US5316736A - Apparatus for reacting a gas and a particulate material in an enclosure, and method for operating said apparatus - Google Patents

Apparatus for reacting a gas and a particulate material in an enclosure, and method for operating said apparatus Download PDF

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US5316736A
US5316736A US07/778,089 US77808991A US5316736A US 5316736 A US5316736 A US 5316736A US 77808991 A US77808991 A US 77808991A US 5316736 A US5316736 A US 5316736A
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zone
reactor
fluidized bed
gas
particulate material
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Jean Vidal
Philippe Payen
Jean-Claude Semedard
Jean-Xavier Morin
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Stein Industrie SA
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Stein Industrie SA
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • B01J8/28—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
    • B01J8/388—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B31/00—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus
    • F22B31/0007—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed
    • F22B31/0084—Modifications of boiler construction, or of tube systems, dependent on installation of combustion apparatus; Arrangements of dispositions of combustion apparatus with combustion in a fluidized bed with recirculation of separated solids or with cooling of the bed particles outside the combustion bed
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C15/00—Apparatus in which combustion takes place in pulses influenced by acoustic resonance in a gas mass

Definitions

  • the present invention relates to apparatus for performing an exothermal or an endothermal reaction inside an enclosure (referred to below as a "reactor") between at least one gas and at least one particulate material, the apparatus comprising at least one means for introducing particulate material, at least one means for introducing reaction and fluidization gas, with the respective introduced flow rates of the particulate material and of the fluidization gas being such that they enable a fast upward flow of gas and particulate material to be established within fast circulating fluidized bed zones, means for directing a mixture of the reaction gas and the particulate material reaching the top of the reactor into a separator, means for exhausting the gas produced by the reaction, and means for recycling the particulate material from the separator to the bottom of the reactor.
  • a first group uses a dense fluidized bed [also called a "bubbling" bed] characterized by the existence of two zones having distinct particle concentrations within the reaction enclosure, with particle concentration being high in a first zone, e.g. 1,000 kg/m 3 for a combustion fluidized bed, and much lower, less than 1 kg/m 3 in a second zone above the first and separated therefrom by a relatively well-defined surface.
  • the velocity difference between the gases and the solid particles is not large.
  • combustion efficiencies are low, e.g. 85% to 95%, and the rates at which sulfur oxides and nitrogen oxides are rejected are significant, thereby limiting this technique to small plants.
  • This type of apparatus suffers from the above-mentioned drawbacks of dense fluidized bed reactors, mainly the existence of a reaction zone having a very low concentration of particles above the dense bed. Further, it recirculates particulate matter taken solely from the upper part of the dense fluidized zone in the same manner as would a cyclone if located at the outlet from a circulating fluidized bed of the type described below.
  • a second group of known techniques makes use of a "circulating" fluidized bed of a type described in an article by REH published in the journal Chemical Engineering Progress, February 1971. This is described, in particular, in French Pat. Nos. 2 323 101 and 2 353 332 (Metallgesellschaft) [corresponding to U.S. Pat. No. 4,165,717]. It differs from the first group in particular by the lack of any separation surface between two zones and by the existence of a uniform reaction temperature throughout the reactor. The concentration or suspension density of particulate material varies substantially continuously from the bottom to the top of the reactor body, and the difference between the velocities of the gases and of the solid particles is much higher. For combustion reactors, combustion efficiencies are improved and the rates at which sulfur oxides and nitrogen oxides are rejected are lower. This technique is suitable for application to large plants, but it nevertheless suffers from drawbacks.
  • Heat exchange takes place in this higher zone, and in general it has tubes occupying the empty space in the reactor or it has walls lined with tubes through which a reactor cooling fluid passes.
  • the concentration of particles varies from the bottom to the top of this zone, from about 50 kg/m 3 to about 10 kg/m 3 , for example, and the figures may sometimes be even lower.
  • the concentrations of particles provide heat exchange with the tubes lining the walls.
  • the velocity of the gases is at full load is generally limited to values in the range 4 meters per second (m/s) to 6 m/s in order to avoid any risk of erosion; and
  • a lower zone of smaller volume having a much higher concentration of particles varying from bottom to top, for example, from 500 kg/m 3 to 50 kg/m 3 , i.e. in a ratio of 10:1, which ratio may even exceed 20:1 if the reactor is operating at half load, i.e. with the fluidization gas flowing at half velocity.
  • This lower zone is where combustion takes place.
  • a portion of the gas required for combustion generally referred to as "primary" gas, is blown therein through a fluidization grid located at the bottom of the reactor.
  • the major portion of the remainder of the combustion gas, called “secondary" gas is injected at various levels above said grid, and the use of these levels may vary depending on the load in the reactor (with some of the levels being unused when the reactor is at partial load).
  • concentration of unburnt particles and carbon monoxide may be high at the outlet of the reactor especially with some fuels that are difficult to burn;
  • desulfurization efficiency may be too low, thus requiring large quantities of desulfurization agent to be injected;
  • the velocity of the fluidzation gas in the combustion zone is related to the velocity selected in the higher zone where heat exchange occurs;
  • solid particles are moving both up and down as shown in diagrammatic FIG. 1, and many solid particles of small size never move down to the vicinity of the fluidization grid, thereby producing vertical particle size stratification inside the reactor and causing the lower zone of the reactor to operate with larger sized particles.
  • the solid concentration in the first meter above the fluidization grid comes close to that of a dense bed, which is costly in energy and of no use for combustion.
  • U.S. Pat. No. 4,594,967 and European patent No. 0 332 360 provide for the installation of a dense fluidized bed for capturing material at the outlet from the circulating fluidized bed, the material captured in this way reducing the amount of material captured in a conventional cyclone situated downstream from the expansion chamber constituting a clearance zone situated above the dense bed.
  • the cyclone is situated either directly downstream from the expansion chamber (EP patent No. 0 332 360) or else after a tubular enclosure fitted with heat exchangers for reducing the temperature of the gases (U.S. Pat. No. 4,594,967) and therefore not forming a part of the circulating fluidized bed of the patent; in all of these cases the material taken by the dense fluidized bed reduces the material collected in the cyclone and does not alter the maximum quantity of material recycled in the circulating fludized bed; and
  • the expansion chamber situated downstream from the zone containing the dense fluidized bed that does not have all of the fundamental characteristics of a circulating bed (uniform temperature, rising gas speed, solid matter concentration) that enable said zone to be used for transferring heat from the gas-solid mixture to the walls while retaining uniform temperature and gas-solid mixing good for containing chemical reactions.
  • U.S. Pat. No. 4 788 919 provides for subdividing a single chamber into three, two, or one, with the boundaries between each of these chambers being provided by means of an expansion chamber whose section, as mentioned, may be four times that of the reactor, such that the gas velocity therein is no longer that of a circulating fluidized bed reactor.
  • An object of the present invention is to provide apparatus for obtaining a reaction in an enclosure between a gas and a particulate material, the apparatus including a new fluidized bed disposition offering greater uniformity in the concentration of solid particles in the lower zone with a moderate concentration of solid particles in said zone which optionally constitutes a combustion zone, and with a relatively high fluidization gas flow velocity through said lower zone.
  • the reactor is divided into three zones:
  • a lower zone operating under fast fluidized bed conditions with a mean upward velocity of the fluidization gas under empty conditions and at full load in the range 4.8 m/s to 12 m/s, the height of said zone being such that the gas residence time through said lower zone lies in the range 0.25 seconds to 4 seconds;
  • the apparatus further including at least one means for reinjecting particulate material from said dense fluidized bed zone to the bottom of said lower zone operating under fast fluidized bed conditions, the rate at which particulate material is re-injected from said zone operating under dense fluidized bed conditions being greater than the quantity:
  • the pressure profile up the height of the circulating fluidized bed zones is as indicated in the graph of FIG. 7.
  • the particle concentration as deduced from the slope at any point on the profile has a region of discontinuity on either side of the overflow from the dense fluidized bed, and this is characteristic of the apparatus.
  • combustion is improved by a decrease in the formation of carbon monoxide and unburnt particles, particularly with fuels that are difficult to burn: e.g. anthracites and coals having low volatile matter content; and
  • the invention also extends to the application of the above-defined apparatus to the combustion of substances containing carbon.
  • Powdered coal burning apparatuses of the invention are described below by way of example and with reference to the diagrammatic figures of the accompanying drawings.
  • FIG. 1 is a diagram showing the flow of particulate materials in a prior art type of circulating fluidized bed reactor.
  • FIG. 2 shows apparatus in accordance with the invention having circulating fluidized beds and an intermediate dense fluidized bed.
  • FIGS. 3A and 3B are two vertical sections at right angles to each other through the lower zone of a reactor having two lateral dense fluidized beds, with FIG. 3B being a section on line IIIB-IIIB of FIG. 3A.
  • FIGS. 4A and 4B are two vertical sections at right angles to each other through the lower zone of a reactor having three dense fluidized beds, with FIG. 4B being a section on line IVB--IVB of FIG. 4A.
  • FIGS. 5A and 5B are two vertical sections at right angles to each other through the lower zone of a reactor having four dense fluidized beds, FIG. 5B being a section on line VB--VB of FIG. 5A.
  • FIGS. 6A, 6B, and 6C show the layout of heat exchange surfaces in the two dense beds of a reactor, FIGS. 6B and 6C being two variants of a section on line VIB--VIB of FIG. 6A.
  • FIG. 7 is a graph showing pressure as a function of height in apparatus of the invention.
  • the reactor 1 includes a flared lower zone 2 and a higher zone 3 of rectangular section. Solid particles rise above the fluidization grid 4 towards the top of the reactor as shown by arrows 5. These particles tend to move off towards the walls and to fall down again. However, some of the finer particles are re-entrained upwards by turbulent motion as shown at 6. Other particles move towards the wall and flow down it as shown by arrows 7.
  • a fast flow fluidized bed F 1 is set up in the flared portion 2 of lower zone over the fluidization grid 4.
  • a primary fluidization gas as per arrow 8a as delivered by a duct 8 is injected through this grid, said gas being constituted by air, possibly mixed with flue gas.
  • Fuel as per arrow 9a in powder form, e.g. a suspension in air of coal dust, is also injected via a duct 9 immediately above the grid.
  • a secondary gas from a secondary gas supply duct 40 is injected into the lower zone I of the reactor at three of successive levels via branch ducts or nozzles as depicted by arrows 10 a , 11 a and 12 a , respectively 10, 11, and 12.
  • the fluidization gas velocity under empty conditions and at full load may vary from about 4.8 m/s to about 12 m/s, with the residence time of the gases under full load varying from 0.25 seconds to 4 seconds.
  • the secondary gas is injected in such a manner as to ensure that the atmosphere in the bottom of the lower zone I is a reducing atmosphere.
  • a second fast circulation fluidized bed F 2 is established in a zone II, with the velocity of the fluidization gas under empty conditions and at full load varying in the range 4 m/s to 10 m/s, and with the residence time thereof varying in the range 2 seconds to 10 seconds.
  • flue gas mixed with solid particles as per arrow 41a taken from the reactor outlet duct 41 enters a separation cyclone 1A from which the dust-free flue gas is removed by a duct 1B and the captured solid particles as per arrow 42 are recycled through the bottom of the reactor by a duct 1C.
  • a dense fluidized bed 13A (represented by shading) is established at the exit from the combustion zone C having a section tail area S 1 , and above a fluidization grid 14 through which an auxiliary fluidization gas as per arrow 15a is injected from a duct 15.
  • the velocity of this gas through the dense bed 13A under empty conditions and at full load may vary in the range 0.3 m/s to 2.5 m/s. In most cases, little residual combustion takes place in this dense bed, since it is located at the outlet from the combustion zone C of the fast circulating bed F 1 , and the residual carbon content of the particles is already very low. Should considerable combustion take place in the dense fluidized bed 13A, e.g.
  • flue gas could be injected into the injection nozzles beneath the grid of this dense bed 13A so as to decrease the oxygen content in the bed, or else, on the contrary, the oxygen content in this zone may be increased to increase combustion, in which case it may be necessary to have heat exchange tubes in the bed.
  • the height of such a dense fluidized bed 13A is preferably relatively low, generally less than 1.5 m. However, its height may be increased to about 3 m to about 4 m if it is desired to install a heat exchanger therein.
  • This dense fluidized bed 13A An essential function of this dense fluidized bed 13A is to capture a fraction of the solid particles falling down from the heat exchange zone located above the dense fluidized bed (arrows 7), and also to capture a fraction of the solid particles rising from the lower zone I of the reactor, located lower than the dense bed 13A (arrows 16). This capture of particles coming form the lower zone I of the reactor is due to the reduction in the velocity of the gas on entering the higher zone of the reactor. Nevertheless, it should be observed that unlike other methods, and except within the dense fluidized beds, gas velocity does not drop anywhere inside the reactor to below a value corresponding to operation under circulating fluidized bed conditions.
  • the solid particles captured by the dense fluidized bed 13A are conveyed by ducts 17 to the bottom of the reactor, as per arrow 17a immediately above the grid 4.
  • These ducts may include respective siphon seals fed with fluidization gas at their bottoms.
  • concentration or suspension density of particles of this size in the combustion zone C of the reactor is thus greatly increased, particularly in its higher region close to the level of the dense bed 13A.
  • the gas velocity in the lower zone I portion 2 of the reactor is higher than the gas velocity in the higher zone II portion 3 above the level of the dense bed 13A.
  • the required value of the gas velocity in the combustion zone C may be obtained by selecting the section areas S 1 and S 2 , with S 1 being the section area of the combustion zone at the level of the dense fluidized bed 13A, and S 2 being the section area of the higher zone portion 3 of the reactor, such that the section area of the dense fluidized bed 13 is then equal to the difference S 2 -S 1 .
  • the flow rate of solid particles being recirculated by the ducts 17 also depends on this ratio of section areas, since the higher the velocity in the combustion zone C, the greater the flow rate of solid particles from the outlet of said zone, and the greater the flow rate of particulate materials captured by the dense fluidized bed 13A, since the quantity of particles falling down to the bottom of the zone II located above the dense bed 14A, 14B depends substantially on the section area S 2 .
  • the selected section area (S 2 -S 1 ) for the dense bed 13 is thus an important criterion in designing the reactor of apparatus in accordance with the invention. By increasing the velocity of the gases and the concentration of particulate materials in the combustion zone, it determines to a large extent the improvement obtained in the uniformity of the solid concentration in the combustion zone, compared with the concentrations in a prior art fluidized bed.
  • FIGS. 3A and 3B show the bottom of a reactor fitted with two dense fluidized beds 14A and 14B at an intermediate level, the beds being connected via respective recirculation ducts 17A and 17B to the bottom of the combustion zone, above the fluidization grid 4.
  • 17B is shown diagrammatically as a particle reinjection duct including a siphon seal fed with fluidization gas at the bottom of the siphon seal.
  • S 2 /S 1 can thus more easily be obtained, with the difference (S 2 -S 1 ) being equal to the sum of the section areas of the two dense fluidized beds.
  • This reactor does not include dense fluidized beds close to its lateral faces 18 and 19 perpendicular to the first faces, as shown in the section plane perpendicular to that of 3A (on line IIIB-IIIB).
  • FIGS. 4A and 4B show the bottom of a reactor having three dense fluidized beds, two of them, 14A and 14B, beneath the walls 20 and 21 of FIG. 4A, and a third, 14C, beneath the wall 22 perpendicular to the first walls in the section plane perpendicular to that of FIG. 4A (line IVB--IVB in said figure).
  • FIGS. 5A and 5B show the bottom of a reactor having four dense fluidized beds, two of them 14A and 14B being beneath the walls 20 and 21, and the other two 14C and 14D being beneath the perpendicular walls 22 and 23.
  • FIG. 6A is a diagram showing heat exchange surfaces in the dense fluidized beds.
  • Heat exchange tubes are represented by coils 26 and 27. They extend over nearly the full height of the dense fluidized beds.
  • FIG. 6B shows a variant of the disposition of heat exchangers in the dense fluidized beds of FIG. 6A, the variant being shown in section on line VIB--VIB of FIG. 6A.
  • Such heat exchangers occupy the major portion of the length of the dense fluidized beds.
  • FIG. 6C shows a second variant of the FIG. 6A arrangement of exchangers in the dense fluidized beds, FIG. 6C being a section on line VIB--VIB of FIG. 6A.
  • the two dense beds are both divided into three respective separate compartments.
  • the end compartments thereof are occupied by heat exchangers such as 26, 28 or 27, 29 while the middle compartments 30, 31 are not occupied by heat exchange tubes.
  • All of the compartments 26, 27, 28, 29, 30, and 31 are connected by re-injection means 17 to the bottom of the reactor, with each compartment having its own re-injection means.
  • the re-injection means of the compartments 30 and 31 are not provided with flow rate control means.
  • All of the dense fluidized beds as shown in FIGS. 3 to 5 are in operation when the reactor is at full load and they participate in cooling the reactor.
  • cooling can be controlled in various ways (modulating or stopping fluidization, controlling the rate at which particles are re-injected into the bottom of the lower part) so as to maintain an optimum temperature close to 850° C. in the reactor, thus ensuring better desulfurization efficiency.
  • the temperature in the reactor also decreases because the cooling surface area becomes too large.
  • apparatus of the invention is capable of providing decoupling between the higher zone where the walls are constituted by heat-exchange tubes where gas velocity is selected to be optimum for obtaining good heat exchange without eroding the heat exchange tubes, and the lower combustion zone where a higher gas velocity is selected and where a more uniform concentration of particulate materials is ensured than in prior art circulating fluidized beds. For example, if a velocity of 6 m/s is required in the higher zone of the reactor, the lower zone thereof may be operated at a velocity in the range 7.2 m/s to 12 m/s.
  • the means for obtaining a reaction between a gas and a particulate material as described above with reference to the figures relate to apparatus for burning carbon-containing substances, with the reactor being cooled by having the walls of its higher zone constituted by or lined with heat exchange tubes, it will be understood that the invention applies to exothermal reactions other than combustion, and even to endothermal reactions, such as the calcination of alumina for example, so long as it is desired to improve the uniformity of solid concentration in the lower zone of the reactor and to operate in said zone at high velocities which are not suitable for the higher zone thereof. With endothermal reactions, the higher zone is naturally not provided with heat exchange tubes in direct contact with the particles.

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  • Chemical & Material Sciences (AREA)
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  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
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  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
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  • Physics & Mathematics (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Crucibles And Fluidized-Bed Furnaces (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
US07/778,089 1990-04-20 1991-04-18 Apparatus for reacting a gas and a particulate material in an enclosure, and method for operating said apparatus Expired - Lifetime US5316736A (en)

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FR9005060A FR2661113B1 (fr) 1990-04-20 1990-04-20 Dispositif de realisation d'une reaction entre un gaz et un materiau solide divise dans une enceinte.
FR9005060 1990-04-20
PCT/FR1991/000325 WO1991016130A1 (fr) 1990-04-20 1991-04-18 Dispositif de realisation d'une reaction entre un gaz et un materiau solide divise dans une enceinte

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US5508007A (en) * 1992-04-27 1996-04-16 Societe Anonyme Dite: Stein Industrie Circulating fluidized bed reactor including external heat exchangers fed by internal recirculation
US5707591A (en) * 1993-11-10 1998-01-13 Gec Alsthom Stein Industrie Circulating fluidized bed reactor having extensions to its heat exchange area
US5954001A (en) * 1995-06-07 1999-09-21 Gec Alsthom Stein Industrie Fluidized bed reactor for heat treatment of waste
US5996512A (en) * 1997-01-30 1999-12-07 Gec Alsthom Stein Industrie System for recycling refuse
US6032591A (en) * 1997-01-30 2000-03-07 Gec Alsthom Stein Industrie System for recycling refuse
US20120237883A1 (en) * 2009-11-10 2012-09-20 Foster Wheeler Energia Oy Method of and Arrangement for Feeding Fuel Into a Circulating Fluidized Bed Boiler
US20170016616A1 (en) * 2013-12-16 2017-01-19 Doosan Lentjes Gmbh Fluidized Bed Heat Exchanger

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DE4135582A1 (de) * 1991-10-29 1993-05-06 Metallgesellschaft Ag, 6000 Frankfurt, De Wirbelbettkuehler fuer eine anlage zum thermischen behandeln koerniger feststoffe in der wirbelschicht
ATE148545T1 (de) * 1992-11-10 1997-02-15 Foster Wheeler Energia Oy Verfahren und vorrichtung zum betrieb eines reaktorsystems mit zirkulierender wirbelschicht
US5406914A (en) * 1992-11-10 1995-04-18 A. Ahlstrom Corporation Method and apparatus for operating a circulating fluidized bed reactor system
US5341766A (en) * 1992-11-10 1994-08-30 A. Ahlstrom Corporation Method and apparatus for operating a circulating fluidized bed system
WO1996002792A2 (fr) * 1994-07-15 1996-02-01 Aalborg Industries A/S Echangeur de chaleur en lit fluidise, systemes de reacteur de combustion en lit fluidise et procedures d'exploitation d'un echangeur de chaleur en lit fluidise ainsi que systeme de reacteur de combustion en lit fluidise
FI105236B (fi) * 1998-06-15 2000-06-30 Outokumpu Oy Syöttölaitteisto sulatusuuniin syötettävän syöttöseoksen esivalmistamiseksi
DE19937521A1 (de) * 1999-08-03 2001-02-15 Harald Martin Verfahren und Vorrichtung zum Trocknen, Trennen, Klassieren und Zersetzen von Abprodukten
FR2896709B1 (fr) * 2006-02-02 2008-02-29 Alstom Technology Ltd Separateur de solides en particulier pour installation de combustion
FR2937886B1 (fr) * 2008-10-30 2011-05-20 Jean Xavier Morin Dispositif de lit fluidise a fluidisation rapide et a flux sature de solides circulants
CN112696665B (zh) * 2020-12-31 2022-03-29 华电国际电力股份有限公司天津开发区分公司 一种快速调节负荷升降速率的循环流化床锅炉

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US4165717A (en) * 1975-09-05 1979-08-28 Metallgesellschaft Aktiengesellschaft Process for burning carbonaceous materials
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5508007A (en) * 1992-04-27 1996-04-16 Societe Anonyme Dite: Stein Industrie Circulating fluidized bed reactor including external heat exchangers fed by internal recirculation
US5707591A (en) * 1993-11-10 1998-01-13 Gec Alsthom Stein Industrie Circulating fluidized bed reactor having extensions to its heat exchange area
US5954001A (en) * 1995-06-07 1999-09-21 Gec Alsthom Stein Industrie Fluidized bed reactor for heat treatment of waste
US5996512A (en) * 1997-01-30 1999-12-07 Gec Alsthom Stein Industrie System for recycling refuse
US6032591A (en) * 1997-01-30 2000-03-07 Gec Alsthom Stein Industrie System for recycling refuse
US20120237883A1 (en) * 2009-11-10 2012-09-20 Foster Wheeler Energia Oy Method of and Arrangement for Feeding Fuel Into a Circulating Fluidized Bed Boiler
US20170016616A1 (en) * 2013-12-16 2017-01-19 Doosan Lentjes Gmbh Fluidized Bed Heat Exchanger
US10900660B2 (en) * 2013-12-16 2021-01-26 Doosan Lentjes Gmbh Fluidized bed heat exchanger

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AU7795991A (en) 1991-11-11
FI104053B1 (fi) 1999-11-15
JPH05501080A (ja) 1993-03-04
DK0453373T3 (da) 1993-12-27
SK279406B6 (sk) 1998-11-04
CZ285304B6 (cs) 1999-07-14
SK112291A3 (en) 1995-08-09
HU212995B (en) 1997-01-28
FI104053B (fi) 1999-11-15
YU72491A (sh) 1994-04-05
FI915961A0 (fi) 1991-12-18
CA2057028A1 (fr) 1991-10-21
PL293179A1 (en) 1992-08-10
RU2048904C1 (ru) 1995-11-27
RO108422B1 (ro) 1994-05-31
FR2661113A1 (fr) 1991-10-25
YU47810B (sr) 1996-01-09
DE69100318D1 (de) 1993-10-07
KR0129711B1 (ko) 1998-04-06
CN1035158C (zh) 1997-06-18
EP0453373B1 (fr) 1993-09-01
KR920702634A (ko) 1992-10-06
ZA912947B (en) 1992-01-29
CA2057028C (fr) 1999-06-08
AU635643B2 (en) 1993-03-25
ATE93747T1 (de) 1993-09-15
CN1056443A (zh) 1991-11-27
HUT61912A (en) 1993-03-29
JP2693864B2 (ja) 1997-12-24
ES2044694T3 (es) 1994-01-01
BR9105719A (pt) 1992-08-04
WO1991016130A1 (fr) 1991-10-31
HU914011D0 (en) 1992-03-30
CZ112291A3 (cs) 1999-07-14
US5453251A (en) 1995-09-26
FR2661113B1 (fr) 1993-02-19
EP0453373A1 (fr) 1991-10-23
DE69100318T2 (de) 1993-12-09
PL167240B1 (pl) 1995-08-31

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