US4855133A - Composition for attracting flies - Google Patents
Composition for attracting flies Download PDFInfo
- Publication number
- US4855133A US4855133A US07/031,068 US3106887A US4855133A US 4855133 A US4855133 A US 4855133A US 3106887 A US3106887 A US 3106887A US 4855133 A US4855133 A US 4855133A
- Authority
- US
- United States
- Prior art keywords
- composition
- cis
- red
- tricosene
- attracting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 239000000877 Sex Attractant Substances 0.000 claims abstract description 12
- IGOWHGRNPLFNDJ-HTXNQAPBSA-N (e)-tricos-9-ene Chemical compound CCCCCCCCCCCCC\C=C\CCCCCCCC IGOWHGRNPLFNDJ-HTXNQAPBSA-N 0.000 claims abstract description 6
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- GZAAPEKTGHKWRZ-UHFFFAOYSA-L dipotassium;2-(2,4,5,7-tetrabromo-3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [K+].[K+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GZAAPEKTGHKWRZ-UHFFFAOYSA-L 0.000 description 1
- VQHHOXOLUXRQFQ-UHFFFAOYSA-L dipotassium;4,5,6,7-tetrachloro-2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 VQHHOXOLUXRQFQ-UHFFFAOYSA-L 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- FHRUGNCCGSEPPE-UHFFFAOYSA-L disodium;2-(4,5-dibromo-3,6-dioxido-9h-xanthen-9-yl)benzoate;hydron Chemical compound [H+].[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1C2=CC=C([O-])C(Br)=C2OC2=C(Br)C([O-])=CC=C21 FHRUGNCCGSEPPE-UHFFFAOYSA-L 0.000 description 1
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- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
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- 230000000855 fungicidal effect Effects 0.000 description 1
- FODTZLFLDFKIQH-FSVGXZBPSA-N gamma-Oryzanol (TN) Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)O[C@@H]2C([C@@H]3CC[C@H]4[C@]5(C)CC[C@@H]([C@@]5(C)CC[C@@]54C[C@@]53CC2)[C@H](C)CCC=C(C)C)(C)C)=C1 FODTZLFLDFKIQH-FSVGXZBPSA-N 0.000 description 1
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- 208000015181 infectious disease Diseases 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
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- 238000009533 lab test Methods 0.000 description 1
- JYNBEDVXQNFTOX-FMQUCBEESA-N lithol rubine Chemical compound OS(=O)(=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C(C(O)=O)=CC2=CC=CC=C12 JYNBEDVXQNFTOX-FMQUCBEESA-N 0.000 description 1
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- 239000002184 metal Substances 0.000 description 1
- 229940051142 metanil yellow Drugs 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 229940048276 new coccine Drugs 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 229940055695 pancreatin Drugs 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003016 pheromone Substances 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- 229940099800 pigment red 48 Drugs 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 235000012731 ponceau 4R Nutrition 0.000 description 1
- 235000019237 ponceau SX Nutrition 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- FZUOVNMHEAPVBW-UHFFFAOYSA-L quinoline yellow ws Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S([O-])(=O)=O)C=C(S(=O)(=O)[O-])C=C2C=C1 FZUOVNMHEAPVBW-UHFFFAOYSA-L 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- RCTGMCJBQGBLKT-PAMTUDGESA-N scarlet red Chemical compound CC1=CC=CC=C1\N=N\C(C=C1C)=CC=C1\N=N\C1=C(O)C=CC2=CC=CC=C12 RCTGMCJBQGBLKT-PAMTUDGESA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229940074386 skatole Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- UWMZZSRDUVJJDP-UHFFFAOYSA-M sodium 2-[3-(2-methylanilino)-6-(2-methyl-4-sulfonatoanilino)xanthen-10-ium-9-yl]benzoate Chemical compound [Na+].Cc1ccccc1Nc1ccc2c(-c3ccccc3C([O-])=O)c3ccc(Nc4ccc(cc4C)S([O-])(=O)=O)cc3[o+]c2c1 UWMZZSRDUVJJDP-UHFFFAOYSA-M 0.000 description 1
- VQLUPOYXKBDWKM-UHFFFAOYSA-M sodium 3-hydroxy-4-[(4-methyl-3-sulfophenyl)diazenyl]naphthalene-2-carboxylate Chemical compound S(=O)(=O)(O)C1=C(C=CC(=C1)N=NC1=C(C(=CC2=CC=CC=C12)C(=O)[O-])O)C.[Na+] VQLUPOYXKBDWKM-UHFFFAOYSA-M 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- XDFLSGNQEUHKPL-UHFFFAOYSA-L strontium 2-[(2-hydroxynaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound OC1=C(C2=CC=CC=C2C=C1)N=NC1=C(C2=CC=CC=C2C=C1)S(=O)(=O)[O-].[Sr+2].OC1=C(C2=CC=CC=C2C=C1)N=NC1=C(C2=CC=CC=C2C=C1)S(=O)(=O)[O-] XDFLSGNQEUHKPL-UHFFFAOYSA-L 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000012751 sunset yellow FCF Nutrition 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- SJDSOBWGZRPKSB-UHFFFAOYSA-N tricos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCCCCC=C SJDSOBWGZRPKSB-UHFFFAOYSA-N 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
Definitions
- the present invention relates to compositions for attracting flies to capture and kill them.
- the invention also relates to attracting-insecticidal compositions for attracting and killing flies and to attractant-bait compositions for poisoning flies by attracting the flies and inducing them to ingest the composition.
- Unexamined Japanese Patent Publication SHO No. 56-115706 discloses that flies are attracted to yellow-colored substances having a hue of 5YR to 7.5GY according to the standard prescribed in JIS Z 8721. However, the attracting effect of the yellow-colored substances of this hue on flies is insufficient and in no way satisfactory.
- the present invention provides a fly attracting composition having an exceedingly higher attracting effect on flies than is achievable by the prior art mentioned.
- the invention further provides an attracting-insecticidal composition for attracting flies very effectively and controlling them.
- the invention further provides an attractant-bait composition for attracting flies very effectively and causing them to be attracted to the bait with enhanced tenacity so that the insecticidal component thereof can be taken into the body in an increased amount to completely control the flies.
- (c) being in the form of a granular preparation about 0.5 to about 5 mm in mean grain size.
- the fly attracting compound to be used in the present invention is known as a sex pheromone of flies having a fly attracting effect, but the effect is low, whereas our research has revealed that when the preparation containing the compound has a yellowish red color in the range of 2.5R to 2.5YR in hue and is in the form of grains having a mean size in the specific range of about 0.5 to about 5 mm, the preparation unexpectedly exhibits a surprisingly high attracting effect on flies.
- the high fly attracting effect is available only when the attracting compound, hue and form of the preparation are as specified above in combination.
- the attracting compound to be used for the present invention is a sex pheromone selected from among 9-tricosene, cis-9-tricosene, 10-methyl-9-tricosene, cis-2-methyl-8-docosene, cis-9-docosene, cis-8-docosene and cis-10-tricosene.
- cis-9-tricosene is especially preferable.
- at least one of these compounds is used.
- the concentration of the attracting compound in the preparation is usually about 0.01 to about 15 wt. %, preferably about 0.02 to 4 wt. %, although widely variable.
- the fly attracting composition of the present invention exhibit a yellowish red color in the range of 2.5R to 2.5YR in hue according to the standard prescribed in JIS Z 8721. If the hue has a closer resemblance to red off 2.5R or to yellow off 2.5YR, the contemplated high fly attracting effect is not available. More preferably, the hue is in the range of 7.5R to 2.5YR. It is also desirable that the present preparation having the above-specified hue be at least 4, more preferably at least 5, in lightness and at least 6, more preferably at least 7, in saturation according to JIS Z 8721.
- the pigments useful for imparting such a color to the composition of the present invention include not only usual pigments (coloring substances) but also fluorescent or luminescent substances. Examples of suitable pigments are as follows.
- Red No. 204 (Lake Red CBA, Pigment Red 53(Ba), 1-(4-chloro-o-sulfo-5-tolylazo)-2-naphtholarium)
- Red No. 226 Helindon Pink CN, Vat Red 1, 5,5,'-dichloro- 3,3'-dimethylthioindigo
- pigments can be used singly, or at least two of them are usable in admixture.
- the amount of pigment is so determined that the preparation obtained will have a hue in the above-specified range.
- the pigment is used usually in an amount of about 0.05 to about 4 wt. %, preferably about 0.08 to about 2 wt. %, based on the present composition.
- the fly attracting composition of the present invention be in a granular form having a mean grain size of about 0.5 to about 5 mm.
- the composition fails to achieve the contemplated high attracting effect if less than 0.5 mm in mean grain size, e.g. powdery or more than 5 mm.
- the grain size of the preparation affects the fly attracting effect has never been reported: it is our research that revealed this for the first time.
- the present composition is in the range of about 1 to about 3 mm in grain size.
- the composition is not limited specifically in configuration, weight, etc. provided that it has the above-specified grain size.
- the composition can be in the form of granules, pellets or spherical or disklike grains, amorphous or of any desired shape.
- Insecticides can be incorporated into the fly attracting composition of the present invention so as to effectively and efficiently kill the attracted flies. While various insecticides are usable for this purpose which have an insecticidal effect on flies, pyrethroid, organic phosphorus and carbamate insecticides are desirable. Examples of such insecticides are as follows.
- pyrethroid compounds are especially preferable.
- the most preferable are 5-benzyl-3-furylmethyl d-cis/trans-chrysanthemate, phenothrin and permethrin.
- These insecticides are used singly, or at least two of them are used in admixture.
- the proportion of the insecticide to be used is usually in the range of about 0.1 to about 15 wt. % based on the entire weight of the present composition although not limited specifically.
- the fly attracting composition of the present invention is prepared by admixing a suitable carrier with the components and shaping or granulating the mixture into a suitable form having a mean grain size in the foregoing range.
- a suitable carrier is finely divided inorganic substances such as talc, kaolin, silicic acid, active carbon, bentonite, silica, alumina, alumina-silica, calcium carbonate, earthen or porcelaneous powder and kieselguhr, and organic substances such as pulp, fiber, wood powder, sugar powder, soybean flour, wheat flour, starch, resin and rubber.
- the fly attracting composition of the present invention is prepared, for example, by mixing together the pigment and the attracting compound serving as an active component, along with a suitable insecticide when required, using a solvent and/or a binder solution, granulating the mixture to a specified grain size, removing the solvent and drying the granular product.
- solvents useful for this method are alcohols such as methanol and ethanol, ketones such as acetone and methyl ethyl ketone, ethers such as tetrahydrofuran and dioxane, and other substances such as hexane, kerosene, paraffin, petroleum benzine, toluene, ethyl acetate and dichloroethane.
- binders examples include cellulose derivatives such as nitrocellulose, hydroxypropylcellulose, acetylcellulose, acetylbutyrylcellulose and methylcellulose, polyvinyl alcohol, gum arabic, sodium carboxymethylcellulose, casein, gelatin, alginic acid.
- Such binder is adantageously usable usually in the form of about 1 to about 20% aqueous solution.
- fly attracting composition of the present invention when so required are various known additives such as synergist, antioxidant, decomposition preventing agent, bactericide, fungicide, accidental ingestion preventing agent, etc.
- Other known attractants are also usable conjointly.
- Examples of useful synergists are N-(2-ethylhexyl)bicyclo[2,2,1]-5-heptene-2,3-dicarboximide, 6-(propylpiperonyl)butyl carbityl ether, etc.
- Examples of useful antioxidants are butylhydroxyanisole, dibutylhydroxyto1uene, tocopherol, ⁇ -oryzanol, etc.
- Examples of useful decomposition preventing agents are phenylglycldyl ether, etc. These agents, all known, are used in the usual manner and can be used in combination.
- Examples of useful bacteriocides are salicylic acid, benzoic acid, sorbic acid, p-chloro-m-xylenol, 2-(4'-thiazoyl)benzimidazole, etc.
- Examples of useful fungicides are ⁇ -bromo cinnamic aldedhyde, N-dimethyl-N-phenyl-N'-(fluorodichloromethyl)thiosulfamide, etc.
- Examples of useful accidental ingestion preventing agents are tincture of Capsicum annum, Japanese bitter wood, chloramphenicol, etc. The proportions of these agents to be used can be determined suitable. For example, accidental ingestion preventing agent can be used in an amount of about 0.1 to about 3 wt. % based on the preparation to be obtained.
- Examples of attractants which can be incorporated into the present fly attracting composition are ingestion-inducing substances including protein- and/or carbohydrate-containing substances such as milk powder, egg powder, pupal powder, krill powder, meat extract, albumin, globulin, amino acids (e.g. proline), malt extract, caramel, vanillin, whey, cereal flours, yeast, glucose, sucrose, maltose, monosaccharides and disaccharides.
- ingestion-inducing substances including protein- and/or carbohydrate-containing substances such as milk powder, egg powder, pupal powder, krill powder, meat extract, albumin, globulin, amino acids (e.g. proline), malt extract, caramel, vanillin, whey, cereal flours, yeast, glucose, sucrose, maltose, monosaccharides and disaccharides.
- Examples of other useful attractants are terpineol, farnesol, geraniol, acetic acid, isovaleric acid, trimethylamine, indole, piperidine, phenylethanol, ammonium carbonate, skatole, formaldehyde, hexamethylenetetramine, ammonium carbamate, papain, butyric acid, isovaleraldehyde, ethylamine, aliphatic monoesters of chlorinated alkene polyols, pancreatin.
- the amounts of these attractants to be used can be determined suitably and are not limited specifically.
- the preferred embodiments of the present invention include a bait composition having incorporating therein at least one pyrethroid insecticide selected from the group consisting of (5-benzyl-3-furyl)methyl d-cis/trans-chrysanthemate (common name: allethrin), 3-phenoxybenzyl cis/trans-chrysanthemate (common name: phenothrin) and 3-phenoxybenzyl cis/trans-3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane carboxylate (common name: permethrin).
- pyrethroid insecticide selected from the group consisting of (5-benzyl-3-furyl)methyl d-cis/trans-chrysanthemate (common name: allethrin), 3-phenoxybenzyl cis/trans-chrysanthemate (common name: phenothrin) and 3-phenoxybenzyl cis/trans-3-(2,2-dichloro
- bait compositions comprise a food for flies impregnated with or incorporating an insecticide.
- the bait composition must meet the following requirements.
- the insecticidal component selected should be least repellent to flies.
- the bait needs to be fully attractive to the taste so as to induce the attracted fly to ingest the bait.
- the bait must be taken in by the fly at a sufficient lethal dose before disgusting the fly in some way or producing toxic symptoms.
- insects The insecticidal components of bait compositions presently known are limited only to some of organic phosphorus or carbamate insecticides, and pyrethroid insecticides are not used commonly. Pyrethroid insecticides generally are known to quickly act on adults of flies (hereinafter referred to merely as "flies") to produce an outstanding knockdown effect because the insecticide enters the body of the fly through the skin or stoma and quickly acts on the nervous system. Accordingly, the application of insecticides of this type is limited only to the stomatal respiratory tract and the cutaneous contact tract.
- pyrethroid insecticides are used not only for flies but also for mosquitos, cockroaches, etc., in the form of preparations such as mosquito-repellent insence (stomatal tract), mosquito-repellent electric mat (same), aerosol (stomatal tract and cutaneous contact tract), fumigant or vaporizable composition (same), etc.
- preparations such as mosquito-repellent insence (stomatal tract), mosquito-repellent electric mat (same), aerosol (stomatal tract and cutaneous contact tract), fumigant or vaporizable composition (same), etc.
- insecticidal bait compositions for the oral tract.
- the fly attracting composition of the present invention has incorporated therein at least one of the foregoing three pyrethroid compounds and is used as a bait composition
- the pyrethroid compound exhibits a powerful insecticidal effect on flies although taken in orally and further that the composition efficiently attracts flies without arousing any aversion and induces the attracted flies to positively take in a lethal dosage of the bait with great tenacity, consequently achieving a high controlling efficiency.
- Attractants for inducing flies to ingest the present bait composition are incorporated into the composition.
- the attractants already exemplified are usable as such attractants.
- the ingestion-inducing attractant is a substance which itself is eatable by flies.
- Useful carriers are preferably edible substances such as sugar powder, soybean flour, wheat flour, starch, etc.
- the ingestion-inducing attractant and/or the edible substance serving as a carrier are used in an amount of at least 70 wt. % based on the composition.
- pyrethroid insecticidal compounds are usable singly, or at least two of them can be used in combination, the amount thereof being 0.1 to 15 wt. %, preferably 0.3 to 10 wt. %, based on the composition. It is especially preferable to use allethrin.
- the sex pheromone is used in an amount of about 0.01 about 15 wt. %, preferably about 0.02 to about 4 wt. %, based on the composition.
- the pyrethroid insecticidal compound and the sex pheromone are usable in a ratio which is not limited particularly but is selectable from a wide range, the former to latter ratio (by weight) is usually about 1:0.001-1, preferably about 1:0.005-0.5.
- the same additives as already mentioned are usable for preparing the bait composition.
- the components can be made into a granular preparation in the same manner as already described.
- the attractant composition of the present invention is usable in the original granular form, or as adhered to a suitable substrate, such as paper, fabric, and film, sheet, plate, ball, polygonal body or the like of synthetic resin, wood or metal.
- the fly attracting composition of the present invention when prepared with the insecticide, etc. incorporated therein, is usable by placement, spreading or adhering in fly occurring areas such as agricultural crop growing fields, orchards, greenhouses, vinyl houses, cattle sheds, poultry houses, grain storehouses, kitchens, dwelling houses, etc.
- the present composition is usable in these places in combination with other known suitable insecticidal preparation or the like.
- the amount of the composition to be used can be determined suitably in accordance with the method and place of application. For example, when to be applied by spreading, the present fly attracting composition is used in such an amount that at least 1 mg, preferably about 3 to about 10 mg, of the active compound will be present per square meter of the area concerned.
- flies attractable by the present attractant composition are those of the family Muscidae such as Musca domestica, Muscina stabulans, Stomoxys calcitrans and Ophyra leucostoma: Fanniinae: the family Calliphoridae such as Calliphora lata, Aldrichina grahami, Phaenicia sericata, Phaenicia cuprina, Lucilia caesar, Lucilia illustris, Chrysomyia megacephala and Phormia regina: the family Sarcophagidae such as Sarcophaga peregrina and Parasarcophaga similis: the family Drosophilidae such as Drosophila melanogaster and Drosophila virilis: the family Piophilidae such as Piophila casei: the family Scatophagidae such as Scatophaga stercoraria: the family Dromyzidae such as Steno
- the cis-9-tricosene concentration of these preparation specimens was 0.025 wt. %.
- Each of the preparation specimens obtained was found to have the same hue as the corresponding one of the specimens 1a to 1m (see Table 1) of Example 1.
- Example 2 The preparations obtained in Example 2 were tested for attracting effect by the following methods.
- the preparations were placed, each in an amount of 60 g, into glass dishes (15.5 cm in diameter) individually, which were then arranged on the floor of a test room along a circle, as spaced apart from one another at a distance of about 30 cm. Houseflies (Musca domestica) were released into the test room. Upon the lapse of a predetermined period of time, the number of dead flies within each dish was checked.
- the fly attracting effect of each preparation was evaluated in terms of the ratio (%) of the number of dead flies in the dish containing the preparation to the total number of dead flies in the test room (i.e. the total of the numbers of dead flies in all dishes).
- the fly attracting effect of the preparations was evaluated in the same manner as in Test I with the exception of placing the preparations, 10 g each, into plastics cups individually and arranging the cups on the floor of a glass chamber (1.45 m ⁇ 1.4 m) placed outdoors, as spaced apart from one another at a distance of about 20 cm.
- Test results are given in Table 2 (Test I) and Table 3 (Test II).
- Fly attracting-insecticidal compositions were prepared in the same manner as in Example 2 except that 0.08 wt. % or 1.3 wt. % of Sunset Yellow F was used. The preparations obtained were tested for fly attracting effect in the same manner as in Example 2, Test I. Table 4 shows the result.
- the specified amounts of the pigment, cis-9-tricosene (used as 1 ml of hexane solution) and sugar powder were mixed together with stirring, and the solid mixture obtained was crushed, thoroughly kneaded with addition of 20% aqueous solution of gum arabic by spraying, granulated under pressure and dried at room temperature.
- invention 4a The insecticide as dissolved in acetone was then sprayed to the mixture obtained in an amount of 15 ml per g of the mixture. The mixture was thoroughly stirred, and the solvent was removed therefrom by a rotary evaporator (50° C.) to obtain a fly attracting composition of the invention.
- This composition will be referred to as "invention 4a”.
- a comparative fly attracting composition having the same hue and the same mean grain size as the composition of Example 4, was prepared in the same manner as in Example 4 except that cis-9-tricosene was not used. This composition will be referred to as "comparative 4b".
- Example 4 The components used in Example 4 were mixed together with stirring, then pulverized and dried to obtain a comparative fly attracting composition in the form of a powder. This composition will be referred to as "comparative 4c".
- the attractant specimens prepared above were tested for attracting-insecticidal activity on flies by placing the specimens, 20 g each, into large dishes, 15 cm in inside diameter, individually, arranging the dishes on the floor of a test room (4 ⁇ 3 ⁇ 2.6 m) and releasing about 140 to 150 flies into the room. The number of dead flies in each dish was counted one to two hours after the start of the test. The activity is evaluated in terms of the average obtained by repeating the above test four times for each specimen.
- the sugar powder and cis-9-tricosene (used as 1 ml of hexane solution) were mixed together with stirring to obtain a solid mixture, which was then crushed, thoroughly kneaded with addition of 20% aqueous solution of gum arabic by spraying, granulated to a mean grain size of 2 mm under pressure and dried at room temperature.
- invention 5a The above insecticide as dissolved in acetone was subsequently sprayed to the granular mixture in an amount of 15 ml per 50 g of the mixture. The mixture was thoroughly stirred, and the solvent was removed therefrom by a rotary evaporator (50° C.) to obtain a fly attracting composition of the invention. This composition will be referred to as "invention 5a".
- the composition has a hue of 1YR and was eventually 1.5 mm in mean grain size.
- a comparative fly attracting composition having the same hue and mean grain size as above was prepared in the same manner as in Example 5 except that no cis-9-tricosene was used.
- the composition will be referred to as "comparative 5b".
- composition specimens obtained in these examples were tested in the same manner as in Example 4 using 20 g of each specimen. Table 6 below shows the result. The activity is evaluated in terms of the average obtained by repeating the test procedure five times for each specimen.
- A-2 Yellow No. 2
- composition specimens of the invention prepared in these examples were tested for attracting-insecticidal activity on flies in the same manner as in Example 4.
- the result achieved by each of the specimens was comparable to those already attained by the compositions of the invention.
- Granular attracting-insecticidal compositions having a mean grain size of 2 mm and the same hue as the composition of Example 4 according to the invention were prepared in the same manner as in Example 4 with the exception of using the sex pheromones listed in Table 8 below in place of cis-9-tricosene.
- compositions obtained were tested in the same manner as in Example 4. Consequently, each of the composition was found to exhibit the same attracting effect as achieved by the composition of the invention in Example 4.
- compound A 5-benzyl-3-furylmethyl d-cis/trans-chrysanthemate
- compound A 5-benzyl-3-furylmethyl d-cis/trans-chrysanthemate
- compound A 1.04 g of Yellow No. 5
- 0.1 g of cis-9-tricosene 60 g of sugar powder and 20 g of pupal powder
- the solvent was removed from the mixture using a rotary evaporator (50° C.).
- the mixture was screened with a 2-mm-mesh sieve, and the oversize portion was further pulverized to particles.
- the combined powder thus obtained was fully kneaded with addition of 1.2 ml of Amycol H (aqueous binder solution) by spraying and granulated to a mean grain size of 2 mm under pressure.
- the granular mixture was dried at 40° C. for 4 hours to obtain a bait composition according to the invention.
- a bait composition of the invention was prepared in the same manner as in Example 18 except that 40 g of pupal powder was used.
- a bait composition of the invention was prepared in the same manner as in Example 18 with the exception of using 10 g of wheat flour and 30 g of glucose in place of sugar powder and 5 g of a meat extract in place of pupal powder.
- a bait composition of the invention was prepared in the same manner as in Example 18 with the exception of using Permethrin in place of compound A.
- a bait composition of the invention was prepared in the same manner as in Example 18 except that Phenothrin was used in place of compound A.
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- Life Sciences & Earth Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
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Abstract
Description
______________________________________ 1. Sugar powder 60 g 2. Pigment 0.8 g 3. cis-9-Tricosene 15 mg (1.5 ml as 1 wt. % acetone solution) 4. Mixture of methanol and acetone 100 ml in equal amounts 5. Binder 7 ml (20 wt. % aqueous solution of gum arabic) ______________________________________
TABLE 1 ______________________________________ Preparation Hue of No. Pigment preparation ______________________________________ 1a Tartrazine No. 4 6 YR 1b Uranine K (202-1) 2 Y 1c Naphthol Yellow S 3 Y 1d Fluoresceine 1 YR 1e Quinoline Yellow SS 10 YR 1f Fast Yellow 3G 7 YR 1g Uranine K (202-2) 2 Y 1h Benzidine Yellow G 5 YR 1i Metanil Yellow 5 Y 1j Hansa Yellow 3 Y 1k Yellow No. 5 9 R 1l Sunset Yellow F 1 YR 1m Yellow No. 4 1.5 R ______________________________________
TABLE 2 ______________________________________ Preparation No. Fly attracting effect (%) ______________________________________ 2a 1 2b 3 2c 2 2d 28 2e 3 2f 4 2g 4 2h 4 2i 3 2j 3 2k 30 2l 11 2m 3 Control 1 2a 3 2b 2 2c 1 2d 16 2e 4 2f 5 2g 5 2h 3 2i 3 2j 5 2k 28 2l 21 2m 3 Control 1 ______________________________________
TABLE 4 ______________________________________ Preparation Pigment Fly attracting No. Name Concn. (wt. %) Hue effect (%) ______________________________________ 3a Sunset 0.08 1 YR 12 Yellow F 3b " 1.3 1 YR 16 ______________________________________
______________________________________ Pigment (Fluoresceine) 1 g Insecticide (Permethrin) 1 g cis-9-Tricosene 25 mg Extender (sugar powder) 100 g ______________________________________
TABLE 5 ______________________________________ Attracting-insecticidal Test No. Specimen activity (number of flies) ______________________________________ 1 Invention 4a 69.1 2 Comparative 4b 9.1 3 Comparative 4c 2.9 ______________________________________
______________________________________ Insecticide (Methomyl, S--methyl 2 g N--(methylcarbamoyloxy)thioacetimidate cis-9-Tricosene 50 mg Sugar powder 100 g Antioxidant (BHT, 2,6-di-tert- 2 g butylmethylphenyl) Fluoresceine 1 g ______________________________________
TABLE 6 ______________________________________ Attracting-insecticidal Test No. Specimen activity (number of flies) ______________________________________ 1 Invention 5a 43.3 2 Comparative 6b 10.4 ______________________________________
TABLE 7 __________________________________________________________________________ cis-9- Sugar Tricosene Insecticide Pigment powder Grain Ex. Amount Amount Amount Amount size No. (part) Name (parts) Name (parts) (parts) (mm) Hue __________________________________________________________________________ 6 0.025 B-1 1.0 A-1 1.0 97.975 1.5 1 YR 7 0.025 B-2 1.0 A-2 1.0 97.975 1.5 9 R 8 0.025 B-3 1.0 A-3 1.0 97.975 1.5 1 YR 9 0.025 B-1 3.0 A-1 3.0 93.975 3.0 1 YR 10 0.025 B-2 3.0 A-1 3.0 93.975 3.0 1 YR 11 0.025 B-3 3.0 A-1 3.0 93.975 3.0 1 YR __________________________________________________________________________
TABLE 8 ______________________________________ Example No. Sex pheromone ______________________________________ 12 9-Tricosene 13 10-Methyl-9-tricosene 14 cis-2-Methyl-8-docosene 15 cis-9-Docosene 16 cis-8-Docosene 17 cis-10-Tricosene ______________________________________
TABLE 9 ______________________________________ Knockdown Example 5 Minutes later 24 Hours later ______________________________________ 18 100 100 21 100 100 22 100 100 ______________________________________
Claims (9)
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60-158835 | 1985-07-18 | ||
JP60158835A JPS6219504A (en) | 1985-07-18 | 1985-07-18 | Attractant for fly |
JP60-166358 | 1985-07-26 | ||
JP60166358A JPS6226207A (en) | 1985-07-26 | 1985-07-26 | Toxic feed agent for fly |
JP60166359A JPS6226208A (en) | 1985-07-26 | 1985-07-26 | Attractant and insecticidal composition for fly |
JP60-166359 | 1985-07-26 | ||
JP60180749A JPS6242903A (en) | 1985-08-16 | 1985-08-16 | Fly attractant |
JP60-180749 | 1985-08-16 |
Publications (1)
Publication Number | Publication Date |
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US4855133A true US4855133A (en) | 1989-08-08 |
Family
ID=27473576
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/031,068 Expired - Fee Related US4855133A (en) | 1985-07-18 | 1986-07-18 | Composition for attracting flies |
Country Status (7)
Country | Link |
---|---|
US (1) | US4855133A (en) |
EP (1) | EP0229191B1 (en) |
KR (1) | KR940000802B1 (en) |
AU (1) | AU591161B2 (en) |
BR (1) | BR8606797A (en) |
DE (1) | DE3688525T2 (en) |
WO (1) | WO1987000401A1 (en) |
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WO1992009199A1 (en) * | 1990-11-23 | 1992-06-11 | Kansas State University Research Foundation | Method of attracting male hessian flies |
US5229126A (en) * | 1989-06-16 | 1993-07-20 | Ecolab Inc. | Flying insect attractant composition |
US5399344A (en) * | 1992-04-16 | 1995-03-21 | Sandoz Ltd. | Synergistic fly attractant composition |
US5484599A (en) * | 1993-11-30 | 1996-01-16 | The President And Fellows Of Harvard College | Control of insect pests |
AU667550B2 (en) * | 1992-08-12 | 1996-03-28 | Bayer Aktiengesellschaft | Methods for combating insects and agents for combating insects |
WO1996018295A1 (en) * | 1994-12-12 | 1996-06-20 | The United States Of America, Represented By The Secretary, Department Of Agriculture | Pesticide composition and method for controlling the mediterranean fruit fly and the oriental fruit fly |
WO1997014304A1 (en) * | 1995-10-16 | 1997-04-24 | Photodye International, Inc. | Phototoxic insecticidal composition and method for controlling insect populations |
US5728394A (en) * | 1994-12-12 | 1998-03-17 | Photodye International, Inc. | Pesticide composition and method for controlling the oriental fruit fly |
US5753686A (en) * | 1992-09-18 | 1998-05-19 | International Flavors & Fragrances Inc. | Method for repelling fire ants and horn flies and compositions for repelling fire ants and horn flies and acting as anti-feedants for fire ants and horn flies |
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US5850707A (en) * | 1993-06-01 | 1998-12-22 | Virginia Tech Intellectual Properties, Inc. | Insect bait |
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US20040115235A1 (en) * | 2002-12-12 | 2004-06-17 | Simpson Arthur W. | Adhesive device for capturing insects |
US20040208953A1 (en) * | 2003-04-17 | 2004-10-21 | Heath Robert R. | Baiting system for suppressing populations of insects such as mediterranean and carribean fruit flies (Diptera: Tephritidae) |
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US20110158934A1 (en) * | 2009-12-28 | 2011-06-30 | Nishiguchi Naonobu | Fly attractant composition and fly attracting method, as well as fly expellant composition and fly expelling method |
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US20150359215A1 (en) * | 2013-01-28 | 2015-12-17 | Laurentian University | Compositions and methods for directing the oviposition of mosquitoes |
US20160157496A1 (en) * | 2013-07-22 | 2016-06-09 | Emekatech, Llc | Compositions for effective fly population suppression |
US10980235B2 (en) | 2017-02-13 | 2021-04-20 | Clarke Mosquito Control Products, Inc. | Insecticidal composition |
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US5843710A (en) * | 1987-07-07 | 1998-12-01 | Biotech Australia Pty. Limited And Csiro | Vaccines against animal parasitic nematodes |
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BR9406243A (en) * | 1993-03-31 | 1996-01-09 | Zeneca Ltd | Solid insecticidal composition and processes for the preparation of a granulated composition and to combat the larvae and adult stages of dipterous insect pests |
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US5229126A (en) * | 1989-06-16 | 1993-07-20 | Ecolab Inc. | Flying insect attractant composition |
WO1992009199A1 (en) * | 1990-11-23 | 1992-06-11 | Kansas State University Research Foundation | Method of attracting male hessian flies |
US5399344A (en) * | 1992-04-16 | 1995-03-21 | Sandoz Ltd. | Synergistic fly attractant composition |
US5679363A (en) * | 1992-04-16 | 1997-10-21 | Sandoz Ltd. | Synergistic fly attractant composition |
AU667550B2 (en) * | 1992-08-12 | 1996-03-28 | Bayer Aktiengesellschaft | Methods for combating insects and agents for combating insects |
US5753686A (en) * | 1992-09-18 | 1998-05-19 | International Flavors & Fragrances Inc. | Method for repelling fire ants and horn flies and compositions for repelling fire ants and horn flies and acting as anti-feedants for fire ants and horn flies |
US5811095A (en) * | 1993-04-30 | 1998-09-22 | Alternative Methods, Inc. | Basal and chitinase broth compositions for enhancing anti-fungal activity of a chemical fungicide and methods for preparing and using same |
US5850707A (en) * | 1993-06-01 | 1998-12-22 | Virginia Tech Intellectual Properties, Inc. | Insect bait |
US5900243A (en) * | 1993-11-30 | 1999-05-04 | The President And Fellows Of Harvard College | Control of insect pests |
US5484599A (en) * | 1993-11-30 | 1996-01-16 | The President And Fellows Of Harvard College | Control of insect pests |
US5798112A (en) * | 1994-12-09 | 1998-08-25 | The United States Of America As Represented By The Secretary Of Agriculture | Phototoxic insecticidal composition and method for controlling insect populations |
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Also Published As
Publication number | Publication date |
---|---|
KR870700286A (en) | 1987-12-28 |
WO1987000401A1 (en) | 1987-01-29 |
DE3688525T2 (en) | 1994-01-13 |
DE3688525D1 (en) | 1993-07-08 |
EP0229191B1 (en) | 1993-06-02 |
AU6136886A (en) | 1987-02-10 |
EP0229191A1 (en) | 1987-07-22 |
KR940000802B1 (en) | 1994-02-02 |
AU591161B2 (en) | 1989-11-30 |
BR8606797A (en) | 1987-10-13 |
EP0229191A4 (en) | 1990-04-10 |
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