structures is the sheet resistant (R S ) of the layer of material 12 after dopant materials are introduced into the layer of gate electrode material 12 . This parameter may have an impact on one or more electrical performance characteristics of the final transistor device.
- a variety of dopant materials may be introduced into the layer of gate electrode material 12 , and it may be accomplished using a variety of techniques.
- an N-type dopant material such as phosphorous or arsenic
- a variety of P-type dopant materials such as boron or boron difluoride
- the dopants may be introduced by a variety of techniques.
- the dopant atoms may be introduced by a diffusion process, an ion implant process, and/or by introducing dopants during the deposition process used to form the layer of gate electrode material 12 .
- FIG. 2 is an illustrative embodiment of a system 20 wherein a diffusion process will be used to introduce the desired dopant atoms into the layer of gate electrode material 12 .
- the system 20 is comprised of a furnace 22 , a controller 24 and a metrology tool 26 .
- An illustrative substrate 10 having a layer of gate electrode material 12 , is provided to the furnace 22 .
- a dopant source e.g., a gas, is introduced into the furnace 22 and one or more heating processes are performed to cause the dopant materials to diffuse into the layer of gate electrode material 12 . This processing results in a doped layer of gate electrode material 12 D.
- the process(es) performed in the furnace 22 may vary depending upon the particular devices under construction.
- a two-step heating process is performed to introduce and drive the dopant atoms into the layer of gate electrode material 12 .
- a source gas such as phosphorous chloride (POCL) may be introduced into the furnace 22 and an initial heat treatment may be performed at a temperature ranging from approximately 500–1100° C. for a duration ranging from approximately 5–120 minutes.
- POCL phosphorous chloride
- a second heat treating process is performed to drive the dopant materials diffused into the layer of gate electrode material 12 during the initial heat treatment deeper into the layer of gate electrode material 12 .
- the parameters of this second heat treatment may also vary depending upon the devices under construction.
- the second heat treating process is performed at a temperature ranging from approximately 500–1100° C. for a duration of approximately 5–120 minutes.
- a single heat treatment process may be performed to accomplish both purposes.
- a first heat treatment process may be performed at a temperature of about 900° C. for 5–90 minutes to introduce dopants into the gate electrode material layer 12
- a second heat treatment process may be performed at a temperature of approximately 900° C. for a duration of about 5–90 minutes to drive the dopant material into the gate electrode material layer 12 .
- a single heat treatment process may be performed to accomplish the induction and drive-in of the dopant material.
- the metrology tool 26 may be any type of metrology tool capable of measuring or determining the sheet resistance (R S ) of the doped layer of gate electrode material 12 D.
- the metrology tool 26 is a four-point probe sold by Prametrix. The number of substrates measured may be varied as a matter of choice.
- a preselected number of substrates from each lot processed in the furnace 22 may be measured in the metrology tool 26 to determine the sheet resistance (R S ) of the doped layer of gate electrode material 12 D.
- an arbitrary selection rate may be established for measuring the sheet resistance (R S ), e.g., every 10 th or 30 th substrate processed in the furnace 22 .
- Whatever sampling scheme is selected it should be such that there is reasonable expectation that the measured results reflect the process performed in the furnace 22 in terms of introducing and distributing the desired amount of dopant material into the doped layer of gate electrode material 12 D. If a plurality of measurements are taken, the data may be averaged or otherwise statistically compiled and manipulated if desired.
- the measured value(s) for the sheet resistivity (R S ) of the doped layer of gate electrode material 12 D is provided to the controller 24 . Based upon this measured sheet resistivity (R S ), the controller 24 may control or adjust one or more parameters of the processes performed in the furnace 22 to drive the process toward a desired or target value, or range of values, of the sheet resistance (R S ) for doped layers of gate electrode material 12 D produced by the processes performed in the furnace 22 . In short, a feedback control loop may be created such that the processes performed in the furnace 22 are producing doped layers of gate electrode material 12 D in accordance with a preselected target value for sheet resistance (R S ), or at least within an acceptable range of target values.
- the controller 24 may control one or more parameters of the process operations performed in the furnace 22 .
- the controller 24 may control the duration of one or more heat treatment processes, the temperature of one or more heat treatment processes, the number of heat treating processes performed in the furnace 22 , the type of sources gases used in the furnace 22 , the flow rate or composition of process gases or dopant source gases used in the furnace 22 , a location or placement of the wafers in the furnace or process chamber, etc.
- the duration of one or more of the heat treating processes performed in the furnace 22 may be increased in an effort to increase the dopant concentration and/or distribution of the dopant material within the doped layer of gate electrode material 12 D.
- the temperature of one or more of the heat treating processes may also be increased.
- FIG. 3 is an alternative embodiment of a system 20 in which the present invention may also be practiced.
- dopant materials are introduced into the layer of gate electrode material 12 by performing at least one ion implant process.
- the system 20 depicted in FIG. 3 is comprised of the controller 24 , the metrology tool 26 and an ion implant tool 28 .
- the system 20 in FIG. 3 may also comprise an anneal chamber 30 .
- the ion implant tool 28 may be any type of ion implant tool useful for introducing dopant atoms into a layer of material.
- the type of dopant atoms implanted, the dopant dose and the energy level of the ion implant process performed in the ion implant tool 28 may vary depending upon the particular devices under construction.
- a heat treatment process may be performed on substrates in the anneal chamber 30 after the ion implantation step is performed.
- the anneal chamber 30 may be a traditional furnace or a rapid thermal anneal tool. In the case where an anneal process is performed after the ion implantation process is performed, it may be performed at a temperature of approximately 800–1200° C. for a duration of approximately 10–90 minutes. In some cases, an anneal process may not be required after performing the ion implantation process, as indicated by the dashed line 27 that bypasses the anneal chamber 30 . Moreover, in some cases, the anneal processes may actually be part of subsequent processes performed on the device at later stages of fabrication.
- the controller 24 may control or adjust one or more of the parameters of the processes performed in the ion implant tool 28 and/or the anneal chamber 30 if the measured sheet resistance (R S ) does not meet limitations set for the sheet resistance or an acceptable range of values for the sheet resistance (R S ).
- the controller 24 may control or adjust the dopant dose and/or implant energy of the ion implant process performed in the ion implant tool 28 .
- the controller 24 may control or adjust the temperature or duration of the anneal process performed in the anneal chamber 30 .
- the feedback control loop depicted in FIG. 3 may be used to insure that the system 20 depicted therein is providing doped layers of gate electrode material 12 D having acceptable sheet resistance (R S ) values.
- FIG. 4 depicts yet another illustrative embodiment of the present invention, wherein dopant atoms are introduced into a layer of gate electrode material 12 during the deposition process used to form the layer of gate electrode material 12 .
- the system 20 depicted in FIG. 4 is comprised of the controller 24 , the metrology tool 26 and a deposition chamber 32 .
- the deposition chamber 32 may be any type of deposition tool capable of forming a layer of gate electrode material 12 . Any of a variety of deposition processes may be performed in the deposition chamber 32 to form the layer of gate electrode material, e.g., chemical vapor deposition (CVD), low pressure chemical vapor deposition (LPCVD), etc.
- CVD chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- a substrate 10 is provided to the deposition chamber 32 .
- dopant atoms are introduced into the deposition chamber 32 such that the end result of the deposition process is a doped layer of gate electrode material 12 D formed above the substrate 10 .
- the dopant material may be introduced into the deposition chamber 32 by introducing one or more source gases into the deposition chamber 32 .
- source gases such as phosphine (for N-type dopants) may be introduced into the deposition chamber 32 during the deposition process.
- the source gases may be introduced on a continuous or intermittent basis.
- an anneal process may be performed. As before, this may be a separate anneal process or it may be performed as part of subsequent anneal processes performed on the wafer.
- the metrology tool 26 is used to obtain values for the sheet resistance (R S ) of that layer, and the measured sheet resistance (R S ) values are provided to the controller 24 . If the measured sheet resistance values do not fall within acceptable limits, the controller 24 may control one or more parameters of the deposition process performed in the deposition chamber 32 . For example, the controller 24 may control or adjust the temperature, pressure or duration of the deposition process or the composition or flow rate of the various processes and dopant source gases supplied to the deposition chamber 32 in an effort to insure that subsequently formed doped layers of gate electrode material 12 D produced by the deposition chamber 32 have sheet resistance (R S ) values that are within acceptable limits.
- the controller 24 is a computer programmed with software to implement the functions described herein. Moreover, the functions described for the controller 24 may be performed by one or more controllers spread through the system.
- the controller 24 may be a fab level controller that is used to control processing operations throughout all or a portion of a semiconductor manufacturing facility. Alternatively, the controller 24 may be a lower level computer that controls only portions or cells of the manufacturing facility.
- the controller 24 may be a stand-alone device, or it may reside on the furnace 22 , the ion implant tool 28 and/or the deposition tool 32 , depending upon the particular application.
- a hardware controller (not shown) designed to implement the particular functions may also be used.
- An exemplary software system capable of being adapted to perform the functions of the controller 24 , as described, is the Catalyst system offered by KLA Tencor, Inc.
- the Catalyst system uses Semiconductor Equipment and Materials International (SEMI) Computer Integrated Manufacturing (CIM) Framework compliant system technologies, and is based on the Advanced Process Control (APC) Framework.
- SEMI Semiconductor Equipment and Materials International
- CIM Computer Integrated Manufacturing
- API Advanced Process Control
- CIM SEMI E81-0699—Provisional Specification for CIM Framework Domain Architecture
- APC SEMI E93-0999—Provisional Specification for CIM Framework Advanced Process Control Component
- the present invention is generally directed to various methods of controlling gate electrode doping.
- the method disclosed herein comprises performing at least one process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of at least one process if the measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one diffusion process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one diffusion process if said measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one ion implant process operation to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one ion implant process if said measured sheet resistance does not fall within acceptable limits.
- the method comprises performing at least one deposition process in a deposition chamber while introducing dopant material therein to form a doped layer of gate electrode material, measuring a sheet resistance of the doped layer of gate electrode material and adjusting at least one parameter of the at least one deposition process if the measured sheet resistance does not fall within acceptable limits.
- the present invention is also directed to various systems that may be used to perform the methods described herein.
- the system is comprised of a process tool for performing at least one process operation to form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of at least one process operation if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises a furnace for performing at least one heating process to introduce dopant atoms into a doped layer of gate electrode material by a diffusion process, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the at least one heating process if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises an ion implant tool for performing at least one ion implant process operation to form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the at least one ion implant process operation if the measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
- the system comprises a deposition tool adapted to perform a deposition process while dopant atoms are introduced into the deposition tool to thereby form a doped layer of gate electrode material, a metrology tool for measuring a sheet resistance of the doped layer of gate electrode material and a controller for adjusting at least one parameter of the deposition process if said measured sheet resistance of the doped layer of gate electrode material does not fall within acceptable limits.
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Abstract
Description
Claims (15)
Priority Applications (1)
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US10/246,572 US7033873B1 (en) | 2002-09-18 | 2002-09-18 | Methods of controlling gate electrode doping, and systems for accomplishing same |
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US10/246,572 US7033873B1 (en) | 2002-09-18 | 2002-09-18 | Methods of controlling gate electrode doping, and systems for accomplishing same |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060068514A1 (en) * | 2004-09-30 | 2006-03-30 | Solid State Measurements, Inc. | Method of detecting un-annealed ion implants |
US20090283860A1 (en) * | 2008-05-13 | 2009-11-19 | Stmicroelectronics, Inc. | High precision semiconductor chip and a method to construct the semiconductor chip |
US8535957B1 (en) * | 2010-06-30 | 2013-09-17 | Kla-Tencor Corporation | Dopant metrology with information feedforward and feedback |
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