US361191A - springer - Google Patents
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- US361191A US361191A US361191DA US361191A US 361191 A US361191 A US 361191A US 361191D A US361191D A US 361191DA US 361191 A US361191 A US 361191A
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- Prior art keywords
- coke
- gas
- chamber
- pipe
- heated
- Prior art date
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- 239000007789 gas Substances 0.000 description 68
- 239000000571 coke Substances 0.000 description 66
- 238000002485 combustion reaction Methods 0.000 description 52
- 239000002802 bituminous coal Substances 0.000 description 32
- 239000000446 fuel Substances 0.000 description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 24
- 239000003245 coal Substances 0.000 description 22
- 239000011819 refractory material Substances 0.000 description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- 150000002430 hydrocarbons Chemical class 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 14
- 239000001257 hydrogen Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 238000004939 coking Methods 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 8
- 239000011449 brick Substances 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 229910021385 hard carbon Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000001105 regulatory Effects 0.000 description 4
- 206010022114 Injury Diseases 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N Methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 2
- 239000003830 anthracite Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 235000012970 cakes Nutrition 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000001535 kindling Effects 0.000 description 2
- 239000006233 lamp black Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000011470 perforated brick Substances 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
Definitions
- This invention relates to the process of and apparatus for manufacturing heating and illuminating gas; and the object of the invention is more particularly to utilize soft or bituminous coal in the manufacture of watergas by first coking such coal,and thereby feeding or replenishing the body of incandescent coke in which steam is decomposed.
- a second bed of coke or other form of hard carbon may be heatedto incandescence, and a second body of bituminous or soft coal be reduced to coke, as in the first cupola, and the resulting gaseous products from both sources burned, and the heat stored in a second body of refractory material in a regenerator-chamber.
- the water-gas or mixture of carbonic oxide andlight carbureted hydrogen passing from the fuel-chamber of the first cupola may then be passed through the fuel of the second cupola, and thence into the second body of refractory material, where it is carbureted and converted into a fixed illuminating-gas.
- Figure 1 represents a vertical longitudinal section of the single form of my apparatus; and Fig. 2 represents a vertical longitudinal section of the apparatus in connected or double form, adapted for making illuminating-gas.
- the cupola A is built tall, and is partially divided by the ledge a into the lower combustion and decomposing fuel-chamber, A, and the upper cokingchamber, A". It is constructed of fire-brick and surrounded and incloscd by a tight iron jacket in the usual manner.
- An air-blast pipe, B connects with the ash-pit for producing active combustion of the coke or other form of hard carbon in compartment A, and a small air-blast pipe, 13, having a controllingrvalve, t, connects with the coking chamber or compartment
- Escapepipes D D connect, respectively, with the tops of the compartments A and A for conducting off the gaseous products from each, and these pipes connect with the vertical pipe E, which is connected by pipe F with the top of chamber G of the regenerator G.
- a conical valve, d provided with a stem and operating-lever, is arranged to close upon a seat, cl, in pipe E, and thus close pipe D and communication between coking-chamber A and the regenerator.
- a plug or stopper valve, 0, having a stem, 6, is provided in the lower end of pipe E, for closing pipe D.
- a fuel-supply opening, I), having a tight-closing lid, 00, is provided in the top cupola, A.
- the regenerator G is divided into two vertical chambers, G and G, by the vertical partition I, and chamber G is provided with two perforated brick arches, h h, dividing it into upper and lower compartments, and serving to support the brick checker-work placed in the chamber.
- a perforated arch, h is also arranged near the base of chamber G, for supporting its brick checker-work.
- Chamber G is provided at the top with passage g, and tightly-closing lid 5 and chamber G is provided at its top with passage i and tightlyelosing lid i. These passages or openings serve for the escape of products of combustion and for giving access to the chambers for cleaning or repairing the brick-work.
- Air-blast pipes L L connect with chamber G, the first at its top and the second just below arch h, for supplying air to cause combustion of gaseous products from the cupola, and thereby heat the brick-work in chambers G'and G.
- a second cupola, A, and a second regenerator, G constructed, arranged, and connected like those above described, are connected at the base through the medium of gaspipe 0.
- water-gas, or the mixture of earbonic oxide and hydrogen which is madeiu one set of chambers, (viz., a cupola and regenerator,) can be converted into illuminating-gas of any desired candle-power by passing it through the body of fuel in the second cupola and then into the second heated regeuerator, where it is carbureted or enriched with hydrocarbons and converted into fixed gas by contact with the heated refractory material.
- the volatile and tarry matters are thus slowly driven off from the soft coal and consumed with the poor gaseous products from the coke without waste and without injury to the brick-work of the superheater, and such coal is reduced to coke, which is perfectly adapted to undergo active combustion and be raised to a high heat, and to subsequently be used for decomposing steam.
- a fire is first kindled on the grate of the cupola, and coke or other hard carbon-such as anthracite coal is fed in during the admission of the air-blast till compartment A is nearly or quite filled with heated fuel.
- a deep body of bituminous coal is supplied to compartment A on top of the body of hot fuel, and to such coal is admitted a limited and regulated supply of air through pipe 13, just sufficient to cause a slow incomplete combustion, such as is best adapted for the coking operation.
- Valves d and ebeing open the products of active combustion from the fuel in compartment A pass off through pipe D, and the volatile matter and gases from the distilling coal in compartment A pass out through pipe D, and both then flow into the top of the superhcating regenerator-chamber G, where they are burned by the admission of air by pipe L.
- the products pass down and are given a second supply of air by pipe L, which causes their complete combustion.
- the hot products then pass down to the base of chamber G, and then up through chamber G, from which they escape by passage 17, thus highly heating the refractory brick-work in both chambers.
- the lid .50 should be open, then, after the air-blasts are admitted, lid is opened and lid w closed.
- the mixture of hydrocarbon oil with steam in excess is decomposed in contact with the heated brick-work in chamber G, so as to form carbonic acid and hydrogen; and these gases, in a hlghly heated state, are conducted through the incandescent fuel, and thereby converted into carbonic oxide and light carbureted hydrogen.
- the mixture of carbonic acid and hydrogen may be passed through the incandescent coke only, or firstthrough the partiallydistilled coal and then through incandescent coke.
- the water-gas is finally passed off tht jough pipes O and I, leading from the ash-
- the two sets of fuel and regenerator chambers may be conveniently operated at the same time, but independently of each other, for making heating-gas, as above described, and when it is desired to make illuminating-gas they are connected at their bases through the medium of pipes'G, by opening the valves 0 c and closing valvep. (Shown in Fig. 2.)
- valve 0 may be closed and the right-hand cupola and regenerator blasted with air and heated up, while valves 0 and p are opened and water-gas is generated in the left-hand regenerator and cupola, and such gas passed off through pipes O and P. Then, of course, the left-hand set may be heated up, while gas is generated in the right-hand set by closing valve 0 and opening valve 0. In this manner two sets of generators can be con veniently and economically used for generating water-gas,or for generating illuminatinggas, as desired.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Coke Industry (AREA)
Description
(No Model.) 1 2 SheetS Sheet 1.
T. G. SPRINGER.
PROCESS OF AND APPARATUS FOR MANUFACTURING GAS.
Patented A r. 12, 1887.
PETERS. Phololilhflgnpher, Walhinglnn. D. C.
(No Model.) 2 Sheets-S'heet 2.
T, G. SPRINGER. PROCESS OF AND APPARATUS FOR MANUFACTURING GAS.
No. 361,191. Patented Apr. 12, 1887.
n me i Jive/1Z0. F
, v flla M M? N PETERS. Molillwgnpber. Walbirlqion. D C,
UNITED, STATES PATENT OFFICE.
THEODORE efsrnmenn, OF NEW YORK, N. Y.
PROCESS OF ANDAPPARATUS? FOR MANUFACTURING GAS.
SPECIFICATION forming part of Letters Patent No. 361,191, dated April 12, 1887. Application filed November 29,1886. Serial No. 220,198 (No model.)
To all whom it may concern.-
Be it known that I, THEODORE G. SPRINGER, a citizen of the United States, residing at New York city, in the county of New York and State of New York, have invented a [certain new and useful Improvement in Process of and Apparatus for Manufacturing Heating and Illuminating Gas; and I do hereby declare the following to be a full, clear, and exact descriptionof the invention, such as will enable others skilled in the art to which it appertains tomake and use the same.
This invention relates to the process of and apparatus for manufacturing heating and illuminating gas; and the object of the invention is more particularly to utilize soft or bituminous coal in the manufacture of watergas by first coking such coal,and thereby feeding or replenishing the body of incandescent coke in which steam is decomposed.
In carrying out my invention one portion of a body of fuel contained in a cupola-namely, the coke or other form of hard carbonis blasted with air, causing its active combustion till it is heated to incandescence, and at the same time "a body of bituminous or soft coal is subjected to direct contact with the body of highly-heated coke and to incomplete or smothered combustion, so as to distill off the volatile hydrocarbons, and thereby replenish the coke as fast as consumed by active combustion. The gaseous products resulting from the active combustion of the coke and from the distillation and incomplete or'smothered combustion of the bituminous coal are burned in a regenerating-chamber and the heat stored in a body of refractory material. Steam is then highly superheated by passage through such heated refractory material and is then decomhydrogen, and these mixed gases are passed into contact with the heated fuel, and thereby converted into carbonic oxide and light carbureted hydrogen. A second bed of coke or other form of hard carbon may be heatedto incandescence, and a second body of bituminous or soft coal be reduced to coke, as in the first cupola, and the resulting gaseous products from both sources burned, and the heat stored in a second body of refractory material in a regenerator-chamber. The water-gas or mixture of carbonic oxide andlight carbureted hydrogen passing from the fuel-chamber of the first cupola may then be passed through the fuel of the second cupola, and thence into the second body of refractory material, where it is carbureted and converted into a fixed illuminating-gas.
The matter constituting my-invention will be defined in the claims.
V In the drawings, Figure 1 represents a vertical longitudinal section of the single form of my apparatus; and Fig. 2 represents a vertical longitudinal section of the apparatus in connected or double form, adapted for making illuminating-gas. a
The cupola A is built tall, and is partially divided by the ledge a into the lower combustion and decomposing fuel-chamber, A, and the upper cokingchamber, A". It is constructed of fire-brick and surrounded and incloscd by a tight iron jacket in the usual manner. An air-blast pipe, B, connects with the ash-pit for producing active combustion of the coke or other form of hard carbon in compartment A, and a small air-blast pipe, 13, having a controllingrvalve, t, connects with the coking chamber or compartment A Escapepipes D D connect, respectively, with the tops of the compartments A and A for conducting off the gaseous products from each, and these pipes connect with the vertical pipe E, which is connected by pipe F with the top of chamber G of the regenerator G. A conical valve, d, provided with a stem and operating-lever, is arranged to close upon a seat, cl, in pipe E, and thus close pipe D and communication between coking-chamber A and the regenerator. A plug or stopper valve, 0, having a stem, 6, is provided in the lower end of pipe E, for closing pipe D. A fuel-supply opening, I), having a tight-closing lid, 00, is provided in the top cupola, A.
v The regenerator G is divided into two vertical chambers, G and G, by the vertical partition I, and chamber G is provided with two perforated brick arches, h h, dividing it into upper and lower compartments, and serving to support the brick checker-work placed in the chamber. A perforated arch, h, is also arranged near the base of chamber G, for supporting its brick checker-work. Chamber G is provided at the top with passage g, and tightly-closing lid 5 and chamber G is provided at its top with passage i and tightlyelosing lid i. These passages or openings serve for the escape of products of combustion and for giving access to the chambers for cleaning or repairing the brick-work. An outlet gas-pipe, H, having valve it, connects with the top of chamber G, for conducting gas which it is desired to save to a place of storage or use. Steamsupply pipe K, having valve 7;, connects with the top of chamber G. An oilsupply pipe, m, connects with the base of chamber G, below arch h. Air-blast pipes L L connect with chamber G, the first at its top and the second just below arch h, for supplying air to cause combustion of gaseous products from the cupola, and thereby heat the brick-work in chambers G'and G. The takeoff pipe 0, for water gas, or mixture of carbonic oxide and light carbureted hydrogen,
' connects with the ash-pit of cupola A and leads to the seal and wash-box. shown.)
As shown in the drawings, Fig. 2, a second cupola, A, and a second regenerator, G, constructed, arranged, and connected like those above described, are connected at the base through the medium of gaspipe 0. By this connection, water-gas, or the mixture of earbonic oxide and hydrogen,which is madeiu one set of chambers, (viz., a cupola and regenerator,) can be converted into illuminating-gas of any desired candle-power by passing it through the body of fuel in the second cupola and then into the second heated regeuerator, where it is carbureted or enriched with hydrocarbons and converted into fixed gas by contact with the heated refractory material.
It has heretofore been proposed, and I have described in my Patents Nos. 257,100 and 263,612, the operation of supplying bituminous coal to the steam-decomposing chamber in a water-gas generator, and heating it to incandescence by active combustion with blasts of air for subsequently decomposing steam; but for reasons stated below such operation was not successful.
I have learned by experience that bituminous orsoft coal cannot be successfully blasted and heated to ineandescence and used for decomposing steam, for the reason that when highly heated in a deep body it runs together and cakes in large masses, so that steam cannot be advantageously passed through it for decomposition, and also for the reason that soot and lampblack are given off from it in such large quantities as to clog up the brickwork of the regenerator, and so render it inoperative. It is, however, very desirable to use such soft or bituminous coal in making (Not here watergas, on account of its abundance and cheapness in many localities; and in order to use it and avoid the above-mentioned objections I apply the air-blast in large volumes directly to a body of coke, and cause its active combustion till it is heated to incandescence, and pass off the products of combustion below the body of bituminous coal, and at the same time subject such body of the bituminous coal to direct contact with the highly-heated coke and to a slow and incomplete or smothered combustion, with a limited and regulated airsupply, in order to gradually distill off the volatile matter and reduce it to coke, so as to thereby replenish the body of coke as it is consumed by the active combustion. The volatile and tarry matters are thus slowly driven off from the soft coal and consumed with the poor gaseous products from the coke without waste and without injury to the brick-work of the superheater, and such coal is reduced to coke, which is perfectly adapted to undergo active combustion and be raised to a high heat, and to subsequently be used for decomposing steam.
The operation is as follows: A fire is first kindled on the grate of the cupola, and coke or other hard carbon-such as anthracite coal is fed in during the admission of the air-blast till compartment A is nearly or quite filled with heated fuel. Then a deep body of bituminous coal is supplied to compartment A on top of the body of hot fuel, and to such coal is admitted a limited and regulated supply of air through pipe 13, just sufficient to cause a slow incomplete combustion, such as is best adapted for the coking operation. Valves d and ebeing open, the products of active combustion from the fuel in compartment A pass off through pipe D, and the volatile matter and gases from the distilling coal in compartment A pass out through pipe D, and both then flow into the top of the superhcating regenerator-chamber G, where they are burned by the admission of air by pipe L. The products pass down and are given a second supply of air by pipe L, which causes their complete combustion. The hot products then pass down to the base of chamber G, and then up through chamber G, from which they escape by passage 17, thus highly heating the refractory brick-work in both chambers. \Vhen kindling the fire, the lid .50 should be open, then, after the air-blasts are admitted, lid is opened and lid w closed. The body of coke in compartment A being heated to incandescence and the supcrhcat-ingregenerator G G G being heated to the desired temperature, the air-blasts are shut off, the lids i and g and a: are tightly closed, and steam is admitted by pipe K into the top of chamber G and passed down through such chamber and up through chamber G in contact with the heated brick-work, by which it is highly superheated, and is thence passed either directly through pipes E and D into the body of incandescent coke, where it is decomposed, or
1t ispassed by pipe D into compartment A, and thence down through the body of partlally-coked bituminous coal, and thence on down throughiheincandescent body of fuel in compartmentA,where it is completely decomposed and converted into watergas. The superheated steam, in passing-down through the partially-distilled bituminous coal, carries some of the volatile and tarry matters down 1nto the incandescent coke, where they are decomposed, together with the steam, resulting in the formation of carbureted hydrogenand water-gas. The steam having been passed down through chamber G and therein superheated, may be commingled with oil vapor resulting from the admission'of a limited supply of oil through pipe m at the base of chamber G, and
the mixture of hydrocarbon oil with steam in excess is decomposed in contact with the heated brick-work in chamber G, so as to form carbonic acid and hydrogen; and these gases, in a hlghly heated state, are conducted through the incandescent fuel, and thereby converted into carbonic oxide and light carbureted hydrogen. The mixture of carbonic acid and hydrogen may be passed through the incandescent coke only, or firstthrough the partiallydistilled coal and then through incandescent coke. The water-gas is finally passed off tht jough pipes O and I, leading from the ash- The two sets of fuel and regenerator chambers may be conveniently operated at the same time, but independently of each other, for making heating-gas, as above described, and when it is desired to make illuminating-gas they are connected at their bases through the medium of pipes'G, by opening the valves 0 c and closing valvep. (Shown in Fig. 2.)
.Before commencing the {generation of illuminating-gas both valves of pipe 0 are closed and both bodies of fuel in the two cupolas are blasted and heated at the same time, and
them. 0 c are opened and valve 1) closed. Then water-gas, or themixture of carbonic-oxide and light carbureted hydrogen gas, is made,as heretofore described, preferablyin the right-hand side superheater, G, and cupola A, and such gas is passed through connecting-pipe C and up through the hot coke in compartment A, and thence directly into chamber G, to be carbureted and fixed, or through the hot coke and on through the partially-distilled bituminous coal, and then into chamber G. As
the gas passes into chamber G through pipe F hydrocarbon oil is admitted by pipe R, having valve 1', into the top of such chamber in suitable quantity to carburet the gas to the desired candle-power. The oil is quickly va-- H, the valve n of which is open. In case the two cupolas are connected together at the base by pipe 0 and it is desired to make water-gas in each, then steam, or steam and oil, is preferably decomposed in one set while the other set is being blasted with air and heated up. For instance, valve 0 may be closed and the right-hand cupola and regenerator blasted with air and heated up, while valves 0 and p are opened and water-gas is generated in the left-hand regenerator and cupola, and such gas passed off through pipes O and P. Then, of course, the left-hand set may be heated up, while gas is generated in the right-hand set by closing valve 0 and opening valve 0. In this manner two sets of generators can be con veniently and economically used for generating water-gas,or for generating illuminatinggas, as desired.
Having described my invention, what I claim, and desire to secure by Letters Patent,
1. In the manufacture of gas, the process of raising one portion of a body of fuel to incandescence and coking simultaneously a body of bituminous coal preparatory to decomposing steam, which consists in blasting the coke with air and causing active combustion till it is heated to incandescence, and at the same time subjecting a body of bituminous coal to direct contact with the highly-h eated coke and to incomplete or smothered combustion, (by admitting a limited supply of air,) thereby distilling 0d the volatile hydrocarbons and forming coke to replenish the body of coke below as consumed by the active combustion,
and at the same time subjecting a body of bituminous coal to direct contact with the highly-heated coke and to incomplete or smothered combustion by admitting a limited supply of air, so as to distill off the volatile hydrocarbons and replenish the coke as consumed by active combustion, and at the sametime burning the gaseous products resulting from the coke and bituminous coal and storing the heat in a body of refractory material, then superheating steam in the refractory material and decomposing it by passing it through the heated fuel.
3. The process of manufacturing gas, which consists in raising two bodies of coke to incandescence by active combustion with air-blasts, and at the same time subjecting two bodies of bituminous coal to direct contact with the highly-heated coke and to incomplete or smothered combustion by admitting a limited supply of air, so as to distill off the volatile hydrocarbons and replenish the coke as consumed by active combustion, and at the same time burning the gaseous products resulting from the coke and bituminous coal and storing the heat pipe,in combination with a regenerating-chamin two bodies of refractory material, then suber containing refractory matcriahand a gasperheating steam in one of the bodies of the eduction pipe having a controlling-valve lead- 15 refractory material and decomposingitby passing from each compartment of the fuel-cham 5 ingitthrongh thebodies offuel,and,finally,earher and connecting with such regeneratingbureting the resulting gas and fixing it by passchamber. ing it through the second body of refractory In testimony whereof I affix my signature 1n material to form illuminatinggas. presence of two witnesses.
4. A cnpola gas-generator having a lower THEODORE G. SPRINGER. 1o compartment for decomposing steam and an Vitnesses:
upper compartn'ient for coking coal each com- A. P. HUNSHAUP, partment being provided with an air-blast J. \V. I. Hymns.
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US361191A true US361191A (en) | 1887-04-12 |
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