US6599594B1 - Glass container for medicinal purposes - Google Patents
Glass container for medicinal purposes Download PDFInfo
- Publication number
- US6599594B1 US6599594B1 US09/564,758 US56475800A US6599594B1 US 6599594 B1 US6599594 B1 US 6599594B1 US 56475800 A US56475800 A US 56475800A US 6599594 B1 US6599594 B1 US 6599594B1
- Authority
- US
- United States
- Prior art keywords
- weight
- glass container
- fluorine
- coating
- equal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/045—Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
- C03C2217/282—Carbides, silicides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
- C03C2218/153—Deposition methods from the vapour phase by cvd by plasma-enhanced cvd
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S215/00—Bottles and jars
- Y10S215/03—Medical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/131—Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
- Y10T428/1317—Multilayer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/131—Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
- Y10T428/1317—Multilayer [continuous layer]
- Y10T428/1321—Polymer or resin containing [i.e., natural or synthetic]
Definitions
- the present invention relates to a glass container for medicinal purposes, and, more particularly, to a glass container for storing and preserving pharmaceutical or diagnostic solutions for medicinal purposes, which is provided with an anti-adherent coating on its interior surface or surfaces.
- Glass containers for medicinal purposes i.e. containers having pharmaceuticals or diagnostics as contents
- containers having pharmaceuticals or diagnostics as contents are on the market in a most wide variety of embodiments, in order to take into account their respective purposes, associated administration forms and the respective contents.
- Glass containers for medicinal contents should have interior surfaces which have the least possible adherence for their contents, i.e. as large as possible a wetting angle for aqueous contents, in order to permit a complete emptying of residues from the container. This is particularly true for comparatively small glass containers with very expensive contents.
- silicone oil is dispensed from the surfaces and that the silicone oil may be introduced into human or animal bodies. Furthermore undesirable adsorption phenomena occur on the silicone-coated surface. Protein binding is one of the undesirable adsorption phenomena and is particularly notable. Furthermore heavy metal impurities are unavoidably present in the silicone oil. Thus suitable expensive testing is prescribed In European formularies. Furthermore auxiliary substances (eg. detergents), which must be used for stabilizing silicone emulsions, are critical.
- a glass container for storing and preserving pharmaceutical or diagnostic solutions for medicinal purposes comprising a container closure device and an amorphous, transparent and pharmaceutically acceptable anti-adherent coating provided on the entire interior surface of the glass container over the entire interior surface up to the closure device, and wherein the anti-adherent coating has a contact angle for wetting with water of ⁇ 80°, even after autoclaving at about 120° C. for about 20 min, contains the elements Si, O, C and H and is deposited by means of a plasma-enhanced chemical vapor deposition method (PECVD), preferably by means of a plasma-pulsed, chemical vapor deposition method (PICVD).
- PECVD plasma-enhanced chemical vapor deposition method
- PICVD plasma-pulsed, chemical vapor deposition method
- Medicinal glass containers of this type i.e. according to the invention, have interior surfaces that to a large extent reject water or wetting with water, which permits a nearly complete emptying of the container. It also has the great medically related advantage that no silicone substances are introduced into the pharmaceutical or diagnostic contents and thus into the human body.
- the anti-adherent layer or coating according to the invention is equal to typical pharmaceutical stress test conditions, e.g. typical sterilization conditions, without loosing its function.
- the glass container according to the invention is thus to a large extent pharmaceutically acceptable.
- the anti-adherent layer comprises at least 1% by weight silicon and at least 5% by weight carbon.
- the hydrophobic properties of the coating can be augmented, when the anti-adherent coating contains fluorine according to a further embodiment of the invention.
- FIGURE is a partially side, partially cutaway cross-sectional view through a glass container for medicinal purposes according to the invention.
- the sole FIGURE shows a glass container 1 for medicinal purposes in a configuration suitable for a typical application, which is provided with a conventional closure device 2 .
- the glass container 1 serves for storage and preservation of a pharmaceutical or diagnostic solution 5 .
- the glass container 1 is preferably made from a glass type I according to German Dispensatory, 10th Edition, corresponding to a borosilicate glass.
- the particular glass type mentioned above and the.shape of the glass bottle are features of preferred embodiments.
- the glass bottle may also have other shapes and can be made from other types of glass, which have the required properties for other applications.
- Especially the glass bottle may be made from glass of a lower hydrolytic class, especially the so-called neutral glass.
- the interior of the glass bottle should reject water to a large extent. That means that it should have as large as possible a wetting angle for its aqueous contents 5 , especially in order to permit complete emptying so as to minimize any residue left in the bottle. This is also true for a comparatively small glass container with very expensive contents.
- a special coating 4 is provided over the whole interior surface of the wall 3 of the glass bottle 1 .
- This coating comprises an anti-adherent layer with a contact angle for water of ⁇ 80°, which is pharmaceutically acceptable, i.e. free of heavy metals and stable under the usual test conditions, especially autoclaving for 20 minutes at 121° C. and/or in hot air sterilization for 30 minutes at 300° C.
- the layer is amorphous, clear and transparent and contains the elements Si, O, C and H, with silicon content of at least 1% by weight and a C content of at least 5% by weight.
- the layer 4 also contains fluorine, whose content is in a reciprocal relationship to the carbon content.
- the coating or layer 4 is produced bymeans of a plasma-enhanced chemical vapor deposition process (PECVD).
- PECVD plasma-enhanced chemical vapor deposition process
- a plasma-assisted layer deposition from the gas phase occurs, in which the layer material is supplied in the form of so-called precursor gases.
- precursor gases are broken down with the required energy being supplied to the system by electrical high frequency plasma, particularly in a plasma-pulsed chemical vapor deposition process (PICVD).
- the container for medical purposes according to the present invention has the following properties:
- PFCVD reactor Glass containers in the form of glass bottles are placed in a PFCVD reactor, whose structure corresponds principally to that disclosed in DE 44 38 359 A1.
- a gas nozzle device extends into the mouth of the bottle.
- the reactor is evacuated to 0.05 mbar by a pump.
- CF 3 C 6 F 10
- HMDEO hexamethyldisiloxane
- RF power is coupled to an electrode in the reactor inductively by means of coils through a matching network and Ignites plasma in the reactor.
- the entire apparatus is arranged within an electrical shielding. In this process the reaction gas is converted into a coating in the whole bottle at about 300 W HF power (13.56 MHz).
- a contact angle of 95° to 102° (relative to water) is produced in all bottles by this process. This contact angle becomes 85° to 95° during autoclaving at. 121° C. for 20 minutes. All bottles were filled with an aqueous.suspension. After a storage time of 1 week the pouring behavior was tested. In contrast to the uncoated bottles, in which a residue of flecks of the suspension remained over the entire interior surface after emptying the bottles, the bottles coated in the above-described manner according to the invention, could be completely emptied without leaving a residue.
- Glass containers in the form of glass bottles are placed in a PICVD reactor, whose structure corresponds principally to that disclosed in DE 196 29 877 C1.
- the reactor is evacuated to 0.9 mbar by a pump.
- a gas mixture comprising 10 sccm HMDSO, 5 sccm O 2 and 2 sccm C 6 F 6 is supplied by a supply device.
- Pulsed power was provided at 2.45 GHz by a microwave discharge source, which ignites a plasma in the glass bottle. After deposition of a 30 nm layer the microwave power is turned off and the bottles are aerated.
- the tests found that after the coating is formed the contact angle for water was 91° to 105°. This contact angle is reduced about 6° on average after autoclaving. This behavior of a watery suspension that is poured out of bottles coated in this manner is similar to that described in connection with the previous PECVD method.
- German Patent Application 199 21 303.8 of May 7, 1999 is incorporated here by reference.
- This German Patent Application describes the invention described hereinabove and claimed in the claims appended hereinbelow and provides the basis for a claim of priority for the instant invention under 35 U.S.C. 119.
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Description
Claims (3)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19921303 | 1999-05-07 | ||
DE19921303A DE19921303C1 (en) | 1999-05-07 | 1999-05-07 | Medical glass container, for holding pharmaceutical or medical diagnostic solution, has an inner PECVD non-stick layer containing silicon, oxygen, carbon and hydrogen |
DE19921303.8-45 | 1999-05-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
US20030134060A1 US20030134060A1 (en) | 2003-07-17 |
US6599594B1 true US6599594B1 (en) | 2003-07-29 |
Family
ID=7907452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/564,758 Expired - Lifetime US6599594B1 (en) | 1999-05-07 | 2000-05-04 | Glass container for medicinal purposes |
Country Status (5)
Country | Link |
---|---|
US (1) | US6599594B1 (en) |
EP (1) | EP1050517B1 (en) |
JP (1) | JP4351363B2 (en) |
DE (2) | DE19921303C1 (en) |
HK (1) | HK1032776A1 (en) |
Cited By (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040199138A1 (en) * | 2001-07-21 | 2004-10-07 | Mcbay William Edward | Storage of liquid compositions |
US20070187280A1 (en) * | 2006-01-11 | 2007-08-16 | Daniel Haines | Method of preparing a macromolecule deterrent surface on a pharmaceutical package |
EP1992567A2 (en) | 2007-05-15 | 2008-11-19 | Kraft Foods Holdings, Inc. | Container with Improved Release Properties |
EP1992420A1 (en) | 2007-05-15 | 2008-11-19 | Kraft Foods Holdings, Inc. | Method of forming a container with improved release properties |
US20110108551A1 (en) * | 2009-11-12 | 2011-05-12 | Postech Academy-Industry Foundation | Liquid container |
US7985188B2 (en) | 2009-05-13 | 2011-07-26 | Cv Holdings Llc | Vessel, coating, inspection and processing apparatus |
US20110226658A1 (en) * | 2008-05-23 | 2011-09-22 | Hospira, Inc. | Packaged Iron Sucrose Products |
US8512796B2 (en) | 2009-05-13 | 2013-08-20 | Si02 Medical Products, Inc. | Vessel inspection apparatus and methods |
WO2014116401A1 (en) | 2013-01-22 | 2014-07-31 | General Electric Company | Apparatus for storage and sampling of de-ionized water samples and the like |
US20140231282A1 (en) * | 2012-06-18 | 2014-08-21 | Innova Dynamics, Inc. | Agglomerate reduction in a nanowire suspension stored in a container |
US9034442B2 (en) | 2012-11-30 | 2015-05-19 | Corning Incorporated | Strengthened borosilicate glass containers with improved damage tolerance |
US20150197371A1 (en) * | 2012-09-26 | 2015-07-16 | Katholieke Universiteit Leuven | Bottles with means to prevent gushing |
US9272095B2 (en) | 2011-04-01 | 2016-03-01 | Sio2 Medical Products, Inc. | Vessels, contact surfaces, and coating and inspection apparatus and methods |
US9428302B2 (en) | 2012-06-28 | 2016-08-30 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US20160251261A1 (en) * | 2014-03-13 | 2016-09-01 | Stevanato Group International A.S. | Method of Handling a Liquid Drug Formation |
US9458536B2 (en) | 2009-07-02 | 2016-10-04 | Sio2 Medical Products, Inc. | PECVD coating methods for capped syringes, cartridges and other articles |
US9517966B2 (en) | 2011-10-25 | 2016-12-13 | Corning Incorporated | Glass compositions with improved chemical and mechanical durability |
US9545360B2 (en) | 2009-05-13 | 2017-01-17 | Sio2 Medical Products, Inc. | Saccharide protective coating for pharmaceutical package |
US9554968B2 (en) | 2013-03-11 | 2017-01-31 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging |
US9603775B2 (en) | 2013-04-24 | 2017-03-28 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9664626B2 (en) | 2012-11-01 | 2017-05-30 | Sio2 Medical Products, Inc. | Coating inspection method |
US9662450B2 (en) | 2013-03-01 | 2017-05-30 | Sio2 Medical Products, Inc. | Plasma or CVD pre-treatment for lubricated pharmaceutical package, coating process and apparatus |
US9668936B2 (en) | 2012-02-28 | 2017-06-06 | Corning Incorporated | Glass articles with low-friction coatings |
US9700486B2 (en) | 2013-04-24 | 2017-07-11 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9700485B2 (en) | 2013-04-24 | 2017-07-11 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707155B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707153B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707154B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9713572B2 (en) | 2013-04-24 | 2017-07-25 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9717648B2 (en) | 2013-04-24 | 2017-08-01 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9717649B2 (en) | 2013-04-24 | 2017-08-01 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9764093B2 (en) | 2012-11-30 | 2017-09-19 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition |
US9839579B2 (en) | 2013-04-24 | 2017-12-12 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9849066B2 (en) | 2013-04-24 | 2017-12-26 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9863042B2 (en) | 2013-03-15 | 2018-01-09 | Sio2 Medical Products, Inc. | PECVD lubricity vessel coating, coating process and apparatus providing different power levels in two phases |
US9878101B2 (en) | 2010-11-12 | 2018-01-30 | Sio2 Medical Products, Inc. | Cyclic olefin polymer vessels and vessel coating methods |
US9903782B2 (en) | 2012-11-16 | 2018-02-27 | Sio2 Medical Products, Inc. | Method and apparatus for detecting rapid barrier coating integrity characteristics |
US9937099B2 (en) | 2013-03-11 | 2018-04-10 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging with low oxygen transmission rate |
US9988174B2 (en) | 2012-06-07 | 2018-06-05 | Corning Incorporated | Delamination resistant glass containers |
US10065884B2 (en) | 2014-11-26 | 2018-09-04 | Corning Incorporated | Methods for producing strengthened and durable glass containers |
US10117806B2 (en) | 2012-11-30 | 2018-11-06 | Corning Incorporated | Strengthened glass containers resistant to delamination and damage |
US10189603B2 (en) | 2011-11-11 | 2019-01-29 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US10201660B2 (en) | 2012-11-30 | 2019-02-12 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition on medical syringes, cartridges, and the like |
US10413483B2 (en) | 2011-10-25 | 2019-09-17 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10626047B2 (en) | 2016-10-18 | 2020-04-21 | Owens-Brockway Glass Container Inc. | Glass container coating process |
US10654069B2 (en) | 2013-05-24 | 2020-05-19 | BSH Hausgeräte GmbH | Coating of usage surfaces with plasma polymer layers under atmospheric pressure in order to improve the cleanability |
US10737973B2 (en) | 2012-02-28 | 2020-08-11 | Corning Incorporated | Pharmaceutical glass coating for achieving particle reduction |
US10899659B2 (en) | 2014-09-05 | 2021-01-26 | Corning Incorporated | Glass articles and methods for improving the reliability of glass articles |
US11014701B2 (en) | 2018-05-18 | 2021-05-25 | Schott Ag | Glass container with an improved bottom geometry |
US11066745B2 (en) | 2014-03-28 | 2021-07-20 | Sio2 Medical Products, Inc. | Antistatic coatings for plastic vessels |
US11077233B2 (en) | 2015-08-18 | 2021-08-03 | Sio2 Medical Products, Inc. | Pharmaceutical and other packaging with low oxygen transmission rate |
US11116695B2 (en) | 2011-11-11 | 2021-09-14 | Sio2 Medical Products, Inc. | Blood sample collection tube |
US11208348B2 (en) | 2015-09-30 | 2021-12-28 | Corning Incorporated | Halogenated polyimide siloxane chemical compositions and glass articles with halogenated polyimide siloxane low-friction coatings |
EP4063334A1 (en) * | 2021-03-25 | 2022-09-28 | Schott Ag | Coated glass element |
WO2022200623A1 (en) * | 2021-03-25 | 2022-09-29 | Schott Ag | Pharmaceutical container |
EP4067319A3 (en) * | 2021-03-25 | 2022-10-26 | Schott Ag | Coated glass element |
EP4067318A3 (en) * | 2021-03-25 | 2022-10-26 | Schott Ag | Coated glass element |
US11497681B2 (en) | 2012-02-28 | 2022-11-15 | Corning Incorporated | Glass articles with low-friction coatings |
US11624115B2 (en) | 2010-05-12 | 2023-04-11 | Sio2 Medical Products, Inc. | Syringe with PECVD lubrication |
US11709155B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved chromatography of metal interacting analytes |
US11709156B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved analytical analysis |
US11772846B2 (en) | 2015-10-30 | 2023-10-03 | Corning Incorporated | Glass articles with mixed polymer and metal oxide coatings |
US11918936B2 (en) | 2020-01-17 | 2024-03-05 | Waters Technologies Corporation | Performance and dynamic range for oligonucleotide bioanalysis through reduction of non specific binding |
US12121829B2 (en) | 2020-02-25 | 2024-10-22 | Waters Technologies Corporation | Chromatographic seal and coated flow paths for minimizing analyte adsorption |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10300323A1 (en) * | 2003-01-09 | 2004-10-14 | Baxter Healthcare S.A. | Safety container filled with a biologically active substance, especially a cytostatic agent, is at least partially coated |
DE10131156A1 (en) * | 2001-06-29 | 2003-01-16 | Fraunhofer Ges Forschung | Articles with a plasma polymer coating and process for its production |
WO2003031362A1 (en) * | 2001-10-05 | 2003-04-17 | Dow Global Technologies Inc. | Coated glass for use in displays and other electronic devices |
DE10231698A1 (en) * | 2002-03-26 | 2003-10-23 | Fraunhofer Ges Forschung | Process for improving the transfer of additive material to support used in the production of printed circuit boards comprises using template having openings with coating for the structured transfer of the additive material to the support |
DE102006018491A1 (en) * | 2006-04-19 | 2007-10-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Flexible plasma polymer products, corresponding articles, manufacturing methods and use |
JP5001015B2 (en) * | 2006-09-28 | 2012-08-15 | 富士フイルム株式会社 | Biochemical instrument having a surface with reduced non-specific adsorption |
DE102006058771B4 (en) | 2006-12-12 | 2018-03-01 | Schott Ag | Container with improved emptiness and method for its production |
DE102009008766A1 (en) * | 2009-02-06 | 2010-08-12 | Optima Group Pharma Gmbh | Method for coating the inner surfaces of a glass container comprises relieving the pressure of a sterile vapor in the container, adding a determined amount of silicone oil and/or a water/silicone emulsion and further processing |
US20120018338A1 (en) * | 2009-03-30 | 2012-01-26 | Hoffman-La Roche Inc. | Method for avoiding glass fogging |
CN102349855A (en) * | 2011-06-23 | 2012-02-15 | 宁波正力药品包装有限公司 | Glass bottle with inorganic silicon membranous layer for medical packaging and production process thereof |
WO2013038119A2 (en) * | 2011-09-16 | 2013-03-21 | Rexam Healthcare La Verpilliere | Device for storing and dispensing liquid |
US20150136723A1 (en) * | 2012-05-28 | 2015-05-21 | Namicos Corporation | Glass container and method for manufacturing same |
DE102013103676A1 (en) * | 2013-04-11 | 2014-10-30 | Schott Ag | Containers with low particulate emission and frictionally controlled dry sliding surface, and process for its production |
US20170037568A1 (en) | 2015-08-05 | 2017-02-09 | Milliken & Company | Installation of Multi-Component Floor Mat |
US20180055266A1 (en) | 2016-08-24 | 2018-03-01 | Milliken & Company | Floor Mat with Hidden Base Component |
US20190099489A1 (en) * | 2017-09-29 | 2019-04-04 | Janssen Biotech, Inc. | Novel Formulations Which Stabilize Low Dose Antibody Compositions |
WO2019117267A1 (en) | 2017-12-15 | 2019-06-20 | ニプロ株式会社 | Medical glass container and method for manufacturing same |
EP3539887B1 (en) * | 2018-03-16 | 2021-05-26 | Schott AG | Hollow body, in particular for packaging a pharmaceutical composition, having a layer of glass and a surface region with a contact angle for wetting with water |
EP3560897B1 (en) | 2018-04-26 | 2021-11-24 | Schott AG | Process for making a functionalised hollow body, having a layer of glass, including a superposition of one or more siloxanes and contacting with a plasma |
EP3590896B1 (en) | 2018-05-18 | 2023-12-06 | SCHOTT Pharma AG & Co. KGaA | Glass container with an improved bottom geometry |
JPWO2020027220A1 (en) * | 2018-07-31 | 2021-08-02 | テルモ株式会社 | How to remove silicone oil when administering protein preparations |
US11806716B2 (en) * | 2019-12-20 | 2023-11-07 | Schott Pharma Ag & Co. Kgaa | Glass container comprising a glass bottom with improved properties |
Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2504482A (en) | 1949-06-17 | 1950-04-18 | Premo Pharmaceutical Lab Inc | Drain-clear container for aqueous-vehicle liquid pharmaceutical preparations |
US3939834A (en) * | 1974-09-24 | 1976-02-24 | Mcmahon Patrick J | Metal coated articles |
EP0252870A2 (en) | 1986-07-09 | 1988-01-13 | Battelle Memorial Institute | Abrasion-resistant plasma coatings |
GB2230260A (en) | 1989-01-17 | 1990-10-17 | United Glass Ltd | Strengthening of glass containers |
JPH05132065A (en) | 1991-11-05 | 1993-05-28 | Nichiden Rika Glass Hanbai Kk | Surface-treated glass bottle |
US5437894A (en) * | 1991-01-23 | 1995-08-01 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a water- and oil-repelling film having surface irregularities |
DE4438359A1 (en) | 1994-10-27 | 1996-05-02 | Schott Glaswerke | Plastic container with a barrier coating and process for its manufacture |
US5521351A (en) * | 1994-08-30 | 1996-05-28 | Wisconsin Alumni Research Foundation | Method and apparatus for plasma surface treatment of the interior of hollow forms |
DE4445427A1 (en) | 1994-12-20 | 1996-06-27 | Schott Glaswerke | Gradient layer |
EP0811367A2 (en) | 1996-06-05 | 1997-12-10 | Schott Glaswerke | Glass container particularly for storing pharmaceutical or diagnostic solutions |
US5702770A (en) * | 1996-01-30 | 1997-12-30 | Becton, Dickinson And Company | Method for plasma processing |
US5721027A (en) * | 1994-02-04 | 1998-02-24 | Tetra Laval Holdings & Finance S.A. | Package possessing superior barrier properties |
EP0881197A2 (en) | 1997-05-27 | 1998-12-02 | Leybold Systems GmbH | Method and apparatus for coating glass or plastic containers using PCVD for coating |
US5972436A (en) * | 1996-07-24 | 1999-10-26 | Schott Glaswerke | CVD process for coating the inside of hollow bodies |
US6143417A (en) * | 1996-04-04 | 2000-11-07 | Matsushita Electric Industrial Co., Ltd. | Contamination-resistant float glass |
US6180191B1 (en) * | 1996-10-08 | 2001-01-30 | Nano Scale Surface Systems, Inc. | Method for plasma deposition of a thin film onto a surface of a container |
-
1999
- 1999-05-07 DE DE19921303A patent/DE19921303C1/en not_active Expired - Fee Related
-
2000
- 2000-04-13 EP EP00108144A patent/EP1050517B1/en not_active Expired - Lifetime
- 2000-04-13 DE DE50000581T patent/DE50000581D1/en not_active Expired - Lifetime
- 2000-05-02 JP JP2000133348A patent/JP4351363B2/en not_active Expired - Lifetime
- 2000-05-04 US US09/564,758 patent/US6599594B1/en not_active Expired - Lifetime
-
2001
- 2001-05-03 HK HK01103139A patent/HK1032776A1/en not_active IP Right Cessation
Patent Citations (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2504482A (en) | 1949-06-17 | 1950-04-18 | Premo Pharmaceutical Lab Inc | Drain-clear container for aqueous-vehicle liquid pharmaceutical preparations |
US3939834A (en) * | 1974-09-24 | 1976-02-24 | Mcmahon Patrick J | Metal coated articles |
EP0252870A2 (en) | 1986-07-09 | 1988-01-13 | Battelle Memorial Institute | Abrasion-resistant plasma coatings |
GB2230260A (en) | 1989-01-17 | 1990-10-17 | United Glass Ltd | Strengthening of glass containers |
US5437894A (en) * | 1991-01-23 | 1995-08-01 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a water- and oil-repelling film having surface irregularities |
JPH05132065A (en) | 1991-11-05 | 1993-05-28 | Nichiden Rika Glass Hanbai Kk | Surface-treated glass bottle |
US5721027A (en) * | 1994-02-04 | 1998-02-24 | Tetra Laval Holdings & Finance S.A. | Package possessing superior barrier properties |
US5521351A (en) * | 1994-08-30 | 1996-05-28 | Wisconsin Alumni Research Foundation | Method and apparatus for plasma surface treatment of the interior of hollow forms |
DE4438359A1 (en) | 1994-10-27 | 1996-05-02 | Schott Glaswerke | Plastic container with a barrier coating and process for its manufacture |
DE4445427A1 (en) | 1994-12-20 | 1996-06-27 | Schott Glaswerke | Gradient layer |
US5702770A (en) * | 1996-01-30 | 1997-12-30 | Becton, Dickinson And Company | Method for plasma processing |
US6143417A (en) * | 1996-04-04 | 2000-11-07 | Matsushita Electric Industrial Co., Ltd. | Contamination-resistant float glass |
EP0811367A2 (en) | 1996-06-05 | 1997-12-10 | Schott Glaswerke | Glass container particularly for storing pharmaceutical or diagnostic solutions |
DE19622550A1 (en) | 1996-06-05 | 1997-12-11 | Schott Glaswerke | Glass containers, in particular for storing pharmaceutical or diagnostic solutions |
US5972436A (en) * | 1996-07-24 | 1999-10-26 | Schott Glaswerke | CVD process for coating the inside of hollow bodies |
US6180191B1 (en) * | 1996-10-08 | 2001-01-30 | Nano Scale Surface Systems, Inc. | Method for plasma deposition of a thin film onto a surface of a container |
EP0881197A2 (en) | 1997-05-27 | 1998-12-02 | Leybold Systems GmbH | Method and apparatus for coating glass or plastic containers using PCVD for coating |
US6242053B1 (en) * | 1997-05-27 | 2001-06-05 | Leybold Systems Gmbh | Process for coating plastic containers or glass containers by means of a PCVD coating process |
Non-Patent Citations (5)
Title |
---|
Derwent Abstract Translation of DE 196 29 877 (Derwent Acc No. 1997-181111).* * |
Dictionary of Chemistry, 2nd Ed., Penguin Books: London, 1990, pp. 357-359.* * |
JPO Abstract translation to Tokkyo Kokai JP-05-132065A (Clipped Image No. JP405132065A).* * |
M. Walther et al: "Multilayer Barrier Coating System Produced By Plasma-Inpulse Chemical Vapor Depoistion (PICVD)" Surface and Coating Technology, NL, Amsterdam, BD. 80, 1996, pp. 200-202, XP 002099295. |
Patent Abstract of Japan, C-1275 Nov. 17, 1994, vol. 18/No. 604. |
Cited By (128)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040199138A1 (en) * | 2001-07-21 | 2004-10-07 | Mcbay William Edward | Storage of liquid compositions |
US20110062047A1 (en) * | 2006-01-11 | 2011-03-17 | Daniel Haines | Method Of Preparing Macromolecule Deterrent Surface On a Pharmaceutical Packages |
US20070187280A1 (en) * | 2006-01-11 | 2007-08-16 | Daniel Haines | Method of preparing a macromolecule deterrent surface on a pharmaceutical package |
US8025915B2 (en) * | 2006-01-11 | 2011-09-27 | Schott Ag | Method of preparing a macromolecule deterrent surface on a pharmaceutical package |
US7877968B2 (en) | 2007-05-15 | 2011-02-01 | Kraft Foods Global Brands Llc | Method for forming a container with improved release properties |
EP1992567A2 (en) | 2007-05-15 | 2008-11-19 | Kraft Foods Holdings, Inc. | Container with Improved Release Properties |
US20080286480A1 (en) * | 2007-05-15 | 2008-11-20 | Kraft Foods Holdings, Inc. | Method For Forming A Container With Improved Release Properties |
US20080283483A1 (en) * | 2007-05-15 | 2008-11-20 | Kraft Foods Holdings, Inc. | Container With Improved Release Properties |
EP1992420A1 (en) | 2007-05-15 | 2008-11-19 | Kraft Foods Holdings, Inc. | Method of forming a container with improved release properties |
US8003178B2 (en) | 2007-05-15 | 2011-08-23 | Kraft Foods Global Brands Llc | Container with improved release properties |
US20160184183A1 (en) * | 2008-05-23 | 2016-06-30 | Hospira, Inc. | Packaged Iron Sucrose Products |
US20110226658A1 (en) * | 2008-05-23 | 2011-09-22 | Hospira, Inc. | Packaged Iron Sucrose Products |
US8834954B2 (en) | 2009-05-13 | 2014-09-16 | Sio2 Medical Products, Inc. | Vessel inspection apparatus and methods |
US8512796B2 (en) | 2009-05-13 | 2013-08-20 | Si02 Medical Products, Inc. | Vessel inspection apparatus and methods |
US7985188B2 (en) | 2009-05-13 | 2011-07-26 | Cv Holdings Llc | Vessel, coating, inspection and processing apparatus |
US10390744B2 (en) | 2009-05-13 | 2019-08-27 | Sio2 Medical Products, Inc. | Syringe with PECVD lubricity layer, apparatus and method for transporting a vessel to and from a PECVD processing station, and double wall plastic vessel |
US10537273B2 (en) | 2009-05-13 | 2020-01-21 | Sio2 Medical Products, Inc. | Syringe with PECVD lubricity layer |
US9572526B2 (en) | 2009-05-13 | 2017-02-21 | Sio2 Medical Products, Inc. | Apparatus and method for transporting a vessel to and from a PECVD processing station |
US9545360B2 (en) | 2009-05-13 | 2017-01-17 | Sio2 Medical Products, Inc. | Saccharide protective coating for pharmaceutical package |
US9458536B2 (en) | 2009-07-02 | 2016-10-04 | Sio2 Medical Products, Inc. | PECVD coating methods for capped syringes, cartridges and other articles |
US20110108551A1 (en) * | 2009-11-12 | 2011-05-12 | Postech Academy-Industry Foundation | Liquid container |
US11624115B2 (en) | 2010-05-12 | 2023-04-11 | Sio2 Medical Products, Inc. | Syringe with PECVD lubrication |
US9878101B2 (en) | 2010-11-12 | 2018-01-30 | Sio2 Medical Products, Inc. | Cyclic olefin polymer vessels and vessel coating methods |
US11123491B2 (en) | 2010-11-12 | 2021-09-21 | Sio2 Medical Products, Inc. | Cyclic olefin polymer vessels and vessel coating methods |
US9272095B2 (en) | 2011-04-01 | 2016-03-01 | Sio2 Medical Products, Inc. | Vessels, contact surfaces, and coating and inspection apparatus and methods |
US11707410B2 (en) | 2011-10-25 | 2023-07-25 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10441505B2 (en) | 2011-10-25 | 2019-10-15 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9517966B2 (en) | 2011-10-25 | 2016-12-13 | Corning Incorporated | Glass compositions with improved chemical and mechanical durability |
US11707408B2 (en) | 2011-10-25 | 2023-07-25 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US11707409B2 (en) | 2011-10-25 | 2023-07-25 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10413483B2 (en) | 2011-10-25 | 2019-09-17 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10413482B2 (en) | 2011-10-25 | 2019-09-17 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10413481B2 (en) | 2011-10-25 | 2019-09-17 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10577154B2 (en) | 2011-11-11 | 2020-03-03 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US11148856B2 (en) | 2011-11-11 | 2021-10-19 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US11116695B2 (en) | 2011-11-11 | 2021-09-14 | Sio2 Medical Products, Inc. | Blood sample collection tube |
US10189603B2 (en) | 2011-11-11 | 2019-01-29 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US11884446B2 (en) | 2011-11-11 | 2024-01-30 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US11724860B2 (en) | 2011-11-11 | 2023-08-15 | Sio2 Medical Products, Inc. | Passivation, pH protective or lubricity coating for pharmaceutical package, coating process and apparatus |
US9763852B2 (en) | 2012-02-28 | 2017-09-19 | Corning Incorporated | Glass articles with low-friction coatings |
US9775775B2 (en) | 2012-02-28 | 2017-10-03 | Corning Incorporated | Glass articles with low-friction coatings |
US11786441B2 (en) | 2012-02-28 | 2023-10-17 | Corning Incorporated | Glass articles with low-friction coatings |
US11737951B2 (en) | 2012-02-28 | 2023-08-29 | Corning Incorporated | Glass articles with low-friction coatings |
US9744099B2 (en) | 2012-02-28 | 2017-08-29 | Corning Incorporated | Glass articles with low-friction coatings |
US9668936B2 (en) | 2012-02-28 | 2017-06-06 | Corning Incorporated | Glass articles with low-friction coatings |
US10737973B2 (en) | 2012-02-28 | 2020-08-11 | Corning Incorporated | Pharmaceutical glass coating for achieving particle reduction |
US10034816B2 (en) | 2012-02-28 | 2018-07-31 | Corning Incorporated | Glass articles with low-friction coatings |
US11497681B2 (en) | 2012-02-28 | 2022-11-15 | Corning Incorporated | Glass articles with low-friction coatings |
US11007117B2 (en) | 2012-02-28 | 2021-05-18 | Corning Incorporated | Glass articles with low-friction coatings |
US11872189B2 (en) | 2012-02-28 | 2024-01-16 | Corning Incorporated | Glass articles with low-friction coatings |
US11020317B2 (en) | 2012-02-28 | 2021-06-01 | Corning Incorporated | Glass articles with low-friction coatings |
US11939259B2 (en) | 2012-02-28 | 2024-03-26 | Corning Incorporated | Pharmaceutical glass coating for achieving particle reduction |
US11071689B2 (en) | 2012-02-28 | 2021-07-27 | Corning Incorporated | Glass articles with low-friction coatings |
US9918898B2 (en) | 2012-02-28 | 2018-03-20 | Corning Incorporated | Glass articles with low-friction coatings |
US10273048B2 (en) | 2012-06-07 | 2019-04-30 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US9988174B2 (en) | 2012-06-07 | 2018-06-05 | Corning Incorporated | Delamination resistant glass containers |
US11124328B2 (en) | 2012-06-07 | 2021-09-21 | Corning Incorporated | Delamination resistant glass containers |
EP2861526A4 (en) * | 2012-06-18 | 2015-12-16 | Innova Dynamics Inc | Agglomerate reduction in a nanowire suspension stored in a container |
US20140231282A1 (en) * | 2012-06-18 | 2014-08-21 | Innova Dynamics, Inc. | Agglomerate reduction in a nanowire suspension stored in a container |
US11608290B2 (en) | 2012-06-28 | 2023-03-21 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US10787292B2 (en) | 2012-06-28 | 2020-09-29 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US9428302B2 (en) | 2012-06-28 | 2016-08-30 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US10273049B2 (en) | 2012-06-28 | 2019-04-30 | Corning Incorporated | Delamination resistant glass containers with heat-tolerant coatings |
US10011391B2 (en) * | 2012-09-26 | 2018-07-03 | Katholieke Universiteit Leuven | Bottles with means to prevent gushing |
US20150197371A1 (en) * | 2012-09-26 | 2015-07-16 | Katholieke Universiteit Leuven | Bottles with means to prevent gushing |
US9664626B2 (en) | 2012-11-01 | 2017-05-30 | Sio2 Medical Products, Inc. | Coating inspection method |
US9903782B2 (en) | 2012-11-16 | 2018-02-27 | Sio2 Medical Products, Inc. | Method and apparatus for detecting rapid barrier coating integrity characteristics |
US10117806B2 (en) | 2012-11-30 | 2018-11-06 | Corning Incorporated | Strengthened glass containers resistant to delamination and damage |
US10307334B2 (en) | 2012-11-30 | 2019-06-04 | Corning Incorporated | Glass containers with delamination resistance and improved damage tolerance |
US10363370B2 (en) | 2012-11-30 | 2019-07-30 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition |
US9346707B2 (en) | 2012-11-30 | 2016-05-24 | Corning Incorporated | Methods for forming delamination resistant glass containers |
US9272946B2 (en) | 2012-11-30 | 2016-03-01 | Corning Incorporated | Glass containers with delamination resistance and improved strength |
RU2634133C2 (en) * | 2012-11-30 | 2017-10-24 | Корнинг Инкорпорейтед | Containers of a strengthened borosilicate glass with increased damage tolerance |
US9764093B2 (en) | 2012-11-30 | 2017-09-19 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition |
US11406765B2 (en) | 2012-11-30 | 2022-08-09 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition |
US10507164B2 (en) | 2012-11-30 | 2019-12-17 | Corning Incorporated | Glass containers with improved strength and improved damage tolerance |
US10307333B2 (en) | 2012-11-30 | 2019-06-04 | Corning Incorporated | Glass containers with delamination resistance and improved damage tolerance |
US10201660B2 (en) | 2012-11-30 | 2019-02-12 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition on medical syringes, cartridges, and the like |
US11963927B2 (en) | 2012-11-30 | 2024-04-23 | Corning Incorporated | Glass containers with delamination resistance and improved damage tolerance |
US11951072B2 (en) | 2012-11-30 | 2024-04-09 | Corning Incorporated | Glass containers with improved strength and improved damage tolerance |
TWI629980B (en) * | 2012-11-30 | 2018-07-21 | 康寧公司 | Methods for forming delamination resistant glass containers |
US9034442B2 (en) | 2012-11-30 | 2015-05-19 | Corning Incorporated | Strengthened borosilicate glass containers with improved damage tolerance |
US10786431B2 (en) | 2012-11-30 | 2020-09-29 | Corning Incorporated | Glass containers with delamination resistance and improved damage tolerance |
US10023495B2 (en) | 2012-11-30 | 2018-07-17 | Corning Incorporated | Glass containers with improved strength and improved damage tolerance |
US10813835B2 (en) | 2012-11-30 | 2020-10-27 | Corning Incorporated | Glass containers with improved strength and improved damage tolerance |
WO2014116401A1 (en) | 2013-01-22 | 2014-07-31 | General Electric Company | Apparatus for storage and sampling of de-ionized water samples and the like |
US9662450B2 (en) | 2013-03-01 | 2017-05-30 | Sio2 Medical Products, Inc. | Plasma or CVD pre-treatment for lubricated pharmaceutical package, coating process and apparatus |
US10537494B2 (en) | 2013-03-11 | 2020-01-21 | Sio2 Medical Products, Inc. | Trilayer coated blood collection tube with low oxygen transmission rate |
US10912714B2 (en) | 2013-03-11 | 2021-02-09 | Sio2 Medical Products, Inc. | PECVD coated pharmaceutical packaging |
US9554968B2 (en) | 2013-03-11 | 2017-01-31 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging |
US10016338B2 (en) | 2013-03-11 | 2018-07-10 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging |
US9937099B2 (en) | 2013-03-11 | 2018-04-10 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging with low oxygen transmission rate |
US11344473B2 (en) | 2013-03-11 | 2022-05-31 | SiO2Medical Products, Inc. | Coated packaging |
US11298293B2 (en) | 2013-03-11 | 2022-04-12 | Sio2 Medical Products, Inc. | PECVD coated pharmaceutical packaging |
US11684546B2 (en) | 2013-03-11 | 2023-06-27 | Sio2 Medical Products, Inc. | PECVD coated pharmaceutical packaging |
US9863042B2 (en) | 2013-03-15 | 2018-01-09 | Sio2 Medical Products, Inc. | PECVD lubricity vessel coating, coating process and apparatus providing different power levels in two phases |
US9849066B2 (en) | 2013-04-24 | 2017-12-26 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9717648B2 (en) | 2013-04-24 | 2017-08-01 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9713572B2 (en) | 2013-04-24 | 2017-07-25 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9700486B2 (en) | 2013-04-24 | 2017-07-11 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9717649B2 (en) | 2013-04-24 | 2017-08-01 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9839579B2 (en) | 2013-04-24 | 2017-12-12 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707153B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9700485B2 (en) | 2013-04-24 | 2017-07-11 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9603775B2 (en) | 2013-04-24 | 2017-03-28 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707154B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US9707155B2 (en) | 2013-04-24 | 2017-07-18 | Corning Incorporated | Delamination resistant pharmaceutical glass containers containing active pharmaceutical ingredients |
US10654069B2 (en) | 2013-05-24 | 2020-05-19 | BSH Hausgeräte GmbH | Coating of usage surfaces with plasma polymer layers under atmospheric pressure in order to improve the cleanability |
US20160251261A1 (en) * | 2014-03-13 | 2016-09-01 | Stevanato Group International A.S. | Method of Handling a Liquid Drug Formation |
US11066745B2 (en) | 2014-03-28 | 2021-07-20 | Sio2 Medical Products, Inc. | Antistatic coatings for plastic vessels |
US10899659B2 (en) | 2014-09-05 | 2021-01-26 | Corning Incorporated | Glass articles and methods for improving the reliability of glass articles |
US11807570B2 (en) | 2014-09-05 | 2023-11-07 | Corning Incorporated | Glass articles and methods for improving the reliability of glass articles |
US10065884B2 (en) | 2014-11-26 | 2018-09-04 | Corning Incorporated | Methods for producing strengthened and durable glass containers |
US11077233B2 (en) | 2015-08-18 | 2021-08-03 | Sio2 Medical Products, Inc. | Pharmaceutical and other packaging with low oxygen transmission rate |
US11208348B2 (en) | 2015-09-30 | 2021-12-28 | Corning Incorporated | Halogenated polyimide siloxane chemical compositions and glass articles with halogenated polyimide siloxane low-friction coatings |
US11772846B2 (en) | 2015-10-30 | 2023-10-03 | Corning Incorporated | Glass articles with mixed polymer and metal oxide coatings |
US12103734B2 (en) | 2015-10-30 | 2024-10-01 | Corning Incorporated | Glass articles with mixed polymer and metal oxide coatings |
US12110151B2 (en) | 2015-10-30 | 2024-10-08 | Corning Incorporated | Glass articles with mixed polymer and metal oxide coatings |
US10626047B2 (en) | 2016-10-18 | 2020-04-21 | Owens-Brockway Glass Container Inc. | Glass container coating process |
US11709156B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved analytical analysis |
US11709155B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved chromatography of metal interacting analytes |
US11014701B2 (en) | 2018-05-18 | 2021-05-25 | Schott Ag | Glass container with an improved bottom geometry |
US11918936B2 (en) | 2020-01-17 | 2024-03-05 | Waters Technologies Corporation | Performance and dynamic range for oligonucleotide bioanalysis through reduction of non specific binding |
US12121829B2 (en) | 2020-02-25 | 2024-10-22 | Waters Technologies Corporation | Chromatographic seal and coated flow paths for minimizing analyte adsorption |
EP4063334A1 (en) * | 2021-03-25 | 2022-09-28 | Schott Ag | Coated glass element |
WO2022200623A1 (en) * | 2021-03-25 | 2022-09-29 | Schott Ag | Pharmaceutical container |
EP4067319A3 (en) * | 2021-03-25 | 2022-10-26 | Schott Ag | Coated glass element |
EP4067318A3 (en) * | 2021-03-25 | 2022-10-26 | Schott Ag | Coated glass element |
Also Published As
Publication number | Publication date |
---|---|
EP1050517B1 (en) | 2002-10-02 |
JP2000350770A (en) | 2000-12-19 |
HK1032776A1 (en) | 2001-08-03 |
US20030134060A1 (en) | 2003-07-17 |
DE19921303C1 (en) | 2000-10-12 |
JP4351363B2 (en) | 2009-10-28 |
EP1050517A1 (en) | 2000-11-08 |
DE50000581D1 (en) | 2002-11-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6599594B1 (en) | Glass container for medicinal purposes | |
JP5197625B2 (en) | Container with improved ease of discharge of product residue (EASEOFDISCHARGEPRODUCTRESIDUE) and manufacturing method thereof | |
AU740485B2 (en) | Container with material coating having barrier effect and method and apparatus for making same | |
US5833752A (en) | Manifold system | |
JP5362941B2 (en) | Composite materials with improved chemical resistance | |
US6001429A (en) | Apparatus and method for plasma processing | |
EP0794007A1 (en) | Blood collection tube assembly | |
WO2017087032A1 (en) | Polymeric substrate with a surface having reduced biomolecule adhesion, and thermoplastic articles of such substrate | |
US6171652B1 (en) | Method for modifying surfaces with ultra thin films | |
JP4566719B2 (en) | Carbon film coated plastic container manufacturing method, plasma CVD film forming apparatus and plastic container | |
JP2006224992A (en) | Plastic container coated with gas barrier membrane, its manufacturing device, and its manufacturing method | |
JP2021519387A (en) | Containers, containers, and surfaces coated with a water barrier coating | |
US20040076836A1 (en) | Barrier coating | |
US6171450B1 (en) | Method for plasma treatment in hollow bodies | |
JP2019513898A (en) | Method of applying a PECVD lubricant layer using a movable gas inlet | |
US20020182319A1 (en) | Method for depositing a coating on the wall of metallic containers | |
CN111479544A (en) | Medical glass container and method for manufacturing same | |
CN114174236B (en) | Glass with coating film, method for producing same, and modified glass substrate | |
WO2019117267A1 (en) | Medical glass container and method for manufacturing same | |
DE29923238U1 (en) | Glass containers for medical purposes | |
JP2001220679A (en) | Film deposition system and film deposition method | |
WO2024056302A1 (en) | Treatment of a glass container | |
US20190118220A1 (en) | Method for the Production of a Layer for Coating the Plastic Inner Surface of a Receptacle, and Receptacle Obtained by a Method of Said Type |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SCHOTT GLAS, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WALTHER, MARTEN;GEIGER, ANDREAS;AUCHTER-KRUMMEL, PETRA;AND OTHERS;REEL/FRAME:011236/0623;SIGNING DATES FROM 20000824 TO 20000913 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
AS | Assignment |
Owner name: SCHOTT AG, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SCHOTT GLAS;REEL/FRAME:015766/0926 Effective date: 20050209 Owner name: SCHOTT AG,GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SCHOTT GLAS;REEL/FRAME:015766/0926 Effective date: 20050209 |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |