US3912846A - Apparatus for manufacturing steel plates coated with aluminium powder - Google Patents

Apparatus for manufacturing steel plates coated with aluminium powder Download PDF

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US3912846A
US3912846A US376111A US37611173A US3912846A US 3912846 A US3912846 A US 3912846A US 376111 A US376111 A US 376111A US 37611173 A US37611173 A US 37611173A US 3912846 A US3912846 A US 3912846A
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heating
furnace
housing means
coated
steel plate
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US376111A
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Hidehisa Yamagishi
Takashi Kamata
Yoshio Ujiki
Fumitoshi Yokoi
Tadao Takahashi
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JFE Engineering Corp
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Nippon Kokan Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/082Coating starting from inorganic powder by application of heat or pressure and heat without intermediate formation of a liquid in the layer
    • C23C24/085Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
    • C23C24/087Coating with metal alloys or metal elements only
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B11/00Heating by combined application of processes covered by two or more of groups H05B3/00 - H05B7/00
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B6/00Heating by electric, magnetic or electromagnetic fields
    • H05B6/02Induction heating
    • H05B6/36Coil arrangements

Definitions

  • the present invention relates to apparatus for manufacturing steel plates coated with aluminum powder.
  • a steel plate to be coated with aluminum powder is heated in a medium having very low thermal conductivity as an oxidizing atmosphere, a non-oxidizing atmosphere or a reducing atmosphere.
  • U.S. Pat. No. 3,382,085 discloses a method of coating 0.10 inches thick and 6 inches wide coil with aluminum by heating it in a semi-muffle furnace at 500C for 1 hour.
  • French Pat. No. 66,915 discloses a method of coating steel plates with a mixture of zinc and aluminum powders by heating in a 100 percent hydrogen atmosphere either at 3 l6454C for 6 hours or at 3l6-357C for 24-48 hours.
  • a steel plate may be coated with aluminum, subjected to mechanical working with a reduction of 35-70 percent and heated at an arbitrary temperature within the range 400700C for an arbitrary period within the range of 1 second to 1 hour so as to prevent forming of an alloy layer or to limit such an alloy layer, if formed, to be less than 3 ,u. thick by heat treatment.
  • Japanese Patent Publication No. Japanese Patent Publication No.
  • a steel plate may be coated with aluminum, by heating in a non-oxidizing atmosphere or reducing atmosphere at a temperature less than that of melting point of aluminum for a short period of time to perform a preliminary sintering, then at a pressure with a reduction rate of less than 10 percent to compact the aluminum layer and heating as well as sintering at 350500C.
  • steel plates coated with such metal powders as aluminum powder are subjected to a pretreatment such'as degreasing with alkali, washing in water, pickling, etc.', then coated with a slurry consisting of metal powders and water, and then dried, rolled and heated.
  • a pretreatment such'as degreasing with alkali, washing in water, pickling, etc.'
  • a slurry consisting of metal powders and water and then dried, rolled and heated.
  • metal powders mixed with water or solvent and binder in a form of a slurry are painted or electrostatically coated on steel plates.
  • the coated steel plates are subjected to a heat treatment for drying and sintering the coated layer prior to rolling, and the steel plates coated with metal powder are continuously rolled after the L heat treatment.
  • the present invention aims to substantially eliminate the defects of the prior art.
  • An object of the present invention is to provide apparatus for continuously manufacturing aluminum-coated steel plates having excellent adherence, wherein steel plates to which aluminum powder is applied are rolled to comminute the aluminum powders sufficiently and to achieve a nearly theoretical aluminum density (the same density as that of pure aluminum sheet), thus forming a continuous aluminum layer thereon. The plates are then subjected to a rapid heat treatment.
  • Another object of the present invention is to eliminate defects of the prior art processes of drying, rolling and heat treatment and to provide a rapid and continuous method of manufacturing aluminum-coated steel plates.
  • Still another object of the present invention is to eliminate defects of the prior art heating furnace used for manufacturing steel plates coated with metal powder.
  • Still another object of the present invention is to eliminate defects of the conventional rolls and to provide novel hollow compacting rolls wherein cooling water is circulated to cool the same and the ball bearings thereof are provided with rotary joints which facilitates the supply and drainage of water to and from the bearings while the rolls are rotating.
  • FIG. 1 schematically shows the whole process for manufacturing steel plates coated with aluminum powder
  • FIG. 2 is a diagram showing conditions for heat treatment
  • FIG. 3 is a diagram showing the temperature rises in various heating furnaces
  • FIG. 4 shows a longitudinal section of a high frequency induction heating furnace
  • FIG. 5 is a cross-sectional view of the furnace shown in FIG. 4 taken along the line VV;
  • FIG. 6 shows a longitudinal section of a part of hollow rollers.
  • FIG. 7 shows a longitudinal section of a heating furnace employing high frequency induction heating and radiation heating
  • FIG. 8 is a cross-sectional view of the furnace shown in FIG. 7 taken along the line VIIIVIII;
  • FIG. 9 is a cross-sectional view of the furnace shown in FIG. 7 taken along the line IX-IX.
  • steel strip (A) is transferred to a pretreatment tank 9 through a pay-off reel 1, a feeder leveller 2, a pinch roll and shearing device 3, a welder 4, the first bridle 5, an entry side looper 6, the second bridle 7 and a tension unit 8.
  • the strip is subjected to degreasing with alkali, washing in water, pickling, washing in water and water scrubbing. Degreasing and pickling may be conducted by either the dipping method or the electrolytic method dependent on the conditions of the surface of the steel strip.
  • After the pre-treatment hot air is blown onto the strip from a drier 10 to rapidly dry the surfaces thereof in order to prevent rusting and to facilitate painting of a slurry of aluminum powder and water in the subsequent process.
  • the dried strip (A) is fed to a slurry coater 12 through the third bridle 11 to be coated with a slurry consisting of aluminum powder and water.
  • the reverse type slurry coated is provided with devices for mixing aluminum powder and water and for circulating slurry to supply prepared slurry to the coater.
  • As the slurry may be left as prepared for a long time before coating, there is a possibility that aluminum powder will react with water thereby making use of the slurry impossible.
  • slurry stabilizing agents as phytinic acid, aluminum chloride, aluminum sulfate and malonic acid are added to the slurry.
  • rust When steel strip is fed at a slow speed, rust may generate on the strip during the process time between coating of the strip with slurry and drying. Such rust is effectively prevented by addition of a corrosion inhibitor such as sodium nitrite and sodium benzoate.
  • the strip (A), coated with slurry, is fed to a rapid heating drying furnace 13 from which the evaporating water is rapidly exhausted, in order to complete drying in as short a time as possible; the degree of drying must be uniform at the upper and lower surfaces of the strip without looping of the strips in the furnace; and exfoliation of dried aluminum powder caused by a supporting member for said looping must be prevented.
  • a high frequency induction heating furnace provided with a device for exhausting vapour meets the foregoing requirements. The structure of the heating furnace 13 will be described later in the specification.
  • the steel strip delivered from the drying furnace 13 is then fed to a rolling mill 14 where aluminum powder is completed and adhered to the surface of the steel strip.
  • a considerable amount of the aluminum powder sticks to the rolls of the mill 14 not only spoiling the surface of the steel strip but also damaging the uniformity of the coated metal.
  • hollow rolls the surfaces of which are cooled from inside thereof are used.
  • a roll cleaning apparatus is provided at the delivery side of the rolls to clean the surface of the rolls and remove aluminum powder stuck thereto.
  • the steel strip delivered from the rolling mill 14 is then fed to the heat treatment furnace 15, 16 wherein the strip is rapidly and continuously subjected to a heat treatment to impart to the aluminum layer resistance to bending, drawing, etc.
  • Time and temperature for heat treatment depend on the thickness of the strip and the aluminum layer thereon. It is necessary to provide for rapidly changing temperature for heat treatment corresponding to changes in the production schedule.
  • a continuous high frequency induction heating furnace 15 and radiation tube type furnace 16 are employed as heating furnaces, but the invention is not limited thereto.
  • the high frequency induction heating furnace 15 when the strip is thin and is rapidly coated with slurry, only the high frequency induction heating furnace 15 (FIGS.
  • the steel strip delivered from the heat treatment furnaces l5, 16 is fed to a water quenching tank 17 which is provided with a water circulation device having a spray nozzle to maintain the temperature of water at the entry side of the tank 17 at a constant value and with a wringer roll at the delivery side of the tank.
  • the temperature of water for cooling the strip is adjustable in accordance with the requirements of the drying process.
  • the strip is further fed to a post treatment tank 19, to impart to the strip a corrosion resistant property, via a drier 18.
  • the drier 18 is used dependent upon the kind of chemical treatments to which the strip is subjected in said tank 19.
  • the method of post treatment may be selected from among chromate treatment, chromate treatment with soluble organic high molecular compound, etc., by immersing or spraying.
  • the strip delivered from the post treatment tank 19 passes through a hot air blowing type drier 20, the fourth bridle 21, a delivery side looper 22, the fifth bridle 23 and a delivery side shear 24, and is fed to a tension reel 25 where the strip is coiled as a final product.
  • the method of the present invention shortens drying and heat treatment processes, thus bringing about rapid and continuous manufacturing of aluminum-coated steel plates.
  • Rapid heat treatment will be described in further detail hereinafter.
  • FIG. 2 shows the relation between temperature of a steel plate and treatment time.
  • the upper line in FIG. 2 represents the upper limit of heat treatment temperature for not forming an alloy layer of Fe and Al in the interface of the aluminum layer and the steel plate. If the hard and brittle alloy layer of Fe and A1 is formed, cracks are easily caused in the coated layer on a steel plate while it is being formed. Moreover, aluminumcoated steel plate, treated under such conditions as to form an Fe Al alloy layer, does not have the lustre peculiar to aluminum and becomes yellowish in color. Consequently, heat treatment at a temperature above the aforementioned upper limit is undesirable.
  • the lower line shown in FIG. 2 represents the lower limit of heat treatment temperature below which adherence between the aluminum layer and the steel plate is not sufficient and exfoliation of the aluminum layer or minute cracks therein are caused during working of the aluminum-coated steel plate.
  • the intermediate part between the upper and lower lines shown in FIG. 2 is the optimum range for the heat treatment.
  • Aluminum-coated steel plates having excellent properties, in which no cracks are caused in the aluminum layer, are obtained by heat treatment under the conditions within the above range.
  • the range (B) indicated by oblique lines in FIG. 2 is obtained.
  • the present invention is characterized by rapid heat treatment under the conditions within the range (B).
  • suitable heating methods are: (a) heating aluminum-coated steel plates with a metal having both good heat conductivity and not reacting with aluminum; (b) heating by means of induction heating as described in reference to FIG. 1; or (c) rapidly heating the steel plate up to a predetermined temperature by induction heating and maintaining the same at the temperature in a furnace containing gas therein. Rapid heat conduction is effected by a metal bath, such as a lead bath or an induction heating furnace, and steel plates are heated up to a predetermined temperature in a short time.
  • FIG. 3 shows the manner in which the temperature rises in some heating furnaces.
  • (a) shows a case of heating with a lead bath
  • (b) heating in an induction heating furnace (c) in a combination of an induction heating furnace and a siliconit furnace and (d) in a siliconit furnace.
  • EMBODIMENT 2 A slurry consisting of atomized aluminum powder comprising particles having an average particle size of 15 1.1. and an aqueous solution of NaNO having a concentration of IO moIe/l, mixed in the ratio of 6:4, was coated on a steel plate by means of a reverse roll coater. The coating rate was 80 g/m Then the steel plate was dried and rolled in a rolling mill so as to reduce the steel plate by 5 percent. The aluminumcoated steel plate thus obtained was subjected to oil quenching after heat treatment for 3 seconds in a lead bath which was maintained at 600C. The steel plate thus obtained had the metallic luster peculiar to aluminum and no cracks were caused in the coated layer in bending tests to an angle of 180. In a salt spraying test (Japanese Industrial Standard Z -2371), red rusts did not appear at all, even after being subjected to a test for 200 hours. Thus, it is shown that the steel plate has an excellent corrosion resistant property.
  • EMBODIMENT 3 A rolled aluminum-coated steel plate obtained in the same way as Embodiment 2 was subjected to heat treatment for 5 seconds in a lead bath maintained at 550C, and then to water quenching. Aluminum-coated steel plate having the same properties as Embodiment 2 was obtained.
  • EMBODIMENT 4 A slurry comprising the same compositions as that of Embodiment 2 was continuously coated on a coldrolled coil having a thickness of 0.8 mm and a width of 100 mm by a reverse system roll coated at a rate of dried weight of g/m and the coated coil was dried and rolled to 5 percent reduction rate. The coil was then heated for 2 seconds at a heating rate of 225C/sec with an input power of 7 KW in an induction heating furnace having frequency of 10 KC, maintained at 550C for 3 seconds with 0.5 KW and subjected to water quenching.
  • Aluminum-coated steel plate thus obtained had the same excellent properties as Embodiment 2, having beautiful luster, excellent workability and resistance to corrosion.
  • EMBODIMENT 5 The rolled aluminum-coated steel plate obtained in the same way as Embodiment 4 was heated for 2 seconds in such a way that the temperature at the surface of the steel plate became 500C with an input power of 7 KW in an induction heating furnace having a frequency of 10 KC and then heated for 3 seconds at 500C in a furnace in the atmosphere.
  • the steel plate thus obtained has luster on the surface thereof and no defects were seen in the coated layer in a deep drawing test. Though white rust was caused in a humidity cabinet test at 50C and with percent of moisture, red rust did not generate after a test for 3000 hours.
  • the present invention is characterized by the abovementioned rapid heat treatment. Embodiments of heating furnaces will be described hereinafter, reference being made to FIGS. 4-9 of the accompanying drawing.
  • 40 denotes a steel plate coated on both surfaces with a slurry consisting of aluminum powder and water, which is fed to a heating furnace 41 as shown in FIGS. 4 and 7.
  • the ,heating furnace is equipped with a hot air blowing device 42 at the entry side thereof, where the hot air heated up to 80l00C is applied to the steel plate entering the heating furnace 41 to accelerate drying.
  • 43a, 43b and 430 denote coils for high frequency induction heating. Inductance at the respective coils 43a, 43b and 430 is continuously adjusted to facilitate continuously varying the curve of temperatures at the respective coils independently of each other by means of respective control systems which are respectively independent of each other.
  • input power to the respective coils for heating is made adjustable at loading. As shown in FIG.
  • the coils 43 comprise an outer protective insulating wall 44 for mechanical portection of the coil and prevention of dust and danger, and an inner protective insulating wall 45 which is exchangeable for mechanical protection of the coils 43 when the strip 40 is damaged and to prevent slurry which is not dried yet from dropping directly on the inside of the coils 43 and adhering thereto.
  • Connecting devices for exhaust 46a, 46b and 46c are provided at the delivery side of the heating furnace 41 and between the respective coils 43a, 43b and 43c. These exhaust devices 46 which may be connected to exhaust blowers accelerate drying by exhausting vapours and gases which are generated upon heating from the top and bottom ends of the devices 46.
  • Windows 47a,-47b and 470 (FIGS.
  • FIGS. 7 and 9 show radiation tubes 48 in the furnace to additionally provide radiation heating as hereinbefore described.
  • the high frequency induction heating furnace of the present invention comprises a plurality of high frequency induction heating coils which facilitate independent control of the temperature curve by means of the control systems which are independent of each other, the hot air blowing device at the entry side of the heating furnace, and the connecting devices for exhaust between respective coils and at the delivery side of the furnace. Further, radiation heating is supplied. Thus, a great deal of vapour and gas generated when slurry containing alminum powder coated on the steel strip is dried is exhausted through the exhaust device to promote drying and effective heating.
  • heating speed and temperature are adjusted to provide the optimum conditions for each coil depending upon the thickness of the strip which is being treated, the number of heating coils which can be controlled independently of each other, the kind of coated metals and the thickness of coated layer.
  • 51 denotes a lower work roll and 52 denotes an upper work roll.
  • a steel strip coated with aluminum powder and subjected to heat treatment is rolled between said upper and lower rolls 51, 52.
  • 53 denotes ball bearings to support said rolls 51, 52.
  • the rolls 51, 52 are provided with a hollow portion 54 extending in the axial direction and one end of which is closed, in which a water supply tube 55 supported by a receiving member 56 at the closed end of the hollow portion 54 is provided in the centerthereof.
  • a plurality of water supply apertures 57 are provided in the water supply tube 55. Cooling water is supplied to the inside of the hollow portion 54 through the apertures 57 of the water supply tube 55 to cool the rolls 51, 52.
  • 58 denotes a rotary joint connected to the open end of the hollow portion 54 in the rolls 51, 52, comprising double rotary sleeves 60, 61 installed in the fixed casing 59, ball bearings 62, 63 to support said two rotary sleeves 60, 61, and flexible hoses 64, 65 to supply said sleeves with cooling water.
  • the end of the rolls 51, 52 is fixed to the outer rotary sleeve in a liquid-tight manner, and the gap between the outer rotary sleeve 60 and the inner rotary sleeve 61 is connected to the hollow portion 54 and the flexible hose for drainage of cooling water supplied in the hollow portion 54.
  • the water supply tube 55 is connected to the inner rotary sleeve 61 at one end thereof and the other end of the inner rotary sleeve 61 is opened to a cover 66 which is fixed to the fixed casing 59 and in which the flexible hose 64 for supplying water is connected.
  • Cooling water supplied through the flexible hose 64 is fed to the water supply tube 55 through the inner rotary sleeve 61 and to the hollow portion 54 from the water supply apertures 57. Water fed to the hollow portion 54 and cooling the rolls 51, 52 is drained from the flexible hose 65 through the gap 67 in the outer rotary sleeve 60.
  • the rolls are cooled from the inside thereof. Therefore, coated aluminum powder is not washed away by cooling water or lubricant oil as often happened in the prior art, nor does it adhere to the rolls and damage the uniform surface of the rolled steel strip.
  • a heating furnace for use in the manufacture of steel plates coated with aluminum powder comprising:
  • a high frequency induction heating means in said housing means for heating said steel plate, said heated steel plate conducting heat gradually to the outer portion of said coating;
  • a radiation type heating means in said housing means for heating said coating, the heated coating conducting heat gradually toward the inside thereof;
  • a hot air blowing device at the entry side of said housing means for supplying fresh air to said furnace
  • exhaust means coupled to said housing means for removing wetted hot air from said furnace.
  • said high frequency induction heating means comprises a plurality of high frequency induction heaters spaced from each other and distributed along said housing means in the'direction of movement of said steel plate.
  • a heating furnace according to claim 4 wherein said radiation type heating means comprises a plurality of radiation heaters spaced from each other and distributed along said housing means in the direction of movement of said steel plate.
  • said plurality of high frequency induction heating means for controlling the heating temperature thereof so as to control the temperature gradient in said furnace;
  • a hot air blowing device at the entry side of said housing means for supplying fresh air to said furnace
  • exhaust means coupled to said housing means for removing wetted hot air from said furnace.

Abstract

Apparatus for rapidly and continuously manufacturing steel plates coated with aluminum powder wherein the plates are cleaned and coated with a slurry of aluminum powder in water, dried, rolled between special internally water-cooled rolls to achieve substantially theoretical density of the coated aluminum and then heat treated at between 450*C and 700*C for 1-5 seconds in a furnace high frequency induction furnace or a radiation tube type furnace or combination of both.

Description

United States Patent Yamagishi et a1.
APPARATUS FOR MANUFACTURING STEEL PLATES COATED WITH ALUMINIUM POWDER Inventors: Hidehisa Yamagishi; Takashi Kamata; Yoshio Ujiki; Fumitoshi Yokoi; Tadao Takahashi, all of Kawasaki, Japan Assignee: Nippon Kokan Kabushiki Kaisha,
Tokyo, Japan Filed: July 3, 1973 Appl. No.: 376,111
Related US. Application Data Division of Ser. No. 170,063, Aug. 9, 1971, Pat. No. 3,769,068.
US. Cl. 13/5; 13/22; 13/26 Int. Cl. HOSB 11/00 Field of Search 13/26, 27, 34, 22, 2, 5;
HOT AIR BLOWER Oct. 14, 1975 [56] References Cited UNITED STATES PATENTS 2,130,756 9/1938 Malam 13/2 2,325,638 8/1943 Strickland... 13/26 X 2,441,500 5/1948 Miess 13/2 X 6/1971 Seelandt 13/34 X Primary ExaminerR. N. Envall, Jr. Attorney, Agent, or Firm-Flynn & Frishauf ABSIRACT Apparatus for rapidly and continuously manufacturing steel plates coated with aluminum powder wherein the plates are cleaned and coated with a slurry of aluminum powder in water, dried, rolled between special internally water-cooled rolls to achieve substantially theoreticaldensity of the coated aluminum and then heat treated at between 450C and 700C for l-5 seconds in a furnace high frequency induction furnace or a radiation tube type furnace or combination of both.
8 Claims, 9 Drawing Figures O ct. 14,1975 Sheet 0f4 3,912,846
U.S. Patent Oct. 14,1975 Sheet2 of4 3,912,846
FIG. 2
6 8 1012145 Time, seconds FIG. 3
lllllllllll Time, seconds APPARATUS FOR MANUFACTURING STEEL PLATES COATED WITH ALUIVIINIUM POWDER This is a division of application Ser. No. 170,063, filed Aug. 9, 1971, now U.S. Pat. No. 3,769,068.
The present invention relates to apparatus for manufacturing steel plates coated with aluminum powder.
According to the prior art, a steel plate to be coated with aluminum powder is heated in a medium having very low thermal conductivity as an oxidizing atmosphere, a non-oxidizing atmosphere or a reducing atmosphere.
For example, U.S. Pat. No. 3,382,085 discloses a method of coating 0.10 inches thick and 6 inches wide coil with aluminum by heating it in a semi-muffle furnace at 500C for 1 hour. French Pat. No. 66,915 discloses a method of coating steel plates with a mixture of zinc and aluminum powders by heating in a 100 percent hydrogen atmosphere either at 3 l6454C for 6 hours or at 3l6-357C for 24-48 hours. Japanese Patent Publication No. 40/4131 discloses that a steel plate may be coated with aluminum, subjected to mechanical working with a reduction of 35-70 percent and heated at an arbitrary temperature within the range 400700C for an arbitrary period within the range of 1 second to 1 hour so as to prevent forming of an alloy layer or to limit such an alloy layer, if formed, to be less than 3 ,u. thick by heat treatment. According to the disclosure of Japanese Patent Publication No. 44/20841, a steel plate may be coated with aluminum, by heating in a non-oxidizing atmosphere or reducing atmosphere at a temperature less than that of melting point of aluminum for a short period of time to perform a preliminary sintering, then at a pressure with a reduction rate of less than 10 percent to compact the aluminum layer and heating as well as sintering at 350500C.
According to these prior art methods, it takes a considerable time to heat steel plates up to a predetermined temperature (heat treatment temperature) because the steel plates are heated in a gas having very low thermal conductivity. Continuous operation from rolling toheat treatment, consequently, requires heating to an unnecessarily high temperature or in a furnace having a long oven length. Such a furnace has a high construction cost, and raising the atmosphere temperature in a short time will also raise the production cost.
In manufacturing steel plates coated with such metal powders as aluminum powder, steel plates are subjected to a pretreatment such'as degreasing with alkali, washing in water, pickling, etc.', then coated with a slurry consisting of metal powders and water, and then dried, rolled and heated. In the prior art, it is difficult to perform rapid and continuous processing efficiently as respective stages of drying, rolling and heat treatment all require considerable time.
In any of the above prior art processes so much steam is generated in drying the slurry of metal powder coated on the steel plates that drying speed is considerably slowed down particularly when drying is carried out only by means of an induction heating, thus bringing about inefficiency. In order to accelerate drying, generated steam must be exhausted rapidly from the furnace and air must be blown into the same simultaneously. In a heating furnace used for drying slurry, coatings of metal powder and for heat treatment after rolling, the heating speeds, temperatures, etc., must be adjustable dependent on the thickness of strips, speeds of treatments, kinds of metals for coating and thicknesses of the coated layer. The conventional high frequency induction heating furnace has often been used 'only for heat treatment. A continuous heating furnace for strips,- for drying coated layers mainly consisting of aqueous solution, in which temperature is arbitrarily adjustable, has not yet been proposed.
In coating with metal powders, metal powders mixed with water or solvent and binder in a form of a slurry are painted or electrostatically coated on steel plates. In any of these cases, the coated steel plates are subjected to a heat treatment for drying and sintering the coated layer prior to rolling, and the steel plates coated with metal powder are continuously rolled after the L heat treatment.
In the prior art, when rolling such heated steel plates, the surfaces of the rolls are cooled and smoothed by means of water or a rolling lubricant oil. However, when the rolls are cooled from the outside the metal powder coated on the steel plates may possibly flow out from the same thus preventing formation of the desired coated layer. In the absence of a cooling operation, the surface temperature of the rolls becomes too high, so that the metal powder easily adheres to the rolls thus it is impossible to obtain a uniform ancl smooth layer. Moreover, the lubricating properties of the grease in the ball bearings is damaged at high temperatures.
The present invention aims to substantially eliminate the defects of the prior art..An object of the present invention is to provide apparatus for continuously manufacturing aluminum-coated steel plates having excellent adherence, wherein steel plates to which aluminum powder is applied are rolled to comminute the aluminum powders sufficiently and to achieve a nearly theoretical aluminum density (the same density as that of pure aluminum sheet), thus forming a continuous aluminum layer thereon. The plates are then subjected to a rapid heat treatment.
Another object of the present invention is to eliminate defects of the prior art processes of drying, rolling and heat treatment and to provide a rapid and continuous method of manufacturing aluminum-coated steel plates.
Still another object of the present invention is to eliminate defects of the prior art heating furnace used for manufacturing steel plates coated with metal powder.
Still another object of the present invention is to eliminate defects of the conventional rolls and to provide novel hollow compacting rolls wherein cooling water is circulated to cool the same and the ball bearings thereof are provided with rotary joints which facilitates the supply and drainage of water to and from the bearings while the rolls are rotating.
The present invention can be more fully understood from the following detailed description taken in conjunction with the accompanying drawings in which:
FIG. 1 schematically shows the whole process for manufacturing steel plates coated with aluminum powder;
FIG. 2 is a diagram showing conditions for heat treatment; Y
FIG. 3 is a diagram showing the temperature rises in various heating furnaces;
FIG. 4 shows a longitudinal section of a high frequency induction heating furnace;
FIG. 5 is a cross-sectional view of the furnace shown in FIG. 4 taken along the line VV;
FIG. 6 shows a longitudinal section of a part of hollow rollers.
FIG. 7 shows a longitudinal section of a heating furnace employing high frequency induction heating and radiation heating;
FIG. 8 is a cross-sectional view of the furnace shown in FIG. 7 taken along the line VIIIVIII; and
FIG. 9 is a cross-sectional view of the furnace shown in FIG. 7 taken along the line IX-IX.
EMBODIMENT 1 In FIG. 1 steel strip (A) is transferred to a pretreatment tank 9 through a pay-off reel 1, a feeder leveller 2, a pinch roll and shearing device 3, a welder 4, the first bridle 5, an entry side looper 6, the second bridle 7 and a tension unit 8. In the pre-treatment tank 9 the strip is subjected to degreasing with alkali, washing in water, pickling, washing in water and water scrubbing. Degreasing and pickling may be conducted by either the dipping method or the electrolytic method dependent on the conditions of the surface of the steel strip. After the pre-treatment hot air is blown onto the strip from a drier 10 to rapidly dry the surfaces thereof in order to prevent rusting and to facilitate painting of a slurry of aluminum powder and water in the subsequent process.
The dried strip (A) is fed to a slurry coater 12 through the third bridle 11 to be coated with a slurry consisting of aluminum powder and water. The reverse type slurry coated is provided with devices for mixing aluminum powder and water and for circulating slurry to supply prepared slurry to the coater. As the slurry may be left as prepared for a long time before coating, there is a possibility that aluminum powder will react with water thereby making use of the slurry impossible. To prevent such a reaction, such slurry stabilizing agents as phytinic acid, aluminum chloride, aluminum sulfate and malonic acid are added to the slurry. When steel strip is fed at a slow speed, rust may generate on the strip during the process time between coating of the strip with slurry and drying. Such rust is effectively prevented by addition of a corrosion inhibitor such as sodium nitrite and sodium benzoate.
The strip (A), coated with slurry, is fed to a rapid heating drying furnace 13 from which the evaporating water is rapidly exhausted, in order to complete drying in as short a time as possible; the degree of drying must be uniform at the upper and lower surfaces of the strip without looping of the strips in the furnace; and exfoliation of dried aluminum powder caused by a supporting member for said looping must be prevented. A high frequency induction heating furnace provided with a device for exhausting vapour meets the foregoing requirements. The structure of the heating furnace 13 will be described later in the specification.
The steel strip delivered from the drying furnace 13 is then fed to a rolling mill 14 where aluminum powder is completed and adhered to the surface of the steel strip. In rolling the strip, a considerable amount of the aluminum powder sticks to the rolls of the mill 14 not only spoiling the surface of the steel strip but also damaging the uniformity of the coated metal. In order to prevent such defects, hollow rolls the surfaces of which are cooled from inside thereof are used. In addition, a roll cleaning apparatus is provided at the delivery side of the rolls to clean the surface of the rolls and remove aluminum powder stuck thereto.
The steel strip delivered from the rolling mill 14 is then fed to the heat treatment furnace 15, 16 wherein the strip is rapidly and continuously subjected to a heat treatment to impart to the aluminum layer resistance to bending, drawing, etc. Time and temperature for heat treatment depend on the thickness of the strip and the aluminum layer thereon. It is necessary to provide for rapidly changing temperature for heat treatment corresponding to changes in the production schedule. In one embodiment of the present invention a continuous high frequency induction heating furnace 15 and radiation tube type furnace 16 are employed as heating furnaces, but the invention is not limited thereto. In the embodiment, when the strip is thin and is rapidly coated with slurry, only the high frequency induction heating furnace 15 (FIGS. 4 and 5) is employed while when the strip is thick and coated with slurry at a slow speed and must be heated for a long time, the radiation tube type furnace 16 as well as said high frequency induction furnace 15 is employed, as shown in FIGS. 7-9, to attain maintenance of desired temperature. In this way, temperature for heat treatment is adjusted continuously corresponding to the change of conditions for heat treatment caused by change in strip thickness and speed of coating by means of the combination of these two furnaces. Consequently, it is possible to conduct heat treatment in a simple manufacturing line and reduce the construction cost.
The steel strip delivered from the heat treatment furnaces l5, 16 is fed to a water quenching tank 17 which is provided with a water circulation device having a spray nozzle to maintain the temperature of water at the entry side of the tank 17 at a constant value and with a wringer roll at the delivery side of the tank. The temperature of water for cooling the strip is adjustable in accordance with the requirements of the drying process. The strip is further fed to a post treatment tank 19, to impart to the strip a corrosion resistant property, via a drier 18. The drier 18 is used dependent upon the kind of chemical treatments to which the strip is subjected in said tank 19. The method of post treatment may be selected from among chromate treatment, chromate treatment with soluble organic high molecular compound, etc., by immersing or spraying.
The strip delivered from the post treatment tank 19 passes through a hot air blowing type drier 20, the fourth bridle 21, a delivery side looper 22, the fifth bridle 23 and a delivery side shear 24, and is fed to a tension reel 25 where the strip is coiled as a final product.
As has been described so far, the method of the present invention shortens drying and heat treatment processes, thus bringing about rapid and continuous manufacturing of aluminum-coated steel plates.
Rapid heat treatment will be described in further detail hereinafter.
FIG. 2 shows the relation between temperature of a steel plate and treatment time. The upper line in FIG. 2 represents the upper limit of heat treatment temperature for not forming an alloy layer of Fe and Al in the interface of the aluminum layer and the steel plate. If the hard and brittle alloy layer of Fe and A1 is formed, cracks are easily caused in the coated layer on a steel plate while it is being formed. Moreover, aluminumcoated steel plate, treated under such conditions as to form an Fe Al alloy layer, does not have the lustre peculiar to aluminum and becomes yellowish in color. Consequently, heat treatment at a temperature above the aforementioned upper limit is undesirable.
The lower line shown in FIG. 2 represents the lower limit of heat treatment temperature below which adherence between the aluminum layer and the steel plate is not sufficient and exfoliation of the aluminum layer or minute cracks therein are caused during working of the aluminum-coated steel plate. Thus, the intermediate part between the upper and lower lines shown in FIG. 2 is the optimum range for the heat treatment. Aluminum-coated steel plates having excellent properties, in which no cracks are caused in the aluminum layer, are obtained by heat treatment under the conditions within the above range. By further examining the said range to obtain better and more economical conditions for a continuous process of manufacturing aluminum-coated steel plate comprising painting, roll and heat treatment, the range (B) indicated by oblique lines in FIG. 2 is obtained. The present invention is characterized by rapid heat treatment under the conditions within the range (B).
Heat treatment under such conditions is impossible by the conventional heating method with gases.
In order to attain such a heat treatment for the present invention, suitable heating methods are: (a) heating aluminum-coated steel plates with a metal having both good heat conductivity and not reacting with aluminum; (b) heating by means of induction heating as described in reference to FIG. 1; or (c) rapidly heating the steel plate up to a predetermined temperature by induction heating and maintaining the same at the temperature in a furnace containing gas therein. Rapid heat conduction is effected by a metal bath, such as a lead bath or an induction heating furnace, and steel plates are heated up to a predetermined temperature in a short time. FIG. 3 shows the manner in which the temperature rises in some heating furnaces. In FIG. 3, (a) shows a case of heating with a lead bath, (b) heating in an induction heating furnace, (c) in a combination of an induction heating furnace and a siliconit furnace and (d) in a siliconit furnace.
Other embodiments of the present invention will be described hereinafter.
EMBODIMENT 2 A slurry consisting of atomized aluminum powder comprising particles having an average particle size of 15 1.1. and an aqueous solution of NaNO having a concentration of IO moIe/l, mixed in the ratio of 6:4, was coated on a steel plate by means of a reverse roll coater. The coating rate was 80 g/m Then the steel plate was dried and rolled in a rolling mill so as to reduce the steel plate by 5 percent. The aluminumcoated steel plate thus obtained was subjected to oil quenching after heat treatment for 3 seconds in a lead bath which was maintained at 600C. The steel plate thus obtained had the metallic luster peculiar to aluminum and no cracks were caused in the coated layer in bending tests to an angle of 180. In a salt spraying test (Japanese Industrial Standard Z -2371), red rusts did not appear at all, even after being subjected to a test for 200 hours. Thus, it is shown that the steel plate has an excellent corrosion resistant property.
EMBODIMENT 3 A rolled aluminum-coated steel plate obtained in the same way as Embodiment 2 was subjected to heat treatment for 5 seconds in a lead bath maintained at 550C, and then to water quenching. Aluminum-coated steel plate having the same properties as Embodiment 2 was obtained.
EMBODIMENT 4 A slurry comprising the same compositions as that of Embodiment 2 was continuously coated on a coldrolled coil having a thickness of 0.8 mm and a width of 100 mm by a reverse system roll coated at a rate of dried weight of g/m and the coated coil was dried and rolled to 5 percent reduction rate. The coil was then heated for 2 seconds at a heating rate of 225C/sec with an input power of 7 KW in an induction heating furnace having frequency of 10 KC, maintained at 550C for 3 seconds with 0.5 KW and subjected to water quenching.
Aluminum-coated steel plate thus obtained had the same excellent properties as Embodiment 2, having beautiful luster, excellent workability and resistance to corrosion.
EMBODIMENT 5 The rolled aluminum-coated steel plate obtained in the same way as Embodiment 4 was heated for 2 seconds in such a way that the temperature at the surface of the steel plate became 500C with an input power of 7 KW in an induction heating furnace having a frequency of 10 KC and then heated for 3 seconds at 500C in a furnace in the atmosphere. The steel plate thus obtained has luster on the surface thereof and no defects were seen in the coated layer in a deep drawing test. Though white rust was caused in a humidity cabinet test at 50C and with percent of moisture, red rust did not generate after a test for 3000 hours.
As has been described so far, aluminum powder coated on a steel plate is compacted to provide almost theoretical density, and subjected to heat treatment at a temperature within the range from 450 to 700C for l5 seconds. As the result of the foregoing, time for heat treatment is remarkably shortened. Further, it is possible to shorten furnace length and to conduct rapid and continuous operation. Moreover, operation is easily performed at low cost because heat treatment is conducted in the atmosphere and heating in a nonoxidizing or reducing atmosphere is unnecessary. Heat treatment under these particular conditions prevents forming a hard and brittle alloy layer, damaging the luster peculiar to aluminum or causing insufficient adherence.
The present invention is characterized by the abovementioned rapid heat treatment. Embodiments of heating furnaces will be described hereinafter, reference being made to FIGS. 4-9 of the accompanying drawing.
In the drawing, 40 denotes a steel plate coated on both surfaces with a slurry consisting of aluminum powder and water, which is fed to a heating furnace 41 as shown in FIGS. 4 and 7. The ,heating furnace is equipped with a hot air blowing device 42 at the entry side thereof, where the hot air heated up to 80l00C is applied to the steel plate entering the heating furnace 41 to accelerate drying. 43a, 43b and 430 denote coils for high frequency induction heating. Inductance at the respective coils 43a, 43b and 430 is continuously adjusted to facilitate continuously varying the curve of temperatures at the respective coils independently of each other by means of respective control systems which are respectively independent of each other. Thus, input power to the respective coils for heating is made adjustable at loading. As shown in FIG. 5, the coils 43 comprise an outer protective insulating wall 44 for mechanical portection of the coil and prevention of dust and danger, and an inner protective insulating wall 45 which is exchangeable for mechanical protection of the coils 43 when the strip 40 is damaged and to prevent slurry which is not dried yet from dropping directly on the inside of the coils 43 and adhering thereto. Connecting devices for exhaust 46a, 46b and 46c are provided at the delivery side of the heating furnace 41 and between the respective coils 43a, 43b and 43c. These exhaust devices 46 which may be connected to exhaust blowers accelerate drying by exhausting vapours and gases which are generated upon heating from the top and bottom ends of the devices 46. Windows 47a,-47b and 470 (FIGS. 4 and 8) are provided in the connecting devices 46a, 46b and 460 to enable one to observe the state of drying within the heating coils 43 so that the load on the heating coils can be adjusted if necessary. FIGS. 7 and 9 show radiation tubes 48 in the furnace to additionally provide radiation heating as hereinbefore described.
As is described hereinabove, the high frequency induction heating furnace of the present invention comprises a plurality of high frequency induction heating coils which facilitate independent control of the temperature curve by means of the control systems which are independent of each other, the hot air blowing device at the entry side of the heating furnace, and the connecting devices for exhaust between respective coils and at the delivery side of the furnace. Further, radiation heating is supplied. Thus, a great deal of vapour and gas generated when slurry containing alminum powder coated on the steel strip is dried is exhausted through the exhaust device to promote drying and effective heating. At the time of drying and of heat treatment after rolling, heating speed and temperature are adjusted to provide the optimum conditions for each coil depending upon the thickness of the strip which is being treated, the number of heating coils which can be controlled independently of each other, the kind of coated metals and the thickness of coated layer.
An embodiment of rolling rolls which are employed in the rolling process will be described hereinafter, reference being made to FIG. 6.
In FIG. 6, 51 denotes a lower work roll and 52 denotes an upper work roll. A steel strip coated with aluminum powder and subjected to heat treatment is rolled between said upper and lower rolls 51, 52. 53 denotes ball bearings to support said rolls 51, 52.
The rolls 51, 52 are provided with a hollow portion 54 extending in the axial direction and one end of which is closed, in which a water supply tube 55 supported by a receiving member 56 at the closed end of the hollow portion 54 is provided in the centerthereof. A plurality of water supply apertures 57 are provided in the water supply tube 55. Cooling water is supplied to the inside of the hollow portion 54 through the apertures 57 of the water supply tube 55 to cool the rolls 51, 52.
58 denotes a rotary joint connected to the open end of the hollow portion 54 in the rolls 51, 52, comprising double rotary sleeves 60, 61 installed in the fixed casing 59, ball bearings 62, 63 to support said two rotary sleeves 60, 61, and flexible hoses 64, 65 to supply said sleeves with cooling water.
The end of the rolls 51, 52 is fixed to the outer rotary sleeve in a liquid-tight manner, and the gap between the outer rotary sleeve 60 and the inner rotary sleeve 61 is connected to the hollow portion 54 and the flexible hose for drainage of cooling water supplied in the hollow portion 54. The water supply tube 55 is connected to the inner rotary sleeve 61 at one end thereof and the other end of the inner rotary sleeve 61 is opened to a cover 66 which is fixed to the fixed casing 59 and in which the flexible hose 64 for supplying water is connected.
Cooling water supplied through the flexible hose 64 is fed to the water supply tube 55 through the inner rotary sleeve 61 and to the hollow portion 54 from the water supply apertures 57. Water fed to the hollow portion 54 and cooling the rolls 51, 52 is drained from the flexible hose 65 through the gap 67 in the outer rotary sleeve 60.
As above-described, the rolls are cooled from the inside thereof. Therefore, coated aluminum powder is not washed away by cooling water or lubricant oil as often happened in the prior art, nor does it adhere to the rolls and damage the uniform surface of the rolled steel strip.
The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A heating furnace for use in the manufacture of steel plates coated with aluminum powder, comprising:
housing means for receiving a moving steel plate coated with aluminum powder;
a high frequency induction heating means in said housing means for heating said steel plate, said heated steel plate conducting heat gradually to the outer portion of said coating;
a radiation type heating means in said housing means for heating said coating, the heated coating conducting heat gradually toward the inside thereof;
a hot air blowing device at the entry side of said housing means for supplying fresh air to said furnace; and
exhaust means coupled to said housing means for removing wetted hot air from said furnace.
2. A heating furnace according to claim 1 wherein said exhaust means is located at least at the delivery side of said housing means.
3. A heating furnace according to claim 2 wherein said exhaust means includes a plurality of outlets for exhausting gas from said furnace at different portions thereof.
4. A heating furnace according to claim 1 wherein said high frequency induction heating means comprises a plurality of high frequency induction heaters spaced from each other and distributed along said housing means in the'direction of movement of said steel plate.
5. A heating furnace according to claim 4 wherein said radiation type heating means comprises a plurality of radiation heaters spaced from each other and distributed along said housing means in the direction of movement of said steel plate.
6. A heating furnace according to claim 1 wherein said housing means includes openings therein for observance of the conditions inside said furnace.
said plurality of high frequency induction heating means for controlling the heating temperature thereof so as to control the temperature gradient in said furnace;
a hot air blowing device at the entry side of said housing means for supplying fresh air to said furnace; and
exhaust means coupled to said housing means for removing wetted hot air from said furnace.

Claims (8)

1. A HEATING FURNACE FOR USE IN THE MANUFACTURER OF STEEL PLATES COATED WITH ALUMINUM POWDER, COMPRISING: HOUSING MEANS FOR RECEIVING A MOVING STEEL PLATE COATED WITH ALUNIMUM POWDER, A HIGH FREQUENCY INDUCTION HEATING MEANS IN SAID HOUSING MEANS FOR HEATING SAID STEEL PLATE, SAID HEATED STEEL PLATE CONDUCTING HEAT GRADUALLY TO THE OUTER PORTION OF SAID COATING, A RADIATION TYPE HEATING MEANS IN SAID HOUSING MEANS FOR HEATING SAID COATING, THEHEATED COATING CONDUCTING HEAT GRADUALLY TOWARD THE INSIDE THEREOF, A HOT AIR BLOWING DEVICE AT THE ENTRY SIDE OF SAID HOUSING MEANS FOR SUPPLYING FRESH AIR TO SAID FURNACE, AND EXHAUST MEANS COUPLED TO SAID HOUSING MEANS FOR REMOVING WETTED HOT AIR FROM SAID FURNACE.
2. A heating furnace according to claim 1 wherein said exhaust means is located at least at the delivery side of said housing means.
3. A heating furnace according to claim 2 wherein said exhaust means includes a plurality of outlets for exhausting gaS from said furnace at different portions thereof.
4. A heating furnace according to claim 1 wherein said high frequency induction heating means comprises a plurality of high frequency induction heaters spaced from each other and distributed along said housing means in the direction of movement of said steel plate.
5. A heating furnace according to claim 4 wherein said radiation type heating means comprises a plurality of radiation heaters spaced from each other and distributed along said housing means in the direction of movement of said steel plate.
6. A heating furnace according to claim 1 wherein said housing means includes openings therein for observance of the conditions inside said furnace.
7. A heating furnace according to claim 6 wherein said housing means includes a plurality of said openings spaced from each other along the direction of movement of said steel plate.
8. A heating furnace for use in the manufacture of steel plates coated with aluminum powder, comprising: housing means for receiving a moving steel plate coated with aluminum powder; a plurality of high frequency induction heating means in said housing means; an independent control system coupled to each of said plurality of high frequency induction heating means for controlling the heating temperature thereof so as to control the temperature gradient in said furnace; a hot air blowing device at the entry side of said housing means for supplying fresh air to said furnace; and exhaust means coupled to said housing means for removing wetted hot air from said furnace.
US376111A 1971-08-09 1973-07-03 Apparatus for manufacturing steel plates coated with aluminium powder Expired - Lifetime US3912846A (en)

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EP0159029A2 (en) * 1984-04-20 1985-10-23 Park-Ohio Industries, Inc. Method of and apparatus for heating magnetizable metal work pieces
FR2701719A1 (en) * 1993-02-19 1994-08-26 Maubeuge Fer Methods and installations for continuously producing a plurality of metal alloy coatings on a steel strip
US20060151479A1 (en) * 2002-12-09 2006-07-13 Wilson Timothy E Induction dryer
US20110171590A1 (en) * 2008-09-22 2011-07-14 I.A.S. Induktions-Anlagen + Service Gmbh & Co. Kg Device for heating rod-type work pieces

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US2325638A (en) * 1941-09-19 1943-08-03 Budd Wheel Co Billet heating apparatus
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US2130756A (en) * 1935-10-17 1938-09-20 Ici Ltd Heat treatment of metals
US2325638A (en) * 1941-09-19 1943-08-03 Budd Wheel Co Billet heating apparatus
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US3588305A (en) * 1970-02-18 1971-06-28 Sola Basic Ind Inc Electrically heated vessel enclosed car bottom furnace system

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Publication number Priority date Publication date Assignee Title
EP0159029A2 (en) * 1984-04-20 1985-10-23 Park-Ohio Industries, Inc. Method of and apparatus for heating magnetizable metal work pieces
EP0159029A3 (en) * 1984-04-20 1987-05-06 Park-Ohio Industries, Inc. Method of and apparatus for heating magnetizable metal work pieces
FR2701719A1 (en) * 1993-02-19 1994-08-26 Maubeuge Fer Methods and installations for continuously producing a plurality of metal alloy coatings on a steel strip
WO1994019510A1 (en) * 1993-02-19 1994-09-01 Fabrique De Fer De Maubeuge Methods and plants for continuously producing a plurality of metal alloy coatings on a steel tape
US20060151479A1 (en) * 2002-12-09 2006-07-13 Wilson Timothy E Induction dryer
US7432480B2 (en) * 2002-12-09 2008-10-07 Nordson Corporation Induction dryer
US20080302786A1 (en) * 2002-12-09 2008-12-11 Nordson Corporation Induction dryer
US8258445B2 (en) 2002-12-09 2012-09-04 Nordson Corporation Induction dryer
US8796601B2 (en) 2002-12-09 2014-08-05 Nordson Corporation Induction dryer
US9814103B2 (en) 2002-12-09 2017-11-07 Nordson Corporation Induction dryer
US20110171590A1 (en) * 2008-09-22 2011-07-14 I.A.S. Induktions-Anlagen + Service Gmbh & Co. Kg Device for heating rod-type work pieces

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