US3770525A - High luminosity infrared pyrotechnical composition - Google Patents
High luminosity infrared pyrotechnical composition Download PDFInfo
- Publication number
- US3770525A US3770525A US00086193A US3770525DA US3770525A US 3770525 A US3770525 A US 3770525A US 00086193 A US00086193 A US 00086193A US 3770525D A US3770525D A US 3770525DA US 3770525 A US3770525 A US 3770525A
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- pyrotechnical
- barium stearate
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B27/00—Compositions containing a metal, boron, silicon, selenium or tellurium or mixtures, intercompounds or hydrides thereof, and hydrocarbons or halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C15/00—Pyrophoric compositions; Flints
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S149/00—Explosive and thermic compositions or charges
- Y10S149/116—Flare contains resin
Definitions
- ABSTRACT A high-luminosity pyrotechnical composition
- an illuminant substance of high emissivity in the infrared band at least one halogenated resin with fluorine atoms constituting at least two-thirds of the total number of halogen atoms and a metal which is highly reductive with the halogen atoms of the resin.
- the composition is in the form of an agglomerate mixture with the amount of reducing metal being between that stoichiometrically required for the reduction of the halogen atoms and an excess of 20 percent in relation to the stoichiometrical determination.
- the composition may optionally include a binder and it is press molded to shape the composition as a body.
- the composition may also contain barium stearate to regulate emission time.
- the invention also relates to the process of manufacture of such pyrotechnical compositions.
- Pyrotechnical compositions are generally mixtures of combustible substances with metallic oxides or salts selected for the required effect such as a luminous effect obtained when such metallic oxides or salts are raised to incandescence at the instant of combustion of the composition.
- compositions are especially used in tracer devices located in back of rockets and similar vehicles for providing emission of radiance allowing the trajectory of such vehicles to be tracked. It is important that such radiation should be powerful and sustainable as long as possible.
- deflectors on the tracers so as to keep the apparent diameter of the flame constant; also it is known to employ an extrusion cowling around the flame so as to create a zone of lesser tur bulence thereat.
- An object of the present invention is to eliminate the aforesaid disadvantages but by another means consisting of a new formulation of the pyrotechnical composition which propagates an emissive power much greater in comparison to that obtained from known pyrotechnical compositions.
- the high-luminosity pyrotechnical composition is characterized by containing in finely divided state an illuminant substance of high emissivity in the infrared band, at least one fluorinated resin having fluorine atoms which make up at least twothirds of the total of the halogen atoms, and a metal which is highly reductive in the presence of the resin halogens, the composition being in the form of an agglomerate mix in which the amount of the reducing metal is between that required stoichiometrically and an excess of 20 percent over such stoichiometric amount.
- Fluorinated resins are known to decompose at a high temperature in the range of 300 to 400 while liberating gases containing the resin halogens. These halogens, and fluorine in particular, are powerful oxidants and react with numerous metals with a strongly exothermic oxido-reduction reaction.
- the amount of reducing metal is experimentally calculated with an excess from 10 to 15 percent of the amount required for complete reduction.
- the amount of illuminant substance is selected in the range of 2 to 10 percent by weight of the pyrotechnical composition.
- the pyrotechnical composition also comprises barium stearate in the ratio of two to 15 percent by weight of the composition. This addition noticeably affects the fundamental reduction reaction time and through the lubricating properties of the stearate promotes the forming of the composition as well as its molding at high temperature.
- the pyrotechnical composition can further contain a binding agent composed of a polymerized polyester resin in a ratio not greater than seven percent by weight of the composition.
- FIGURE of the drawing is a graphical representation of emission for various compositions.
- the fluorinated resin is preferably polytetrafluoroethylene.
- other fluorinated resins can also be used, such as polytrifluorochloroethylene, polyvinylidene fluoride, a copolymer of tetrafluoroethylene and hexafluoropropylene and a copolymer of vinylidene fluoride and hexafluoropropylene.
- these resins are used in finely powdered form.
- the resin is used in the form of particles, as finely divided as possible.
- the resins can be used singly or mixed together.
- the reducing metal is chosen from the group consisting of magnesium, silicon, zirconium, aluminium and chromium.
- the illuminant substance is preferably an oxide of a metal chosen from the group consisting of iron, nickel, copper and hafnium.
- Market quality barium stearate is also used in powder form.
- the polymerized polyester resin before being put to use, is preferably composed of a liquid unsaturated resin mixed with monomeric styrene. At the moment of use, it is treated with a catalyzer which allows the polymerization to be primed at a moderate temperature.
- the pyrotechnical composition according to the invention can be obtained by press-molding a mixture of 5 powders of the illuminant substance, the reducing metal, at least one fluorinated resin and the barium stearate.
- molding is effected at a temperature around 320 C by the method known as fritting.
- the binding agent for the pyrotechnical composition is here composed of polytetrafluoroethylene.
- the molding is carried out at ambient temperature or at a temperature slightly higher, the components of the mixture being the powdered ingredients and a non-polymerized polyester resin; then the molded composition is allowed to stand whereby the polymerization of the resin is achieved.
- the molding mixture is then completed by adding the fluorinated resin to the polyester resin and adding in succession, to the fluorinated'resin thus coated, first the reducing metal and barium stearate, and then the illuminant substance.
- the pyrotechnical composition binder is here made and compressed to a pressure of 1,500 bars.
- compositions comprising an amount p of barium stearate respectively equal to zero percent, three percent, nine percent and 13 percent and complying with following formulation: Polytetrafluoroethylene 30 g, Magnesium 45 g (40 to micron grain size), Fe O 7.5 g, Barium stearate pg, Polyester resin 5 g.
- the mean emission-curves were determined for each of these series.
- Emission curve A for the second series comprising three percent barium stearate, exhibited two maxima at 1950 w/stearadian and 1,850 w/sr over a doubled combustion time, namely four seconds.
- Emission curve B for the third series comprising 9 percent barium stearate exhibited a maximum power level at 1 w/sr extending over a time of 4.7 seconds whereas the entire combustion time was considerably longer than in the two preceding series, viz., 5.2 seconds.
- Emission curve C for the fourth series comprising 13 percent barium stearate differed from the third set by having a slightly sloping, but longer, plateau corresponding to maximum power levels from 900 to 860 w/sr and a substantially longer combustion time of 13.3 seconds.
- the pyrotechnical composition, according to the invention is eminently adapted thereto, because of the localization of its emissive power, for use in rockets and similar tracers.
- a smokeless high-luminosity pyrotechnical composition consisting essentially of an agglomerate mixture of an illuminant substance of highemissivity in the infrared band, and in finely divided state, the amount of illuminant substance being between two and 10 percent by weight of the composition, said illuminant substance being selected from the group consisting of iron, nickel, copper, hafnium and the oxides thereof, the remainder of said mixture consisting essentially of at least one halogenated resin having fluorine atoms constituting at least two thirds of the total number of halogen atoms, and a metal which is highly reductive with the halogen atoms of the resin, said metal being selected from the group consisting of magnesium, zirconium, aluminium, chromium and silicon, and being present in an amount between that required stoichiometrically for the reduction of said halogen atoms and an excess of 20 percent over such stoichiometrical amount.
- composition as claimed in claim 1 containing barium stearate.
- a composition as claimed in claim 2 wherein the amount of barium stearate is in the range of two to percent by weight of the composition.
- composition as claimed in claim 1. containing a binding agent of polymerized polyester resin resulting from the polymerization of unsaturated resin with monomeric styrene.
- composition as claimed in claim 4 wherein the amount of polyester resin does not exceed seven percent of the composition.
- composition as claimed in claim 1 wherein the excess of reducing metal in relation to the stoichiometrical amount is between 10 and 15 percent.
- halogenated resin is polytetrafluoroethylene, polytrifluorochloroethylene, polyvinylidene fluoride, the copolymer of tetrafluoroethylene and hexafluoropropylene, or the copolymer of vinylidene fluoride and hexafluoropropylene.
Abstract
A high-luminosity pyrotechnical composition comprising, in finely divided state, an illuminant substance of high emissivity in the infrared band, at least one halogenated resin with fluorine atoms constituting at least two-thirds of the total number of halogen atoms and a metal which is highly reductive with the halogen atoms of the resin. The composition is in the form of an agglomerate mixture with the amount of reducing metal being between that stoichiometrically required for the reduction of the halogen atoms and an excess of 20 percent in relation to the stoichiometrical determination. The composition may optionally include a binder and it is press molded to shape the composition as a body. The composition may also contain barium stearate to regulate emission time.
Description
Villey-Desmeserets et a1.
Nov. 6, 1973 HIGH LUMINOSITY INFRARED PYROTECHNICAL COMPOSITION [75] inventors: Frank Pierre A. Villey-Desmeserets,
Yves A. Pouliguen; Germain Guillauma, all of Pont de Buis, France I73] Assignce: Etat Francais Delegation Ministerielle Pour LArmement [22] Filed: Nov. 2, 1970 [21] Appl. No.: 86,193
[30] Foreign Application Priority Data Nov. 5. 1969 France 6938022 [52] US. Cl 149/l9.3, 149/20, 149/37, 149/1 16, 149/4f1 1 49/ 8 7 [51] int. Cl C06d 1/10 [58] Field of Search 149/19, 87, 37, 44, 149/20 [56] References Cited UNITED STATES PATENTS 3,634,283 1/1972 Rozncr et a1. 149/87 X 3,163,113 12/1964 Davis et al...... 149/37 X 3,203,171 8/1965 Burke et a1. 149/19 Primary Examiner-Carl D. Quarforth Assistant Examiner-E. A. Miller Attorney-Waters, Roditi, Schwartz & Nissen [57] ABSTRACT A high-luminosity pyrotechnical composition comprising, in finely divided state, an illuminant substance of high emissivity in the infrared band, at least one halogenated resin with fluorine atoms constituting at least two-thirds of the total number of halogen atoms and a metal which is highly reductive with the halogen atoms of the resin. The composition is in the form of an agglomerate mixture with the amount of reducing metal being between that stoichiometrically required for the reduction of the halogen atoms and an excess of 20 percent in relation to the stoichiometrical determination. The composition may optionally include a binder and it is press molded to shape the composition as a body. The composition may also contain barium stearate to regulate emission time.
8 Claims, 1 Drawing Figure POWER LEI/EL PATENTED NOV 8 I975 MOO-- ll-IlllGI-I LUMINOSITY INFRARED lPYROTECHNICAL COMPOSITION DETAILED DESCRIPTION The present invention relates to a high-luminosity pyrotechnical composition which can be used for the production of rockets and similar tracers.
The invention also relates to the process of manufacture of such pyrotechnical compositions.
Pyrotechnical compositions are generally mixtures of combustible substances with metallic oxides or salts selected for the required effect such as a luminous effect obtained when such metallic oxides or salts are raised to incandescence at the instant of combustion of the composition. 7
Some of such compositions are especially used in tracer devices located in back of rockets and similar vehicles for providing emission of radiance allowing the trajectory of such vehicles to be tracked. It is important that such radiation should be powerful and sustainable as long as possible.
Experience has shown that such tracers exhibit very appreciable power losses in flight in comparison with the results obtained when measurements are taken at the datum point. Efforts have been made to reduce such disadvantages by improvements of a mechanical nature.
In particular, it is known to arrange deflectors on the tracers so as to keep the apparent diameter of the flame constant; also it is known to employ an extrusion cowling around the flame so as to create a zone of lesser tur bulence thereat.
It is further known to mount a nozzle at the tracer device outlet forming a convergent-divergent assembly which imparts sufficient velocity to the incandescent particles for them tocross the turbulent zone and reach an area where the propellent-gas and air run side by side to form an extension of the flame and thus render it more visible.
An object of the present invention is to eliminate the aforesaid disadvantages but by another means consisting of a new formulation of the pyrotechnical composition which propagates an emissive power much greater in comparison to that obtained from known pyrotechnical compositions.
According to the invention, the high-luminosity pyrotechnical composition is characterized by containing in finely divided state an illuminant substance of high emissivity in the infrared band, at least one fluorinated resin having fluorine atoms which make up at least twothirds of the total of the halogen atoms, and a metal which is highly reductive in the presence of the resin halogens, the composition being in the form of an agglomerate mix in which the amount of the reducing metal is between that required stoichiometrically and an excess of 20 percent over such stoichiometric amount.
Fluorinated resins are known to decompose at a high temperature in the range of 300 to 400 while liberating gases containing the resin halogens. These halogens, and fluorine in particular, are powerful oxidants and react with numerous metals with a strongly exothermic oxido-reduction reaction.
Experience has shown that at the start of pyrolysis of a fluorinated resin mixed with a reducing metal and an illuminant substance, by means of an electrically ignited primer paste capable of radiating a temperature of the order of 330 C, the gases liberated by such resin combine violently with the reducing metal on contact. Through the heat liberated at the onset of such reaction, pyrolysis continues independently inside the pyrotechnical composition until the resin is completey consumed. The combination of resin and metal operates advantageously as a heat generating unit wherein the resin is consumed and at the same time it allows the particles of illuminant substance dispersed through the composition to be raised to the incandescent state.
In a preferred procedure the amount of reducing metal is experimentally calculated with an excess from 10 to 15 percent of the amount required for complete reduction.
The amount of illuminant substance is selected in the range of 2 to 10 percent by weight of the pyrotechnical composition.
According to one preferred embodiment of the invention, the pyrotechnical composition also comprises barium stearate in the ratio of two to 15 percent by weight of the composition. This addition noticeably affects the fundamental reduction reaction time and through the lubricating properties of the stearate promotes the forming of the composition as well as its molding at high temperature.
The pyrotechnical composition can further contain a binding agent composed of a polymerized polyester resin in a ratio not greater than seven percent by weight of the composition.
BRIEF DESCRIPTION OF THE DRAWING The sole FIGURE of the drawing is a graphical representation of emission for various compositions.
The various constituents of the pyrotechnical composition will now be described in greater detail.
The fluorinated resin is preferably polytetrafluoroethylene. However, other fluorinated resins can also be used, such as polytrifluorochloroethylene, polyvinylidene fluoride, a copolymer of tetrafluoroethylene and hexafluoropropylene and a copolymer of vinylidene fluoride and hexafluoropropylene.
Whenever possible these resins are used in finely powdered form. In other cases, for instance, with the copolymer of vinylidene fluoride and hexafluoropropylene which is an elastomer, the resin is used in the form of particles, as finely divided as possible.
The resins can be used singly or mixed together.
According to the invention, the reducing metal is chosen from the group consisting of magnesium, silicon, zirconium, aluminium and chromium.
All these metals, selected because of their particular affinity for the fluorine and possibly the chlorine contained in the resin are used in the form of a fine powder.
The illuminant substance is preferably an oxide of a metal chosen from the group consisting of iron, nickel, copper and hafnium.
Those metals and their oxides are expediently employed in the form of exceedingly fine-grained powders.
Market quality barium stearate is also used in powder form.
The polymerized polyester resin. before being put to use, is preferably composed of a liquid unsaturated resin mixed with monomeric styrene. At the moment of use, it is treated with a catalyzer which allows the polymerization to be primed at a moderate temperature.
Beside the catalyzer, it can also be treated with an accelerator which will allow such polymerization at ordinary temperature.
The pyrotechnical composition according to the invention can be obtained by press-molding a mixture of 5 powders of the illuminant substance, the reducing metal, at least one fluorinated resin and the barium stearate.
When one or more of the fluorinated resins cannot be reduced to powder, such resin is put into a solvent beforehand to be dissolved therein and then the mixture of the other powdered constituents of the composition is impregnated with such solution; then, the impregnated mixture is dried.
Preferably, when at least one of the fluorinated resins is polytetrafluoroethylene, molding is effected at a temperature around 320 C by the method known as fritting.
Before molding, all of the ingredients except the fluorinated resin or resins are dried for an hour-and-a-half at 150 C.
The binding agent for the pyrotechnical composition is here composed of polytetrafluoroethylene.
According to a second equally preferred method, when for reasons of convenience or safety, it is desirable to avoid bringing the mixture to be molded to a high temperature, the molding is carried out at ambient temperature or at a temperature slightly higher, the components of the mixture being the powdered ingredients and a non-polymerized polyester resin; then the molded composition is allowed to stand whereby the polymerization of the resin is achieved.
Before molding, all of the powdered ingredients except the fluorinated resin or resins are dried as before.
The molding mixture is then completed by adding the fluorinated resin to the polyester resin and adding in succession, to the fluorinated'resin thus coated, first the reducing metal and barium stearate, and then the illuminant substance.
The pyrotechnical composition binder is here made and compressed to a pressure of 1,500 bars.
2. Cold Molding The ingredients other than PFTE were heated and the mixing of the ingredients was effected as follows:
a. premix of PTFE with liquid polyester resin,
b. addition of magnesium and barium stearate to the premix (a), 0. addition of ferric oxide to intermediate mixture The final resultant mix was dried for at least 12 hours and then placed into a mold on a press bed and finally compressed at 800 bars pressure. Then the molded composition was left for at least 15 days for completion of the polymerization of the polyester resin.
All of the pyrotechnical compositions, molded as just described, were formulated in the same way. They were then placed in casings of corresponding form and the molded compositions were tested in trials. It was found that the total energy supplied by a tracer made according to the invention was approximately twice that furnished by a tracer of equal weight, equal emissive surface and equal combustion time made by the conventional method.
Furthermore, the efficiency of producing pyrotechnical compositions according to the invention with variable amounts of barium stearate was established in trials, and the results are shown by the curves in the drawing wherein the combustion times t in seconds are along the abscissa, and the light-flux power levels in watts per steradian are shown along the ordinate (P axis).
Four series of 10 tests were made with compositions comprising an amount p of barium stearate respectively equal to zero percent, three percent, nine percent and 13 percent and complying with following formulation: Polytetrafluoroethylene 30 g, Magnesium 45 g (40 to micron grain size), Fe O 7.5 g, Barium stearate pg, Polyester resin 5 g. The mean emission-curves were determined for each of these series.
The emission curve for the first series not containing any barium stearate and not shown in FIG. 1, exhibited a sharp peak for a combustion time of two seconds.
Emission curve A for the second series comprising three percent barium stearate, exhibited two maxima at 1950 w/stearadian and 1,850 w/sr over a doubled combustion time, namely four seconds.
Emission curve B for the third series comprising 9 percent barium stearate exhibited a maximum power level at 1 w/sr extending over a time of 4.7 seconds whereas the entire combustion time was considerably longer than in the two preceding series, viz., 5.2 seconds.
Emission curve C for the fourth series comprising 13 percent barium stearate differed from the third set by having a slightly sloping, but longer, plateau corresponding to maximum power levels from 900 to 860 w/sr and a substantially longer combustion time of 13.3 seconds.
These tests clearly demonstrate the regulative effect of the barium stearate on the combustion time. An amount of barium stearate between two and four percent according to the invention produces very high maximum power levels of the order of those shown in emission curve A, having at the same time combustion times of adequate duration.
These tests also show that for equal weight of combustion, equal combustion time and equal emission area, the pyrotechnical compositions, according to the invention, offer the outstanding technical advantage of having twice the power obtainable with pyrotechnical compositions of known types.
Furthermore, since rocket tracking stations are usually equipped with infrared ray receivers, the pyrotechnical composition, according to the invention, is eminently adapted thereto, because of the localization of its emissive power, for use in rockets and similar tracers.
What is claimed is:
l. A smokeless high-luminosity pyrotechnical composition consisting essentially of an agglomerate mixture of an illuminant substance of highemissivity in the infrared band, and in finely divided state, the amount of illuminant substance being between two and 10 percent by weight of the composition, said illuminant substance being selected from the group consisting of iron, nickel, copper, hafnium and the oxides thereof, the remainder of said mixture consisting essentially of at least one halogenated resin having fluorine atoms constituting at least two thirds of the total number of halogen atoms, and a metal which is highly reductive with the halogen atoms of the resin, said metal being selected from the group consisting of magnesium, zirconium, aluminium, chromium and silicon, and being present in an amount between that required stoichiometrically for the reduction of said halogen atoms and an excess of 20 percent over such stoichiometrical amount.
2. A composition as claimed in claim 1, containing barium stearate.
3. A composition as claimed in claim 2 wherein the amount of barium stearate is in the range of two to percent by weight of the composition.
4. A composition as claimed in claim 1., containing a binding agent of polymerized polyester resin resulting from the polymerization of unsaturated resin with monomeric styrene.
5. A composition as claimed in claim 4, wherein the amount of polyester resin does not exceed seven percent of the composition.
6. A composition as claimed in claim 1, wherein the excess of reducing metal in relation to the stoichiometrical amount is between 10 and 15 percent.
7. A composition as claimed in claim 1, wherein the halogenated resin is polytetrafluoroethylene, polytrifluorochloroethylene, polyvinylidene fluoride, the copolymer of tetrafluoroethylene and hexafluoropropylene, or the copolymer of vinylidene fluoride and hexafluoropropylene.
8. A composition as claimed in claim 1 wherein the illuminant substance is iron oxide, the halogenated resin is polytetrafluoroethylene and the metal is magnesium.
Claims (7)
- 2. A composition as claimed in claim 1, containing barium stearate.
- 3. A composition as claimed in claim 2 wherein the amount of barium stearate is in the range of two to 15 percent by weight of the composition.
- 4. A composition as claimed in claim 1, containing a binding agent of polymerized polyester resin resulting from the polymerization of unsaturated resin with monomeric styrene.
- 5. A composition as claimed in claim 4, wherein the amount of polyester resin does not exceed seven percent of the composition.
- 6. A composition as claimed in claim 1, wherein the excess of reducing metal in relation to the stoichiometrical amount is between 10 and 15 percent.
- 7. A composition as claimed in claim 1, whErein the halogenated resin is polytetrafluoroethylene, polytrifluorochloroethylene, polyvinylidene fluoride, the copolymer of tetrafluoroethylene and hexafluoropropylene, or the copolymer of vinylidene fluoride and hexafluoropropylene.
- 8. A composition as claimed in claim 1 wherein the illuminant substance is iron oxide, the halogenated resin is polytetrafluoroethylene and the metal is magnesium.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6938022A FR2070262A5 (en) | 1969-11-05 | 1969-11-05 |
Publications (1)
Publication Number | Publication Date |
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US3770525A true US3770525A (en) | 1973-11-06 |
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ID=9042642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US00086193A Expired - Lifetime US3770525A (en) | 1969-11-05 | 1970-11-02 | High luminosity infrared pyrotechnical composition |
Country Status (8)
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US (1) | US3770525A (en) |
JP (1) | JPS497206B1 (en) |
BE (1) | BE757673A (en) |
CA (1) | CA953112A (en) |
DE (1) | DE2054210A1 (en) |
FR (1) | FR2070262A5 (en) |
GB (1) | GB1320352A (en) |
NL (1) | NL7016053A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4276100A (en) * | 1976-02-13 | 1981-06-30 | The United States Of America As Represented By The Secretary Of The Navy | Process for disposing of decoy flare material |
US4445947A (en) * | 1983-03-18 | 1984-05-01 | Thiokol Corporation | Low cost fluorocarbon flare compositions |
US4698108A (en) * | 1985-06-07 | 1987-10-06 | Etat Francais | Castable smoke-generating compounds effective against infrared |
US4719857A (en) * | 1981-04-01 | 1988-01-19 | Pains-Wessex Limited | Pyrotechnic device |
US5435224A (en) * | 1979-04-04 | 1995-07-25 | The United States Of America As Represented By The Secretary Of The Navy | Infrared decoy |
WO1996034249A1 (en) * | 1995-04-24 | 1996-10-31 | Thiokol Corporation | High-intensity infrared decoy flare |
US5639984A (en) * | 1995-03-14 | 1997-06-17 | Thiokol Corporation | Infrared tracer compositions |
EP1637829A1 (en) * | 2004-09-15 | 2006-03-22 | Saab Ab | Pack of heat-generating countermeasures |
US20070272112A1 (en) * | 2000-02-23 | 2007-11-29 | Alliant Techsystems Inc. | Reactive material compositions, shot shells including reactive materials, and a method of producing same |
US20080035007A1 (en) * | 2005-10-04 | 2008-02-14 | Nielson Daniel B | Reactive material enhanced projectiles and related methods |
US20080229963A1 (en) * | 2004-03-15 | 2008-09-25 | Alliant Techsystems Inc. | Reactive material enhanced munition compositions and projectiles containing same |
US8075715B2 (en) | 2004-03-15 | 2011-12-13 | Alliant Techsystems Inc. | Reactive compositions including metal |
DE102012015762A1 (en) * | 2012-08-09 | 2014-02-13 | Diehl Bgt Defence Gmbh & Co. Kg | High-performance active mass for a pyrotechnic decoy with a fluorinated carbon compound |
USRE45899E1 (en) * | 2000-02-23 | 2016-02-23 | Orbital Atk, Inc. | Low temperature, extrudable, high density reactive materials |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5172603A (en) * | 1974-12-18 | 1976-06-23 | Asahi Chemical Ind | AKURIRUKEIGENSHI |
FR2465187A1 (en) * | 1979-05-23 | 1981-03-20 | Thomson Brandt | Infrared radiation generator of consumable type - comprising emissive refractory material layers of approximate black body properties, heat source and source initiator |
FR2471959A1 (en) * | 1979-12-19 | 1981-06-26 | France Etat | Castable, lighting, pyrotechnic compsn. - comprising inorganic oxidant, pref. magnesium powder and aminoplast or phenoplast resin binder |
DE3236418C2 (en) * | 1982-10-01 | 1984-11-15 | Bayern-Chemie Gesellschaft für flugchemische Antriebe mbH, 8261 Aschau | Infrared light pack |
US5456455A (en) * | 1994-02-01 | 1995-10-10 | Thiokol Corporation | Flare pellet and process for making same |
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US3634283A (en) * | 1968-11-05 | 1972-01-11 | Us Navy | Smoke generating compositions and methods of use |
-
0
- BE BE757673D patent/BE757673A/en not_active IP Right Cessation
-
1969
- 1969-11-05 FR FR6938022A patent/FR2070262A5/fr not_active Expired
-
1970
- 1970-10-14 JP JP45090379A patent/JPS497206B1/ja active Pending
- 1970-10-21 GB GB5004570A patent/GB1320352A/en not_active Expired
- 1970-11-02 US US00086193A patent/US3770525A/en not_active Expired - Lifetime
- 1970-11-03 CA CA097,314*7A patent/CA953112A/en not_active Expired
- 1970-11-03 NL NL7016053A patent/NL7016053A/xx unknown
- 1970-11-04 DE DE19702054210 patent/DE2054210A1/en active Pending
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---|---|---|---|---|
US3203171A (en) * | 1958-12-18 | 1965-08-31 | Burke | New missile fuel compositions containing halogens and method of propulsion |
US3163113A (en) * | 1959-01-12 | 1964-12-29 | Burke | High energy fuel units and assemblies |
US3629019A (en) * | 1964-08-11 | 1971-12-21 | Aerojet General Co | Solid propellant composition containing polyesters and an inorganic oxide burning rate catalyst |
US3632632A (en) * | 1967-06-29 | 1972-01-04 | American Cyanamid Co | Carboxy-terminated polyester resins |
US3565706A (en) * | 1968-01-19 | 1971-02-23 | Hal R Waite | Incendiary composition containing a metallic fuel and a solid fluoro-carbon polymer |
US3634283A (en) * | 1968-11-05 | 1972-01-11 | Us Navy | Smoke generating compositions and methods of use |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4276100A (en) * | 1976-02-13 | 1981-06-30 | The United States Of America As Represented By The Secretary Of The Navy | Process for disposing of decoy flare material |
US5435224A (en) * | 1979-04-04 | 1995-07-25 | The United States Of America As Represented By The Secretary Of The Navy | Infrared decoy |
US4719857A (en) * | 1981-04-01 | 1988-01-19 | Pains-Wessex Limited | Pyrotechnic device |
US4445947A (en) * | 1983-03-18 | 1984-05-01 | Thiokol Corporation | Low cost fluorocarbon flare compositions |
US4698108A (en) * | 1985-06-07 | 1987-10-06 | Etat Francais | Castable smoke-generating compounds effective against infrared |
US5639984A (en) * | 1995-03-14 | 1997-06-17 | Thiokol Corporation | Infrared tracer compositions |
WO1996034249A1 (en) * | 1995-04-24 | 1996-10-31 | Thiokol Corporation | High-intensity infrared decoy flare |
US20150203415A1 (en) * | 2000-02-23 | 2015-07-23 | Alliant Techsystems Inc. | Reactive material compositions and projectiles including the same |
US9982981B2 (en) | 2000-02-23 | 2018-05-29 | Orbital Atk, Inc. | Articles of ordnance including reactive material enhanced projectiles, and related methods |
US20070272112A1 (en) * | 2000-02-23 | 2007-11-29 | Alliant Techsystems Inc. | Reactive material compositions, shot shells including reactive materials, and a method of producing same |
USRE45899E1 (en) * | 2000-02-23 | 2016-02-23 | Orbital Atk, Inc. | Low temperature, extrudable, high density reactive materials |
US7977420B2 (en) | 2000-02-23 | 2011-07-12 | Alliant Techsystems Inc. | Reactive material compositions, shot shells including reactive materials, and a method of producing same |
US9103641B2 (en) | 2000-02-23 | 2015-08-11 | Orbital Atk, Inc. | Reactive material enhanced projectiles and related methods |
US20080229963A1 (en) * | 2004-03-15 | 2008-09-25 | Alliant Techsystems Inc. | Reactive material enhanced munition compositions and projectiles containing same |
US8361258B2 (en) | 2004-03-15 | 2013-01-29 | Alliant Techsystems Inc. | Reactive compositions including metal |
US8568541B2 (en) * | 2004-03-15 | 2013-10-29 | Alliant Techsystems Inc. | Reactive material compositions and projectiles containing same |
US8075715B2 (en) | 2004-03-15 | 2011-12-13 | Alliant Techsystems Inc. | Reactive compositions including metal |
EP1637829A1 (en) * | 2004-09-15 | 2006-03-22 | Saab Ab | Pack of heat-generating countermeasures |
US8122833B2 (en) | 2005-10-04 | 2012-02-28 | Alliant Techsystems Inc. | Reactive material enhanced projectiles and related methods |
US20080035007A1 (en) * | 2005-10-04 | 2008-02-14 | Nielson Daniel B | Reactive material enhanced projectiles and related methods |
DE102012015762A1 (en) * | 2012-08-09 | 2014-02-13 | Diehl Bgt Defence Gmbh & Co. Kg | High-performance active mass for a pyrotechnic decoy with a fluorinated carbon compound |
Also Published As
Publication number | Publication date |
---|---|
BE757673A (en) | 1971-04-01 |
FR2070262A5 (en) | 1971-09-10 |
DE2054210A1 (en) | 1971-05-13 |
NL7016053A (en) | 1971-05-07 |
GB1320352A (en) | 1973-06-13 |
CA953112A (en) | 1974-08-20 |
JPS497206B1 (en) | 1974-02-19 |
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