US5110474A - Method for liquid chromatographic extraction of strontium from acid solutions - Google Patents

Method for liquid chromatographic extraction of strontium from acid solutions Download PDF

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Publication number
US5110474A
US5110474A US07/507,419 US50741990A US5110474A US 5110474 A US5110474 A US 5110474A US 50741990 A US50741990 A US 50741990A US 5110474 A US5110474 A US 5110474A
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Prior art keywords
strontium
solution
values
column
technetium
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US07/507,419
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English (en)
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E. Philip Horwitz
Mark L. Dietz
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Arch Development Corp
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Arch Development Corp
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Priority to US07/507,419 priority Critical patent/US5110474A/en
Priority to DE69125275T priority patent/DE69125275T2/de
Priority to PCT/US1991/002424 priority patent/WO1991015280A1/en
Priority to EP91908830A priority patent/EP0525100B1/de
Priority to JP3508601A priority patent/JP2620447B2/ja
Assigned to ARCH DEVELOPMENT CORP. reassignment ARCH DEVELOPMENT CORP. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: DIETZ, MARK L., HORWITZ, E. PHILIP
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Publication of US5110474A publication Critical patent/US5110474A/en
Priority to US08/051,608 priority patent/US5346618A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/09—Reaction techniques
    • Y10S423/14—Ion exchange; chelation or liquid/liquid ion extraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer

Definitions

  • the present invention is concerned generally with a method and apparatus for selectively extracting strontium values from acidic aqueous solutions. More particularly, the invention is concerned with a method and apparatus for selectively extracting strontium and technetium values from biological, commercial waste and environmental samples by use of a chromatographic column.
  • the beta emitting isotope 90 Sr produced by nuclear fission, is of particular concern. Because of its chemical similarity to calcium, 90 Sr released to the environment can quickly enter the food chain. Ultimately, the 90 Sr can be permanently incorporated into the inorganic matrix of human bones. There is, therefore, a clear need for an analytical procedure and methodology suitable for use in the routine monitoring of persons whose activities expose them to the risk of internal contamination from this element and for the determination of the levels of radiostrontium in various environmental samples (e.g., soils, plants, natural waters, and waste streams).
  • various environmental samples e.g., soils, plants, natural waters, and waste streams.
  • FIG. 1 illustrates a flow chart of chromatographic extraction of strontium and/or technetium from acidic solutions.
  • FIG. 1 illustrates schematically the method of a preferred extraction process. Substantial details concerning preparation of the extractant are set forth in a companion application U.S. Ser. No. 506,125 filed contemporaneously with the subject application. This companion application is assigned to the same entity, has the same inventors; and said companion application is incorporated by reference herein.
  • a preferred extractant consists of 1.0M bis 4,4'(5')[t-butylcyclohexano]18-Crown-6 (also expressed hereinafter as either di-t-butylcyclohexono-18-Crown-6 or as DtBuCH18C6) in 1-octanol as a diluent.
  • the macrocyclic polyether can be any of the dicyclohexano-Crown ethers, such as cis-dicyclohexano-18-Crown-6 (also expressed hereinafter as DCH18C6) and bis-methylcyclohexano-18-Crown-6 (also expressed hereinafter as DMeCH18C6).
  • the preferred Crown ether cited above can be generally expressed by the formula: 4,4'(5')[R,R'dicyclohexano]-18-Crown-6, where R and R' are one or more members selected from the groups consisting of H and straight chains or branched alkyls containing 1 to 12 carbon atoms, such as, methyl, propyl, isobutyl, t-butyl, hexyl and heptyl.
  • a preferred Crown ether includes the above listed DMeCH18C6 and the most preferred is bis 4,4'(5')[(t-butyl)cyclohexano]-18-Crown-6. As mentioned hereinbefore, further details concerning the Crown ethers are included in the copending incorporated application U.S. Ser. No. 506,125.
  • the diluents for the Crown ethers are also explained in detail in the incorporated copending application, including extensive data illustrating the extractant solutions in the preferred embodiments.
  • the diluents include alcohols, ketones, carboxylic acids and esters. As is understood by one of ordinary skill in the art, this is qualified by the fact that the diluent should have limited solubility in water since the extractant is exposed to substantial water volumes during the chromatographic extraction process of the invention. This qualification also applies to the selected Crown ether dissolved in the diluent. Examples in the copending application also provide illustrations of the liquid/liquid extraction efficiency over a wide range of acidity conditions. Subject to the qualifications concerning diluent and Crown ether water solubility, comparisons were made between the extraction results using the chromatographic column and liquid/liquid extraction in the copending application, and excellent correlation has been found.
  • Preparation of a chromatographic separation column involved use of a raw Amberlite XAD-7 resin substrate material (manufactured by Rohm & Haas, Philadelphia, Pa.) and treated in a conventional manner to remove all traces of preservatives (for example, see U.S. Pat. No. 4,835,107 which is incorporated by reference herein).
  • Ten grams of the purified resin substrate material were slurried in methanol and 6.26 grams of a 1M solution of DtBuCH18C6 in 1-octanol were added. The resulting mixture was gently stirred for several minutes, and the methanol was removed under vacuum at 40° C. to yield about 16 g of the Crown ether/diluent dispersed on the resin substrate material.
  • Chromatographic columns can also be prepared in 23 cm long glass Pasteur pipettes having a small glass wool plug in the bottom and a layer of 80/100 mesh glass beads on top of the resin substrate material to prevent disruption of the bed by sample introduction. Because these pipettes lack a reservoir, sample solutions were introduced using a small polyethylene funnel attached to the top of the pipette via a short length of vinyl tubing.
  • Strontium retention can be improved somewhat by use of 2M HNO 3 /0.5M Al(NO 3 ) 3 for sample loading and column washing (see Table II). Under these conditions, less than 1% of the strontium tracer introduced is eluted in the first ⁇ 30 free column volumes. More than 99% of a calcium tracer will elute in the same volume. Thus, Sr/Ca separation is essentially complete. (Strontium/barium separation under the same conditions is not as efficient with ⁇ 80% of the initial barium eluting in the first 30 free column volumes.)

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
US07/507,419 1990-04-09 1990-04-09 Method for liquid chromatographic extraction of strontium from acid solutions Expired - Lifetime US5110474A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US07/507,419 US5110474A (en) 1990-04-09 1990-04-09 Method for liquid chromatographic extraction of strontium from acid solutions
DE69125275T DE69125275T2 (de) 1990-04-09 1991-04-09 Verfahren zur flüssigchromatografischen extraction von strontium aus säurelösungen
PCT/US1991/002424 WO1991015280A1 (en) 1990-04-09 1991-04-09 Method for liquid chromatographic extraction of strontium from acid solutions
EP91908830A EP0525100B1 (de) 1990-04-09 1991-04-09 Verfahren zur flüssigchromatografischen extraction von strontium aus säurelösungen
JP3508601A JP2620447B2 (ja) 1990-04-09 1991-04-09 酸溶液からのストロンチウムの液体クロマトグラフ抽出方法
US08/051,608 US5346618A (en) 1990-04-09 1993-04-23 Liquid chromatographic extraction medium

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US07/507,419 US5110474A (en) 1990-04-09 1990-04-09 Method for liquid chromatographic extraction of strontium from acid solutions

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US08/051,608 Expired - Lifetime US5346618A (en) 1990-04-09 1993-04-23 Liquid chromatographic extraction medium

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JP (1) JP2620447B2 (de)
DE (1) DE69125275T2 (de)
WO (1) WO1991015280A1 (de)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5225173A (en) * 1991-06-12 1993-07-06 Idaho Research Foundation, Inc. Methods and devices for the separation of radioactive rare earth metal isotopes from their alkaline earth metal precursors
US5344623A (en) * 1993-06-15 1994-09-06 The United States Of America As Represented By The United States Department Of Energy Process for the extraction of strontium from acidic solutions
US5346618A (en) * 1990-04-09 1994-09-13 Arch Development Corporation Liquid chromatographic extraction medium
US5368736A (en) * 1993-07-26 1994-11-29 The United States Of America As Represented By The United States Department Of Energy Process for the separation and purification of yttrium-90 for medical applications
US5443731A (en) * 1994-07-21 1995-08-22 The United States Of America As Represented By The United States Department Of Energy Process for extracting technetium from alkaline solutions
US5478953A (en) * 1994-11-03 1995-12-26 Eichrom Industries, Inc. Process for the preparation of cis-syn-cis-4,4' (5')-[di-t-butyldicyclohexano]-18-crown-6
US5626757A (en) * 1994-02-22 1997-05-06 Advanced Separation Technologies Inc. Macrocyclic antibiotics as separation agents
US5702608A (en) * 1993-07-08 1997-12-30 Compagnie Generales Des Matieres Nucleaires Process and installation for the decontamination of radioactive nitric effluents containing strontium and sodium
US5865994A (en) * 1997-03-13 1999-02-02 Dionex Corporation Bifunctional crown ether-based cation-exchange stationary phase for liquid chromatography
US5965026A (en) * 1995-12-21 1999-10-12 Daicel Chemical Industries, Ltd. Packing material for high-performance liquid chromatography
EP0979513A1 (de) * 1996-08-26 2000-02-16 Arch Development Corporation VERFAHREN UND VORRICHTUNG ZUR EREUGUNG VON Bi-212 UND DESSEN VERWENDUNG
US6309614B1 (en) 2000-04-14 2001-10-30 Pg Research Foundation, Inc. Method for isolating and purifying 90Y From 90strontium in multi-curie quantities
US20020195391A1 (en) * 2001-06-22 2002-12-26 Young John E. Compact automated radionuclide separator
US6511603B1 (en) 2000-10-24 2003-01-28 Arch Development Corp. Alkaline earth cation extraction from acid solution
US20030105375A1 (en) * 2001-11-15 2003-06-05 Bond Andrew H. Purification of 4,4'(5')- di-t-butylcyclohexano-18-crown-6
US20040062695A1 (en) * 2002-09-30 2004-04-01 Horwitz E. Philip Multivalent metal ion extraction using diglycolamide-coated particles
CN100336920C (zh) * 2004-02-19 2007-09-12 中国科学院过程工程研究所 用硫化钡黑灰水浸液直接制备高纯产品的方法
US20110056157A1 (en) * 2008-02-18 2011-03-10 Ocv Intellectual Capital, Llc Urea-formaldehyde resin reinforced gypsum composites and building materials made therefrom
US20110190434A1 (en) * 2008-02-18 2011-08-04 Ocv Intellectual Capital, Llc Urea-formaldehyde resin reinforced gypsum composites and building materials made therefrom
US20130017613A1 (en) * 2011-07-14 2013-01-17 Uchicago Argonne, Llc Method and apparatus for extraction of strontium from urine

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5722303A (en) * 1993-03-03 1998-03-03 University Of Chicago Mixed-mu superconducting bearings
US5508011A (en) * 1995-05-24 1996-04-16 National Tsing Hua University Method and generation for generating 90 Y from 90 SR
US5651883A (en) * 1995-06-06 1997-07-29 Argonne National Laboratory/University Of Chicago Development Corp. Method for the chromatographic separation of cations from aqueous samples
US6077421A (en) * 1996-07-18 2000-06-20 The United States Of America As Represented By The Secretary Of The Navy Metal complexing
US6303936B1 (en) * 1998-11-12 2001-10-16 Clemson University Extraction-scintillation medium and method of use
US7291316B2 (en) 2004-03-23 2007-11-06 Battelle Energy Alliance, Llc Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants
US7723114B1 (en) 2006-01-11 2010-05-25 Clemson University Methods and systems for detection of radionuclides
US8133740B1 (en) 2008-08-19 2012-03-13 Clemson University Research Foundation Colorimetric detection of uranium in water
US8158088B2 (en) * 2008-11-10 2012-04-17 Battelle Energy Alliance, Llc Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
US8270554B2 (en) * 2009-05-19 2012-09-18 The United States Of America, As Represented By The United States Department Of Energy Methods of producing cesium-131
CN103316502B (zh) * 2012-03-22 2015-06-10 宁波大学 一种基于离子液体萃取剂的管内循环流液液微萃取方法
JP6464475B2 (ja) * 2015-03-02 2019-02-06 清水建設株式会社 放射性ストロンチウムの分析方法

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3827986A (en) * 1971-08-06 1974-08-06 Radiochemical Centre Ltd Technetium-99m generators
US3970583A (en) * 1973-02-20 1976-07-20 U.S. Philips Corporation Isotope generator provided with a carrier material which in addition to Al2 O3 contains fully or partly hydrated MnO2
US4001387A (en) * 1973-07-30 1977-01-04 Medi-Physics, Inc. Process for preparing radiopharmaceuticals
US4162231A (en) * 1977-12-28 1979-07-24 The United States Of America As Represented By The United States Department Of Energy Method for recovering palladium and technetium values from nuclear fuel reprocessing waste solutions
US4548790A (en) * 1983-07-26 1985-10-22 The United States Of America As Represented By The United States Department Of Energy Method for extracting lanthanides and actinides from acid solutions
US4574072A (en) * 1983-07-26 1986-03-04 The United States Of America As Represented By The United States Department Of Energy Method for extracting lanthanides and actinides from acid solutions by modification of purex solvent
US4738834A (en) * 1984-02-24 1988-04-19 Australia Nuclear Science & Technology Organization Treatment of technetium containing solutions
EP0294528A2 (de) * 1987-06-02 1988-12-14 Jerald S. Bradshaw Makrozyklische Protonenionisierbare Verbindungen und selektive kompetitive Trennung bevorzugter Metallionen aus ihren Mischungen mit anderen Ionen
US4835107A (en) * 1986-10-21 1989-05-30 Arch Development Corp. Method for the concentration and separation of actinides from biological and environmental samples
US4837110A (en) * 1985-09-03 1989-06-06 Hoechst Aktiengesellschaft Technetium-99m generator, its preparation and its use
US5023061A (en) * 1990-07-02 1991-06-11 Westinghouse Electric Corp. Chromatographic separation of zirconium isotopes with anhydrous readily recyclable eluents

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5817783B2 (ja) * 1976-07-08 1983-04-09 日本曹達株式会社 固体表面に担持されたヘテロ巨大環化合物
US4123931A (en) * 1976-08-03 1978-11-07 The Dow Chemical Company Method for uniformly coating liquid phases on glass beads and applications thereof
JPS62210053A (ja) * 1986-03-07 1987-09-16 Agency Of Ind Science & Technol 光学異性体分離用充填剤
IL86767A (en) * 1987-09-04 1993-02-21 Jerald S Bradshaw Reed M Izatt Recovery of ions present at low concentrations in solutions containing other ions
JPH01142462A (ja) * 1987-11-30 1989-06-05 Japan Atom Energy Res Inst 抽出クロマトグラフィ材の製造方法
US4996277A (en) * 1988-02-08 1991-02-26 Bradshaw Jerald S Novel oligoethylene oxide-containing alkenes, alkoxysilanes, and polysiloxanes
US4909935A (en) * 1988-06-03 1990-03-20 Brigham Young University Chromatographic arylcarboxamide polysiloxanes
US4957620A (en) * 1988-11-15 1990-09-18 Hoechst Celanese Corporation Liquid chromatography using microporous hollow fibers
US5100585A (en) * 1990-04-09 1992-03-31 United States Department Of Energy Process for the recovery of strontium from acid solutions
US5110474A (en) * 1990-04-09 1992-05-05 Arch Development Corporation Method for liquid chromatographic extraction of strontium from acid solutions

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3827986A (en) * 1971-08-06 1974-08-06 Radiochemical Centre Ltd Technetium-99m generators
US3970583A (en) * 1973-02-20 1976-07-20 U.S. Philips Corporation Isotope generator provided with a carrier material which in addition to Al2 O3 contains fully or partly hydrated MnO2
US4001387A (en) * 1973-07-30 1977-01-04 Medi-Physics, Inc. Process for preparing radiopharmaceuticals
US4162231A (en) * 1977-12-28 1979-07-24 The United States Of America As Represented By The United States Department Of Energy Method for recovering palladium and technetium values from nuclear fuel reprocessing waste solutions
US4548790A (en) * 1983-07-26 1985-10-22 The United States Of America As Represented By The United States Department Of Energy Method for extracting lanthanides and actinides from acid solutions
US4574072A (en) * 1983-07-26 1986-03-04 The United States Of America As Represented By The United States Department Of Energy Method for extracting lanthanides and actinides from acid solutions by modification of purex solvent
US4738834A (en) * 1984-02-24 1988-04-19 Australia Nuclear Science & Technology Organization Treatment of technetium containing solutions
US4837110A (en) * 1985-09-03 1989-06-06 Hoechst Aktiengesellschaft Technetium-99m generator, its preparation and its use
US4835107A (en) * 1986-10-21 1989-05-30 Arch Development Corp. Method for the concentration and separation of actinides from biological and environmental samples
EP0294528A2 (de) * 1987-06-02 1988-12-14 Jerald S. Bradshaw Makrozyklische Protonenionisierbare Verbindungen und selektive kompetitive Trennung bevorzugter Metallionen aus ihren Mischungen mit anderen Ionen
US5023061A (en) * 1990-07-02 1991-06-11 Westinghouse Electric Corp. Chromatographic separation of zirconium isotopes with anhydrous readily recyclable eluents

Non-Patent Citations (14)

* Cited by examiner, † Cited by third party
Title
C. R. Porter, et al., "Determination of Radiostrontium in Food and Other Environmental Samples", Environmental Science & Technology, vol. 1, pp. 745-750, (1967).
C. R. Porter, et al., Determination of Radiostrontium in Food and Other Environmental Samples , Environmental Science & Technology, vol. 1, pp. 745 750, (1967). *
E. A. Filippov, et al., "Extraction of Alkaline-Earth Metals from Nitric Acid Solutions with the Crown Ether Dicyclohexyl-18-Crown-6", Radiokhimiya, vol. 14, (1982), pp. 177-181.
E. A. Filippov, et al., Extraction of Alkaline Earth Metals from Nitric Acid Solutions with the Crown Ether Dicyclohexyl 18 Crown 6 , Radiokhimiya, vol. 14, (1982), pp. 177 181. *
E. Blasius, et al., "Separation of Strontium from Nuclear Waste Solutions by Solvent Extraction with Crown Ethers", Journal of Radioanalytical and Nuclear Chemistry Articles, vol. 89/2, (1985), pp. 389-398.
E. Blasius, et al., Separation of Strontium from Nuclear Waste Solutions by Solvent Extraction with Crown Ethers , Journal of Radioanalytical and Nuclear Chemistry Articles, vol. 89/2, (1985), pp. 389 398. *
R. G. Shuler, et al., "The Extraction of Cesium and Strontium from Acidic High Activity Nuclear Waste Using a Purex Process Compatible Organic Extractant", Solvent Extraction and Ion Exchange, vol. 3, (1985) pp. 567-604.
R. G. Shuler, et al., The Extraction of Cesium and Strontium from Acidic High Activity Nuclear Waste Using a Purex Process Compatible Organic Extractant , Solvent Extraction and Ion Exchange, vol. 3, (1985) pp. 567 604. *
T. Kimura, et al., "Separation of Strontium Ion from a Large Amount of Calcium Ion by the Use of a Macrocyclic Ether", Chemistry Letters, (1977), pp. 563-564.
T. Kimura, et al., "Separation of Strontium-89 and -90 from Calcium in Milk with a Macrocyclic Ether", Analytical Chemistry, vol. 51, (1979), pp. 1113-1116.
T. Kimura, et al., Separation of Strontium 89 and 90 from Calcium in Milk with a Macrocyclic Ether , Analytical Chemistry, vol. 51, (1979), pp. 1113 1116. *
T. Kimura, et al., Separation of Strontium Ion from a Large Amount of Calcium Ion by the Use of a Macrocyclic Ether , Chemistry Letters, (1977), pp. 563 564. *
W. J. McDowell, "Crown Ethers as Solvent Extraction Reagents: Where Do We Stand?", Separation Science and Technology, vol. 23, (1988), pp. 1251-1268.
W. J. McDowell, Crown Ethers as Solvent Extraction Reagents: Where Do We Stand , Separation Science and Technology, vol. 23, (1988), pp. 1251 1268. *

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5346618A (en) * 1990-04-09 1994-09-13 Arch Development Corporation Liquid chromatographic extraction medium
US5225173A (en) * 1991-06-12 1993-07-06 Idaho Research Foundation, Inc. Methods and devices for the separation of radioactive rare earth metal isotopes from their alkaline earth metal precursors
US5344623A (en) * 1993-06-15 1994-09-06 The United States Of America As Represented By The United States Department Of Energy Process for the extraction of strontium from acidic solutions
US5702608A (en) * 1993-07-08 1997-12-30 Compagnie Generales Des Matieres Nucleaires Process and installation for the decontamination of radioactive nitric effluents containing strontium and sodium
US5368736A (en) * 1993-07-26 1994-11-29 The United States Of America As Represented By The United States Department Of Energy Process for the separation and purification of yttrium-90 for medical applications
US5874005A (en) * 1994-02-22 1999-02-23 The Curators Of The University Of Missouri Macrocyclic antibiotics as separation agents
US5964996A (en) * 1994-02-22 1999-10-12 Curators Of The University Of Missouri Macrocyclic antibiotics as separation agents
US5626757A (en) * 1994-02-22 1997-05-06 Advanced Separation Technologies Inc. Macrocyclic antibiotics as separation agents
US6669842B1 (en) 1994-02-22 2003-12-30 Curators Of The University Of Missouri Macrocyclic antibiotics as separation agents
US5443731A (en) * 1994-07-21 1995-08-22 The United States Of America As Represented By The United States Department Of Energy Process for extracting technetium from alkaline solutions
US5478953A (en) * 1994-11-03 1995-12-26 Eichrom Industries, Inc. Process for the preparation of cis-syn-cis-4,4' (5')-[di-t-butyldicyclohexano]-18-crown-6
US5965026A (en) * 1995-12-21 1999-10-12 Daicel Chemical Industries, Ltd. Packing material for high-performance liquid chromatography
US6117325A (en) * 1995-12-21 2000-09-12 Daicel Chemical Industries, Ltd. Packing material for high-performance liquid chromatography
US6358418B1 (en) * 1995-12-21 2002-03-19 Daicel Chemical Industries, Ltd. Packing material for high-performance liquid chromatography
EP0979513A4 (de) * 1996-08-26 2002-04-10 Arch Dev Corp VERFAHREN UND VORRICHTUNG ZUR EREUGUNG VON Bi-212 UND DESSEN VERWENDUNG
EP0979513A1 (de) * 1996-08-26 2000-02-16 Arch Development Corporation VERFAHREN UND VORRICHTUNG ZUR EREUGUNG VON Bi-212 UND DESSEN VERWENDUNG
US6126909A (en) * 1996-08-26 2000-10-03 Arch Development Corporation Process and apparatus for the production of BI-212 and a use thereof
US5865994A (en) * 1997-03-13 1999-02-02 Dionex Corporation Bifunctional crown ether-based cation-exchange stationary phase for liquid chromatography
US5968363A (en) * 1997-03-13 1999-10-19 Dionex Corporation Bifunctional crown ether-based cation-exchange stationary phase for liquid chromatography
US6309614B1 (en) 2000-04-14 2001-10-30 Pg Research Foundation, Inc. Method for isolating and purifying 90Y From 90strontium in multi-curie quantities
US6511603B1 (en) 2000-10-24 2003-01-28 Arch Development Corp. Alkaline earth cation extraction from acid solution
US20020195391A1 (en) * 2001-06-22 2002-12-26 Young John E. Compact automated radionuclide separator
US6770195B2 (en) * 2001-06-22 2004-08-03 Pg Research Foundation, Inc. Compact automated radionuclide separator
US7091338B2 (en) 2001-11-15 2006-08-15 Pg Research Foundation Purification of 4,4′(5′)- di-t-butylcyclohexano-18-crown-6
US20030105375A1 (en) * 2001-11-15 2003-06-05 Bond Andrew H. Purification of 4,4'(5')- di-t-butylcyclohexano-18-crown-6
US7157022B2 (en) 2002-09-30 2007-01-02 .Pg Research Foundation, Inc. Multivalent metal ion extraction using diglycolamide-coated particles
US20040062695A1 (en) * 2002-09-30 2004-04-01 Horwitz E. Philip Multivalent metal ion extraction using diglycolamide-coated particles
US20070131618A1 (en) * 2002-09-30 2007-06-14 Horwitz E P Multivalent metal ion extraction using diglycolamide-coated particles
US20070163957A1 (en) * 2002-09-30 2007-07-19 Horwitz E P Multivalent metal ion extraction using diglycolamide-coated particles
US7553461B2 (en) 2002-09-30 2009-06-30 Pg Research Foundation, Inc. Multivalent metal ion extraction using diglycolamide-coated particles
CN100336920C (zh) * 2004-02-19 2007-09-12 中国科学院过程工程研究所 用硫化钡黑灰水浸液直接制备高纯产品的方法
US20110056157A1 (en) * 2008-02-18 2011-03-10 Ocv Intellectual Capital, Llc Urea-formaldehyde resin reinforced gypsum composites and building materials made therefrom
US20110190434A1 (en) * 2008-02-18 2011-08-04 Ocv Intellectual Capital, Llc Urea-formaldehyde resin reinforced gypsum composites and building materials made therefrom
US20130017613A1 (en) * 2011-07-14 2013-01-17 Uchicago Argonne, Llc Method and apparatus for extraction of strontium from urine
US8507284B2 (en) * 2011-07-14 2013-08-13 Uchicago Argonne, Llc Method and apparatus for extraction of strontium from urine

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US5346618A (en) 1994-09-13
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DE69125275D1 (de) 1997-04-24
EP0525100A1 (de) 1993-02-03

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