US464700A - William a - Google Patents
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- US464700A US464700A US464700DA US464700A US 464700 A US464700 A US 464700A US 464700D A US464700D A US 464700DA US 464700 A US464700 A US 464700A
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- gas
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- heat
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- oil
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/46—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using discontinuously preheated non-moving solid materials, e.g. blast and run
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
Definitions
- the object of my invention is to provide an .[0 improved apparatus which will produce a fixed fuel-gas from hydrocarbon oil (crude petroleum) by a simple and comparatively lnexpensive but direct and continuous (or single) proceeding.
- My improved apparatus is shown in broken sectional elevation in the accompanying drawing, and involves a heat-storage chamber A, comprising a shell filled with spaced firebrick forming a checker-chamber B, a fore- 2o hearth C, communicating with thechamber A near its base, and a conduit D, leading from the contracted upper outlet end of the chamberA to the point of storage or of utilization of the generated gas'and containing an exhaust appliance or compressor-such as the fan Efor forcing the gas as it is generated, it it is to be stored, (as in a gasometer,) to the outlet end of the conduit, and maintain it under pressure in the receiver, the compressor 0 also serving to relieve the chamber A of the gas as rapidly as it is generated, and thereby preventing back-pressure by the generated, combustion-impeding, carbonic-acid-gas element of the products of the primary combus- 3 5 tion.
- a heat-storage chamber A comprising a shell filled with spaced firebrick forming a checker-chamber B,
- the fore-hearth C which is practically like that set forth in my pending applications serially numbered, respectively, 353,995 and 353,996, and both filed on the 2d day of June, 1890, comprises a structure forming internally a vertically-tapering flue m, into the flaring or rear portion of which the hydrocarbon oil, with air or steam, or both, are injected and therein ignited, and wherein the products of combustion in their course to the contracted outlet become so thoroughly compacted and intermixed by the tapering form of the flue that they are reduced therein to a condition of complete or approximately complete combustion, whereby practically only carbonicacid gas emerges therefrom.
- a supply-pipe q for air under pressure and an oil-pipe 19 and a steam-pipe 0 also lead into the fore-hearth, preferably by Way of the horizontal portion of the pipe q, into which they should extend, as shown.
- the supply sources of the compressed air, oil, and steam are not illustrated, as they will readily be understood without illustration, and to present them in the drawing would be superfluous and would unnecessarily crowd it.
- I also lead an oil-pipe p, and besides, if desired, a steam-pipe 0, into the chamber A through its wall at. a point above the forehearth C, andthey may be respectively supplied from the same sources as the pipes 29 and 0.
- the passage through the various supply-pipes is controlled by suitable valves, as indicated, or by other suitable contrivances.
- the first step required is to supply the necessaryheat to the storagechamber A, which is done by introducing into the fore-hearth C, through the pipes p and q, oil and atmospheric air and igniting the oil. If desired, steam may, but not necessarily for producing the heat to be stored, be simultaneously introduced through the pipe 0.
- the liquid fuel thus forced into the chamber m of the fore-l1earth,which chamber is gradually 8o contracted vertically toward its mouth, is supplied with sufficient oxygen from the fluid introduced with it and so thoroughly intermixed and compacted bythe contracted form of the passage m that its combustionis forced 8 5 to an extent which renders it complete, or approximately so, by the time it reaches the storage-chamber A, so that only, or practically only, the hot products of combustion enter the heat-storage chamber.
- the 0 material forming the checker chamber is gradually heated to a greatintensity, the firebrick thereof being reduced to a white heat, and to maintain that condition only so much heat need be supplied to it continually through 5 the medium of the fore-hearth as will compensate for that abstracted by the gas-generating process hereinafter described. So it will be understood that only so much air need be supplied with the amount of oil fed to the fore-hearth as is necessary to generate suliicient heat to maintain the intensity thereof required in the chamber A.
- the steam injected is superheated to sucha degree by absorption of heat in the chamber A that its chemical decomposition is readily thereby produced, the oxygen forming with the carbon protoxide of carbon gas, and the hydrogen one or another of the various combinations of hydrocarbon gas or remaining in the free state and entering the ultimate complex gas as free hydrogen.
- the purpose of the air and steam is of course primarily to supply the oxygen necessary for combustion to generate the heat for the l1eatstorage chamber and to combine with the free carbon of theIoil for producing the protoxideof-carbon gas, so that to that end air without steam could be used for producing simply a hydrocarbon fuel-gas, though not so advantageously, owing to its smaller proportion of oxygen compared with Water and to its large proportion of useless nitrogen; also, steam could be used Without air; but I prefer to employ both and in the manner described. ⁇ Vhether or not the gasiproduct of my improved apparatus is a so-called water-gas depends, of course, upon the proportionate quantity of steam used.
- the gas is removed as fast as formed, the action of the fan taking it out rapidly and forcing it under pressure into the holder, whence it may be taken for use as required. If it is to be rendered an illuminating-gas, any of the known or suitable methods of purification and abstraction of the nitrogen and of carbureting it may for the purpose be resorted to.
- An apparatus for manufacturing fuel-gas from fluid hydrocarbon comprising, in combination, the following elements: a chamber A, formed of a shell filled with spaced fire-brick, a forc-hearth O extraneous to the said chamber and formed with a vertically-tapering fine on, leading at its contracted end into the base of the said chamber, supply-pipes for the hydrocarbon and combustion'inducing fluid leading into the rear portion of the forehearth and into the chamber A above the fine 77?, and an exhaust-fan communicating with the upper end of the said chamber, substant-ially as and for the purpose set forth.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Description
(No Model.) W. A. KONEMAN. i APPARATUS FOR MANUFACTURING FUEL GAS.
No. 464,700; Patented No.8, 1891.
jwezzi vf,
mzzmm Z6276 %W Unrrnn TATES AT T FFICEo IVILLIAM A. KONEMAN, OF CHICAGO, ILLINOIS, ASSIGNOR TO THE CHICAGO HEAT STORAGE COMPANY, OF SAME PLACE.
APPARATUS FOR MANUFACTURING FUEL-GAS.
SPECIFICATION forming part Of Letters Patent No. 464,700, dated December 8, 1891. Application filed July 14, 1890' Serial No, 358,606. (No inodel.)
To all whom it may concern:
Be it known that I, WILLIAM A. KONEMAN, a citizen of the United States, residing at Chica-go, in the county of Cook and State of Illimm, have invented a new and useful Improvement iii-Apparatus for Manufacturing Fuel-Gas from Hydrocarbon, of which the following is a specification. V I The object of my invention is to provide an .[0 improved apparatus which will produce a fixed fuel-gas from hydrocarbon oil (crude petroleum) by a simple and comparatively lnexpensive but direct and continuous (or single) proceeding.
My improved apparatus is shown in broken sectional elevation in the accompanying drawing, and involves a heat-storage chamber A, comprising a shell filled with spaced firebrick forming a checker-chamber B, a fore- 2o hearth C, communicating with thechamber A near its base, and a conduit D, leading from the contracted upper outlet end of the chamberA to the point of storage or of utilization of the generated gas'and containing an exhaust appliance or compressor-such as the fan Efor forcing the gas as it is generated, it it is to be stored, (as in a gasometer,) to the outlet end of the conduit, and maintain it under pressure in the receiver, the compressor 0 also serving to relieve the chamber A of the gas as rapidly as it is generated, and thereby preventing back-pressure by the generated, combustion-impeding, carbonic-acid-gas element of the products of the primary combus- 3 5 tion. The fore-hearth C, which is practically like that set forth in my pending applications serially numbered, respectively, 353,995 and 353,996, and both filed on the 2d day of June, 1890, comprises a structure forming internally a vertically-tapering flue m, into the flaring or rear portion of which the hydrocarbon oil, with air or steam, or both, are injected and therein ignited, and wherein the products of combustion in their course to the contracted outlet become so thoroughly compacted and intermixed by the tapering form of the flue that they are reduced therein to a condition of complete or approximately complete combustion, whereby practically only carbonicacid gas emerges therefrom.
Into the rear portion of the fore-hearth C, and preferably through the rear wall thereof, extends a supply-pipe q for air under pressure, and an oil-pipe 19 and a steam-pipe 0 also lead into the fore-hearth, preferably by Way of the horizontal portion of the pipe q, into which they should extend, as shown. The supply sources of the compressed air, oil, and steam are not illustrated, as they will readily be understood without illustration, and to present them in the drawing would be superfluous and would unnecessarily crowd it. I also lead an oil-pipe p, and besides, if desired, a steam-pipe 0, into the chamber A through its wall at. a point above the forehearth C, andthey may be respectively supplied from the same sources as the pipes 29 and 0. The passage through the various supply-pipes is controlled by suitable valves, as indicated, or by other suitable contrivances.
To start the operation,the first step required is to supply the necessaryheat to the storagechamber A, which is done by introducing into the fore-hearth C, through the pipes p and q, oil and atmospheric air and igniting the oil. If desired, steam may, but not necessarily for producing the heat to be stored, be simultaneously introduced through the pipe 0. The liquid fuel thus forced into the chamber m of the fore-l1earth,which chamber is gradually 8o contracted vertically toward its mouth, is supplied with sufficient oxygen from the fluid introduced with it and so thoroughly intermixed and compacted bythe contracted form of the passage m that its combustionis forced 8 5 to an extent which renders it complete, or approximately so, by the time it reaches the storage-chamber A, so that only, or practically only, the hot products of combustion enter the heat-storage chamber. Thus the 0 material forming the checker chamber is gradually heated to a greatintensity, the firebrick thereof being reduced to a white heat, and to maintain that condition only so much heat need be supplied to it continually through 5 the medium of the fore-hearth as will compensate for that abstracted by the gas-generating process hereinafter described. So it will be understood that only so much air need be supplied with the amount of oil fed to the fore-hearth as is necessary to generate suliicient heat to maintain the intensity thereof required in the chamber A. \Vhen the heatsupply in the storage-chamber has been attained, the supply thereto of oil and steam is admitted from which to generate the gas, this supply being introduced through the pipes 19 and 0, though a surplus of oil beyond what is required for heating the storagechamber may also be introduced with steam through the pipes 19 and 0. In the chamber A the carbonic'acid gas generated in the forehearth (J and injected into the chamber A is thus supplied with sufficient carbon in the additional supply of oil (vaporized by the heat in the chamber A) to force the disunion of one atom of the oxygen in the carbonicacid gas to tie such atom of oxygen to a corresponding atom of free carbon, resulting in a double volume of in flam mable protoxide of carbon gas. The steam injected is superheated to sucha degree by absorption of heat in the chamber A that its chemical decomposition is readily thereby produced, the oxygen forming with the carbon protoxide of carbon gas, and the hydrogen one or another of the various combinations of hydrocarbon gas or remaining in the free state and entering the ultimate complex gas as free hydrogen. The purpose of the air and steam is of course primarily to supply the oxygen necessary for combustion to generate the heat for the l1eatstorage chamber and to combine with the free carbon of theIoil for producing the protoxideof-carbon gas, so that to that end air without steam could be used for producing simply a hydrocarbon fuel-gas, though not so advantageously, owing to its smaller proportion of oxygen compared with Water and to its large proportion of useless nitrogen; also, steam could be used Without air; but I prefer to employ both and in the manner described. \Vhether or not the gasiproduct of my improved apparatus is a so-called water-gas depends, of course, upon the proportionate quantity of steam used. From the gas-generating heat-storage chamber A the gas is removed as fast as formed, the action of the fan taking it out rapidly and forcing it under pressure into the holder, whence it may be taken for use as required. If it is to be rendered an illuminating-gas, any of the known or suitable methods of purification and abstraction of the nitrogen and of carbureting it may for the purpose be resorted to.
While it is desirable to maintain the supply of heat in the chamber A in the propor tion as stated of its abstraction by the gasgenerating operation therein, it would be feasible to interrupt the action through the tore-hearth O or the supplying of heat to the chamber A after it has once become adequately heated and again supply it as often as the gas-generation therein has lowered the heat thereof sufficiently to require replenishment.
WhatI claim as new, and desire to secure by Letters Patent, is
An apparatus for manufacturing fuel-gas from fluid hydrocarbon, comprising, in combination, the following elements: a chamber A, formed of a shell filled with spaced fire-brick, a forc-hearth O extraneous to the said chamber and formed with a vertically-tapering fine on, leading at its contracted end into the base of the said chamber, supply-pipes for the hydrocarbon and combustion'inducing fluid leading into the rear portion of the forehearth and into the chamber A above the fine 77?, and an exhaust-fan communicating with the upper end of the said chamber, substant-ially as and for the purpose set forth.
\VILLIAM A. KONEMAN.
In presence of- J. W. DYRENFORTH, M. J. Fnosr.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US464700A true US464700A (en) | 1891-12-08 |
Family
ID=2533569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US464700D Expired - Lifetime US464700A (en) | William a |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US464700A (en) |
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- US US464700D patent/US464700A/en not_active Expired - Lifetime
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