US588289A - Carl v - Google Patents
Carl v Download PDFInfo
- Publication number
- US588289A US588289A US588289DA US588289A US 588289 A US588289 A US 588289A US 588289D A US588289D A US 588289DA US 588289 A US588289 A US 588289A
- Authority
- US
- United States
- Prior art keywords
- furnace
- fume
- lead
- low
- hearth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003517 fume Substances 0.000 description 60
- 238000003723 Smelting Methods 0.000 description 14
- 229910052949 galena Inorganic materials 0.000 description 14
- 239000002893 slag Substances 0.000 description 12
- 239000003818 cinder Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- PIJPYDMVFNTHIP-UHFFFAOYSA-L Lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 2
- 235000011158 Prunus mume Nutrition 0.000 description 2
- 240000002546 Prunus mume Species 0.000 description 2
- 206010039509 Scab Diseases 0.000 description 2
- 241001062472 Stokellia anisodon Species 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000010978 jasper Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001590 oxidative Effects 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/02—Obtaining lead by dry processes
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
N IiTE CARL v. PE'IRAEUS,
STATES or JOPLIN, MISSOURI, ASSIGNOR TO OLIVERH.
PICHER, OF SAME PLACE.
METHOD OF SMELTING GALENA.
SPECIFICATION forming part of Letters Patent No. 588,289, dated August 17, 1897.
Application filed April '7, 1896. Serial No. 586,587. (No specimens.)
To all whom it may concern:
Be it known that I, CARL V. PETRAEUS, a citizen of the United States, residing in J oplin, in the county of Jasper and State of Missouri, have invented a certain new and useful Improvement in Methods of Smelting Galena, of which the following is a true and exact description.
My invention relates to the smelting of galena ore, and has for its object to reduce substantially all the lead contents of such ore to metallic form and at a low cost of treatment.
In my former patent, No. 556,691, dated March 17, 1896, I have described a method of treating galena ore in which the 'ore is first treated in an open-hearth blast-furnace, with the result of producing a certain quantity of metallic lead, a certain quantity of lead f ume; consisting largely of lead sulfid, and slag and cinder both rich in lead. The fumes collected from this furnace are cintered together and resmelted and the metal-bearing slag and cinder are also resmelted in a low-cupola blastfurnace, the fume driven oif from this furnace consisting, essentially, of lead sulfate and lead oxid, being agglomerated by pressure or cementation and again smelted to reduce them to metallic lead. In the treatment of my said former patent it was necessary to provide separate screen systems for the fumes obtained from the low-cupola blast-furnace and those obtained from the open-hearth furnace, because the'fume obtained from the openhearth furnace, consisting largely of lead sulfid, can be cintered together in condition for charging into a furnace by simply igniting it, while the fume from the low-cupola furnace cannot be cintered in this way, but requires comparatively expensive modes of treatment to fit it for use in a furnace, and it has been found that the mixture which would result from collecting the fumes from both furnacesin one screen system would require to be treated in the same manner as the fume from the low-cupola furnace, which treatment is more expensive and less satisfactory in result which shall consist largely of lead sullid and be of a character which will permit it to cinter by ignition, thus enabling me to provide a single screen system for all the fumes generated in the treatment of the ore as well as to obtain a cintered fume of the best character for further furn ace treatment from the entire mass of fume produced.
In the so-called low-cupola blast-furnace referred to in my former patent, also technically known as a slag hearth-furnace, the surface of the charge and the top of the furnace are both very hot and of an oxidizing character, so that any lead sulfid which may be thrown off from the furnace in the form of fume is oxidized in the top of the furnace and passes to the lines and screen system as lead sulfate and lead oxid. In an ordinary stackfurnace, on the other hand, it has been found impracticable to treat material so rich in leadand sulfur as the slag-cinder and agglomerated fume from the open-hearth blast-furnace, because the fume generated in such a furnace forms scal'folds, as they are called, upon the walls of the furnace so rapidly as to interfere very seriously with the operation of the furnace and because that from the airpressure necessarily used in the ordinary stack-furnace there is produced alarge quantity of lead matte, which is highly undesirable and which can only be avoided by the use of a very large quantity of iron flux, which is not always available, and if available is apt to be expensive.
NowI have discovered that the rich loadbearing material, which in accordance with my former patented process was treated in the low-cupola blast-furnace, can be smelted in such a Way as to produce a fumelargely consisting of lead sulfid without serious trouble from the formation of scaffolds or crusts in the furnace and without producing any considerable amount of lead matte by smelting it in a stack-furnace the-height and air-pressure of which are so regulated that the top of the charge and top of the furnace will be at a temperature too low to cause the oxidation of lead-sulfid fumes and in which the mini mum air-pressure is maintained-that is to say, the furnace is made as low as practicable consistent with the desired low temperature of the top of the charge-and the principal reason for this is that by constructing and operating a furnace as above described I keep the smelting-zone of the furnace at a comparatively low temperature compared with the temperature used in stack-furnaces, and the formation of the lead matte appears only to occur when the temperature of the smelting-zone is high.
In practice I have constructed my furnaces with aheightof about five feet from the twyers to the top of the charge and have used an airblast which gives in this furnace a pressure of from two to three inches of water, and this furnace I have found to give excellentresults, producing a fume rich in lead sulfid and substantially no lead matte. The minimum height of the furnace charge should not be less than four feet, nor is it advisable to construct a furnace for my purposes the charge in which would exceed six feet.
My new method of smelting galena ore con sists, therefore, in first treating the galena in the open-hearth blast-furnace, as in myformer patented process, and collecting the fumes from this furnace and centering them by ignition. Then I take the slag and cinder from the open-hearth furnace together with the cintered fume from the open-hearth furnace and the cintered fume prepared, as described, from the fume of the second furnace treatment and smelt these materials in a furnace of the construction above describedthat is to say, one having a temperature at the top of the charge too low to cause the oxidation of sulfid fume and a low blastpressnre-and I collect and einter by ignition the fume from this furnace, charging the centered fume again into the stack-furnace.
s As the fume from both furnace treatments is of substantially the same character, I am enabled to use a single-screen system for collecting the fume from both treatments, which is a considerable source of economy in cost of plant, and whether the fume is collected in one or two screen systems it is in any case of a better and more suitable character for further furnace treatment than where the lowcupola furnace of my former patented process is used.
Having now described my invention, what I claim as new, and desire to secure by Letters Patent, is
The method of smelting galena which consists in first treating the ore in an open-hearth blast-furnace and collecting the lead fume containing a large percentage of lead sulfid driven off therefrom, treating the metal-bearing slag of the open-hearth furnace and cintered fume in a stack-furnace in which the temperature at the top of the furnace is maintained at so low a point as to prevent the oxidation of the lead-sulfid fume generated in the furnace, collecting the fume containing a large percentage of lead suliid drawn 01f from the stack-furnace, agglomerating the fume from both furnaces by cintering and smelting it in the stack-furnace aforesaid together with the slag from the open-hearth f urnaee.
- CARI, V. PETRAEUS.
\Vitnesses:
A. E. SPENCER, GALEN SPENCER.
Publications (1)
Publication Number | Publication Date |
---|---|
US588289A true US588289A (en) | 1897-08-17 |
Family
ID=2656955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US588289D Expired - Lifetime US588289A (en) | Carl v |
Country Status (1)
Country | Link |
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US (1) | US588289A (en) |
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0
- US US588289D patent/US588289A/en not_active Expired - Lifetime
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