US547967A - Jacob sohalus - Google Patents
Jacob sohalus Download PDFInfo
- Publication number
- US547967A US547967A US547967DA US547967A US 547967 A US547967 A US 547967A US 547967D A US547967D A US 547967DA US 547967 A US547967 A US 547967A
- Authority
- US
- United States
- Prior art keywords
- acid
- sohalus
- jacob
- solution
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 25
- 239000004744 fabric Substances 0.000 description 13
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Chinese gallotannin Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 7
- 235000006408 oxalic acid Nutrition 0.000 description 7
- 229920002258 tannic acid Polymers 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 235000019416 cholic acid Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- BHQCQFFYRZLCQQ-UHFFFAOYSA-N (3alpha,5alpha,7alpha,12alpha)-3,7,12-trihydroxy-cholan-24-oic acid Natural products OC1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)=O)C)C1(C)C(O)C2 BHQCQFFYRZLCQQ-UHFFFAOYSA-N 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 2
- 239000004380 Cholic acid Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N anhydrous gallic acid Natural products OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 210000000941 bile Anatomy 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- BHQCQFFYRZLCQQ-OELDTZBJSA-N cholic acid Chemical compound C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 BHQCQFFYRZLCQQ-OELDTZBJSA-N 0.000 description 2
- 229960002471 cholic acid Drugs 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- KXGVEGMKQFWNSR-UHFFFAOYSA-N deoxycholic acid Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(CCC(O)=O)C)C1(C)C(O)C2 KXGVEGMKQFWNSR-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002812 cholic acid derivative Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- JMTCDHVHZSGGJA-UHFFFAOYSA-M potassium hydrogenoxalate Chemical compound [K+].OC(=O)C([O-])=O JMTCDHVHZSGGJA-UHFFFAOYSA-M 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
Definitions
- My improved liquid consists of a liquid containing a suitable oxalate or oxalic acid and a substance capable of neutralizing its corrosive and bleaching action upon the fabric to be cleansed without destroying its power to remove such stains as ordinarily will occur upon garments or grease or similar soiling.
- a suitable oxalate or oxalic acid and a substance capable of neutralizing its corrosive and bleaching action upon the fabric to be cleansed without destroying its power to remove such stains as ordinarily will occur upon garments or grease or similar soiling.
- the preferable constituents of my invented liquid are salt of sorrel, (acid potassium oxalate C HKOQ a solution of bile, (the most important ingredients being a cholic acid or acids and soda or potassa, forming partly a resinoid soap, as is well known) or a gallnut solution, (principally gallotannic acid C H O, and spirits of wine, the proportion being preferably, by weight, about forty per cent. each of the solution of potassium oxalate and gall-nut or bilious solution and twenty percent. of alcohol. This is most suitable for fine cambrics. For coarser fabrics spirit of sal-ammoniac may be substituted for gallnut. solution and the proportions preferably varied to, say, fifty per cent. of the oxalate, thirty per cent. of the spirit of ammonium chloride, and twenty per cent. of the alcohol.
- the action of the oxalic acid or an oxalate alone is bleaching and corrosive, and while it will take out stains and remove the grease spots it will also completely destroy the fab ric and remove the color.
- the gallic, tannic, or gallotannic acid in the gall-nut solution or the cholic acid, and in less degree perhaps the resinoid soapy material of the bile solution, will act upon the fiber and the dye and protect them from destruction by the oxalic acid or oxalate, and will also combine with the oxalic acid or its salt to render it innocuous to the fabric and its dye.
- ammonium chloride with the oxalic acid or its salt is also mainly for the purpose of rendering the oxalic acid innocuous to the fabric and dye.
- the spirit of wine in this case also is merely a diffuser and drier, oausing'the mixture to diffuse quickly and thoroughly through the fabric and also to dry out quickly, and when this is not requisite it may be omitted both with the solution containing chloride and that containing the tannic acid.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
UNITED STATES PATENT EErcE.
JACOB SCHALUS, OF GUNTERSBLUM, GERMANY.
LIQUID FO R REMOVING STAINS FROM TEXTILE FABRICS.
SPECIFICATION forming part of Letters Patent No. 547,967, dated October 15, 1895. Application filed December 15 1894. Serial No. 531,953. (No specimens.)
Z' 0 whom it may concern;
Be it known that I, JACOB SOHALUS, of Guntersblum, in the German Empire, have invented a new and useful Liquid for Removing Stains from Textile Fabrics, of which the following is a specification.
My improved liquid consists of a liquid containing a suitable oxalate or oxalic acid and a substance capable of neutralizing its corrosive and bleaching action upon the fabric to be cleansed without destroying its power to remove such stains as ordinarily will occur upon garments or grease or similar soiling. To make the compound thus formed capable of penetrating freely into the material, and at the same time cause it to dry out therefrom quickly,I dissolve them in a medium suitable to produce these results.
The preferable constituents of my invented liquid are salt of sorrel, (acid potassium oxalate C HKOQ a solution of bile, (the most important ingredients being a cholic acid or acids and soda or potassa, forming partly a resinoid soap, as is well known) or a gallnut solution, (principally gallotannic acid C H O, and spirits of wine, the proportion being preferably, by weight, about forty per cent. each of the solution of potassium oxalate and gall-nut or bilious solution and twenty percent. of alcohol. This is most suitable for fine cambrics. For coarser fabrics spirit of sal-ammoniac may be substituted for gallnut. solution and the proportions preferably varied to, say, fifty per cent. of the oxalate, thirty per cent. of the spirit of ammonium chloride, and twenty per cent. of the alcohol.
' These proportions act very successfully. First each spot will be removed entirely and without leaving any border or outline of the stain, such as has frequently been observed after cleansing liquids have been used heretofore. At the same time there is no destruction of the fiber, and the fabric therefore does not become rotten or brittle at the parts subject to the action of the liquid.
The action of the oxalic acid or an oxalate alone is bleaching and corrosive, and while it will take out stains and remove the grease spots it will also completely destroy the fab ric and remove the color. The gallic, tannic, or gallotannic acid in the gall-nut solution or the cholic acid, and in less degree perhaps the resinoid soapy material of the bile solution, will act upon the fiber and the dye and protect them from destruction by the oxalic acid or oxalate, and will also combine with the oxalic acid or its salt to render it innocuous to the fabric and its dye.
The use of ammonium chloride with the oxalic acid or its salt is also mainly for the purpose of rendering the oxalic acid innocuous to the fabric and dye. The spirit of wine in this case also is merely a diffuser and drier, oausing'the mixture to diffuse quickly and thoroughly through the fabric and also to dry out quickly, and when this is not requisite it may be omitted both with the solution containing chloride and that containing the tannic acid.
What I claim, and desire to secure by Letters Patent, isv 1. Aliquid for removing stains from fabrics containing oxalic acid or salt thereof gallotannic acid and a diffusing medium substantially as describedr 2. Aliquid for removing stains from fabrics containing acid potassium oxalate, gallotannic acid, and a diffusing and drying medium substantially as described.
3. Aliquid for removing stains from fabrics containing acid potassium oxalate, an anticorrosive material for protecting the fabric and its dye and a diffusing and drying medium in which the same are dissolved substantially as described.
In witness whereof I have hereunto set my hand in presence of two witnesses.
J AGOB SOHALUS. Witnesses:
JAMES H. SMITH, CARL ED. HAHN.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US547967A true US547967A (en) | 1895-10-15 |
Family
ID=2616710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US547967D Expired - Lifetime US547967A (en) | Jacob sohalus |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US547967A (en) |
-
0
- US US547967D patent/US547967A/en not_active Expired - Lifetime
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