US6835478B2 - Method and apparatus for fuel cell system fault detection - Google Patents
Method and apparatus for fuel cell system fault detection Download PDFInfo
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 - US6835478B2 US6835478B2 US10/166,937 US16693702A US6835478B2 US 6835478 B2 US6835478 B2 US 6835478B2 US 16693702 A US16693702 A US 16693702A US 6835478 B2 US6835478 B2 US 6835478B2
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 - 238000000034 method Methods 0.000 title claims abstract description 29
 - 238000001514 detection method Methods 0.000 title claims abstract description 12
 - 238000005259 measurement Methods 0.000 claims abstract description 40
 - 238000001914 filtration Methods 0.000 claims description 35
 - 238000011217 control strategy Methods 0.000 description 6
 - 239000000463 material Substances 0.000 description 6
 - 239000007789 gas Substances 0.000 description 4
 - 239000007800 oxidant agent Substances 0.000 description 4
 - 238000006243 chemical reaction Methods 0.000 description 3
 - 239000012528 membrane Substances 0.000 description 3
 - NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
 - 239000006227 byproduct Substances 0.000 description 2
 - 239000003054 catalyst Substances 0.000 description 2
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 - 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
 - QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
 - 230000015556 catabolic process Effects 0.000 description 1
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 - 230000003292 diminished effect Effects 0.000 description 1
 - 239000003792 electrolyte Substances 0.000 description 1
 - 239000002803 fossil fuel Substances 0.000 description 1
 - 239000002737 fuel gas Substances 0.000 description 1
 - 239000001257 hydrogen Substances 0.000 description 1
 - 229910052739 hydrogen Inorganic materials 0.000 description 1
 - 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
 - 238000013507 mapping Methods 0.000 description 1
 - 239000001301 oxygen Substances 0.000 description 1
 - 229910052760 oxygen Inorganic materials 0.000 description 1
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 - XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
 
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 - H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
 - H01M8/04298—Processes for controlling fuel cells or fuel cell systems
 - H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
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 - H01M8/04365—Temperature; Ambient temperature of other components of a fuel cell or fuel cell stacks
 
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
 - Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
 - Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
 - Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
 - Y02E60/30—Hydrogen technology
 - Y02E60/50—Fuel cells
 
 
Definitions
- the present invention relates generally to the field of fuel cell systems and more specifically to fault detection in fuel cell systems.
 - a conventional fuel cell system comprises a fuel cell and a fuel cell controller.
 - the fuel cell typically comprises a means for bringing a fuel gas, typically hydrogen, and an oxidizer gas, typically air or oxygen, into contact with opposite faces of an electrolyte membrane. Chemical reaction develops a voltage across the membrane, and this voltage can be used to power external electrical devices. Byproducts of the reaction include chemical byproducts, typically water, and heat. Additionally, the fuel cell typically comprises numerous sensors for measuring critical operating parameters of the fuel cell and numerous actuators for modulating the fuel and oxidizer gas flows.
 - the fuel cell controller typically comprises an electronic processor for implementing a nominal control strategy, where the nominal control strategy is an algorithm for calculating gas flow modulation from the measured operating parameters and from a set of desired operating parameters.
 - the nominal control strategy assumes a normally working fuel cell.
 - fuel cell partial failures also called “faults”
 - system performance generally tends to degrade.
 - Such performance degradation arises from a combination of at least two causes: diminished fuel cell capability, and mismatch between the nominal control strategy and the dynamic behavior of the partially failed fuel cell.
 - the second cause is a significant factor, if it were possible to detect and classify the fault, then it may also be possible to adopt an alternative control strategy tailored to the dynamic behavior of the partially failed fuel cell and thereby recover a portion of the lost performance.
 - a method of detecting faults in a fuel cell system comprising: comparing a plurality of fuel cell measurements to respective ones of a plurality of range limits to yield a plurality of range flags; differentiating the fuel cell measurements to yield a plurality of fuel cell rates; comparing the fuel cell rates to respective ones of a plurality of rate limits to yield a plurality of rate flags; and classifying the range flags and the rate flags to yield a fault detection decision.
 - FIGURE illustrates a block diagram of an apparatus in accordance with one embodiment of the present invention.
 - the FIGURE illustrates a block diagram of an apparatus 100 comprising a fuel cell 105 , a dynamic filter 150 , a range limit comparator 110 , a differentiator 120 , a rate limit comparator 130 , a residual computer 160 , a residual threshold comparator 170 , and a fault classifier 140 .
 - dynamic filter 150 performs dynamic filtering of a plurality of unfiltered fuel cell measurements from fuel cell 105 to yield a plurality of fuel cell measurements.
 - Range limit comparator 110 compares the fuel cell measurements to respective ones of a plurality of range limits to yield a plurality of range flags.
 - Differentiator 120 differentiates the fuel cell measurements to yield a plurality of fuel cell rates which rate limit comparator 130 compares to respective ones of a plurality of rate limits to yield a plurality of rate flags.
 - residual computer 160 computes a residual statistic which residual threshold comparator 170 compares to a residual threshold to yield a residual flag.
 - Fault classifier 140 classifies the range flags, the rate flags, and the residual flag to yield a fault detection decision.
 - fuel cell controller 180 adopts a control strategy appropriate to the condition of fuel cell 105 .
 - Fuel cell 105 comprises any device or system comprising a flowing fuel material, a flowing oxidizer material, and a catalyst material, and being configured to promote chemical reactions among the flowing fuel material, the flowing oxidizer material, and the catalyst material.
 - Examples of fuel cell 105 include, without limitation, polymer electrolyte membrane fuel cells, alkaline fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, and solid oxide fuel cells.
 - dynamic filtering refers to any process of calculating an output signal from present and past values of an input signal.
 - dynamic filtering include, without limitation, discrete-time and continuous-time realizations of lowpass filters, bandpass filters, highpass filters, and Kalman filters and discrete-time rank filters including, without limitation, median filters, minimum filters and maximum filters.
 - Kalman filtering refers to any method of signal processing that utilizes a dynamic model propagated by calculating an innovation, wherein the innovation is the difference between an input signal and a signal estimate produced by the dynamic model.
 - Kalman filters include, without limitation, Wiener filters, finite-horizon and infinite-horizon Kalman filters, Luenberger observers and extended Kalman filters.
 - “differentiating” refers to any method of approximating a time derivative; examples include, without limitation, AC coupled filtering and backward differencing.
 - a residual statistic is any mathematical quantity nominally zero when fuel cell 105 is operating normally, and nominally non-zero when fuel cell 105 exhibits a fault. Examples of computing residual statistics include, without limitation:
 - x ⁇ n is a fuel cell state vector (assumed measured)
 - u ⁇ m is a fuel cell input vector (assumed measured)
 - a ⁇ n ⁇ n , B ⁇ n ⁇ m define a linear fuel cell model
 - z ⁇ n is a Kalman filter state vector
 - y ⁇ p is a measured fuel cell output vector
 - x ⁇ n is a fuel cell state vector (assumed unmeasured)
 - C ⁇ p ⁇ n denotes a linear fuel cell model output matrix
 - H ⁇ n ⁇ p is a Kalman filter gain matrix.
 - range flags denote signals, possibly vector-valued, comprising respective binary signals having true values when range limit comparator 110 , rate limit comparator 130 , and residual threshold comparator 170 sense inputs greater than the range limits, rate limits, and residual threshold, respectively, and having false values, otherwise.
 - the range flags, rate flags, and residual flags may also comprise auxiliary signals comprising, for example, the respective comparator input signals.
 - fault detection decision refers to any signal used to communicate the condition of fuel cell 105 to fuel cell controller 180 ; examples include, without limitation, integer valued signals and decoded binary signals.
 - classifying the range flags, rate flags, and residual flag denotes any method of statically mapping the flags into the fault detection decision; examples include, without limitation, combinational (combinatorial) logic, decision trees, and table look-up.
 - Range limit comparator 110 , differentiator 120 , rate limit comparator 130 , fault classifier 140 , dynamic filter 150 , residual computer 160 , and residual threshold comparator 170 comprise any electrical or electronic device or system capable of performing the indicated functions. Examples include, without limitation, analog electronic computation modules and digital electronic computation modules (digital computers) including, without limitation, array processors, microcomputers, microprocessors, microcontrollers, and single-chip digital signal processors (DSPs).
 - DSPs digital signal processors
 - fuel cell measurements comprise at least one quantity selected from a group consisting of voltage, temperature, power, current, pressure, gas flow, and concentration. These fuel cell measurements may refer to multiple quantities local to individual cells, or quantities global to stacks of cells in fuel cell 105 .
 
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Abstract
Description
Claims (20)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US10/166,937 US6835478B2 (en) | 2002-06-11 | 2002-06-11 | Method and apparatus for fuel cell system fault detection | 
| EP03253602A EP1391957A3 (en) | 2002-06-11 | 2003-06-06 | Method and apparatus for fuel cell system fault detection | 
| KR10-2003-0037091A KR20030095350A (en) | 2002-06-11 | 2003-06-10 | Method and apparatus for fuel cell system fault detection | 
| SG200303389A SG110056A1 (en) | 2002-06-11 | 2003-06-10 | Method and apparatus for fuel cell system fault detection | 
| JP2003164474A JP4878726B2 (en) | 2002-06-11 | 2003-06-10 | Method and apparatus for detecting failure in fuel cell system | 
| CNA031330088A CN1477404A (en) | 2002-06-11 | 2003-06-11 | Fault detecting method and device for fuel cell system | 
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| US10/166,937 US6835478B2 (en) | 2002-06-11 | 2002-06-11 | Method and apparatus for fuel cell system fault detection | 
Publications (2)
| Publication Number | Publication Date | 
|---|---|
| US20030228506A1 US20030228506A1 (en) | 2003-12-11 | 
| US6835478B2 true US6835478B2 (en) | 2004-12-28 | 
Family
ID=29710759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| US10/166,937 Expired - Lifetime US6835478B2 (en) | 2002-06-11 | 2002-06-11 | Method and apparatus for fuel cell system fault detection | 
Country Status (6)
| Country | Link | 
|---|---|
| US (1) | US6835478B2 (en) | 
| EP (1) | EP1391957A3 (en) | 
| JP (1) | JP4878726B2 (en) | 
| KR (1) | KR20030095350A (en) | 
| CN (1) | CN1477404A (en) | 
| SG (1) | SG110056A1 (en) | 
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| US20070077462A1 (en) * | 2005-09-30 | 2007-04-05 | Warner Gregory L | System and method for fuel cell operation with in-situ reformer regeneration | 
| US20080176118A1 (en) * | 1999-10-06 | 2008-07-24 | Edlund David J | System and method for controlling the operation of a fuel processsing system | 
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| WO2006006672A1 (en) * | 2004-07-14 | 2006-01-19 | Matsushita Electric Industrial Co., Ltd. | Fuel cell electric power generation system | 
| WO2006056076A1 (en) * | 2004-11-29 | 2006-06-01 | Hydrogenics Corporation | Systems and methods for detecting and indicating fault conditions in electrochemical cells | 
| ATE475997T1 (en) * | 2005-01-04 | 2010-08-15 | Ansaldo Fuel Cells Spa | METHOD AND SYSTEM FOR OPERATING MOLTEN CARBON FUEL CELLS | 
| KR100941258B1 (en) * | 2007-07-20 | 2010-02-11 | 현대자동차주식회사 | Hydrogen Recirculation Blower Operation System and Control Method for Fuel Cell | 
| CN102012487B (en) * | 2010-11-29 | 2014-01-01 | 中兴通讯股份有限公司 | Charging detection method and detector of battery | 
| KR101315764B1 (en) * | 2011-02-23 | 2013-10-10 | 현대자동차주식회사 | Method for detecting fail of hydrogen supply system for fuel cell | 
| KR101362741B1 (en) * | 2012-12-20 | 2014-02-14 | 현대오트론 주식회사 | Fault diagnosis method and apparatus of fuel cell stack | 
| CN105759217B (en) * | 2016-02-26 | 2020-01-07 | 江苏快乐电源(涟水)有限公司 | Online fault diagnosis method for lead-acid storage battery pack based on measurable data | 
| DE102016116049A1 (en) * | 2016-08-29 | 2018-03-01 | Audi Ag | A method of estimating a state vector of a fuel cell system, a method of controlling a state quantity of a fuel cell system, and a fuel cell system | 
| AT520558B1 (en) * | 2017-11-27 | 2019-05-15 | Avl List Gmbh | Recursive, time series-based method for determining the state of an electrochemical reactor | 
| KR102540876B1 (en) | 2017-12-19 | 2023-06-07 | 현대자동차주식회사 | Apparatus for diagnosing fail in fuel cell | 
| US10615438B2 (en) * | 2018-02-23 | 2020-04-07 | Cummins Enterprise Llc | Degradation detecting device for fuel cell stack, fuel cell system and managing method thereof | 
| CN109143091B (en) * | 2018-10-15 | 2020-12-29 | 四川长虹电器股份有限公司 | Battery management system fault FDIR system and method based on double redundancy | 
| KR102115268B1 (en) | 2020-01-31 | 2020-05-26 | 서울대학교산학협력단 | Fuel cell system fault diagnosis method based on fault severity | 
| CN115966733B (en) * | 2023-02-07 | 2024-11-15 | 西南石油大学 | Method for estimating internal temperature of flat plate type solid oxide fuel cell stack | 
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| Publication number | Priority date | Publication date | Assignee | Title | 
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| DE4338178C2 (en) * | 1993-11-09 | 2003-04-30 | Aeg Energietechnik Gmbh | Arrangement for monitoring the condition of fuel cell modules | 
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- 2003-06-06 EP EP03253602A patent/EP1391957A3/en not_active Withdrawn
 - 2003-06-10 SG SG200303389A patent/SG110056A1/en unknown
 - 2003-06-10 JP JP2003164474A patent/JP4878726B2/en not_active Expired - Fee Related
 - 2003-06-10 KR KR10-2003-0037091A patent/KR20030095350A/en not_active Ceased
 - 2003-06-11 CN CNA031330088A patent/CN1477404A/en active Pending
 
 
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| US20080176118A1 (en) * | 1999-10-06 | 2008-07-24 | Edlund David J | System and method for controlling the operation of a fuel processsing system | 
| US7771882B2 (en) * | 1999-10-06 | 2010-08-10 | Idatech, Llc | System and method for controlling the operation of a fuel processing system | 
| US20070077462A1 (en) * | 2005-09-30 | 2007-04-05 | Warner Gregory L | System and method for fuel cell operation with in-situ reformer regeneration | 
| US7713642B2 (en) | 2005-09-30 | 2010-05-11 | General Electric Company | System and method for fuel cell operation with in-situ reformer regeneration | 
Also Published As
| Publication number | Publication date | 
|---|---|
| KR20030095350A (en) | 2003-12-18 | 
| JP4878726B2 (en) | 2012-02-15 | 
| EP1391957A2 (en) | 2004-02-25 | 
| US20030228506A1 (en) | 2003-12-11 | 
| EP1391957A3 (en) | 2011-01-12 | 
| JP2004134361A (en) | 2004-04-30 | 
| SG110056A1 (en) | 2005-04-28 | 
| CN1477404A (en) | 2004-02-25 | 
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