US5981434A - Herbicidal composition for the control of epiphytic weeds - Google Patents

Herbicidal composition for the control of epiphytic weeds Download PDF

Info

Publication number
US5981434A
US5981434A US09/090,503 US9050398A US5981434A US 5981434 A US5981434 A US 5981434A US 9050398 A US9050398 A US 9050398A US 5981434 A US5981434 A US 5981434A
Authority
US
United States
Prior art keywords
dichlobenil
epiphytic
wettable powder
composition
simazine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US09/090,503
Inventor
Jeff Kaplan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US09/090,503 priority Critical patent/US5981434A/en
Application granted granted Critical
Publication of US5981434A publication Critical patent/US5981434A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/681,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom

Definitions

  • This invention relates to novel compositions comprising mixtures of three herbicides and to a method of controlling undesired epiphytic species by the application of an effective amount of one of the herbicides that comprise the mixture, alone or the composition comprising the mixtures.
  • the genus Tillandsia which belongs to the Bromeliaceae includes almost 400 species distributed from the south of the United States Of America to the northern part of Patagonia in Argentina.
  • the population of these epiphytic species such as Tillandsia Recurvata (Ball Moss) and Tillandsia Aeranthos on trees and shrubs in the southermost areas of the United States has increased dramatically, causing severe deleterious effects on their hosts.
  • Epiphytes are generically known as symbionic air plants and for two decades have been considered harmless to their hosts. Typically, epiphytic plants are not rooted in soil. Instead, they live above ground level on the stems and branches of other plants and trees. Epiphytes obtain water from trapped rainwater and from moisture in the air. They obtain minerals from organic matter that has accumulated on the surface of the host plant on which they are growing.
  • epiphytic weeds have a great multiplication capacity owing to the numerous plume seeds that allow them to fix onto the wrinkled surfaces of trees and branches.
  • the foregoing difficulties are obviated in that there is provided a low cost, easily dispersed formulation consisting of commercially available herbicides.
  • the formulation is initially comprised of three herbicides, Dichlobenil-(2,6-dichlorobensonitrile), Atrazine-(2-chloro-4(ethylamino)-6-(isopropylamino)-s-triazine, and Simazine-(2-chloro-4,6-bis(ethylamino)-s-triazine.
  • the doses are chosen by a dose response assay and is familiar to those skilled in the art.
  • the formulated mixtures can be dispersed using conventional methods such as knapsack, power and bottle sprayers as well as aircraft sprayers. These mixtures produce a synergistic action and have an increase in the effectiveness of the treatment.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A herbicidal composition to selectively control undesirable epiphytic weeds by applying active ingredients in an effective amount of Atrazine, Simazine, Dichlobenil, Atrazine+Dichlobenil, Simazine+Dichlobenil and the surfactant Tween 80.

Description

BACKGROUND--FIELD OF INVENTION
This invention relates to novel compositions comprising mixtures of three herbicides and to a method of controlling undesired epiphytic species by the application of an effective amount of one of the herbicides that comprise the mixture, alone or the composition comprising the mixtures.
BACKGROUND--DISCUSSION OF PRIOR ART
The genus Tillandsia which belongs to the Bromeliaceae includes almost 400 species distributed from the south of the United States Of America to the northern part of Patagonia in Argentina. The population of these epiphytic species such as Tillandsia Recurvata (Ball Moss) and Tillandsia Aeranthos on trees and shrubs in the southermost areas of the United States has increased dramatically, causing severe deleterious effects on their hosts.
Epiphytes are generically known as symbionic air plants and for two decades have been considered harmless to their hosts. Typically, epiphytic plants are not rooted in soil. Instead, they live above ground level on the stems and branches of other plants and trees. Epiphytes obtain water from trapped rainwater and from moisture in the air. They obtain minerals from organic matter that has accumulated on the surface of the host plant on which they are growing.
The present inventor has studied this extensive growth and the deleterious effects of these epiphytes and has concluded that they should be redefined as epiphytic weeds. These epiphytic weeds have a great multiplication capacity owing to the numerous plume seeds that allow them to fix onto the wrinkled surfaces of trees and branches.
A severe invasion of the growth of these epiphytic weeds cause significant shade that causes light competition and release some kind of growth inhibitor which is responsible for leaf abscission. Resulting from their position on the hosts, epiphytes such as the Tillandsia specie individuals cannot be controlled by cutting or pulling, thus selective herbicides are needed and are in great demand.
The use of selective herbicides to control various weeds is well established in the art. Typical herbicides that are commercially available are 2,4-dichlorophenoxyacetic acid (2,4-D), Copper sulfate. Cutrine, Thiocarbamates. Butylate, CDEC, Diallate, EPTC and many others. The majority of commercially available herbicides that control weeds are limited to soil application where they are readily adsorbed from the soil by roots and translocated via the xylem to the foliage where they inhibit oxygen evolution in photo-synthesis.
Typical new herbicidal formulations are set forth in the U.S. Pat. No. 5,420,098 to Hodogaya Chemical Co. Ltd (1995), in U.S. Pat. No. 5,668,089 to Zeneca Ltd (1997), and in U.S. Pat. No. 5,696,024 to American Cyanamid Co. (1997). Unfortunately, these Patent formulations as well as others have many disadvantages such as high toxicity, flammability, and are primarily used in the soil. It has been discovered by the inventor that there is no cited prior art relating to the control of epiphytes. Thus, a need exists for a fast acting herbicide formulation that is specifically designed to control the unique problems associated with epiphytic weeds and their respective physiology.
OBJECTS AND ADVANTAGES
Accordingly, several objects and advantages of my invention are:
(a) to provide a novel herbicidal formulation designed specifically to control the growth of epiphytic weeds.
(b) to provide a novel herbicidal formulation that will be absorbed through the trichomes of the epiphyte.
(c) to provide a novel herbicidal formulation that can be absorbed by the epiphyte without affecting the host species and causing phytotoxic effects on the terminal buds and leaves of the host plant.
(d) to provide a novel herbicidal formulation that is safe for humans and wildlife when used at the recommended doses.
(e) to provide a novel herbicidal formulation that is easily dispersed onto the epiphytes and is inexpensive.
DETAILED DESCRIPTION OF THE INVENTION
In the present invention, the foregoing difficulties are obviated in that there is provided a low cost, easily dispersed formulation consisting of commercially available herbicides. In accordance with the invention, the formulation is initially comprised of three herbicides, Dichlobenil-(2,6-dichlorobensonitrile), Atrazine-(2-chloro-4(ethylamino)-6-(isopropylamino)-s-triazine, and Simazine-(2-chloro-4,6-bis(ethylamino)-s-triazine.
These herbicides can be applied in five different formulations. (1) Dichlobenil 50 wettable powder (WP), 5 gl-1 +Tween 80 (0.5%), (2) Simazine 80 Wettable Powder (WP), 5 gl-1 +Tween 80 (0.5%), (3) Atrazine 80 emulsifiable concentrate (EC), 10 gl-1 +Tween 80 (0.5%), (4) Simazine+Dichlobenil+Tween 80 and (5) Atrazine +Dichlobenil +Tween 80in the same doses of the formulated product. The Tween 80 is used as a surfactant and is also a wetting agent. The formulation is sprayed onto the foliage of the host and to the epiphytic weeds. The doses are chosen by a dose response assay and is familiar to those skilled in the art. The formulated mixtures can be dispersed using conventional methods such as knapsack, power and bottle sprayers as well as aircraft sprayers. These mixtures produce a synergistic action and have an increase in the effectiveness of the treatment.
During October 1997 to May 1998 in the area of Plantation, Fla., the inventor tested these herbicide formulations on ten different host species which were actively growing and were infested with epiphytes of the Tillandsia species. The following treatments were applied: Atrazine 10 gl-1, Dichlobenil 5 gl-1, Simazine 5 gl-1, Simazine 5 gl-1 +Dichlobenil 5 gl-1 and Atrazine 10 gl-1 +Dichlobenil 5 gl-1. Tween 80 (0.5%) was added to all the formulations.
All the selected herbicides, alone or in combination controlled the epiphytes without causing phytotoxicity to their host plant, owing to the different absorption systems of the epiphytes and their hosts.
The following example is given as specific illustration of the invention. It should be understood, however, that the invention is not limited to the specific details set forth therein.
              TABLE 1                                                     
______________________________________                                    
Population level of epiphytic species Tillandsia recurvata                
  (Number of individuals) before and after treatments:                    
  (Tween 80 was included in the formulations)                             
          Oct.   Nov.   Dec.  Feb. Mar. April May                         
  20 20 20 20 20 20 20                                                    
Treatment TREATMENT                                                       
______________________________________                                    
Control   140    135    133        156  150   150                         
  Atrz. & Dich. 140 138 139   1  1  1                                     
  Simaz. & Dich. 140 136 146  18 18 18                                    
  Atrazine 140 139 122  115  45  3                                        
  Simazine 140 140 143  22  2  4                                          
  Dichlobenil 140 124 117   5  1  1                                       
______________________________________                                    
CONCLUSION, RAMIFICATION AND SCOPE OF THE INVENTION
Accordingly, the reader will see that a selectivly formulated herbicidal composition of the invention provides that:
it will specifically control the growth of epiphytic weed.
it will be absorbed through the trichomes of the epiphytes.
it will be absorbed by the epiphyte without affecting the host species and causing phytotoxic effects on the terminal buds and leaves of the host plant.
it will be safe for humans and wildlife when used at the recommended doses.
it will be inexpensive and easily dispersed using conventional methods.
Those skilled in the art will have no difficulty in determining suitable proportions of the above compositions to be used. The invention has been described as applied to preferred embodiments and it will be understood that various substitutions and changes may be effected without departing from the spirit and scope of the novel concepts and principals of this invention.

Claims (7)

I claim:
1. A herbicidal composition consisting essentially of a herbicide or a combination of herbicides selected from a group consisting of Dichlobenil 50 wettable powder, Simazine 80 wettable powder, Atrazine 80 emulsifiable concentrate, Atrazine 80 emulsifiable concentrate and Dichlobenil, Simazine 80 wettable powder and Dichlobenil, plus a surfactant and copper hydroxide.
2. A composition as in claim 1 consisting essentially of 5 g/l of Dichlobenil 50 wettable powder, 0.5% surfactant and copper hydroxide.
3. A composition as in claim 1 consisting essentially of 5 g/l of Simazine 80 wettable powder, 0.5% surfactant and copper hydroxide.
4. A composition as in claim 1 consisting essentially of 10 g/l of Atrazine 80 emulsifable concentrate, 0.5% surfactant and copper hydroxide.
5. A composition as in claim 1 consisting essentially of 5 g/l of Simazine 80 wettable powder, 5 g/l or Dichlobenil 50 wettable powder, 0.5% surfactant and copper hydroxide.
6. A composition as in claim 1 consisting essentially of 10 g/l of Atrazine 80 emulsifable concentrate, 5 g/l of Dichlobenil 50 wettable powder, 0.5% surfactant and copper hydroxide.
7. A method or controlling and eradicating the species tillandsia recurvata and epiphytic weeds which comprises applying the composition of any one of claims 1-6, to the branches and canopies of the infected hosts.
US09/090,503 1998-06-04 1998-06-04 Herbicidal composition for the control of epiphytic weeds Expired - Fee Related US5981434A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US09/090,503 US5981434A (en) 1998-06-04 1998-06-04 Herbicidal composition for the control of epiphytic weeds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/090,503 US5981434A (en) 1998-06-04 1998-06-04 Herbicidal composition for the control of epiphytic weeds

Publications (1)

Publication Number Publication Date
US5981434A true US5981434A (en) 1999-11-09

Family

ID=22223064

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/090,503 Expired - Fee Related US5981434A (en) 1998-06-04 1998-06-04 Herbicidal composition for the control of epiphytic weeds

Country Status (1)

Country Link
US (1) US5981434A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040121026A1 (en) * 2002-12-23 2004-06-24 Kaplan Jeffrey Lee Non-toxic composition for the control of epiphytic weeds

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5420098A (en) * 1993-03-31 1995-05-30 Hodogaya Chemical Co., Ltd. Herbicidal composition comprising HW-52 and one of atrazine, cyanazine, ioxynil, bromoxynil, or metribuzin
US5668089A (en) * 1996-04-08 1997-09-16 Zeneca Limited Selective corn herbicide
US5696024A (en) * 1995-06-06 1997-12-09 American Cyanmid Herbicidal water soluble granular compositions
US5719310A (en) * 1993-09-17 1998-02-17 Bayer Aktiengesellschaft 3-aryl-4-hydroxy-Δ3 -dihydrofuranone derivatives
US5739326A (en) * 1995-12-13 1998-04-14 E. I. Du Pont De Nemours And Company Heterobicyclic herbicides

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5420098A (en) * 1993-03-31 1995-05-30 Hodogaya Chemical Co., Ltd. Herbicidal composition comprising HW-52 and one of atrazine, cyanazine, ioxynil, bromoxynil, or metribuzin
US5719310A (en) * 1993-09-17 1998-02-17 Bayer Aktiengesellschaft 3-aryl-4-hydroxy-Δ3 -dihydrofuranone derivatives
US5696024A (en) * 1995-06-06 1997-12-09 American Cyanmid Herbicidal water soluble granular compositions
US5739326A (en) * 1995-12-13 1998-04-14 E. I. Du Pont De Nemours And Company Heterobicyclic herbicides
US5668089A (en) * 1996-04-08 1997-09-16 Zeneca Limited Selective corn herbicide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Royal Society of Chemistry, The Argochemicals Handbook, 3rd ed., 1991. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040121026A1 (en) * 2002-12-23 2004-06-24 Kaplan Jeffrey Lee Non-toxic composition for the control of epiphytic weeds

Similar Documents

Publication Publication Date Title
RU95110769A (en) Herbicide compositions and weed control methods
AU597609B2 (en) Synergistic herbicide combinations and method of preparation
US4456587A (en) Pheromone delivery system
JP2901794B2 (en) Herbicidal composition
US5981434A (en) Herbicidal composition for the control of epiphytic weeds
Fagerness et al. Spray Application Parameters That Influence the Growth Inhibiting Effects of Trinexapac‐Ethyl
CA1168978A (en) Method to reduce animal browsing damage to plants
CA2266261A1 (en) Foliar saline spray solution for selective control of noxious weeds
Wendel Glyphosate controls hardwoods in West Virginia
US20040121026A1 (en) Non-toxic composition for the control of epiphytic weeds
Foy et al. Some research approaches toward minimizing herbicidal residues in the environment
US6599500B1 (en) Communication disruptant and communication disruption method
Parker et al. Herbicides for nutgrass control-conclusions from ten years of testing at Oxford
GB2024016A (en) Degradation of pesticide residues
HU205823B (en) Aqouos glifozate solutions containing surfactants and process for extirpating weeds
Sterling et al. Picloram absorption by broom snakeweed (Gutierrezia sarothrae) leaf tissue
Patel et al. Comparative Efficacy and Economics of Various Insecticides Against Aphid, Lipaphis erysimi (Kalt) on Mustard in Gujarat.
Manthey et al. Relationship between surfactant characteristics and the phytotoxicity of CGA-136872
NO151026B (en) INSECTICID AND AKARICID MIXTURE CONTAINING GELATIN, AND USING THE MIXTURE FOR AA FIGHTING INSECT AND MEDICINE
Mayer Effects of methyl salicylate on honey bee (Apis mellifera L.) foraging
Wright et al. Dissipation and water activation of UCC-C4243
SU1161055A1 (en) Herbicide composition
Caldiz et al. Control of the epiphytic weeds Tillandsia recurvata and T. aeranthos with simazine
Horowitz Control of Established Portulaca oleracea L.
US3515535A (en) Herbicidal composition

Legal Events

Date Code Title Description
FPAY Fee payment

Year of fee payment: 4

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
LAPS Lapse for failure to pay maintenance fees

Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20071109