US6441305B1 - High temperature slip-sealing grommet systems - Google Patents
High temperature slip-sealing grommet systems Download PDFInfo
- Publication number
- US6441305B1 US6441305B1 US09/672,385 US67238500A US6441305B1 US 6441305 B1 US6441305 B1 US 6441305B1 US 67238500 A US67238500 A US 67238500A US 6441305 B1 US6441305 B1 US 6441305B1
- Authority
- US
- United States
- Prior art keywords
- grommet
- slip
- shaped
- end region
- cup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02G—INSTALLATION OF ELECTRIC CABLES OR LINES, OR OF COMBINED OPTICAL AND ELECTRIC CABLES OR LINES
- H02G15/00—Cable fittings
- H02G15/02—Cable terminations
- H02G15/04—Cable-end sealings
- H02G15/043—Cable-end sealings with end caps, e.g. sleeve closed at one end
- H02G15/046—Cable-end sealings with end caps, e.g. sleeve closed at one end with bores or protruding portions allowing passage of cable conductors
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02G—INSTALLATION OF ELECTRIC CABLES OR LINES, OR OF COMBINED OPTICAL AND ELECTRIC CABLES OR LINES
- H02G15/00—Cable fittings
- H02G15/013—Sealing means for cable inlets
Definitions
- This invention relates to sealing systems for sealing an electrical cable against leakage from ambient. More particularly, the present invention relates to an improved high temperature slip-sealing grommet systems for preventing leakage at splices and cable ends of electrical cables such as heating cables over extended high temperature operating intervals and cool down periods.
- elongate cables such as power cords or heating cables often must be sealed from the ambient in order to provide electrical insulation, environmental protection, leakage from an ambient fluid medium such as moisture or other liquids, and/or mechanical shielding.
- Many methods and devices have been used to provide a seal, including heat-recoverable tubing, end-caps, or boots; molded adhesive-filled boots; enclosures with gaskets or grommet seals; and wrapped tape.
- a sealing device for an elongate heating cable is provided in the U.S. Pat. No. 5,792,987 entitled “Sealing Device”, by the present inventor and others, the disclosure thereof being incorporated herein by reference.
- an electrical cable such as a trace heating cable is slipped through a pressure plate 12 , a spring 14 , a rigid compression ring 16 , a silicone rubber grommet 18 , and a back shim 20 before reaching an enclosed interior space of an enclosure body 22 wherein the cable end terminates or may be spliced to another cable end.
- the enclosure body 22 includes an annular shoulder projection inset from its opening which engages a peripheral region and thereby retains the back shim 20 against further axial displacement as the assembly is pushed into the enclosure body 22 . While present, this projection is not shown in the FIG. 1 illustration. Screws 24 are used to drive the pressure plate inwardly towards the enclosure body 22 , which compresses the spring 14 and grommet 18 .
- the spring 14 comprised a crest-to-crest five-turn, half-inch free height spring, such as a Smalley SpirawaveTM C087-H3 spring having a theoretical spring rate (lbs/in) of 180.
- grommet 18 expands radially against both the heating cable and an interior wall of the enclosure body 22 thereby nominally sealing the heating cable to the grommet 18 , and the grommet to the enclosure body 22 .
- Silicone rubber is widely used as a high temperature elastomer. Although its mechanical properties are not unduly affected by exposure to high temperatures (temperatures above 200° C., for example), silicone rubber may adhesively bond at such high temperatures to certain engineering plastics such as polyphenylene sulfide (PPS). If a silicone rubber grommet, such as grommet 18 , bonds to an enclosure body 22 formed of PPS, the grommet 18 is no longer free to move in response to applied stress and cannot continue to maintain a seal. This behavior has been noted in the S-150-E trace heating cable splice kit 10 illustrated in FIG. 1 .
- PPS polyphenylene sulfide
- the process by which the splice kit 10 loses its seal is as follows. First, the seal kit 10 is assembled onto the heating cable and inserted into the enclosure body 22 . The completed assembly is then subjected to a high temperature, e.g. in excess of 200° C. The assembly components expand in response to the high temperature.
- the volume thermal expansion coefficient of silicone rubber is about three times that of engineering plastics such as glass-filled PPS over the range of temperatures encountered in service. Consequently, the only direction for the silicone rubber grommet 18 to expand is longitudinally along the enclosure body 22 toward the pressure plate in the FIG. 1 example, because the grommet 18 is constrained longitudinally by the back shim and enclosure body but may move longitudinally toward the pressure plate 12 by further compression of the spring 14 .
- the silicone rubber of the grommet 18 adhesively bonds to plastic parts like the PPS enclosure body 22 , but does not adhere to the fluoropolymer outer jacket of the heating cable.
- the silicone rubber grommet 18 shrinks back to its original volume.
- the grommet 18 cannot shrink longitudinally. The only remaining dimension for the material to shrink is radially, and it does so, pulling away from the heating cable outer jacket, and forming a leakage path between the cable jacket and the grommet 18 . This unwanted tendency to develop leakage paths has become increasingly acute in the face of modern industry-initiated uniform testing standards which now require testing of heating cables over extended times at temperatures in excess of 200° C.
- a general object of the present invention is to provide a heating cable sealing kit and assembly for an electrical cable such as a heating cable which does not develop leakage paths over time-extended high temperature cycles and which can be made out of molded plastic and silicone rubber materials which withstand high temperatures.
- Another object of the present invention is to provide a high temperature slip-seal grommet system which includes a slip-plane formed at adjacently confronting cone-cup shaped surfaces for more perfectly translating axial force into radial compression force and for permitting relative slippage of an elastomeric grommet along the slip-plane without becoming entirely axially bonded to an enclosure body over high temperature operational cycles and thereby preventing unwanted leakage at an interface with a heating cable jacket in a manner overcoming limitations and drawbacks of prior grommet systems and methods.
- One more object of the present invention is to provide a kit of parts for assembly by a craft worker into a sealing system for sealing an end region of an elongate heating cable received through a central longitudinal opening, the kit of parts including a high temperature elastomeric grommet forming a slip-plane relative to a spring-loaded cup-shaped member.
- the present invention comprises a seal kit forming a seal assembly for an elongate electrical cable such as a heating cable.
- the kit essentially includes a shaped elastomeric grommet, several molded plastic parts, and a compression spring.
- the compression grommet forms a sealing interface between itself and a molded plastic enclosure body and between itself and an outer jacket of a heating cable.
- electrically live ends of the cable can be effectively sealed within a sealed interior space of the enclosure body.
- a cup-shaped surface of a molded plastic part adjacently facing a congruent cone-shaped surface of the elastomeric grommet forms a slip-plane.
- the compression spring stores mechanical energy which is transferred to compress the elastomeric grommet and to cause it to expand radially against an interior wall of the enclosure body and against an outer jacket of the electrical cable.
- the cup-shaped surface slips over an outer region of the elastomeric grommet and prevents that region from becoming bonded over a high temperature operating interval to the inside wall of the enclosure body.
- the elastomeric grommet is thereby permitted to shrink longitudinally by slippage along the slip-plane formed at the cup-shaped surface, thereby maintaining a radial seal against the outer jacket of the electrical cable.
- an apparatus for sealing an end region of an elongate cable such as a heating cable.
- the apparatus receives the heating cable through a central longitudinal opening, and includes an enclosure body of molded plastic material defining at least a first open end region leading to a fully-enclosed interior space for the cable end.
- the open end region of the body has a spring force stopping structure and defines an interior wall surface.
- a pressure plate formed of rigid material is releasably secured to cover and close the open end region of the body.
- a compression spring applies a longitudinal compression force between the pressure plate and the spring force stopping structure.
- the grommet includes at least one generally cone-shaped face confronting a cup-shaped face of a structural member within a compression path between the pressure plate and the spring force stopping structure, thereby creating a slip-surface.
- the cup-shaped geometry of the member at the slip-surface prevents the grommet from becoming bonded over a high temperature operating interval to the inside wall of the body.
- the compression spring lies between the pressure plate and a rigid molded plastic shim forming the cup-shaped structural member.
- the cup-shaped structural member is a shim of slippery plastic material imposed between the elastomeric grommet and a compression ring within the compression path.
- the cup-shaped structural member is integrally formed with the spring force stopping structure.
- the spring force stopping structure is an end wall of the body opposite the open end, and the compression spring seats directly against the end wall and engages a rigid molded plastic shim forming the cup-shaped structural member.
- FIG. 1 is an exploded isometric view of sealing end portion of a sealing grommet system for preventing leakage at splices and cable ends of electrical trace heating cables in accordance with the prior art;
- FIG. 2 is an axially-exploded isometric view of an end assembly of a high temperature slip-sealing grommet system for preventing leakage at splices and cable ends of electrical trace heating cables in accordance with principles of the present invention
- FIG. 3 is a plan view of the FIG. 2 high temperature slip-sealing assembly with portions broken away to show placement of the structural elements thereof;
- FIG. 4 is a view in elevation and section of the FIG. 2 assembly, taken along line 4 — 4 in FIG. 3;
- FIG. 5 is an exploded isometric assembly view of a cable sealing system having a FIG. 2 high temperature slip-sealing assembly at each end;
- FIG. 6 is a diagrammatic isometric view of the FIG. 5 system showing use of the system in making a heating cable splice
- FIG. 7 is an exploded isometric view of the FIG. 5 system with a top half portion of the enclosure body removed to show an arrangement of internal components;
- FIG. 8 is an axially-exploded isometric view of a sealing end portion of another high temperature sealing grommet system for preventing leakage at splices and cable ends of electrical trace heating cables in accordance with principles of the present invention.
- FIG. 9 is a view in elevation and section of a further high temperature sealing grommet system for preventing leakage at splices and cable ends of electrical trace heating cables in accordance with principles of the present invention.
- one embodiment of a high temperature slip-sealing grommet system 100 comprises an assembly including a pressure plate 102 , an enclosure body 104 , an impact plate 106 , a spring 108 , a cup-shaped compression ring 110 , a cone-shaped elastomeric grommet 112 , a rigid shim 114 which abuts a ledge 116 extending inwardly within an interior space of the enclosure body 104 .
- Threaded screws 122 pass through sized openings in the pressure plate 102 and into threaded openings 124 of the enclosure body 104 in order to complete assembly of grommet system 100 .
- a cable clamp comprising upper clamp plate 126 , lower clamp plate 128 and ledges 130 of pressure plate 102 clamp the heating cable 134 securely to the pressure plate. Screws 132 extend through the upper clamp plate 126 and ledges 130 , and thread into openings in lower clamp plate 128 , in order to secure the cable clamp subassembly to the cable 134 and to the pressure plate 102 .
- the cone-shaped elastomeric grommet 112 is molded of a heat cured silicone rubber elastomeric material such as a General Electric no-post-cure SE series material having heat-aged properties as follows: 43 Shore A; 938 tensile strength in psi; and, 379 elongation percentage.
- the grommet 112 includes a generally cone-shaped surface 118 which directly confronts a cup-shaped surface 120 of the cup-shaped compression ring 110 , thereby forming a slip-plane 115 .
- a heat cured silicone rubber elastomeric material such as a General Electric no-post-cure SE series material having heat-aged properties as follows: 43 Shore A; 938 tensile strength in psi; and, 379 elongation percentage.
- the grommet 112 includes a generally cone-shaped surface 118 which directly confronts a cup-shaped surface 120 of the cup-shaped compression ring 110 , thereby forming a slip-plane 115 .
- the grommet 112 includes a relatively narrow annular peripheral ring region 136 adjacent the rigid shim 114 which forms a primary seal with a facing interior wall surface 105 of the enclosure body 104 .
- a main cylindrical region 138 of the grommet 112 lies between the ring region 136 and the generally cone-shaped region 118 and the main region is slightly relieved or inset relative to the narrow ring region 136 .
- the cup-shaped compression ring 110 is molded of a non-adhering moldable material, preferably a perfluropolymer, such as Hyflon MFA 640 or MFA 680 produced by Ausimont.
- a perfluropolymer such as Hyflon MFA 640 or MFA 680 produced by Ausimont.
- the applied axial force is thereby converted more efficiently into radial force, and the portion of the grommet 112 engaging the cup-shaped surface 120 of the compression ring 110 is prevented from sticking to and bonding to the interior wall surface of the enclosure body 104 in a manner overcoming the limitations and drawbacks of the prior approach described hereinabove in connection with the FIG. 1 illustration.
- the pressure plate 102 , enclosure body 104 , rigid shim 114 , upper clamp 126 and lower clamp 128 are most preferably molded of a high temperature thermoplastic resin material, such as polyphenylene sulfide, which is capable of withstanding relatively high operating temperatures emitted from an elongate heating cable 134 (see FIG. 6) without deformation or decomposition.
- the impact plate 106 is preferably formed of a stainless steel having a thickness (e.g. 0.033 inch) sufficient to spread the force of compression spring 108 across a face of the pressure plate 102 .
- the spring 108 is most preferably a crest-to-crest stainless steel flat wire compression spring, such as a Smalley SpirawaveTM CS-087-H6 9-turn spring having a free height of 0.750 inch, 3.5 waves per coil and a theoretical spring rate (lbs/in) of 104. Following assembly of the system 100 , this spring 108 is more heavily compressed and therefore applies a greater axial force than applied by the spring 14 of the prior system 10 shown in FIG. 1 .
- a crest-to-crest stainless steel flat wire compression spring such as a Smalley SpirawaveTM CS-087-H6 9-turn spring having a free height of 0.750 inch, 3.5 waves per coil and a theoretical spring rate (lbs/in) of 104.
- a compression ring 110 of non-adhering material such as polytetrafluoroethylene (PTFE or TeflonTM)
- PTFE polytetrafluoroethylene
- TeflonTM polytetrafluoroethylene
- the compression ring 110 is able to compress the grommet 112 and to convert axial spring force into radial (circumferential) compressive force around the perimeter of the heating cable 134 .
- a narrow annular part 136 of the grommet 112 is permitted to be in direct contact with a facing interior wall surface 105 of the enclosure body 104 . Bonding of this narrow annular region 136 of the grommet to the PPS material of the facing interior wall surface 105 may occur at high temperatures and may improve the quality of the seal.
- FIG. 1 Sealing performance at high temperatures (such as 240° C.) is greatly improved by addition of the slip-plane 115 formed between the cup-shaped surface 120 of compression ring 110 and generally-cone-shaped surface 118 of the elastomeric grommet 112 .
- a version of the FIG. 1 conventional grommet system 10 was found to seal only for approximately 50-100 hours aging at 215° C., while an example of the FIGS. 2 to 7 grommet system 100 with the slip-plane 115 and a somewhat increased spring force was found to seal up to 589 hours at a higher operating temperature of 240° C.
- the enclosure body 104 alternatively may be formed of a non-adhering material such as PTFE, or a PTFE insert may be provided at the region of system 100 .
- the PTFE insert may be molded or bonded to, or threaded onto, the inside wall of the end region of enclosure body 104 to prevent leakage, and provide a second, axial slip-plane relative to the elastomeric grommet 112 .
- the enclosure body 104 may be configured to provide an end seal for the elongate heating cable 134 , or it may form a container for a splice, as shown in FIGS. 5 to 7 .
- the body 104 A is elongated and has two slip-seal grommet systems 100 and 100 A, wherein the elements of system 100 A correspond directly to like elements of the system 100 and bear the same reference numerals with a suffix “A”.
- Two molded cable insulators 136 slip over stripped ends of the heating cables to be joined. The stripped ends are then locked into contact pairs of a splice block 138 , which also includes a contact pair for a ground braid of the heating cable (if present, as shown in FIG. 6, for example).
- the splice block 138 is moved to a central axial region of the interior space of enclosure body (FIG.
- each slip-seal grommet system 100 , 100 A is completed by threading screws 122 , 122 A into corresponding threads 124 , 124 A, thereby compressing spring 108 , 108 A and causing grommet 112 to engage the outer jacket of cable 134 and the facing interior wall 105 of enclosure body 104 A.
- FIG. 8 illustrates an alternative high temperature slip-sealing grommet system 200 in which the compression ring 110 has been replaced with a cone-cup-shaped ring 111 formed of suitable high temperature plastic such as PPS and a thin shaped slip-plane member 113 formed of a non-adhering moldable material, preferably similar to the perfluropolymer used to form the compression ring 110 .
- the cone-cup-shaped member 111 uses less material than the compression ring 110 , and thereby achieves some incremental cost savings, since perfluropolymer materials tend to be relatively expensive.
- the system 200 is the system 100 , and the same explanations given for the system 100 apply to the same elements found in the system 200 which have the same reference numerals as applied to elements of the system 100 .
- FIG. 9 illustrates another preferred embodiment of the present invention, particularly for cable end seals where there is no need for a splice block.
- a housing 304 includes a distal wall 306 which is opposite an opening closed by a pressure plate 302 .
- the spring 108 seats at one end against an inside surface of wall 306 and applies compressive force to compression ring 110 which is placed onto an end of cable 134 oppositely of the orientation used in the FIGS. 2 to 7 system 100 .
- Elastomeric grommet 112 is also placed oppositely onto the cable end.
- the pressure plate 302 defines an outer shim region 314 which bears against the reversed grommet 112 when the pressure plate 302 is attached to the body 304 via screws 122 and threaded openings 324 .
Landscapes
- Insulating Bodies (AREA)
- Cable Accessories (AREA)
- Insulators (AREA)
- Gasket Seals (AREA)
Abstract
Description
Claims (16)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/672,385 US6441305B1 (en) | 2000-09-28 | 2000-09-28 | High temperature slip-sealing grommet systems |
EP01975388A EP1410478B1 (en) | 2000-09-28 | 2001-09-25 | High temperature slip-sealing grommet systems |
AT01975388T ATE371978T1 (en) | 2000-09-28 | 2001-09-25 | ARRANGEMENTS WITH SLIDING SEAL BUSHING AT HIGH TEMPERATURES |
DE60130267T DE60130267T2 (en) | 2000-09-28 | 2001-09-25 | ARRANGEMENT WITH GASKET BUSHING AT HIGH TEMPERATURES |
PCT/US2001/030045 WO2002027884A2 (en) | 2000-09-28 | 2001-09-25 | High temperature slip-sealing grommet systems |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/672,385 US6441305B1 (en) | 2000-09-28 | 2000-09-28 | High temperature slip-sealing grommet systems |
Publications (1)
Publication Number | Publication Date |
---|---|
US6441305B1 true US6441305B1 (en) | 2002-08-27 |
Family
ID=24698324
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/672,385 Expired - Lifetime US6441305B1 (en) | 2000-09-28 | 2000-09-28 | High temperature slip-sealing grommet systems |
Country Status (5)
Country | Link |
---|---|
US (1) | US6441305B1 (en) |
EP (1) | EP1410478B1 (en) |
AT (1) | ATE371978T1 (en) |
DE (1) | DE60130267T2 (en) |
WO (1) | WO2002027884A2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6521840B1 (en) * | 1999-10-08 | 2003-02-18 | Roxtec Ab | Cable penetration device |
US9954347B1 (en) * | 2017-06-19 | 2018-04-24 | Delphi Technologies, Inc. | Wire harness assembly and seal retainer therefore |
CN116598973A (en) * | 2023-07-17 | 2023-08-15 | 江苏泽润新能科技股份有限公司 | Watertight junction box |
CN117629429A (en) * | 2023-11-30 | 2024-03-01 | 北京锦驰泰达科技有限公司 | Intelligent temperature measuring terminal for power distribution |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019125760A1 (en) * | 2019-09-25 | 2021-03-25 | Connect Com GmbH | Sealing device with a sealing body with a narrowing contour |
DE102019125761A1 (en) * | 2019-09-25 | 2021-03-25 | Connect Com GmbH | Sealing device with a spring in a distributor housing |
DE102019125758A1 (en) * | 2019-09-25 | 2021-03-25 | Connect Com GmbH | Sealing device with a hard sealing body |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847447A (en) * | 1987-06-11 | 1989-07-11 | Heidelberger Druckmaschinen Ag | Protective device for a cable end |
US4877943A (en) * | 1988-12-08 | 1989-10-31 | Raychem Corporation | Sealing device for elongate heater |
US5098752A (en) * | 1990-04-17 | 1992-03-24 | Raychem Corporation | Recoverable elastomeric sleeve and method for installation and use |
US5170008A (en) * | 1991-08-29 | 1992-12-08 | International Business Machines Corp. | External cable grommet for cable entry of EMI protected cabinets |
GB2269945A (en) * | 1992-08-18 | 1994-02-23 | Cooper Ind Inc | Conductive grommet |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5502282A (en) * | 1993-08-11 | 1996-03-26 | Siemens Aktiengesellschaft | Sleeve head for a cable sleeve having a seal insert composed of elastic material |
US5510576A (en) * | 1993-11-29 | 1996-04-23 | Northern Telecom Limited | Telecommunications cable enclosure |
FR2728047B1 (en) * | 1994-12-12 | 1997-04-30 | Aeg Schneider Automation | WATERPROOF CONNECTION FOR CABLE CROSSING |
US5792987A (en) * | 1995-08-28 | 1998-08-11 | Raychem Corporation | Sealing device |
-
2000
- 2000-09-28 US US09/672,385 patent/US6441305B1/en not_active Expired - Lifetime
-
2001
- 2001-09-25 AT AT01975388T patent/ATE371978T1/en not_active IP Right Cessation
- 2001-09-25 DE DE60130267T patent/DE60130267T2/en not_active Expired - Lifetime
- 2001-09-25 EP EP01975388A patent/EP1410478B1/en not_active Expired - Lifetime
- 2001-09-25 WO PCT/US2001/030045 patent/WO2002027884A2/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4847447A (en) * | 1987-06-11 | 1989-07-11 | Heidelberger Druckmaschinen Ag | Protective device for a cable end |
US4877943A (en) * | 1988-12-08 | 1989-10-31 | Raychem Corporation | Sealing device for elongate heater |
US5098752A (en) * | 1990-04-17 | 1992-03-24 | Raychem Corporation | Recoverable elastomeric sleeve and method for installation and use |
US5170008A (en) * | 1991-08-29 | 1992-12-08 | International Business Machines Corp. | External cable grommet for cable entry of EMI protected cabinets |
GB2269945A (en) * | 1992-08-18 | 1994-02-23 | Cooper Ind Inc | Conductive grommet |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6521840B1 (en) * | 1999-10-08 | 2003-02-18 | Roxtec Ab | Cable penetration device |
US9954347B1 (en) * | 2017-06-19 | 2018-04-24 | Delphi Technologies, Inc. | Wire harness assembly and seal retainer therefore |
CN116598973A (en) * | 2023-07-17 | 2023-08-15 | 江苏泽润新能科技股份有限公司 | Watertight junction box |
CN116598973B (en) * | 2023-07-17 | 2023-09-26 | 江苏泽润新能科技股份有限公司 | Watertight junction box |
CN117629429A (en) * | 2023-11-30 | 2024-03-01 | 北京锦驰泰达科技有限公司 | Intelligent temperature measuring terminal for power distribution |
CN117629429B (en) * | 2023-11-30 | 2024-05-03 | 北京锦驰泰达科技有限公司 | Intelligent temperature measuring terminal for power distribution |
Also Published As
Publication number | Publication date |
---|---|
EP1410478B1 (en) | 2007-08-29 |
EP1410478A2 (en) | 2004-04-21 |
DE60130267D1 (en) | 2007-10-11 |
ATE371978T1 (en) | 2007-09-15 |
WO2002027884A2 (en) | 2002-04-04 |
WO2002027884A3 (en) | 2002-07-11 |
DE60130267T2 (en) | 2008-05-29 |
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