US3895938A - Purification of mercury - Google Patents
Purification of mercury Download PDFInfo
- Publication number
- US3895938A US3895938A US43332474A US3895938A US 3895938 A US3895938 A US 3895938A US 43332474 A US43332474 A US 43332474A US 3895938 A US3895938 A US 3895938A
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- United States
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- mercury
- sulfuric acid
- solution
- sulfate
- cell
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/36—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in mercury cathode cells
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B43/00—Obtaining mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- ABSTRACT 30 Forei n A I ation Pr t Data 1 J 27 5 i I0" y 2 04
- an alkali metal I amalgam which is withdrawn and decomposed to re- [52] Cl 75/101 generate mercury containing impurities introduced 51 I Cl 43/00 from the alkali metal chloride.
- the impure mercury is 1 'f 204 64 R mixed turbulently with an aqueous solution of sulfuric [58] 1e 0 earc ll 204 5 acid having mercury (l) sulfate dissolved or suspended therein whereupon the impurities are extracted into 5 References Cited the solution and the purified mercury is recycled.
- mercury A number of chemical elements, especially metals, are soluble in mercury to a certain extent. In practical application, therefore, mercury generally absorbs metals as its principal impurity. For a number of applications involving mercury, for example switches, discharge lamps, diffusion pumps and valves, but especially for the electrolysis of alkali metal chlorides by the amalgam process, the mercury has to be present in a highly pure form. If the electrolysis of alkali metal chlorides is carried out using mercury which, in addition to alkali metals, contains other metals dissolved or dispersed in it, electrolysis is seriously affected insofar as the resulting chlorine has an increased hydrogen content, and the bottom of the cell, the amalgam decomposer vessel, the pipes and the pumps are contaminated.
- German Offenlegungsschrift No. 2,020,480 describes a process for purifying the mercury accumulating after the decomposition of sodium amalgam by means of solutions containing chlorine or iron(lII)-chloride.
- this process it is possible to remove the iron in particular, although the iron content cannot be reduced to less than 0.01 percent by weight without the danger of the mercury itself being dissolved in appreciable quantities.
- This value is not sufficient to avoid detrimental contamination of the cell base in the presence of strong magnetic fields, which corresponds to high specific loads of the electrolysis cells.
- the process according to the invention is eminently suitable for rapidly purifying mercury, either continuously or in batches, by freeing it from metals, metallic phases, alloys and metal oxides down to an impurity content of less than about percent by weight, providing the chemical elements in question are less noble than the mercury, i.e. lower down in the electromotive series.
- the undesirable metal impurities dissolved and/or dispersed in the mercury are dissolved out of the mercury in the form of metal sulfates under the oxidizing effect of the acid solution and/or suspension containing mercury (I) sulfate, the I-lg (I) of the mercury (I) sul fate being reduced to metallic mercury.
- the reaction which takes place during the process according to the invention is in principle a cementation reaction, in other words the base impurities in the mercury cause the more noble mercury in the mercury (I) sulfate solution to be precipitated, and are themselves dissolved so that they can readily be separated from the liquid mercury phase.
- the mercury (I) sulfate solution and/or suspension used for purification will always be referred to hereinafter as the cementing solution.
- the cementation reaction takes place with intensive admixture of the two liquid phases, the mercury phase and the cementing solution.
- Admixture can be carried out turbulently, for example by means of a high speed stirrer, a reciprocating pump, a vibrating mill or by atomizing the mercury by conventional methods for atomizing metal melts. It is also possible to apply an electrical rotary field, under the effect of which the mercury rotates and enables a phase exchange with the underlying cementing solution to occur.
- the process according to the invention can be carried out at temperatures of about 10 to 120C, although it is preferably carried out at temperatures of about 20 to 100C.
- the cementing solution contains mercury (I) sulfate in disolved form, although it can contain more mercury (l) sulfate in solid form beyond the solubility of the mercury (I) sulfate.
- the cementing solution can also contain a mixture of mercury and mercury (II) sulfate, in which case mercury (I) sulfate is formed in situ in accordance with the equation Hg (ll) Hg(O)- Hg(l).
- the cementing solution advantageously contains mercury (I) sulfate from the outset.
- a cementing solution of this kind is easily prepared by suspending mercury (I) sulfate in sulfuric acid or by passing sulfuric acid over mercury (I) sulfate.
- the sulfuric acid should be from 0.05 to 5 molar, preferably from 0.1 to 1 molar.
- the mercury (I) sulfate can be prepared separately by conventional methods. However, the continuous production of a mercury (l) sulfate solution, bypassing the solid salt stage, is of greater advantage.
- Continuous production can be carried out, for example, by directly reacting sulfuric acid with mercury at temperatures above C (Gmelin, Hg, 34 B, 1005), or by electrolysis of a dilute sulfuric acid solution with a mercury anode (G. A. Hulett, Z. phys. Chem, 49, 483 (1904)).
- the process of cementation with sulfuric acid and mercury (I) sulfate according to the invention is particularly suitable for the batch purification and continuous purification of mercury.
- Purification can be carried out, for example, in an ordinary vessel equipped with a stirring mechanism, and the resulting mercury is washed with dilute sulfuric acid and water.
- the cementation reaction is carried out by providing the mercury (I) sulfate in slightly more than stoichiometric amount in relation to the impurities.
- the adjustment can readily be regulated by monitoring the content of mercury (l) sulfate in the already spent cementing solution which is separated.
- FIG. 1 is a schematic perspective view of a battery of electrolysis cells
- FIG. 2 is a schematic lateral elevation of one of the cells and its structure for recycling spent mercury
- FIG. 3 is a schematic lateral elevation of one cell and an alternate structure for recycling spent mercury.
- FIG. 1 shows an embodiment for the electrolysis of alkali metal chlorides comprising a cell 1, an amalgam decomposer 2, a so-called Aussigerecup (Winnacker- Kuchler, Chemische Technolo gie (1969), Vol. 1, page 255) in the form of a mercury pump 3 and an apparatus 4 for producing mercury (I) sulfate, comprising a small electrolysis cell for producing the cementing solution and various pipes.
- the Aussiger-cup and all compo- ..nents which come into contact with the cementing "solution have to be made of or coated with a materialthat is resistant to the cementing solution.
- Materials suitable for this purpose include, for example, ceramic material such as, for example, sintered corundum, enamel, plasticsfs uch as, for example, polypropylene, and rubber.
- Themercury flowing out of the amalgam decomposer 2 into the bottom-of the Aussiger-cup 3 is turbulently admixed by a cup-shaped rotor 5 with the cementing solution flowing in at and, at the same time, is purified.
- the mercury flowing out again from the top of the Aussiger-cup is washed in a chamber 7, separated from the cell 1 and Aussiger-cup 3 by submerged seals, with dilute -sulfuricacid introduced through pipe 8.
- the dilute sulfuric acid collected can be retu med to the apparatus 4.
- cementation is not carried out in an Aussiger-c up, but instead in a stirrer vessel 13 which is situated between the Aussiger-cup 3 and the cell inlet.
- a washing chamber 7 is here also provided.
- FIG. 3 illustrates an embodiment with a pump.
- the contaminated mercury flows back into the cell 1 through a pump 15.
- the cementing solution can be introduced into the feeder (pump) at 17 either directly or by way of a mixing zone 16.
- EXAMPLE 2 Purification by cementation was carried out in an 80 kA cell for the electrolysis of alkali metal chlorides by the amalgam process in accordance with FIG. 1.
- 1 molar sulphuric acid was continuously reacted on amercury anode at 0.12 A and 0.6 V to form mercury (I) sulphate.
- the sulphuric acid cementing solution saturated with 0.5 g of mercury (I) sulphate was passed through the mercury feeder (Aussiger-cup 3) at a rate of 40 litres per day. In this way, it was possible to keep the electrolysis cell, the amalgam decomposer and the Aussiger-cup free from deposits so that the cell did not have to be taken out of operation for several months.
Abstract
In the electrolysis of an alkali metal chloride in a cell containing mercury there is produced an alkali metal amalgam which is withdrawn and decomposed to regenerate mercury containing impurities introduced from the alkali metal chloride. The impure mercury is mixed turbulently with an aqueous solution of sulfuric acid having mercury (I) sulfate dissolved or suspended therein whereupon the impurities are extracted into the solution and the purified mercury is recycled.
Description
United States Patent Klotz July 22, 1975 [54] PURIFICATION OF MERCURY 2,846,305 8/1958 Ashley et a1. 75 121 3,437,476 4/1969 Dotson et al.. 75/l03 [75] Invemo Helm Leverkusenv 3,639,118 2/1972 OGrady 75/121 Germany [73] Assignee: Bayer Aktiengesellschaft, Primary Ozaki Leverkusem Germany Attorney, Agent, or Firm-Burgess, Dinklage & [22] Filed: Jan. 14, 1974 Sprung [2]] Appl. No.: 433,324
[57] ABSTRACT 30 Forei n A I ation Pr t Data 1 J 27 5 i I0" y 2 04 In the electrolysis of an alkali metal chloride in a cell ermany 3 063 containing mercury there is produced an alkali metal I amalgam which is withdrawn and decomposed to re- [52] Cl 75/101 generate mercury containing impurities introduced 51 I Cl 43/00 from the alkali metal chloride. The impure mercury is 1 'f 204 64 R mixed turbulently with an aqueous solution of sulfuric [58] 1e 0 earc ll 204 5 acid having mercury (l) sulfate dissolved or suspended therein whereupon the impurities are extracted into 5 References Cited the solution and the purified mercury is recycled.
UNITED STATES PATENTS 3/1936 Stearns 75/121 X 6 Claims, 3 Drawing Figures PATENTED JUL 2 2 ms SHEET PATENTEDJUL22 ms 3,895,938 $HEET 2 FIGZ PURIFICATION OF MERCURY The present invention relates to the purification of mercury.
A number of chemical elements, especially metals, are soluble in mercury to a certain extent. In practical application, therefore, mercury generally absorbs metals as its principal impurity. For a number of applications involving mercury, for example switches, discharge lamps, diffusion pumps and valves, but especially for the electrolysis of alkali metal chlorides by the amalgam process, the mercury has to be present in a highly pure form. If the electrolysis of alkali metal chlorides is carried out using mercury which, in addition to alkali metals, contains other metals dissolved or dispersed in it, electrolysis is seriously affected insofar as the resulting chlorine has an increased hydrogen content, and the bottom of the cell, the amalgam decomposer vessel, the pipes and the pumps are contaminated. In addition, contamination of the cell base can lead to short circuits between anode and cathode unless the spacing between the electrodes is increased, which in turn has an adverse effect upon the economy of the process. Furthermore, the absorption of impurities by the mercury results in an accumulation of impurities (so-called amalgam butter formation), because, despite careful preparation, the starting materials (for example alkali chloride sols) continuously entrain traces of metal ions, or the material with which the mercury comes into contact and the anodes give off traces of metals or alloys. The metals iron, chromium and vanadium frequently occur as impurities in mer cury with detrimental effects.
German Offenlegungsschrift No. 2,020,480 describes a process for purifying the mercury accumulating after the decomposition of sodium amalgam by means of solutions containing chlorine or iron(lII)-chloride. By virtue of this process, it is possible to remove the iron in particular, although the iron content cannot be reduced to less than 0.01 percent by weight without the danger of the mercury itself being dissolved in appreciable quantities. This value is not sufficient to avoid detrimental contamination of the cell base in the presence of strong magnetic fields, which corresponds to high specific loads of the electrolysis cells. In order to avoid these disadvantages, it is necessary to reduce the foreign metal content to values far below those that can be obtained with the process according to German Offenlegungsschrift No. 2,020,480.
It is accordingly an object of the invention to provide a simple process for purifying mercury to a very high degree.
These and other objects and advantages are realized in accordance with the present invention pursuant to which contaminated, impure mercury is treated with an aqueous solution of sulfuric acid having mercury (I) sulfate dissolved or suspended therein and the purified mercury is separated from the solution into which the impurities have been extracted.
The process according to the invention is eminently suitable for rapidly purifying mercury, either continuously or in batches, by freeing it from metals, metallic phases, alloys and metal oxides down to an impurity content of less than about percent by weight, providing the chemical elements in question are less noble than the mercury, i.e. lower down in the electromotive series.
The undesirable metal impurities dissolved and/or dispersed in the mercury are dissolved out of the mercury in the form of metal sulfates under the oxidizing effect of the acid solution and/or suspension containing mercury (I) sulfate, the I-lg (I) of the mercury (I) sul fate being reduced to metallic mercury. Accordingly, the reaction which takes place during the process according to the invention is in principle a cementation reaction, in other words the base impurities in the mercury cause the more noble mercury in the mercury (I) sulfate solution to be precipitated, and are themselves dissolved so that they can readily be separated from the liquid mercury phase. Accordingly, the mercury (I) sulfate solution and/or suspension used for purification will always be referred to hereinafter as the cementing solution. According to the invention, the cementation reaction takes place with intensive admixture of the two liquid phases, the mercury phase and the cementing solution. Admixture can be carried out turbulently, for example by means of a high speed stirrer, a reciprocating pump, a vibrating mill or by atomizing the mercury by conventional methods for atomizing metal melts. It is also possible to apply an electrical rotary field, under the effect of which the mercury rotates and enables a phase exchange with the underlying cementing solution to occur. The process according to the invention can be carried out at temperatures of about 10 to 120C, although it is preferably carried out at temperatures of about 20 to 100C.
The cementing solution contains mercury (I) sulfate in disolved form, although it can contain more mercury (l) sulfate in solid form beyond the solubility of the mercury (I) sulfate. The cementing solution can also contain a mixture of mercury and mercury (II) sulfate, in which case mercury (I) sulfate is formed in situ in accordance with the equation Hg (ll) Hg(O)- Hg(l). However, the cementing solution advantageously contains mercury (I) sulfate from the outset. By virtue of the low solubility of mercury (I) sulfate in the aqueous medium, a cementing solution of this kind is easily prepared by suspending mercury (I) sulfate in sulfuric acid or by passing sulfuric acid over mercury (I) sulfate. The sulfuric acid should be from 0.05 to 5 molar, preferably from 0.1 to 1 molar. The mercury (I) sulfate can be prepared separately by conventional methods. However, the continuous production of a mercury (l) sulfate solution, bypassing the solid salt stage, is of greater advantage. Continuous production can be carried out, for example, by directly reacting sulfuric acid with mercury at temperatures above C (Gmelin, Hg, 34 B, 1005), or by electrolysis of a dilute sulfuric acid solution with a mercury anode (G. A. Hulett, Z. phys. Chem, 49, 483 (1904)).
As already mentioned, the process of cementation with sulfuric acid and mercury (I) sulfate according to the invention is particularly suitable for the batch purification and continuous purification of mercury. Purification can be carried out, for example, in an ordinary vessel equipped with a stirring mechanism, and the resulting mercury is washed with dilute sulfuric acid and water. The cementation reaction is carried out by providing the mercury (I) sulfate in slightly more than stoichiometric amount in relation to the impurities. The adjustment can readily be regulated by monitoring the content of mercury (l) sulfate in the already spent cementing solution which is separated.
FIG. 1 is a schematic perspective view of a battery of electrolysis cells; FIG. 2 is a schematic lateral elevation of one of the cells and its structure for recycling spent mercury; and FIG. 3 is a schematic lateral elevation of one cell and an alternate structure for recycling spent mercury.
Referring now more particularly to the drawings, FIG. 1 shows an embodiment for the electrolysis of alkali metal chlorides comprising a cell 1, an amalgam decomposer 2, a so-called Aussigerecup (Winnacker- Kuchler, Chemische Technolo gie (1969), Vol. 1, page 255) in the form of a mercury pump 3 and an apparatus 4 for producing mercury (I) sulfate, comprising a small electrolysis cell for producing the cementing solution and various pipes. The Aussiger-cup and all compo- ..nents which come into contact with the cementing "solution have to be made of or coated with a materialthat is resistant to the cementing solution. Materials suitable for this purpose include, for example, ceramic material such as, for example, sintered corundum, enamel, plasticsfs uch as, for example, polypropylene, and rubber. Themercury flowing out of the amalgam decomposer 2 into the bottom-of the Aussiger-cup 3 is turbulently admixed by a cup-shaped rotor 5 with the cementing solution flowing in at and, at the same time, is purified. The mercury flowing out again from the top of the Aussiger-cup is washed in a chamber 7, separated from the cell 1 and Aussiger-cup 3 by submerged seals, with dilute -sulfuricacid introduced through pipe 8. The dilute sulfuric acid collected can be retu med to the apparatus 4. The spent cementing solution flowing out of ventional sol-preparation stage (not .shown) after "r'esaturation of the anolyte. Any undesired residue of mercury salts still present in the anolyte can be removed by cementation with iron scraps (not shown) before entering the anolyte. Additional dilute sulfuric acid may optionally be introduced into the electrolysis cell'4 at '12.
In another embodiment shown in FIG. 2, cementation is not carried out in an Aussiger-c up, but instead in a stirrer vessel 13 which is situated between the Aussiger-cup 3 and the cell inlet. A washing chamber 7 is here also provided.
Itis of course also possible by the process according to the invention to purify only a portion of the mercury following decomposition of the amalgam. This embodiment is advantageous in cases where the mercury reenteririg the cell does not spread completely, which can occur in the case of wide cells, for example.
The process according to the invention can also be pumps. FIG. 3, illustrates an embodiment with a pump.
From a vertical decomposer 14, the contaminated mercury flows back into the cell 1 through a pump 15. The cementing solution can be introduced into the feeder (pump) at 17 either directly or by way of a mixing zone 16. The mercury'is washed in the washing chamber 7 before. entering the cell. 1
In the embodiments shown in FIG. 2 and 3, preparation of the cementing solution, the associated pipe system and introduction of the spent cementing solution into the impoverished sols, correspond to the embodiment shown in FIG. 1. Otherprocesses can also be used for-separating the impurities from excess'mercury (I) sulfate in the aqueous phase, for example cathodic deposition of the more noble mercury or, as already mentioned, cementation with iron scrap.
The process according to the invention is illustrated by the following Examples:
EXAMPLE 1 I tion time of only 2 minutes, the iron content had been reduced to 5X10 percent by weight of iron.
EXAMPLE 2 Purification by cementation was carried out in an 80 kA cell for the electrolysis of alkali metal chlorides by the amalgam process in accordance with FIG. 1. In the apparatus 4, 1 molar sulphuric acid was continuously reacted on amercury anode at 0.12 A and 0.6 V to form mercury (I) sulphate. The sulphuric acid cementing solution saturated with 0.5 g of mercury (I) sulphate was passed through the mercury feeder (Aussiger-cup 3) at a rate of 40 litres per day. In this way, it was possible to keep the electrolysis cell, the amalgam decomposer and the Aussiger-cup free from deposits so that the cell did not have to be taken out of operation for several months.
It will be appreciated that the instant specification and examples are set forth by way of illustration and not limitation, and that various modifications and changes may be made without departing'from the spirit and scope of the present invention.
What is claimed is:
1. In the purification of mercury by contacting it with an aqueous medium to extract the impurities into the aqueous medium the improvement which comprises employing as said aqueous medium a solution of sulfuric acid having mercury (I) sulfate dissolved or suspended therein.
2. The processof claim 1 wherein the temperature is about 10 to 120C.
3. The process of claim 1 wherein the sulfuric acid solution is about 0.05 to 5 molar.
used in electrolysis installations which employ a verti- 7 ca] decomposer instead of a horizontal amalgam de- 4. The process of claim 1 wherein the mercury is turbulently mixed with the sulfuric acid solution.
5. The process of claim 4 wherein the temperature is about 20 to C and the sulfuric acid solution is about 0.1 to 1 molar.
6. The process of claim 5 wherein the impure mercury is obtained by decomposition of an amalgam formed during electrolysis of an alkali metal chloride in a cell containing mercury, and the purified mercury is thereafter returned to said cell.
Claims (6)
1. IN THE PURIFICATION OF MERCURY BY CONTACTING IT WITH AN AQUEOUS MEDIUM TO EXTRACT THE IMPURITIES INTO THE AQUEOUS MEDIUM THE IMPROVEMENT WHICH COMPRISES EMPLOYING AS SAID AQUEOUS MEDIUM A SOLUTION OF SULFURIC ACID HAVING MERCURY (I) SULFATE DISSOLVED OR SUSPENDED THEREIN.
2. The process of claim 1 wherein the temperature is about 10* to 120*C.
3. The process of claim 1 wherein the sulfuric acid solution is about 0.05 to 5 molar.
4. The process of claim 1 wherein the mercury is turbulently mixed with the sulfuric acid solution.
5. The process of claim 4 wherein the temperature is about 20* to 100*C and the sulfuric acid solution is about 0.1 to 1 molar.
6. The process of claim 5 wherein the impure mercury is obtained by decomposition of an amalgam formed during electrolysis of an alkali metal chloride in a cell containing mercury, and the purified mercury is thereafter returned to said cell.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2304063A DE2304063A1 (en) | 1973-01-27 | 1973-01-27 | METHOD FOR CLEANING UP MERCURY |
Publications (1)
Publication Number | Publication Date |
---|---|
US3895938A true US3895938A (en) | 1975-07-22 |
Family
ID=5870154
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US43332474 Expired - Lifetime US3895938A (en) | 1973-01-27 | 1974-01-14 | Purification of mercury |
Country Status (9)
Country | Link |
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US (1) | US3895938A (en) |
JP (1) | JPS49110529A (en) |
AT (1) | ATA62474A (en) |
BE (1) | BE810151A (en) |
DE (1) | DE2304063A1 (en) |
FR (1) | FR2215479B1 (en) |
GB (1) | GB1425670A (en) |
IT (1) | IT1002769B (en) |
NL (1) | NL7400989A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4012297A (en) * | 1976-01-16 | 1977-03-15 | Basf Wyandotte Corporation | Mercury recovery and recycle process |
EP0148023A2 (en) * | 1983-12-30 | 1985-07-10 | MONTEDIPE S.p.A. | Process for the purification of mercury |
WO2002046717A2 (en) * | 2000-12-05 | 2002-06-13 | Ionguard Ltd. | Recycling and purification of dropping mercury electrode |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4339794C2 (en) * | 1993-11-16 | 1996-07-11 | Werec Gmbh Berlin Wertstoff Re | Process for the treatment of waste / residues containing amalgam |
CN113604674A (en) * | 2021-08-23 | 2021-11-05 | 云南金鼎锌业有限公司 | Synergistic waste mercury regeneration technology and soaking precipitation pool thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2032602A (en) * | 1934-02-24 | 1936-03-03 | Sun Oil Co | Process for purifying mercury |
US2846305A (en) * | 1954-04-05 | 1958-08-05 | American Cyanamid Co | Separation and recovery of mercury |
US3437476A (en) * | 1965-08-26 | 1969-04-08 | Dow Chemical Co | Process for purifying mercury |
US3639118A (en) * | 1970-05-22 | 1972-02-01 | Dow Chemical Co | Process for purifying mercury |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR735855A (en) * | 1931-04-30 | 1932-11-16 | Process for the purification of mercury used as a cathode in electrolysis processes | |
FI45767C (en) * | 1970-07-03 | 1972-09-11 | Outokumpu Oy | Method for removing and recovering mercury and / or selenium from mercury and / or selenium-containing gases. |
-
1973
- 1973-01-27 DE DE2304063A patent/DE2304063A1/en active Pending
-
1974
- 1974-01-14 US US43332474 patent/US3895938A/en not_active Expired - Lifetime
- 1974-01-24 NL NL7400989A patent/NL7400989A/xx unknown
- 1974-01-25 FR FR7402603A patent/FR2215479B1/fr not_active Expired
- 1974-01-25 JP JP1031674A patent/JPS49110529A/ja active Pending
- 1974-01-25 IT IT4793474A patent/IT1002769B/en active
- 1974-01-25 AT AT62474A patent/ATA62474A/en not_active IP Right Cessation
- 1974-01-25 GB GB348674A patent/GB1425670A/en not_active Expired
- 1974-01-25 BE BE140167A patent/BE810151A/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2032602A (en) * | 1934-02-24 | 1936-03-03 | Sun Oil Co | Process for purifying mercury |
US2846305A (en) * | 1954-04-05 | 1958-08-05 | American Cyanamid Co | Separation and recovery of mercury |
US3437476A (en) * | 1965-08-26 | 1969-04-08 | Dow Chemical Co | Process for purifying mercury |
US3639118A (en) * | 1970-05-22 | 1972-02-01 | Dow Chemical Co | Process for purifying mercury |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4012297A (en) * | 1976-01-16 | 1977-03-15 | Basf Wyandotte Corporation | Mercury recovery and recycle process |
EP0148023A2 (en) * | 1983-12-30 | 1985-07-10 | MONTEDIPE S.p.A. | Process for the purification of mercury |
EP0148023A3 (en) * | 1983-12-30 | 1985-11-21 | Montedison S.P.A. | Process for the purification of mercury |
WO2002046717A2 (en) * | 2000-12-05 | 2002-06-13 | Ionguard Ltd. | Recycling and purification of dropping mercury electrode |
WO2002046717A3 (en) * | 2000-12-05 | 2003-05-01 | Ionguard Ltd | Recycling and purification of dropping mercury electrode |
Also Published As
Publication number | Publication date |
---|---|
JPS49110529A (en) | 1974-10-21 |
GB1425670A (en) | 1976-02-18 |
IT1002769B (en) | 1976-05-20 |
DE2304063A1 (en) | 1974-08-01 |
BE810151A (en) | 1974-07-25 |
FR2215479B1 (en) | 1977-09-23 |
NL7400989A (en) | 1974-07-30 |
ATA62474A (en) | 1976-03-15 |
FR2215479A1 (en) | 1974-08-23 |
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