US446351A - Aluminum alloy - Google Patents

Aluminum alloy Download PDF

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US446351A
US446351A US446351DA US446351A US 446351 A US446351 A US 446351A US 446351D A US446351D A US 446351DA US 446351 A US446351 A US 446351A
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aluminum
manganese
aluminum alloy
alloy
copper
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/01Alloys based on copper with aluminium as the next major constituent

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  • My invention relates to aluminum alloys, and is more particularly useful with reference to so-called aluminum bronzes, in which a small proportion of aluminum is'alloyed with copper to impart something of its desirable qualities, particularly untarnishability.
  • Most alloys of this character require repeated fusions to render them homogeneous, and, moreover, they are usually (unless the proportion of aluminum is very small) hard and brittle and lacking in both strength and malleability, owing to the crystalline combination formed by the metals.
  • My invention has for its object to improve the quality of thesealloys and is based upon the discovery that the addition of a small proportion of manganese improves the texture and qualities of the alloy.
  • the addition of manganese alone imparts malleability and a suseeptibility, t .o an exceedingly brilliant surface luster, besides enhancing the untarnishability.
  • the resulting regulus consists of aggregations or nodules of varying proportions of the metals, which are then-lixiviated in boiling water to remove the soluble salts, and, finally, remelted to obtain a regulus of uniform composition, which is then remelted with the required proportion of copper.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Investigating And Analyzing Materials By Characteristic Methods (AREA)

Description

- UNITED STATES PATENT OFFICE.
JOHN A. JEANQON, OF NEIVPORT, KENTUCKY.
ALUMINUM ALLOY.
SPECIFICATION forming part of Letters Patent No. 446,351, dated February 10,1891.
Application filed March 20, 1890. Serial No. 344,675. (Specimens) To all whom it may concern.-
Be it known that I, J OHN A. J EANooN, a citizen of the United States, residing at Newport, in the county of Campbell and State of Kentucky, have invented new and useful Improvements in Aluminum Alloys, of which the following is a specification.
My invention relates to aluminum alloys, and is more particularly useful with reference to so-called aluminum bronzes, in which a small proportion of aluminum is'alloyed with copper to impart something of its desirable qualities, particularly untarnishability. Most alloys of this character, however, require repeated fusions to render them homogeneous, and, moreover, they are usually (unless the proportion of aluminum is very small) hard and brittle and lacking in both strength and malleability, owing to the crystalline combination formed by the metals.
My invention has for its object to improve the quality of thesealloys and is based upon the discovery that the addition of a small proportion of manganese improves the texture and qualities of the alloy. The addition of manganese alone imparts malleability and a suseeptibility, t .o an exceedingly brilliant surface luster, besides enhancing the untarnishability.
The improvement is especially valuable, in that a practically new class of bronzes is obtained having a much wider range of useful application than heretofore.
A larger percentage of aluminum can be utilized than has been found practicable here-,
tofore, thereby enhancing the untarnishability of the alloy, besides attaining a marked improvement in texture, luster, and color.
By way of example and illustration I haveappended in tabulated form a list of constituents and proportions of two bronzes produced according to my invention, samples of the same being placed on file as exhibit specimens correspondingly numbered:
Constituents. &2??? gg g Aluminum, partsv 20 15 Manganese, parts 3 3 Copper, parts U 77 62 These specimens are sufiiciently ductile to be rolled, hammered, drawn, or out, and are suitable for all manufactures involvingthese processes. Both possess the brilliant color, luster, and texture of gold alloys with a surface sheen peculiar to themselves.
In carrying out my invention I first produce an alloy of aluminum with manganese. This alloy in determined proportions is afterward used as a basic metal and fused with the copper in the desired proportions of the two. The basic metal can of course be. prepared directly by fusion of the constituent metals themselves with fluxes of the alkaline chlorides,potassium, sodium, and calciumaccording to known practice.
In commercial practice, however, I employ a cheaper method, as follows: To produce the basic metal of the manganese-aluminum bronze, I place in a graphite crucible, say, fifteen pounds anhydrous potassium and calcium chloride, heat slightly, and stir in a quantity of commi-nuted carbon. To this I add fifteen pounds aluminum in small fragments and heat to cherry hardness, fusing the chlorides and softening the aluminum, and, lastly, add and stir in about fifteen pounds anhydrous mangenese chloride, cover the crucible tightly, and heat to whiteness. The resulting regulus consists of aggregations or nodules of varying proportions of the metals, which are then-lixiviated in boiling water to remove the soluble salts, and, finally, remelted to obtain a regulus of uniform composition, which is then remelted with the required proportion of copper. I employ a fairly pure commercial aluminum and make ent-y-five to eighty-five per cent. of copper,
no account of the slight impurities contained twelve to twenty-five per cent. of aluminum,
therein. There is, of course, some loss in the and two to five per cent. manganese, substan- 15 process, for which experience will suggest tially as set forth.
5 the proper allowance, but which I roughly In Witness whereof I have hereunto set my estimate at about one per cent. for aluminum hand in the presence of two subscribing witand eight to ten per cent. for manganese nesses.
chloride. 7
Iclaim as my invention and desire to secure JOHN JEANQON' 10 by Letters Patent of the United States- WVitnesses:
A bronze or alloy of copper, aluminum, and L. M. HOSEA,
manganese in about the proportions of sev- ELLA I-IosEA.
US446351D Aluminum alloy Expired - Lifetime US446351A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038068A (en) * 1976-02-19 1977-07-26 Olin Corporation Method of melting copper alloys with a flux

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4038068A (en) * 1976-02-19 1977-07-26 Olin Corporation Method of melting copper alloys with a flux

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