US3895909A - Process for thermosol dyeing of polyester fabrics - Google Patents
Process for thermosol dyeing of polyester fabrics Download PDFInfo
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- US3895909A US3895909A US367360A US36736073A US3895909A US 3895909 A US3895909 A US 3895909A US 367360 A US367360 A US 367360A US 36736073 A US36736073 A US 36736073A US 3895909 A US3895909 A US 3895909A
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- Prior art keywords
- infrared
- thermosoling
- polyester
- oven
- belt
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- 229920000728 polyester Polymers 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000004043 dyeing Methods 0.000 title claims abstract description 11
- 230000008569 process Effects 0.000 title claims description 13
- 239000004744 fabric Substances 0.000 title description 13
- 238000010791 quenching Methods 0.000 claims abstract description 15
- 239000010453 quartz Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000000171 quenching effect Effects 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 32
- 238000001035 drying Methods 0.000 claims description 7
- 230000006872 improvement Effects 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 230000000452 restraining effect Effects 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920013683 Celanese Polymers 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 4
- 229920004934 Dacron® Polymers 0.000 description 3
- -1 Polyethylene Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000009980 pad dyeing Methods 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101150006573 PAN1 gene Proteins 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 238000009977 space dyeing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- ZHXAZZQXWJJBHA-UHFFFAOYSA-N triphenylbismuthane Chemical compound C1=CC=CC=C1[Bi](C=1C=CC=CC=1)C1=CC=CC=C1 ZHXAZZQXWJJBHA-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2083—Thermic treatments of textile materials heating with IR or microwaves
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
- D06B19/0005—Fixing of chemicals, e.g. dyestuffs, on textile materials
- D06B19/007—Fixing of chemicals, e.g. dyestuffs, on textile materials by application of electric energy
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/922—Polyester fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/93—Pretreatment before dyeing
- Y10S8/931—Washing or bleaching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/933—Thermosol dyeing, thermofixation or dry heat fixation or development
Definitions
- Infrared fixation of dyed polyester/cotton fabrics is known in the art and is disclosed in U.S. Pat. No. 3,576,589. Infrared fixation is also used on other cellulosic textiles as evidenced by U.S. Pat. Nos. 2,992,878; 2,961,288; 3,101,236 and 3,233,961.
- polyesters dyed by these infrared thermosoling processes still exhibit crocking problems, impermissible elongation of the polyester fabric and shiny or inadequate shading.
- thermosoling to eliminate crocking and reduce the elongation to a permissible level.
- the above objects are attained by passing the polyester material to be dyed under tension into a two-zoned infrared oven after the dyeing step, and subsequently quenching the material after it emerges from the oven while still under tension and before it contacts any holding or restraining rolls.
- the two-zoned infrared oven allows more uniform heat control and better thermosoling over prior art methods.
- the immediate cold quench is necessary while the polyester material is still under the tension provided by the restraining rolls and before the polyester cools in order to avoid crocking,
- a further advantage of the present invention lies in the ability to stop the moving polyester in the oven without having the polyester break due to melting.
- conventional hot air thermosoling on polyester materials stopped in the oven results in the material being melted into two pieces which not only hurts the quality of the material, but also results in a considerable waste of material.
- polyesters or polyester blends may be used in the present invention and can be described as synthetic polymers composed from an ester of a dihydric alcohol and terephthalic acid.
- examples of some commercial polyesters are Dacron, Fortrel and Kodel. Such polyesters are used for tire fabrics, seat belts, clothing fabrics and other various uses.
- the present invention is particularly suitable for polyester seat belts which must meet strict elongation and quality dyeing standards.
- the polyesters to be dyed and the particular dyes used in the present invention are not critical to the present invention and various suitable dyes and polyesters are well known in the art.
- any suitable infrared source may be used in the present invention so long as it can raise the temperature of polyester up toat least 425F.
- the preferred infrared source is composed of a series of multiple infrared quartz lamps commercially available and known as infrared quartz rods.
- FIG. 1 Apparatus suitable for carrying out the present invention is shown in the FIGURE.
- the material to be dyed is taken off a supply roll not shown or from other processing equipment.
- the material 10 is fed into a dyeing apparatus which may be any suitable type of apparatus, such as pad dyeing, space dyeing, etc.
- Shown in the FIGURE is a pad dyeing apparatus having a pad pan 1 and pad rolls 2.
- the material 10 is subsequently fed into pre-dryer 3 and then onto hot dry cans 4.
- the infrared thermosoling is accomplished in an infrared oven having two controlled zones which employ any suitable infrared heat source 12.
- the preferred embodiment uses a multiple infrared source 12 comprising quartz rods.
- the first zone is controlled by any suitable mechanism to bring the material 10 up to thermosoling temperature, i.e., 400F.
- the preferred apparatus employs a radiometer 9 to control the temperature of the oven and material 10 in the first zone.
- the second zone is controlled by radiometer 11 in order to keep the material 10 at a constant thermosoling temperature.
- the first zone is preferably controlled to bring the polyester up to a temperature in the range of about 400F to about 410F and while in the second zone the material 10 is preferably held at the thermosoling temperature of about 400F.
- the temperature of the textile material may be generally controlled in the range of about 380F to about 425F.
- the infrared oven may be constructed out of I-beams 6 and 7 from which are suspended the infrared sources 12 and suitable control mechanisms.
- the I-beams 6 and 7 separate the two sets of restraining rolls 5 and 8 in order to maintain the tension on the material 10 as it passes through the infrared oven.
- the material 10 is subjected to a cold spray or quench 13.
- the material may be submerged in a separate quench bath or merely sprayed with a cold inert liquid such as water. It is preferred to use a cold water spray 13 having a detergent added to the water and a drain 14 so that the material I0 can pass in a straight line in and out of the oven without touching a hot roll.
- plain cold water may be used, it is preferred to use a water solution containing a surfactant to attain uniform quenching.
- a surfactant may be used such as anionic, cationic or nonionic surfactants.
- anionic, cationic or nonionic surfactants Especially preferred are any of the commercially available detergents.
- the immediate, cold quenching by spraying on a cold water-detergent solution is applied to the polyester while it is still hot just as it emerges from the second or holding zone. This quenching takes place before the polyester contacts the last set of exit holding rolls, while the polyester is still under tension.
- washing box apparatus 18 The material then travels around the second set of restraining rolls 8 and into a washing box apparatus 18. Washing means 18 is divided up into separate compartments to accomplish various well known washing and rinsing steps. Squeeze rolls 19 are provided where necessary.
- the material 10 finally passes through a drying means, such as drying cans 20, and onto further manufacturing processes or a reel. After washing through the usual wash boxes 18 using only plain hot water, followed by drying on dry cans, the following excellent results are achieved:
- 300 pounds pull is on the spring, but the belt is stiff and damaged by the heat. With 200 pounds pull on each belt as it enters the oven at 410F, the polyester belt is set so it does not shrink during thermosoling. The elongation with 300 pounds pull is about 5%.
- thermosoling was carried out by passing the predried belt through a set of restraining rolls, into a radiometer controlled infrared electric quartz rod oven which is in two zones.
- the first zone is used to heat the belt up to 400F, i.e., the thermosoling temperature.
- a thermocouple was inserted into the belt to determine how long it takes to heat the belt to a thermosoling temperature of 400F in a hot air and in an infrared oven:
- thermosoling In the conventional hot air oven it requires 90 seconds exposure to 400F to complete the thermosoling after the belt has first been raised to 400F. Thermocouples injected into the belt were used to measure these temperatures and an accurate stopwatch was used to measure the time of exposure.
- thermosoled in a conventional hot air thermosol gas-fired oven was thermosoled in a conventional hot air thermosol gas-fired oven; the belt passed over 24 hot stainless steel rolls while in the oven. Exposure time in the oven was 4 minutes, 55 seconds. The belt then emerges out of the oven, passes over the restraining rolls, then down to a cold water wash box.
- the shade on the hot air thermosoled belt was much lighter and more shiny as compared to the belt from the infrared thermosoled oven. Viewed at certain angles, the black of the infrared thermosoling appears about 40% deeper than the belt pulled through the hot air oven that had 25% more dye padded on the belt grams/liter).
- the infrared thermosoled belt was then checked for elongation and thickness. It had a very low elongation (4%). The tensile strength was 6250 pounds. Light fastness was good slight break only after I50 hours exposure to the Fadometer.
- the speed of the machine shown in the FIGURE was set at l8 yds/min. The following steps were then con- 4) Hot Wash Box I 5) Tumbling hoil wash Box 2 6) Tumbling boil wash Box 3 7) Hot water wash Box 4 8) Hot water wash Box 5 9) Hot water wash Box 6 l0) Warm water wash spray Box 7 l l) Squeeze Apply finish Dry on dry cans graduated temperature
- the conventional procedure included a stripping agent of caustic 25 gr/l. and hydrosulphite soda 25 gr/l. at 140F. in boxes No. 2 and No. 3.
- Pad No. l pressure 50 lbs.
- Pad No. 2 pressure 50 lbs.
- thermosoling the polyester material in an infrared oven under tension and subsequently quenching the polyester after the thermosoling but before the polyester material contacts any holding or restraining roll.
- thermosoling is accomplished by means of multiple infrared quartz rods.
- thermosoling is controlled by at least one radiometer.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Treatment Of Fiber Materials (AREA)
- Coloring (AREA)
Abstract
Method and apparatus for thermosol dyeing polyesters where the thermosoling is accomplished by a two-zone infrared oven having multiple infrared quartz rods and employing at least two radiometers to control the temperature followed by an immediate quenching step, all while the polyester is still under tension.
Description
[ July 22, 1975 United States Patent Greer PROCESS FOR THERMOSOL DYEING OF thetic Fibers, (1963), Chapman & Hall Ltd, London,
POLYESTER FABRICS [75] Inventor: James E. Greer, Greensboro, NC. Rayon and Synthetic Textiles. August 1950, p. 62. 1
Burlington Industries, Inc., Greensboro, NC. June 6, 1973 Appl. No.5 367,360
Review of Textile Progress," (The Textile Institute) p. 370, V. 15 (1963).
{73] Assignee:
Primary Examinen-Benjamin R. Padgett Assistant Examiner-:David Leland [22] Filed:
' y I Attorney, Agent, or FirmCushman, Darby & [52] US. CI. 8/176; 8/2; 68/5 D;
T C A R T S B A n a m w 1 7 m w us w zw E 5 5 8 00 6 6 ".1 m6 m3 m0 5 Wu C "P. a 8 ms in n e .mm 1] 8 55 Method and apparatus for thermosol dyeing polyesters where the thermosoling is accomplished by a two-zone infrared oven having multiple infrared quartz rods and [56] References Cited UNITED STATES PATENTS 5 D employing at least two radiometers to control the tem- 68/5 1) perature followed by an immediate quenching step, all Oberholtzer..........,............... 68/5 D while the polyester is still under tension.
1,403,126 1/1922 2,613,522 10/1952 Heffelfinger...... 3,619,831 11/1971 OTHER PUBLICATIONS 3 Cl l D F The Preparation and Dyeing of Synaims rawmg H. U. Schmidlin PROCESS FOR THERMOSOL DYEING OF POLYESTER FABRICS BACKGROUND OF THE INVENTION The present invention relates to the thermosoling of dyed polyester in the form of, for example, seat belts, tapes, ribbons and narrow fabrics.
Infrared fixation of dyed polyester/cotton fabrics is known in the art and is disclosed in U.S. Pat. No. 3,576,589. Infrared fixation is also used on other cellulosic textiles as evidenced by U.S. Pat. Nos. 2,992,878; 2,961,288; 3,101,236 and 3,233,961.
However, polyesters dyed by these infrared thermosoling processes still exhibit crocking problems, impermissible elongation of the polyester fabric and shiny or inadequate shading.
It is, therefore, an object of this invention to improve infrared thermosoling to eliminate crocking and reduce the elongation to a permissible level.
It is also an object of the invention to improve the depth of the dyed shade of the polyester.
DESCRIPTION OF THE INVENTION The above objects are attained by passing the polyester material to be dyed under tension into a two-zoned infrared oven after the dyeing step, and subsequently quenching the material after it emerges from the oven while still under tension and before it contacts any holding or restraining rolls. The two-zoned infrared oven allows more uniform heat control and better thermosoling over prior art methods. The immediate cold quench is necessary while the polyester material is still under the tension provided by the restraining rolls and before the polyester cools in order to avoid crocking,
glazed shade and minimize elongation problems. A further advantage of the present invention lies in the ability to stop the moving polyester in the oven without having the polyester break due to melting. In contrast, conventional hot air thermosoling on polyester materials stopped in the oven results in the material being melted into two pieces which not only hurts the quality of the material, but also results in a considerable waste of material.
All types of conventional polyesters or polyester blends may be used in the present invention and can be described as synthetic polymers composed from an ester of a dihydric alcohol and terephthalic acid. Examples of some commercial polyesters are Dacron, Fortrel and Kodel. Such polyesters are used for tire fabrics, seat belts, clothing fabrics and other various uses. The present invention is particularly suitable for polyester seat belts which must meet strict elongation and quality dyeing standards. The polyesters to be dyed and the particular dyes used in the present invention are not critical to the present invention and various suitable dyes and polyesters are well known in the art.
Any suitable infrared source may be used in the present invention so long as it can raise the temperature of polyester up toat least 425F. The preferred infrared source is composed of a series of multiple infrared quartz lamps commercially available and known as infrared quartz rods.
Apparatus suitable for carrying out the present invention is shown in the FIGURE. The material to be dyed is taken off a supply roll not shown or from other processing equipment. The material 10 is fed into a dyeing apparatus which may be any suitable type of apparatus, such as pad dyeing, space dyeing, etc. Shown in the FIGURE is a pad dyeing apparatus having a pad pan 1 and pad rolls 2. The material 10 is subsequently fed into pre-dryer 3 and then onto hot dry cans 4.
The infrared thermosoling is accomplished in an infrared oven having two controlled zones which employ any suitable infrared heat source 12. The preferred embodiment uses a multiple infrared source 12 comprising quartz rods. The first zone is controlled by any suitable mechanism to bring the material 10 up to thermosoling temperature, i.e., 400F. The preferred apparatus employs a radiometer 9 to control the temperature of the oven and material 10 in the first zone. The second zone is controlled by radiometer 11 in order to keep the material 10 at a constant thermosoling temperature.
The first zone is preferably controlled to bring the polyester up to a temperature in the range of about 400F to about 410F and while in the second zone the material 10 is preferably held at the thermosoling temperature of about 400F. However, depending on the required properties of the fabric and dye the temperature of the textile material may be generally controlled in the range of about 380F to about 425F.
For convenience, the infrared oven may be constructed out of I-beams 6 and 7 from which are suspended the infrared sources 12 and suitable control mechanisms. The I-beams 6 and 7 separate the two sets of restraining rolls 5 and 8 in order to maintain the tension on the material 10 as it passes through the infrared oven.
Following the infrared oven, the material 10 is subjected to a cold spray or quench 13. The material may be submerged in a separate quench bath or merely sprayed with a cold inert liquid such as water. It is preferred to use a cold water spray 13 having a detergent added to the water and a drain 14 so that the material I0 can pass in a straight line in and out of the oven without touching a hot roll.
Although plain cold water may be used, it is preferred to use a water solution containing a surfactant to attain uniform quenching. Any suitable surfactant may be used such as anionic, cationic or nonionic surfactants. Especially preferred are any of the commercially available detergents. The immediate, cold quenching by spraying on a cold water-detergent solution is applied to the polyester while it is still hot just as it emerges from the second or holding zone. This quenching takes place before the polyester contacts the last set of exit holding rolls, while the polyester is still under tension. When this is done the loose dyestuffs, the thickeners in the dye solution, and the dispersing agents if present in the dispersed dyes, simply boil off the very hot belt which is at a temperature of about 4()()F to about 4l()F.
The material then travels around the second set of restraining rolls 8 and into a washing box apparatus 18. Washing means 18 is divided up into separate compartments to accomplish various well known washing and rinsing steps. Squeeze rolls 19 are provided where necessary. The material 10 finally passes through a drying means, such as drying cans 20, and onto further manufacturing processes or a reel. After washing through the usual wash boxes 18 using only plain hot water, followed by drying on dry cans, the following excellent results are achieved:
a. Excellent crock fastness, both wet and dry b. Deep full shades such as a very deep black which is most difficult to dye by conventional hot air thermosol methods.
c. Excellent elongation results of 4 to 9% are achieved without the serious difficulty encountered when using conventional hot air thermosoling methods.
d. Soft flexible hand is obtained on polyester seat belting. This is much more desirable than stiff belting material obtained when conventional hot air thermosol roller oven is used.
e. Full, non-shiny, dull deep shades were obtained by the present method, whereas polyester belt with the same dye padding solution dyed in a conventional hot air, roller thermosol oven showed a very distinct drop in shade of the black.
The present invention is further illustrated by the following examples:
EXAMPLE 1 Celanese Fortrel polyester belt material was padded thickened with 20 grams/liter Superclear gum. The temperature of the padding was l60F. This belt was pre-dried and then dried on dry cans. The dye liquor wet pickup was calculated and measured by weighing the belt before padding and after padding. The pickup was 34% of the 100 grams/liter of Estracyl Black GLH. In order to determine the best tension conditions for thermosoling, the dried belt with the unfixed dye was then mounted in a frame that had a pair of spring scales connected by a double pulley to one end. The other end was fixed to the frame. The frame and belt were then put into an electric oven at 400F; another piece was also exposed at 380F; and still another at 425F. The amount of tension on the contracting belt was then recorded. Exposure time was 4% minutes.
At 380F, 100 pounds tension is on the spring.
At 400F, 200 pounds pull is on the spring.
At 425F, 300 pounds pull is on the spring, but the belt is stiff and damaged by the heat. With 200 pounds pull on each belt as it enters the oven at 410F, the polyester belt is set so it does not shrink during thermosoling. The elongation with 300 pounds pull is about 5%.
The thermosoling was carried out by passing the predried belt through a set of restraining rolls, into a radiometer controlled infrared electric quartz rod oven which is in two zones. The first zone is used to heat the belt up to 400F, i.e., the thermosoling temperature. A thermocouple was inserted into the belt to determine how long it takes to heat the belt to a thermosoling temperature of 400F in a hot air and in an infrared oven:
1. In a radiometer controlled infrared oven it takes 9 seconds to raise the belt to 400F.
2. In a conventional hot air oven it takes 3 minutes to raise the belt to 400F.
3. In a radiometer controlled infrared oven it requires 16 seconds exposure to 400F to complete the oven thermosoling of the color and full development of the shade.
4. In the conventional hot air oven it requires 90 seconds exposure to 400F to complete the thermosoling after the belt has first been raised to 400F. Thermocouples injected into the belt were used to measure these temperatures and an accurate stopwatch was used to measure the time of exposure.
Whilegthe belt was passing through the radiometer controlled two-zone infrared oven, careful control of the voltage was maintained in the infrared quartz rods so the desired temperature would be maintained. Four hundred volts were maintained in the first section. The temperature was measured with an infrared radiometer reading at the 5 micron range. The belt. now up to 4l()F-, was passed continuously into the next section where the voltage through the infrared quartz rods was modulated to 150-200 volts by a second infrared radiometer holding the temperature at 400F for 16 seconds exposure. This gave full, complete development of the dye. While the belt was still under tension and before it was passed around the second set of restraining rolls, a spray of cold water was directed onto the 400F. belt.
For comparison a belt was thermosoled in a conventional hot air thermosol gas-fired oven; the belt passed over 24 hot stainless steel rolls while in the oven. Exposure time in the oven was 4 minutes, 55 seconds. The belt then emerges out of the oven, passes over the restraining rolls, then down to a cold water wash box. The shade on the hot air thermosoled belt was much lighter and more shiny as compared to the belt from the infrared thermosoled oven. Viewed at certain angles, the black of the infrared thermosoling appears about 40% deeper than the belt pulled through the hot air oven that had 25% more dye padded on the belt grams/liter). The infrared thermosoled belt was then checked for elongation and thickness. It had a very low elongation (4%). The tensile strength was 6250 pounds. Light fastness was good slight break only after I50 hours exposure to the Fadometer.
If the black dispersed dye concentration is increased in the conventional hot air process'to compensate for the loss of depth, then the crock fastness becomes unacceptably worse. Repeated scouring with caustic soda/sodium hydrosulphite does not improve the crock fastness to the level of quality obtained by the infrared thermosoling. i I
A further sample was made using a grey'shade instead of the black. The results were similar showing that the radiometer controlled infrared oven is far superior to the gas-fired oven. In place of the polyester belt material, fragile polyester ribbon materials of 4 to 1 Va widths were also successfully run through the infrared oven. Green and red dyes were also employed with similar successful results. Optimum accuracy of the radiometers is obtained if the radiometers are set to read in the 5 micron range. At this range the humidity, dye color and stray radiation or convection heat do not influence the accurate control of the temperature of the material.
It is very surprising and unexpected that experiments showed such excellent results for infrared thermosoling without the usual caustic soda/sodium hydrosulphite baths that are used in the conventional hot air roller oven thermosol procedure. All the desirable properties in polyester seat belting, full deep shades, dull and not shiny, soft hand and excellent crocking fastness, and excellent low elongation were obtained in one pass through the infrared thermosoling process. Excellent fight fastness also is obtained. For example, blacks were dyed that showed hours light fastness in a weatherometer with no more than a trace of a break. Blues, greens, and other colors were also dyed with excellent light fastness results. Using conventional hot air ther- EXAMPLE 2 The following experiments were conducted to show the comparison of conventional thermosoling, the pres ent infrared thermosoling, and the present infrared thermosoling without the quench treatment. Both du- Pont Dacron and Celanese Fortrel polyesters were run in the following processes. For the duPont fabric, 7.500 grams of Estracyl Black GLH. 200 grams of Mannotex RS (thickening agent) and 25 cc of acetic acid were mixed to form an 80 liter dye solution. For the Celanese Fortrel fabric, 10,000 grams of Estracyl Black GLH, 200 grams of Mannotex RS and 25 cc of acetic acid were mixed to make 80 liters of a dye solution. The speed of the machine shown in the FIGURE was set at l8 yds/min. The following steps were then con- 4) Hot Wash Box I 5) Tumbling hoil wash Box 2 6) Tumbling boil wash Box 3 7) Hot water wash Box 4 8) Hot water wash Box 5 9) Hot water wash Box 6 l0) Warm water wash spray Box 7 l l) Squeeze Apply finish Dry on dry cans graduated temperature The conventional procedure included a stripping agent of caustic 25 gr/l. and hydrosulphite soda 25 gr/l. at 140F. in boxes No. 2 and No. 3. Samples of the conventionally thermosoledhydro/caustic stripped polyester were checked (both Dacron and Fortrel) for Conventional (3C) Hot air oven Infrared (3A) Oven Spray Infrared (38) Therrnosol Cold detergent Without 100 yd. oven water quenched quench in 150 yd. steamer under tension cold water detergent DuPont Celanese DuPont Celanese DuPont Celanese Crocking Dry Poor Poor OK OK Poor Poor Wet Poor Poor OK OK Poor Poor Buckle Abrasion A) With Polyethylene OK OK OK OK OK OK (Polyethylene Emulsion 6OG/L padded on wet. Aerotex softner TFL) B) Without Makes Crocking Does Not Hurt Makes Crocking Worse Cracking Worse Abrades Abrades OK OK Abrades Ahrades C) With Silicone Makes Crocking Does Not Hurt Makes Crocking Worse Crockin Worse D) With Rhoplex Makes Crocking Does Not I -Iurt Makes Crocking Worse Crocking Worse E) With Rhoplex Makes Crocking Does Not Hurt Makes Crocking and Polyethylene Worse Crocking Worse (mixed 60 gr.
each per liter) ducted on each of the fabrics:
I) Pad No. l pressure 50 lbs. Pad No. 2 pressure 50 lbs. Temperature (pad) l55F.
Gas fired pre-dry 4 burners Thermosoling A. Infrared oven of 48 Westinghouse T 16 rods 100 watts/inch and then spray the hot belt as it emerges from oven with a cold detergent solution of (Mikon N0. l0) Tetrasodium pyrophosphate) grams l0 grams 1000 cc (liter) Thus, it is clear that the infrared thermosoling with the quench treatment while the fabric is still under tension produces superior and unexpected results over conventional hot-air thermosoling and infrared thermosoling without the quench.
What is claimed is:
1. In a process for dyeing, drying, thermosoling, washing and drying a polyester material, the improvement comprising thermosoling the polyester material in an infrared oven under tension and subsequently quenching the polyester after the thermosoling but before the polyester material contacts any holding or restraining roll.
2. A process according to claim 1, wherein the infrared thermosoling is accomplished by means of multiple infrared quartz rods.
3. A process according to claim 1 wherein the temperature in the infrared thermosoling is controlled by at least one radiometer.
Claims (3)
1. IN A PROCESS FOR DYEING DRYING THERMOSOLING WASHING AND DRYING A POLYESTER MATERIAL THE IMPROVEMENT COMPRISING THERMOSOLING THE POLYESTER MATERIAL IN AN INFRARED OVEN UNDER TENSION AND SUBSEQUENTLY QUENCHING THE POLYESTER AFTER THE THERMOSOLING BUT BEFORE THE POLYESTER MATERIAL CONTACTS ANY HOLDING OR RESTRINING ROLL.
2. A process according to claim 1, wherein the infrared thermosoling is accomplished by means of multiple infrared quartz rods.
3. A process according to claim 1 wherein the temperature in the infrared thermosoling is controlled by at least one Radiometer.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US367360A US3895909A (en) | 1973-06-06 | 1973-06-06 | Process for thermosol dyeing of polyester fabrics |
CA198,113A CA1051615A (en) | 1973-06-06 | 1974-04-25 | Process for thermosol dyeing of polyester fabrics |
US05/533,164 US3973417A (en) | 1973-06-06 | 1974-12-16 | Apparatus for thermosol dyeing of polyester fabrics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US367360A US3895909A (en) | 1973-06-06 | 1973-06-06 | Process for thermosol dyeing of polyester fabrics |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/533,164 Division US3973417A (en) | 1973-06-06 | 1974-12-16 | Apparatus for thermosol dyeing of polyester fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
US3895909A true US3895909A (en) | 1975-07-22 |
Family
ID=23446848
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US367360A Expired - Lifetime US3895909A (en) | 1973-06-06 | 1973-06-06 | Process for thermosol dyeing of polyester fabrics |
Country Status (2)
Country | Link |
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US (1) | US3895909A (en) |
CA (1) | CA1051615A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4534120A (en) * | 1983-11-02 | 1985-08-13 | Wakayama Iron Works, Ltd. | Dryer for a continuous textile fabric |
US5634226A (en) * | 1993-04-03 | 1997-06-03 | Sandoz Ltd. | Apparatus and process for the continuous dyeing of mesh material |
US6071835A (en) * | 1998-06-16 | 2000-06-06 | Alliedsignal Inc. | Load limiting webbing |
US6228488B1 (en) | 1998-05-22 | 2001-05-08 | Alliedsignal Inc. | Process for making load limiting yarn |
WO2002000985A2 (en) * | 2000-06-26 | 2002-01-03 | Breed Automotive Technology, Inc. | Seat belt webbing and method of dyeing same |
US6425926B1 (en) * | 1999-05-04 | 2002-07-30 | Jakobus Hindriks | Thermosol treatment of textiles carrying a dye |
US11591748B2 (en) | 2020-01-14 | 2023-02-28 | Shadow Works, Llc | Heat treated multilayer knitted textile of liquid crystal polymer fibers and modified polyacrylonitrile fibers, and process for making same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1403126A (en) * | 1919-02-10 | 1922-01-10 | Lyth John James | Method of and apparatus for transporting and impregnating material |
US2613522A (en) * | 1949-09-14 | 1952-10-14 | American Viscose Corp | Apparatus for treating fabrics and uncurling the edges thereof |
US3619831A (en) * | 1969-05-29 | 1971-11-16 | O B Dyers Inc | Process for avoiding creases in tubular knit acrylic fabrics |
-
1973
- 1973-06-06 US US367360A patent/US3895909A/en not_active Expired - Lifetime
-
1974
- 1974-04-25 CA CA198,113A patent/CA1051615A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1403126A (en) * | 1919-02-10 | 1922-01-10 | Lyth John James | Method of and apparatus for transporting and impregnating material |
US2613522A (en) * | 1949-09-14 | 1952-10-14 | American Viscose Corp | Apparatus for treating fabrics and uncurling the edges thereof |
US3619831A (en) * | 1969-05-29 | 1971-11-16 | O B Dyers Inc | Process for avoiding creases in tubular knit acrylic fabrics |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4534120A (en) * | 1983-11-02 | 1985-08-13 | Wakayama Iron Works, Ltd. | Dryer for a continuous textile fabric |
US5634226A (en) * | 1993-04-03 | 1997-06-03 | Sandoz Ltd. | Apparatus and process for the continuous dyeing of mesh material |
US6228488B1 (en) | 1998-05-22 | 2001-05-08 | Alliedsignal Inc. | Process for making load limiting yarn |
US6340524B1 (en) | 1998-05-22 | 2002-01-22 | Alliedsignal Inc. | Process for making load limiting yarn |
US6613257B2 (en) | 1998-05-22 | 2003-09-02 | Alliedsignal Inc. | Process for making load limiting yarn |
US6071835A (en) * | 1998-06-16 | 2000-06-06 | Alliedsignal Inc. | Load limiting webbing |
US6425926B1 (en) * | 1999-05-04 | 2002-07-30 | Jakobus Hindriks | Thermosol treatment of textiles carrying a dye |
WO2002000985A2 (en) * | 2000-06-26 | 2002-01-03 | Breed Automotive Technology, Inc. | Seat belt webbing and method of dyeing same |
WO2002000985A3 (en) * | 2000-06-26 | 2002-05-30 | Breed Automotive Tech | Seat belt webbing and method of dyeing same |
US11591748B2 (en) | 2020-01-14 | 2023-02-28 | Shadow Works, Llc | Heat treated multilayer knitted textile of liquid crystal polymer fibers and modified polyacrylonitrile fibers, and process for making same |
Also Published As
Publication number | Publication date |
---|---|
CA1051615A (en) | 1979-04-03 |
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Owner name: CHEMICAL BANK A NY BANKING CORPORATION Free format text: LIEN;ASSIGNORS:BURLINGTON INDUSTRIES, INC., A DE CORPORATION;BURLINGTON FABRICS INC., A DE CORPORATION;B.I. TRANSPORTATION, INC.;REEL/FRAME:006054/0351 Effective date: 19920319 |