US5627339A - Energetic compositions containing no volatile solvents - Google Patents

Energetic compositions containing no volatile solvents Download PDF

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Publication number
US5627339A
US5627339A US08/626,748 US62674896A US5627339A US 5627339 A US5627339 A US 5627339A US 62674896 A US62674896 A US 62674896A US 5627339 A US5627339 A US 5627339A
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United States
Prior art keywords
metal fuel
weight
compositions
aluminum
solvent free
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Expired - Fee Related
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US08/626,748
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Jerry S. Brown
John A. Conkling
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US Department of Navy
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US Department of Navy
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B27/00—Compositions containing a metal, boron, silicon, selenium or tellurium or mixtures, intercompounds or hydrides thereof, and hydrocarbons or halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
    • C06C15/00—Pyrophoric compositions; Flints
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S149/00—Explosive and thermic compositions or charges
    • Y10S149/116—Flare contains resin

Definitions

  • This invention relates generally to ignitable compositions, and relates specifically to energetic compositions containing no volatile solvents and to the solvent-free process of making the same from active metal fuels and fluorocarbons.
  • Energetic mixtures based on the reaction between an active metallic element, such as magnesium or aluminum, and a solid fluorine-rich carbon compound, such as polytetrafluoroethylene (PTFE), are well known for use in infrared-emitting decoy flares and for high-temperature ignition compositions.
  • PTFE polytetrafluoroethylene
  • the processing of these type compositions generally requires the use of a flammable liquid (acetone or hexane), and the unique physical properties of PTFE can make processing difficult.
  • Another object of the present invention is a safe process for making energetic compositions that are free of volatile solvents and require no volatile solvents in the manufacturing process.
  • a further object of the present invention is an ignitable composition formed of fluorinated hydrocarbons, combined with metal powders, to yield an energetic composition for use in flares, high temperature ignition compositions, and the like.
  • An additional object of the present invention is to provide energetic compositions that are free of volatile solvents.
  • the foregoing and additional objects are attained by combining a fluorinated hydrocarbon, either in a liquid state or as a water emulsion, with a powdered metal fuel such as aluminum, magnesium, titanium or zirconium.
  • a fluorinated hydrocarbon either in a liquid state or as a water emulsion
  • a powdered metal fuel such as aluminum, magnesium, titanium or zirconium.
  • the resulting mixture when mixed in the proper proportions, yields an energetic composition that is free of volatile organic solvents, and adaptable for use as a high temperature ignition composition, in infrared-emitting decoy flares, and the like.
  • the process disclosed herein uses fluorocarbon liquids containing no additional solvents, or uses water-based fluorocarbon emulsions. No organic solvents are used and the energetic compositions obtained are therefore free of any volatile organic solvents.
  • liquid fluorocarbon a liquid perfluorinated polyether (PFPE) having a molecular weight of approximately 5000 was employed.
  • PFPE liquid perfluorinated polyether
  • Liquid fluorocarbons of this type are marketed for use in the semi-conductor, electronics and aerospace industries as dielectrics and lubricants and are available, for example, under the trade name FOMBLIN YR, from AUSIMONT of Morristown, N.J.
  • PFPE liquid fluorocarbon
  • PFPE/aluminum mixture also was readily ignitable.
  • Liquid perfluorinated polyether (PFPE) having an average molecular weight of 2000 is commercially available, for example, under the trade name GALDEN D-40 from AUSIMONT of Morristown, N.J.
  • PFPE liquid/PTFE solid mixture was placed in a crucible and one part by weight of a 3 to 10 micron aluminum cautiously added thereto. The mixture was then blended for several minutes to a homogeneous, fluid consistency using a ceramic pestle. A sample of this blended material ignited readily from a piece of pyrotechnic safety fuse and burned with a bright white flame. The material retained its pliable character overnight, and remained readily ignitable.
  • Premixed PFPE liquid/PTFE (micron size) solid of this type is available under the trade name FOMBLIN RT 15 GREASE from AUSIMONT of Morristown, N.J.
  • fluorocarbon applicable for practice of the present invention is a water-based fluorocarbon emulsion.
  • These emulsions contain no organic solvents and are commercially available products currently used in chemical-resistant coating applications and also available, for example, from AUSIMONT of Morristown, N.J. under their trade name TECNOFLON TN LATEX.
  • a fluorcelastomer terpolymer latex was combined with a metal fuel.
  • a metal fuel e.g., a fluorcelastomer terpolymer latex
  • a fluorcelastomer terpolymer latex was combined with a metal fuel.
  • an emulsion of fluorinated terpolymer fluoroelastomer in water minimum 70% solids, 68% fluorine content, by weight
  • the aluminum blended in readily, with stirring, to produce a paste-like mixture.
  • the water was allowed to evaporate overnight, leaving a rubbery, pliable material that ignited readily and burned with considerable intensity.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Energetic compositions and the process for obtaining same for use as the itable composition in infrared-emitting decoy flares, for high-temperature ignition compositions, and the like, are disclosed. These compositions are attained by combining a fluorinated hydrocarbon, either in a liquid state or as a water emulsion, with a powdered metal fuel such as aluminum, magnesium, titanium or zirconium to yield volatile solvent free energetic compositions.

Description

ORIGIN OF THE INVENTION
This invention was made jointly by a U.S. Navy employee and a consultant under a U.S. Navy contract and the U.S. Government, accordingly, has certain rights in the invention.
This is a divisional of application Ser. No. 08/195,249 filed on Feb. 14, 1994, now U.S. Pat. No. 5,531,844.
FIELD OF THE INVENTION
This invention relates generally to ignitable compositions, and relates specifically to energetic compositions containing no volatile solvents and to the solvent-free process of making the same from active metal fuels and fluorocarbons.
BACKGROUND OF THE INVENTION
Energetic mixtures based on the reaction between an active metallic element, such as magnesium or aluminum, and a solid fluorine-rich carbon compound, such as polytetrafluoroethylene (PTFE), are well known for use in infrared-emitting decoy flares and for high-temperature ignition compositions. The processing of these type compositions generally requires the use of a flammable liquid (acetone or hexane), and the unique physical properties of PTFE can make processing difficult.
A static electrical hazard has also been demonstrated in the processing of these materials which can result in spontaneous ignition and disastrous results. There have been a number of tragic explosions associated with the manufacturing of these compositions. Also, once blending has been achieved, the flammable solvent must be removed and recovered, adding to the cost of the manufacturing process. Clean air laws and standards prohibit releasing these volatile organic solvents directly into the environment.
It is therefore an object of the present invention to eliminate the use of organic solvents and provide a safer process of producing active metal/fluorocarbon energetic compositions.
Another object of the present invention is a safe process for making energetic compositions that are free of volatile solvents and require no volatile solvents in the manufacturing process.
A further object of the present invention is an ignitable composition formed of fluorinated hydrocarbons, combined with metal powders, to yield an energetic composition for use in flares, high temperature ignition compositions, and the like.
An additional object of the present invention is to provide energetic compositions that are free of volatile solvents.
SUMMARY OF THE INVENTION
According to the present invention, the foregoing and additional objects are attained by combining a fluorinated hydrocarbon, either in a liquid state or as a water emulsion, with a powdered metal fuel such as aluminum, magnesium, titanium or zirconium. The resulting mixture, when mixed in the proper proportions, yields an energetic composition that is free of volatile organic solvents, and adaptable for use as a high temperature ignition composition, in infrared-emitting decoy flares, and the like. The process disclosed herein uses fluorocarbon liquids containing no additional solvents, or uses water-based fluorocarbon emulsions. No organic solvents are used and the energetic compositions obtained are therefore free of any volatile organic solvents.
DETAILED DESCRIPTION AND SPECIFIC EXAMPLES
A more complete appreciation of the invention and many of the attendant advantages thereof will be better understood when considered in connection with the specific Examples described hereinbelow.
EXAMPLE I
In this specific example, a liquid fluorocarbon, a liquid perfluorinated polyether (PFPE) having a molecular weight of approximately 5000 was employed. Liquid fluorocarbons of this type are marketed for use in the semi-conductor, electronics and aerospace industries as dielectrics and lubricants and are available, for example, under the trade name FOMBLIN YR, from AUSIMONT of Morristown, N.J.
A mixture of this 5000 molecular weight PFPE and a 3 to 10 micron size aluminum were combined in a weight ratio of 2.3 to 1.0. The resulting composition was readily ignitable. Other metal fuels, such as magnesium, titanium and zirconium are equally applicable for mixing with this PFPE to form high-energy composition. The heat of combustion for a stoichiometric combination of magnesium and this fluorocarbon liquid is -3.5 K cal/g.
EXAMPLE II
In another specific example, a liquid fluorocarbon (PFPE) having an average molecular weight of 2000 was mixed with 3 to 10 micron aluminum in a weight ratio of 2.3 to 1.0. This PFPE/aluminum mixture also was readily ignitable. Liquid perfluorinated polyether (PFPE) having an average molecular weight of 2000 is commercially available, for example, under the trade name GALDEN D-40 from AUSIMONT of Morristown, N.J.
EXAMPLE III
Another specific example involved combining a 5000 molecular weight PFPE with a micron-size polytetrafluorcethylene (PTFE). In this example, 2 parts by weight, of the PFPE liquid/PTFE solid mixture was placed in a crucible and one part by weight of a 3 to 10 micron aluminum cautiously added thereto. The mixture was then blended for several minutes to a homogeneous, fluid consistency using a ceramic pestle. A sample of this blended material ignited readily from a piece of pyrotechnic safety fuse and burned with a bright white flame. The material retained its pliable character overnight, and remained readily ignitable. Premixed PFPE liquid/PTFE (micron size) solid of this type is available under the trade name FOMBLIN RT 15 GREASE from AUSIMONT of Morristown, N.J.
EXAMPLE IV
Another form of fluorocarbon applicable for practice of the present invention is a water-based fluorocarbon emulsion. These emulsions contain no organic solvents and are commercially available products currently used in chemical-resistant coating applications and also available, for example, from AUSIMONT of Morristown, N.J. under their trade name TECNOFLON TN LATEX.
In this example, a fluorcelastomer terpolymer latex was combined with a metal fuel. To four parts, by weight, of an emulsion of fluorinated terpolymer fluoroelastomer in water (minimum 70% solids, 68% fluorine content, by weight) was added one part, by weight, of a 3 to 10 micron size aluminum powder. The aluminum blended in readily, with stirring, to produce a paste-like mixture. The water was allowed to evaporate overnight, leaving a rubbery, pliable material that ignited readily and burned with considerable intensity.
The foregoing specific Examples are given as illustrative only and are not to he deemed as exhaustive. It is readily seen that the use of a liquid fluorocarbon, or a water-based fluorocarbon emulsion, in place of the conventionally used volatile organic solvents with PTFE will greatly enhance safety in the manufacturing of metal/fluorine compositions by the elimination of flammable/explosive solvents. This should also lead to cost savings in the overall manufacturing process by allowing for the rapid blending of the components into a homogeneous mixture. Water, when used in the blending process, can be easily removed and disposed of safely and economically.
Although the specific examples described herein are primarily restricted to aluminum as the metal fuel, the invention is not so limited and it is to be understood that magnesium, titanium and zirconium can be used for the metal fuel in each of the examples, as so desired. Also, other fluorocarbon compounds that can be prepared or blended as water emulsions or fluid materials in the practice of the present invention, include PTFE, fluorinated polyethers, and fluorinated hydrocarbon polymers based on monomers other than ethylene. Examples of these additional materials include hexafluoropropylene and vinylidene fluoride. In addition, compositions containing blends or copolymers of these various polymers are also considered to be included in the scope of the present invention.
These and other modifications and variations of the specific Examples described herein will be readily apparent to those skilled in the art in the light of the above teachings. It is therefore to be understood that, within the scope of the appended claims, the invention may be practiced other than as described herein.

Claims (4)

What is claimed as new and desired to be secured by Letters Patent of the United States is:
1. A method of making an organic solvent free energetic composition comprising the steps of:
(a) providing a quantity of a liquid perfluorinated polyether having a molecular weight in the range of approximately 2000 to approximately 5000;
(b) providing a quantity of a metal fuel in the form of a powder consisting of 3 to 10 micron size particles;
(c) combining 2.3 parts, by weight, of the liquid perfluorinated polyether with 1.0 parts, by weight, of the metal fuel powder to yield an organic solvent free energetic composition.
2. The method of claim 1 wherein the metal fuel powder is selected from the group of metal fuel powders consisting of aluminum, magnesium, titanium and zirconium.
3. A method of making an organic solvent free energetic composition comprising the steps of:
(a) providing a mixture of an approximately 5000 molecular weight liquid perfluorinated polyether and a micron-size polytetrafluoroethylene;
(b) providing a quantity of a metal fuel in the form of a powder consisting of 3 to 10 micron size particles;
(c) blending one part by weight of the metal fuel into two parts by weight of the liquid perfluorinated polyether mixture to yield a pliable, readily ignitable, organic solvent free, energetic composition.
4. The method of claim 3 wherein the metal fuel powder is selected from the group of metal fuel powders consisting of aluminum, magnesium, titanium and zirconium.
US08/626,748 1994-02-14 1996-03-28 Energetic compositions containing no volatile solvents Expired - Fee Related US5627339A (en)

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
US6547993B1 (en) 2001-05-09 2003-04-15 The United States Of America As Represented By The Secretary Of The Navy Process for making polytetrafluoroethylene-aluminum composite and product made
US6783615B1 (en) * 2002-01-29 2004-08-31 The United States Of America As Represented By The Secretary Of The Army Insensitive explosives for high speed loading applications
US20040226638A1 (en) * 2003-05-16 2004-11-18 Posson Philip L. Energetics binder of fluoroelastomer or other latex
FR2867468A1 (en) * 2004-03-15 2005-09-16 Alliant Techsystems Inc Reactive material, used as filling materials in e.g. bullets, comprises reactive material component pertaining to the categories of components (e.g. fuel)
US20050212382A1 (en) * 2004-03-25 2005-09-29 Fanuc Ltd Electrostatic motor
US20070272112A1 (en) * 2000-02-23 2007-11-29 Alliant Techsystems Inc. Reactive material compositions, shot shells including reactive materials, and a method of producing same
US8122833B2 (en) 2005-10-04 2012-02-28 Alliant Techsystems Inc. Reactive material enhanced projectiles and related methods
USRE45899E1 (en) 2000-02-23 2016-02-23 Orbital Atk, Inc. Low temperature, extrudable, high density reactive materials
CN111423289A (en) * 2020-05-11 2020-07-17 西安近代化学研究所 Boron-based composite material and preparation process thereof

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FR2764687B1 (en) 1997-06-16 1999-08-27 Ruggieri PYROTECHNICAL PROJECTILE FOR THE REALIZATION IN THE SKY OF PATTERNS OF A CONTINUOUS APPEARANCE
US5886293A (en) * 1998-02-25 1999-03-23 The United States Of America As Represented By The Secretary Of The Navy Preparation of magnesium-fluoropolymer pyrotechnic material
US6962634B2 (en) * 2002-03-28 2005-11-08 Alliant Techsystems Inc. Low temperature, extrudable, high density reactive materials
DE10307627B3 (en) * 2003-02-22 2004-11-04 Diehl Munitionssysteme Gmbh & Co. Kg Pyrotechnic kit, useful for making flares for diverting infra-red seeking missiles, comprises as oxidant a fluorinated, spherical cage molecule, or derived polymer, and metal as fuel
FR2867469A1 (en) 2004-03-15 2005-09-16 Alliant Techsystems Inc Reactive composition, useful in military and industrial explosives, comprises a metallic material defining a continuous phase and having an energetic material, which comprises oxidant and/or explosive of class 1.1
DE102005038986B4 (en) * 2005-08-18 2011-11-24 Diehl Bgt Defence Gmbh & Co. Kg Energetic material
US7857273B2 (en) * 2007-05-01 2010-12-28 Wabtec Holding Corp. Plate for a compressible elastomeric spring
US10173944B2 (en) 2014-10-16 2019-01-08 Northrop Grumman Innovations Systems, Inc. Compositions usable as flare compositions, countermeasure devices containing the flare compositions, and related methods
US11014859B2 (en) 2014-10-16 2021-05-25 Northrop Grumman Systems Corporation Compositions usable as flare compositions, countermeasure devices containing the flare compositions, and related methods
US11851382B1 (en) * 2019-08-29 2023-12-26 The United States Of America As Represented By The Secretary Of The Navy Flexible halocarbon pyrolant
CN112094163A (en) * 2020-09-25 2020-12-18 沈阳理工大学 Nano-scale aluminum/polytetrafluoroethylene active material and preparation process thereof

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Cited By (16)

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Publication number Priority date Publication date Assignee Title
US7977420B2 (en) 2000-02-23 2011-07-12 Alliant Techsystems Inc. Reactive material compositions, shot shells including reactive materials, and a method of producing same
US9982981B2 (en) 2000-02-23 2018-05-29 Orbital Atk, Inc. Articles of ordnance including reactive material enhanced projectiles, and related methods
US20070272112A1 (en) * 2000-02-23 2007-11-29 Alliant Techsystems Inc. Reactive material compositions, shot shells including reactive materials, and a method of producing same
USRE45899E1 (en) 2000-02-23 2016-02-23 Orbital Atk, Inc. Low temperature, extrudable, high density reactive materials
US9103641B2 (en) 2000-02-23 2015-08-11 Orbital Atk, Inc. Reactive material enhanced projectiles and related methods
US6547993B1 (en) 2001-05-09 2003-04-15 The United States Of America As Represented By The Secretary Of The Navy Process for making polytetrafluoroethylene-aluminum composite and product made
US6783615B1 (en) * 2002-01-29 2004-08-31 The United States Of America As Represented By The Secretary Of The Army Insensitive explosives for high speed loading applications
US20040226638A1 (en) * 2003-05-16 2004-11-18 Posson Philip L. Energetics binder of fluoroelastomer or other latex
US6896751B2 (en) 2003-05-16 2005-05-24 Universal Propulsion Company, Inc. Energetics binder of fluoroelastomer or other latex
FR2867468A1 (en) * 2004-03-15 2005-09-16 Alliant Techsystems Inc Reactive material, used as filling materials in e.g. bullets, comprises reactive material component pertaining to the categories of components (e.g. fuel)
US8568541B2 (en) 2004-03-15 2013-10-29 Alliant Techsystems Inc. Reactive material compositions and projectiles containing same
US20080229963A1 (en) * 2004-03-15 2008-09-25 Alliant Techsystems Inc. Reactive material enhanced munition compositions and projectiles containing same
US7304410B2 (en) * 2004-03-25 2007-12-04 Fanuc Ltd Electrostatic motor including projections providing a clearance between stator and slider electrode members
US20050212382A1 (en) * 2004-03-25 2005-09-29 Fanuc Ltd Electrostatic motor
US8122833B2 (en) 2005-10-04 2012-02-28 Alliant Techsystems Inc. Reactive material enhanced projectiles and related methods
CN111423289A (en) * 2020-05-11 2020-07-17 西安近代化学研究所 Boron-based composite material and preparation process thereof

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US5531844A (en) 1996-07-02
US5623120A (en) 1997-04-22
US5574248A (en) 1996-11-12

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