US517533A - Arthur weinberg - Google Patents
Arthur weinberg Download PDFInfo
- Publication number
- US517533A US517533A US517533DA US517533A US 517533 A US517533 A US 517533A US 517533D A US517533D A US 517533DA US 517533 A US517533 A US 517533A
- Authority
- US
- United States
- Prior art keywords
- dye
- stuffs
- diamin
- black
- weinberg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OETHQSJEHLVLGH-UHFFFAOYSA-N [amino-(diaminomethylideneamino)methylidene]-dimethylazanium;chloride Chemical compound Cl.CN(C)C(=N)N=C(N)N OETHQSJEHLVLGH-UHFFFAOYSA-N 0.000 description 12
- 239000002253 acid Substances 0.000 description 10
- 239000000835 fiber Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RUAZVLYSJWBVRB-UTKMUYHOSA-N (3Z)-5-amino-3-[[4-[4-[(2Z)-2-(8-amino-1-oxo-3,6-disulfonaphthalen-2-ylidene)hydrazinyl]-3-methylphenyl]-2-methylphenyl]hydrazinylidene]-4-oxonaphthalene-2,7-disulfonic acid Chemical compound O=C/1C2=C(N)C=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C\1=N/NC(C(C)=C1)=CC=C1C1=CC=C(N\N=C\2C(=CC3=CC(=CC(N)=C3C/2=O)S(O)(=O)=O)S(O)(=O)=O)C(C)=C1 RUAZVLYSJWBVRB-UTKMUYHOSA-N 0.000 description 2
- HFACYLZERDEVSX-UHFFFAOYSA-N Benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000001049 brown dye Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 125000004957 naphthylene group Chemical group 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
Definitions
- the object of this invention is a new method of the production on the fiber, by the aid of 1 5 para-amidodiphenylamin, of dye-stuffs fast to light and washing.
- the para-amidodiphenylamin cannot be combined withdiazo bodies to form normal azo-dye-stuffs. If the two bodies are brought together no diazoamido compounds result, but nitrogen is generated, and colorless or weakly colored substances are formed, the constitution of which has not yet been ascertained.
- the para-amidodiphenylamin reacts on diazo compounds produced on the fiber from dyestufis which contain diazotizableamido-groups.
- the diazotizable dye-stuffs are the diazo dye-stuffs in general deriving from paradiamins, such as benzidin and its analogous bodies, and on the other hand, amidonaphtholsulfo acids, alphanaph- 3 5 thylarnin, alpha naphthylaminsulfo acids alpha beta or alpha betaalpha beta amidonaphtholether, alpha beta amidonaphtholethersulfo acid.
- dye-stuffs are of special value the products from gamma amidonaphtholsulfo acid, namely diamin black R and B, diamin blue black E, diamin black B H, diamin brown V, the products from amidonaphtholdisulfonic acid H, as diamin blue BX, 213,313, the naphthylene violet described in theUnited States Letters PatentNo.4.64,566, the brown dye stuffs mentioned in the German Patent No.
Description
STATES PATENT OFFI E.
ARTHUR WEINBERG, OF FRANKFORT-ON-THE-MAIN, GERMANY, ASSIGNOR TO LEOPOLD OASSELLA & 00., OF SAME PLACE.
PROCESS OF DYEING BY THE AID OF PARAMI DODIPHENYLAMIN.
SPECIFICATION forming part of Letters Patent No. 517,533, dated April 3, 1894.
Application filed November 29,1893i Serial No. 492/1 04. (No specimens.) Patented in England March 2,1893, No. 4,612, and in France March 4,1898,No.228,395.
T at whom it may concern.-
Be it known that I, ARTHUR WEINBERG, a subject of the King of Prussia, Emperor of Germany, and a resident of Fraukfort-on-the- Main, Germany, have invented new and useful Improvements in the Production on the Fiber, by the Aid of Paramidodiphenylamin, of Dye-Stuffs Fast to Light and Washing, (for which patents have beenobtained in Great IO Britain, No. 4,612, dated March 2, 1893, and
in France, No. 228,395, dated March 4, 1893,)
of which the following is a specification.
The object of this invention is a new method of the production on the fiber, by the aid of 1 5 para-amidodiphenylamin, of dye-stuffs fast to light and washing. The para-amidodiphenylamin cannot be combined withdiazo bodies to form normal azo-dye-stuffs. If the two bodies are brought together no diazoamido compounds result, but nitrogen is generated, and colorless or weakly colored substances are formed, the constitution of which has not yet been ascertained. In quite a difierent and unforeseen manner the para-amidodiphenylamin reacts on diazo compounds produced on the fiber from dyestufis which contain diazotizableamido-groups. In these cases intense and exceedingly fast dyeings are produced. For this purpose the most useful 0 among the diazotizable dye-stuffs on the one hand, are the diazo dye-stuffs in general deriving from paradiamins, such as benzidin and its analogous bodies, and on the other hand, amidonaphtholsulfo acids, alphanaph- 3 5 thylarnin, alpha naphthylaminsulfo acids alpha beta or alpha betaalpha beta amidonaphtholether, alpha beta amidonaphtholethersulfo acid. Of such dye-stuffs are of special value the products from gamma amidonaphtholsulfo acid, namely diamin black R and B, diamin blue black E, diamin black B H, diamin brown V, the products from amidonaphtholdisulfonic acid H, as diamin blue BX, 213,313, the naphthylene violet described in theUnited States Letters PatentNo.4.64,566, the brown dye stuffs mentioned in the German Patent No. 58,617 as well as other substitutes recommended for the same purposes, which are brought into the market under different denominations as diazurin, diazoblack, 5o diazobrown, benzoblue, Nyanza black, Tabora black, Zambezi blue, &c.
The process is explained by the following example: One hundred kilos cotton are dyed in an alkaline bath with five kilos diamin blue 5 black E, for-one hour at the boil. It is rinsed and then entered into a cold bath, in which are dissolved 0.5 kilos nitrite and which is acidulated with two kilos muriatic acid. After about five minutes the diazotation is terminated. Then the cotton is entered after being rinsed into a third bath, containing a solution of 1.5 kilos chlorh yd rate of para-amidodiphenylamin. At once a dark blue dyeing appears, which is fast to light and washing. In an analogous way the other colors are developed.
Having now particularly'described and ascertained the nature of my said invention and in what manner the same is to be performed, what I claim, and desire to secure by Letters Patent, is
The method of producing fast colors on the fiber dyed with a diazotizable dye-stuff by treating such dyeings in a first bath with free nitrous acid and developing the color in a second bath containing para-amidodiphenyl amin substantially as herein described.
In testimony that Iclaim the foregoing as my invention I have signed my name,in pres- 8o ence of two witnesses, this 11th day of November, 1893.
ARTHUR WEINBERG.
Witnesses:
ALVESTO S. HOGUE, JEAN GRUND.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US517533A true US517533A (en) | 1894-04-03 |
Family
ID=2586336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US517533D Expired - Lifetime US517533A (en) | Arthur weinberg |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US517533A (en) |
-
0
- US US517533D patent/US517533A/en not_active Expired - Lifetime
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