US4507350A - Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics - Google Patents
Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics Download PDFInfo
- Publication number
- US4507350A US4507350A US06/587,397 US58739784A US4507350A US 4507350 A US4507350 A US 4507350A US 58739784 A US58739784 A US 58739784A US 4507350 A US4507350 A US 4507350A
- Authority
- US
- United States
- Prior art keywords
- fabric
- yarns
- color
- printed
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/001—Special chemical aspects of printing textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
- Y10T428/24901—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
Definitions
- This invention relates to textile pigment printing, and in particular to the production of a printed textile fabric wherein the printed areas are of a predetermined desired color and are characterized by being substantially opaque and thus unaffected by the color of the underlying yarns.
- This invention is related to and is an improvement over the invention described in the above referenced commonly-owned copending applications.
- the aqueous opaque printing process and product of these earlier applications overcome a number of significant limitations and disadvantages of conventional pigment printing techniques and enable the production of a wide variety of patterns and colors not obtainable by the pigment printing techniques heretofore known.
- the printing paste which is used in the opaque printing process unlike the aqueous printing pastes used in conventional screen printing operations, has opacity and can be applied over either dark or light background fabrics without being affected by the color of the underlying yarns.
- the resulting printed pattern areas on the fabric comprise an opaque coating which covers the exposed surfaces of the yarns which form the fabric.
- This coating comprises an opacifying pigment providing opacity in the coating and a cured water insoluble polymer binder which is affixed to the yarns and bonds the opacifying pigment to the yarns.
- the opaque coating which forms the printed pattern areas is characterized by individually coating each of the yarns in the printed area such that the interengaged yarn structure of the fabric is not obliterated, but remains visible. More specifically, the opaque coating at the surface of the yarn is such that the individual surface fibers of the yarn also are not obliterated and remain visible.
- the opaque coating which forms the printed pattern areas may be of any desired color.
- the opacifying pigment itself may be utilized for providing the desired colors.
- Other colors may be produced by including colored pigments or dyestuffs in the printing paste in addition to the opacifying pigment.
- the printing paste is applied to the fabric as a stable aqueous dispersion of the opacifying pigment and polymer binder. After printing on the fabric, the printing paste is dried and cured by heating, with a crosslinking reaction taking place, such that the polymer binder is converted from the aqueous solution or dispersion as it is applied to a tough flexible water insoluble pigmented opaque film. More particularly, the printing paste formulations described in the aforementioned applications rely on acrylic latex and/or aminoplast resins for crosslinking during curing.
- the present invention provides an alternative procedure for producing cured aqueous opaque textile prints which offer a number of advantages over the abovedescribed system of the commonly-owned copending applications referred to earlier.
- a printing paste is utilized which contains the opacifying pigment and a binder which is comprised of monomeric, oligomeric and/or polymeric units capable of being polymerized and cured by free radical initiation.
- the fabric is subjected to free radical initiation to polymerize and cure the binder and thereby bond the opacifying pigment to the yarns.
- the polymerizable binder is a radiation curable binder
- the fabric is subjected to free radical initiation by irradiating the fabric with high energy radiation.
- the polymerizable binder additionally contains a free radical initiator, which may be activated by suitable means such as heating or exposure to radition; and by activating the initiation, the fabric is subjected to free radical initiation to thereby polymerize and cure the binder.
- a free radical initiator which may be activated by suitable means such as heating or exposure to radition; and by activating the initiation, the fabric is subjected to free radical initiation to thereby polymerize and cure the binder.
- An advantage of the free radical curing procedure of the present invention is that the printing paste does not require the presence of a catalyst, which sometimes causes yellowing or discoloration of the fabric under curing conditions. Atmospheric pollutants, associated with solvent systems such as in conventional opaque stencil printing are also eliminated. Additionally, this procedure in many instances makes it possible to carry out curing at a lower temperature, which has many advantages, such as energy savings, reducing fabric shrinkage, and permitting the curing to be carried out at a faster rate.
- the aqueous opaque colored printing paste of the present invention has a relatively high solids content, e.g. preferably at least 25 percent total solids, and consists mainly of an opacifying pigment and a free radical polymerizable binder mixed therewith to form a stable aqueous dispersion.
- the material must be highly opaque, have color properties which permit it to be used alone or mixed with other colorants, such as dyes and colored pigments, and it must be readily dispersable at relatively high concentrations in the aqueous binder system.
- colorants such as dyes and colored pigments
- the preferred opacifying pigment for use in the printing paste formulation of this invention is a white pigment.
- white pigment One particular white pigment which has been found to be especially suitable because of its bright white appearance, cost and availability is titanium dioxide.
- Other suitable white pigments include silicates, aluminum compounds, calcium carbonate, and the like.
- one or more opacifying pigments of lesser whiteness or of intermediate shades may be employed, either alone or in combination with white pigments.
- examples of other compounds suitable for use as opacifying pigments in the present invention include the following: zinc oxide, zinc sulfide, lithopone (ZnS/BaSO 4 ), basic carbonate white lead, basic sulfate white lead, lead oxide (lead dioxide), calcium sulfate, barium sulfate, silica, clay (Al 2 O 3 .2SiO 2 .2H 2 O), lead sulfate, magnesium silicate, mica, wollastonite (CaSiO 3 ), aluminum hydrate, magnesium oxide, magnesium carbonate, aluminum oxide, ferric oxide, sodium carbonate, strontium sulfide, calcium sulfide, barium carbonate, antimonius oxide, zirconium white, barium tungstate, bismuth oxychloride, tin white, lead silicate, chalk, bentonite, barium sulfate, gloss white, gypsum, zinc phosphat
- an opacifying pigment particularly a white opacifying pigment
- the printing thereof against a darker background color are features which clearly distinguish the opaque pigment printing of this invention over conventional non-opaque pigment printing techniques.
- white pigments are used only on a white or light shade background fabric for achieving a "white-on-light" effect.
- Conventional pastel or white pigment printing pastes are not generally applied to darker background colors, since such printing pastes would not provide adequate uniform opacity against the darker background color.
- the amount of the opacifying pigmet used in the printing paste formulation of this invention is considerably greater than the amount of pigment used in conventional aqueous-based non-opaque printing pastes, and is typically considerably greater than the total solids content of the polymer binder.
- the printing paste comprises at least 20 weight percent opacifying pigment (solids basis) and at least 5 weight percent polymer binder (solids basis).
- the binder for the opacifying pigment must be capable of application in an aqueous system, form a stable dispersion with the insoluble opacifying pigments and other additives in the binder system, have good film-forming properties when applied to the fabric, and must be capable of being dried and cured to a water insoluble state imparting good washfastness and abrasion resistance properties to the printed pattern.
- the polymer binder may be suitably applied as an aqueous solution or dispersion.
- the print paste may be thereafter dried to a desired degree by suitable means, such as by heating, and cured via free radical curing as described more fully herein.
- the mechanism involved in free radical curing of the printing paste in accordance with the present invention is significantly different from that in conventional thermal curing.
- strong catalysts such as p-toluenesulfonic acid may be employed with cross-linking agents which cure when the printing paste is subjected to elevated temperatures.
- Free radical curing relies upon the presence of free radicals for the initiation of a free radical addition polymerization reaction.
- selected monomers, oligomers, polymers, or mixtures of these are included in the print paste which contain functional groups which are susceptible to free radical addition polymerization.
- Generation of the free radicals needed to initiate the polymerization reaction may be accomplished in a number of different ways. Certain compounds, such as styrene for example, will polymerize by free radical polymerization with application of heat alone. Other compounds require free radical initiators to provide the free radicals necessary for the free radical polymerization reaction to take place.
- the free radical initiators may be in the form of chemical compounds which will generate free radicals upon being subjected to certain influences, such as heating or radiation.
- Examples of chemical compounds which may be used as initiators to generate free radicals with heating include, but are not limited to, benzoyl peroxide, acetyl peroxide, azodiisobutyronitrile, t-butylhydroperoxide, cumene hydroperoxide, t-butylperoctoate, di-t-butyl peroxide, succinyl peroxide, dicermyl peroxide, dichlorobenzoylperoxide, azodicyclohexylcarbonitrile, and ethoxyethoxyethyl acrylate.
- Examples of monomers, oligomers and/or polymers that are capable of curing through free radical addition polymerization include, vinyl monomers, substituted ethylenes, conjugated dienes, non-conjugated dienes, polysiloxanes, N-vinyl-2-pyrrolidone, 2-methyl butadiene, vinylnaphthalene, glycol dimethacrylate, vinylacetate, acrylamide, methyl acrylate, methyl methacrylate, pentaerythritol acrylate, vinyltriethoxy silane, vinyl functional polydimethylsiloxane, curable urethane monomers, etc.
- EB curing As an alternative to the use of chemical free radical initiators, it is possible to initiate free radical polymerization by irradiation with actinic radiation.
- the most well known methods of radiation curing are electron beam (EB) curing and ultraviolet light (UV) curing.
- UV curing requires the inclusion of a photoinitiator for free radical generation.
- EB curing relies on the generation of free radicals via the transfer of kinetic energy from the accelerated electron to the polymer.
- monomers, oligomers and polymers which are suitable for high energy irradiation curing.
- acrylate and methacrylate monomers and oligomers such as acrylated epoxies, urethanes, polyesters and acrylics, multifunctional monomers, maleates, vinyl compounds such as vinylethyl ethers, linear polyesters, and maleates or itaconates of mono or polyhydric alcohol, and N-vinyl-2-pyrrolidone.
- the printing paste may optionally include colorants, such as colored pigments or dyes, for providing the desired color to the printing paste.
- the dyes which may be suitably employed for coloring the binder may comprise at least one member selected from the group consisting of acid dyes, cationic dyes, direct dyes, disperse dyes, fiber reactive dyes, mordant dyes, and solvent dyes.
- Azoic dyes, vat dyes, and sulfur dyes may also be used; however, the azoic compounds, vat dyes and unreduced sulfur dyes would in effect behave as pigments since in the unreduced form they are insoluble.
- Silicone fluids and elastomers may be incorporated into the printing paste to aid in obtaining a smooth application of the pigment to the fabric.
- the use of silicone polymers has been found to provide dots or designs free of rough edges and crack marks.
- Conventional thickeners may also be utilized to control the viscosity and rheology of the paste, depending upon the size and design of the print pattern and the running speed of the print screen.
- the paste may also contain other conventional additives, such as emulsifiers, antifoam agents, and pH control agents. It is important that the printing paste have good wetting and film-forming properties so that when applied to the fabric, it will penetrate and coat the individual yarns of the fabric rather than remaining on the surface of the fabric. If these properties are not adequately presented by the polymer binder itself, suitable wetting agents or emulsifiers may be included.
- the printing paste may be applied either to uncolored (e.g. white) fabrics or to precolored fabrics, the precolored fabrics being of a predetermined color throughout and produced by any suitable method such as by piece dyeing, yarn dyeing or by pigment padding, for example.
- the particular rate of application of the printing paste to the fabric will vary depending upon various factors, including fabric weight and construction, color of the fabric, and printing color.
- Drying and curing of the printing paste may be carried out under conditions of temperature and time suitable for the particular manner of application and curing mechanism employed.
- drying and curing may be carried out at temperatures of 250 to 425 degrees F. for from several seconds up to several minutes.
- the areas printed with the printing paste are characterized by having a thin flexible opaque coating covering the exposed surfaces of the yarn and thus hiding from view the underlying color of the yarn.
- the coating consists predominantly of the opacifying pigment bonded securely to the yarns by the cured water insoluble polymer binder.
- a fabric F is advanced from a suitable supply source, such as roll 10 through a rotary printing range, generally indicated at 12 consisting of a series of rotary printing cylinders.
- a rotary printing range generally indicated at 12 consisting of a series of rotary printing cylinders.
- Rotary textile printing ranges are well known in the art, and therefore a detailed description of its construction and operation is not warranted.
- the fabric After leaving the printing range 12, the fabric is advanced through a heating zone 14 for drying the printing paste.
- the heating zone 14 may suitably comprise a heated tenter frame as is conventional in the art.
- a radiation source 16 such as ultraviolet lamps or an electron curtain
- the electron curtain 16 may be located downstream from the drying zone 14.
- the present invention makes it possible to produce a variety of colors and patterns not heretofore possible.
- one additional aspect of the present invention is the production of a printed textile fabric formed of precolored yarns, and in particular dyed yarns of a predetermined color, selected areas of the fabric having printed pattern areas of predetermined color contrasting with the color of the yarns, the printed pattern areas being substantially opaque and thus unaffected by the color of the yarns, and the pattern areas being formed of a plurality of colors contrasting with one another and with said predetermined color of the yarns, at least one of the colors being lighter than said predetermined color dyed yarns, and said pattern areas comprising a filmlike coating covering the exposed surfaces of the yarns, said coating comprising an opacifying pigment providing opacity in said coating and a free radical cured binder securely bonding said opacifying pigment to the yarns.
- the print pastes are brought to a suitable viscosity with a conventional print paste thickener, depending on the type printing machine employed--rotary screen, flatbed, etc.
- the fabric is then printed and cured as normal at approximately 360° F. or thermosoled up to 425° F.
- the viscosity of the print paste is adjusted to that necessary for the particular printing machine used, rotary screen, flatbed, etc. using a conventional printing thickener.
- the fabric may either be dried in a conventional oven, then irradiated or simply irradiated immediately after printing, depending on the drying achievable during irradiation. Duration of irradiation depends on the type of irradiation equipment employed; U.V., electron beam, electron curtain, etc., and the intensity of the dose rate.
Abstract
Description
______________________________________ Percent ______________________________________ Example 1 Pioneer White BS Pigment 57 Blockout B (aluminum 13 silicate dispersion) Urethane Oligomer (Uvithane 782) 29 Benzoyl Peroxide 1 Example 2 Pioneer White BS Pigment 57 Blockout B (aluminum 13 silicate dispersion) Urethane Oligomer (Uvithane 783) 14 V-Pyrol 15 Benzoyl Peroxide 1 ______________________________________
______________________________________ Percent ______________________________________ Example 3 Pioneer White BS Pigment 57 Blockout B (aluminum 13 silicate dispersion) Pentaerythritol Acrylate 28 (Uvithane ZA-1192) Photoinitiator (diethoxy- 2 acetophenone) Example 4 Pioneer White BS Pigment 57 Blockout B (aluminum 13 silicate dispersion) Ethoxyethoxyethyl Acrylate 28 (Reactomer RC-20) Photoinitiator (diethoxy- 2 acetophenone) ______________________________________
Claims (16)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/587,397 US4507350A (en) | 1984-03-08 | 1984-03-08 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
EP84308038A EP0154744A3 (en) | 1984-03-08 | 1984-11-20 | Method of producing opaque pigmented textile fabrics with curing by free radical initiation and resulting printed fabrics |
CA000468194A CA1230204A (en) | 1984-03-08 | 1984-11-20 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
KR1019840007282A KR850006564A (en) | 1984-03-08 | 1984-11-21 | Method for producing opaque printed fabric cured by free radical initiation and printed fabric thereof |
ZA849077A ZA849077B (en) | 1984-03-08 | 1984-11-21 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
JP59260604A JPS60194190A (en) | 1984-03-08 | 1984-12-10 | Production of opaque printed fabric by curing through free radical initiated reaction |
AU36657/84A AU565975B2 (en) | 1984-03-08 | 1984-12-13 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/587,397 US4507350A (en) | 1984-03-08 | 1984-03-08 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
US4507350A true US4507350A (en) | 1985-03-26 |
Family
ID=24349629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/587,397 Expired - Lifetime US4507350A (en) | 1984-03-08 | 1984-03-08 | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics |
Country Status (7)
Country | Link |
---|---|
US (1) | US4507350A (en) |
EP (1) | EP0154744A3 (en) |
JP (1) | JPS60194190A (en) |
KR (1) | KR850006564A (en) |
AU (1) | AU565975B2 (en) |
CA (1) | CA1230204A (en) |
ZA (1) | ZA849077B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4689049A (en) * | 1985-07-23 | 1987-08-25 | Spectrachem Corporation | Pigment print paste with improved adhesion characteristics |
US5618546A (en) * | 1994-04-15 | 1997-04-08 | Wood; Monte D. | Composite of selectively removable layers of silk screen printing ink |
WO1998054399A1 (en) * | 1997-05-29 | 1998-12-03 | Ciba Specialty Chemicals Holding Inc. | Process for fixing pigment prints and pigment dyeings with ionising radiation or uv radiation |
US6436484B1 (en) | 1997-12-09 | 2002-08-20 | Coats American, Inc. | Processes for coating sewing thread |
US20160194731A1 (en) * | 2012-12-28 | 2016-07-07 | Posco | Grain-oriented electrical steel sheet, and method for manufacturing same |
Citations (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2310436A (en) * | 1939-12-23 | 1943-02-09 | Pittsburgh Plate Glass Co | Printing upon fabrics |
GB589782A (en) * | 1945-04-04 | 1947-06-30 | Henry Charles Olpin | Improvements in the fixation of pigments on textile materials |
DE1107636B (en) * | 1954-06-29 | 1961-05-31 | Rohm & Haas | Pigmented masses for the colored finishing of textiles |
GB926283A (en) * | 1958-07-03 | 1963-05-15 | Rohm & Haas | Copolymers and aqueous compositions thereof |
GB929451A (en) * | 1960-03-05 | 1963-06-26 | Hoechst Ag | Process for fixing pigments on fibrous materials and flat structures |
GB954588A (en) * | 1960-10-24 | 1964-04-08 | Geigy Ag J R | Improvements relating to low temperature pigment binder compositions and their use in coloring textile material |
DE1444060A1 (en) * | 1963-04-30 | 1968-12-12 | Bayer Ag | Stable aqueous polymer dispersions for printing and padding textile substrates |
US3441427A (en) * | 1966-02-07 | 1969-04-29 | Customark Corp | Method of producing opaque shadow mark |
US3443979A (en) * | 1968-01-22 | 1969-05-13 | Customark Corp | Method of rendering shadowmark opaque by solvent treatment |
FR1593299A (en) * | 1968-11-21 | 1970-05-25 | ||
US3948597A (en) * | 1974-09-23 | 1976-04-06 | Hayashi Chemical Industry Co., Ltd. | Duplex multicolor printed cloth and method for the production of the same |
GB1433609A (en) * | 1972-10-23 | 1976-04-28 | Cassella Farbwerke Mainkur Ag | Dyed and pigmented articles wherein the fixing agent is a polymer based on n-formyl-n-acryloyl methylenediamines |
US4031280A (en) * | 1976-08-09 | 1977-06-21 | Bigelow-Sanford, Inc. | Method and apparatus for coloring a pile fabric, and a pile fabric produced thereby |
GB1514504A (en) * | 1975-07-11 | 1978-06-14 | Milne F | Method of making a woven fabric for permanent press garments and fabrics and garments made thereby |
FR2402733A1 (en) * | 1977-09-13 | 1979-04-06 | Togonal Frederic | Printing motif on darker-coloured textile support - with emulsion contg. titania, butadiene! copolymer, viscosity regulator and other additives |
US4280888A (en) * | 1977-10-14 | 1981-07-28 | W. R. Grace & Co. | Screen printable, UV curable opaque legend ink composition |
US4283452A (en) * | 1979-09-06 | 1981-08-11 | Milliken Research Corporation | Polyester textile material having improved opacity |
US4315790A (en) * | 1979-03-07 | 1982-02-16 | Decor Innovations Limited | Decoration of flexible substrates |
US4351871A (en) * | 1974-02-15 | 1982-09-28 | Lewis Edward J | Decorating textile fabrics |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3097960A (en) * | 1956-05-28 | 1963-07-16 | Gen Electric | Process for improving the crocking and color-fastness of pigment-printed fibrous sheets by irradiation |
DE2808931A1 (en) * | 1977-03-04 | 1978-09-07 | Dynachem Corp | PROCESS FOR COATING OR PRINTING A SUBSTRATE |
ZA82715B (en) * | 1981-08-20 | 1983-09-28 | Springs Ind Inc | Textile fabrics with opaque pigment printing and method for producing same |
US4438169A (en) * | 1982-09-30 | 1984-03-20 | Springs Industries, Inc. | Colored opaque printing of textile fabrics using dyestuffs |
-
1984
- 1984-03-08 US US06/587,397 patent/US4507350A/en not_active Expired - Lifetime
- 1984-11-20 CA CA000468194A patent/CA1230204A/en not_active Expired
- 1984-11-20 EP EP84308038A patent/EP0154744A3/en not_active Withdrawn
- 1984-11-21 ZA ZA849077A patent/ZA849077B/en unknown
- 1984-11-21 KR KR1019840007282A patent/KR850006564A/en not_active Application Discontinuation
- 1984-12-10 JP JP59260604A patent/JPS60194190A/en active Pending
- 1984-12-13 AU AU36657/84A patent/AU565975B2/en not_active Ceased
Patent Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2310436A (en) * | 1939-12-23 | 1943-02-09 | Pittsburgh Plate Glass Co | Printing upon fabrics |
GB589782A (en) * | 1945-04-04 | 1947-06-30 | Henry Charles Olpin | Improvements in the fixation of pigments on textile materials |
DE1107636B (en) * | 1954-06-29 | 1961-05-31 | Rohm & Haas | Pigmented masses for the colored finishing of textiles |
GB926283A (en) * | 1958-07-03 | 1963-05-15 | Rohm & Haas | Copolymers and aqueous compositions thereof |
GB929451A (en) * | 1960-03-05 | 1963-06-26 | Hoechst Ag | Process for fixing pigments on fibrous materials and flat structures |
GB954588A (en) * | 1960-10-24 | 1964-04-08 | Geigy Ag J R | Improvements relating to low temperature pigment binder compositions and their use in coloring textile material |
GB954589A (en) * | 1960-10-24 | 1964-04-08 | Geigy Ag J R | Improvements relating to low temperature pigment binder compositions and their use in colouring textile material |
GB954587A (en) * | 1960-10-24 | 1964-04-08 | Geigy Ag J R | Improvements relating to low temperature pigment binder compositions and their use in coloring textile material |
DE1444060A1 (en) * | 1963-04-30 | 1968-12-12 | Bayer Ag | Stable aqueous polymer dispersions for printing and padding textile substrates |
US3441427A (en) * | 1966-02-07 | 1969-04-29 | Customark Corp | Method of producing opaque shadow mark |
US3443979A (en) * | 1968-01-22 | 1969-05-13 | Customark Corp | Method of rendering shadowmark opaque by solvent treatment |
FR1593299A (en) * | 1968-11-21 | 1970-05-25 | ||
GB1433609A (en) * | 1972-10-23 | 1976-04-28 | Cassella Farbwerke Mainkur Ag | Dyed and pigmented articles wherein the fixing agent is a polymer based on n-formyl-n-acryloyl methylenediamines |
US4351871A (en) * | 1974-02-15 | 1982-09-28 | Lewis Edward J | Decorating textile fabrics |
US3948597A (en) * | 1974-09-23 | 1976-04-06 | Hayashi Chemical Industry Co., Ltd. | Duplex multicolor printed cloth and method for the production of the same |
GB1514504A (en) * | 1975-07-11 | 1978-06-14 | Milne F | Method of making a woven fabric for permanent press garments and fabrics and garments made thereby |
US4031280A (en) * | 1976-08-09 | 1977-06-21 | Bigelow-Sanford, Inc. | Method and apparatus for coloring a pile fabric, and a pile fabric produced thereby |
FR2402733A1 (en) * | 1977-09-13 | 1979-04-06 | Togonal Frederic | Printing motif on darker-coloured textile support - with emulsion contg. titania, butadiene! copolymer, viscosity regulator and other additives |
US4280888A (en) * | 1977-10-14 | 1981-07-28 | W. R. Grace & Co. | Screen printable, UV curable opaque legend ink composition |
US4315790A (en) * | 1979-03-07 | 1982-02-16 | Decor Innovations Limited | Decoration of flexible substrates |
US4283452A (en) * | 1979-09-06 | 1981-08-11 | Milliken Research Corporation | Polyester textile material having improved opacity |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4689049A (en) * | 1985-07-23 | 1987-08-25 | Spectrachem Corporation | Pigment print paste with improved adhesion characteristics |
US5618546A (en) * | 1994-04-15 | 1997-04-08 | Wood; Monte D. | Composite of selectively removable layers of silk screen printing ink |
WO1998054399A1 (en) * | 1997-05-29 | 1998-12-03 | Ciba Specialty Chemicals Holding Inc. | Process for fixing pigment prints and pigment dyeings with ionising radiation or uv radiation |
US6436484B1 (en) | 1997-12-09 | 2002-08-20 | Coats American, Inc. | Processes for coating sewing thread |
US20020168481A1 (en) * | 1997-12-09 | 2002-11-14 | Coats North America | Coated sewing thread |
US6828023B2 (en) | 1997-12-09 | 2004-12-07 | Coats American, Inc. | Coated sewing thread |
US20160194731A1 (en) * | 2012-12-28 | 2016-07-07 | Posco | Grain-oriented electrical steel sheet, and method for manufacturing same |
US10023932B2 (en) * | 2012-12-28 | 2018-07-17 | Posco | Grain-oriented electrical steel sheet, and method for manufacturing the same |
Also Published As
Publication number | Publication date |
---|---|
AU565975B2 (en) | 1987-10-01 |
EP0154744A2 (en) | 1985-09-18 |
JPS60194190A (en) | 1985-10-02 |
AU3665784A (en) | 1985-09-12 |
ZA849077B (en) | 1985-07-31 |
KR850006564A (en) | 1985-10-14 |
EP0154744A3 (en) | 1987-02-04 |
CA1230204A (en) | 1987-12-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4457980A (en) | Textile fabrics with opaque pigment printing and method of producing same | |
DE60209490T2 (en) | MANUFACTURING METHOD OF INK RADIATION RECORDING MEDIA | |
US4406662A (en) | Heat transfer printing on a filled polymethyl methacrylate article | |
US4562107A (en) | Textile fabrics with opaque pigment printing and method of producing same | |
US4438169A (en) | Colored opaque printing of textile fabrics using dyestuffs | |
DE60035558D1 (en) | Printing process and prints produced thereby, and articles produced by this process | |
US4297099A (en) | Process for the production of a synthetic resin sheet material which is dyed unicolored or multicolored in accordance with a pattern | |
US4507350A (en) | Method of producing opaque printed textile fabrics with curing by free radical initiation and resulting printed fabrics | |
CN107503197A (en) | A kind of chalk pretreatment fluid and preparation method thereof, direct-injection digital printing process | |
AU657339B2 (en) | Method of printing on natural fiber fabrics | |
US4231742A (en) | Manufacture and use of heat transfer printings | |
DE60324824D1 (en) | METHOD FOR COLORING OR PRINTING TEXTILE FIBER MATERIALS WITH SHINY PIGMENTS | |
CZ20031720A3 (en) | Substrate surface treatment process | |
GB1595580A (en) | Transfer printing of fabrics | |
JPS56127492A (en) | Manufacture of heat-sensitive transfer recording material | |
PT98282A (en) | PROCESS FOR THE MANUFACTURE OF CORTICAL PLATES (OR SHEETS) WITH HIGH PHOTOCHEMICAL RESISTANCE | |
DE2847762A1 (en) | METHOD OF PRINTING OR COLORING UREA OR MELAMINE FORMALDEHYDE RESINS | |
ATE125009T1 (en) | METHOD FOR PRINTING CELLULOSE-CONTAINING TEXTILE WITH REACTIVE DYES. | |
EP0585394B1 (en) | Flocked fabric printing | |
US5218019A (en) | Sublimation disperson dye receptive resin compositions | |
JPH083899A (en) | Transparent colored paper | |
EP0028154A1 (en) | Process of dyeing textile products | |
RU1793017C (en) | Method of production speckled effect on textile material of chemical fibers | |
MX9606040A (en) | Process for the preparation of color contrasts in articles obtained by molding from polymerizable compositions. | |
US4112136A (en) | Method of making a pattern-dyed, pattern-textures, or lace like textile or foil |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SPRINGS INDUSTRIES, INC., FORT MILL, SC A CORP OF Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:HENDRIX, JAMES E.;DANIELS, JOHN Y.;REEL/FRAME:004238/0587 Effective date: 19840305 Owner name: SPRINGS INDUSTRIES, INC., SOUTH CAROLINA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HENDRIX, JAMES E.;DANIELS, JOHN Y.;REEL/FRAME:004238/0587 Effective date: 19840305 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |
|
AS | Assignment |
Owner name: THE CHASE MANHATTAN BANK, AS COLLATERAL AGENT, NEW Free format text: SECURITY INTEREST;ASSIGNOR:SPRINGS INDUSTRIES, INC.;REEL/FRAME:012177/0667 Effective date: 20010905 |