US3891820A - Weld-plating of steel - Google Patents

Weld-plating of steel Download PDF

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Publication number
US3891820A
US3891820A US281555A US28155572A US3891820A US 3891820 A US3891820 A US 3891820A US 281555 A US281555 A US 281555A US 28155572 A US28155572 A US 28155572A US 3891820 A US3891820 A US 3891820A
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Prior art keywords
weld
plating
steel
decarbonizing
carbon
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Expired - Lifetime
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US281555A
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Werner Debray
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Siemens AG
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Siemens AG
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D3/00Diffusion processes for extraction of non-metals; Furnaces therefor
    • C21D3/02Extraction of non-metals
    • C21D3/04Decarburising
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/24Preliminary treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/235Preliminary treatment

Definitions

  • the present invention relates to the process of weldplating workpieces of one metal with another metal.
  • Such weld-platings are often needed to make certain surfaces, for example, the inner walls of boilers, resistant to corrosion or to wear.
  • the chief fields of application are nuclear-reactor technology, processing technology in the chemical industry, and also the machine building industry.
  • One object of the present invention is to avoid the cracking described above and, in general, to weldplated parts made of steel containing enough carbon to be hardenable, with metals of another type, such as austenitic stainless steel. in an improved manner.
  • this object is attained by first surface decarbonizing the steel part, and then weld-plating the part.
  • the effect is that a relatively low carbon steel surface is weld-plated.
  • the weld-plating with austenitic stainless steel is facilitated.
  • the cracking of the steel surface subjected to the weldplating heat is avoided.
  • a pre-treatment which consists of decarbonizing the steel surface to be plated, to a depth of approximately 1 to 5 mm.
  • this decarbonizing operation can be effected by a heat treatment of up to l,O00C. maximum, and preferably from 800 to 900C, in a decarbonizing gas atmosphere.
  • Another possibility consists of coating the surface which is to be decarbonized with a l to 2 mm thick layer of a paste having a decarbonizing action, followed by a heat treatment in a protective-gas atmosphere at the aforesaid temperatures. with removal of the applied layer prior to the actual weld- 2 plating operation.
  • Gases effective in this process are the so-called forming gases, e.g., mixtures of nitrogen and 20% hydrogen, or a mixture of hydrogen, carbon dioxide and carbon monoxide, or a hydrogen-argon mixture or other combinations having the same effect.
  • the time needed for the decarbonizing depends on the carbon content of the steel, on the temperature used and on the hydrogen content or the decarbonizing power of the gas. The higher the temperature, the shorter the necessary heat treatment time.
  • Parts of the surface of the material that are not to be plated or decarbonized may be covered with suitable protective pastes, as is known from case-hardening technology.
  • the degree of decarbonization should be carried as far as possible.
  • a carbon-steel with 0.6% of carbon should have a surface layer containing less than 0.15% carbon.
  • a heating time of 5 hours is needed at a temperature of 900C.
  • the depth of decarbonization depends on the so-called penetration by burning during the plating process. The less this is, the less can be the decarbonizing depth, and the shorter the pre-treatment time.
  • Some parts to be weld-plated may be too large for the available decarbonizing furnace. Often these parts are fabricated from separate parts which are not individually too large. The separate parts may be processed as described hereinabove including the weld-plating, and the parts then welded together, the weld connections often being amenable to usual plating methods.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Arc Welding In General (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A steel base containing enough carbon to be heat-treatable or hardened is surface decarbonized prior to being weld-plated with another metal, such as austenitic stainless steel, to avoid cracking of the base from the welding heat.

Description

1 WELD-PLATING OF STEEL [75] Inventor:
[73] Assignee: Siemens Akliengesellschaft, Munich,
Germany [22] Filed: Aug. 17, 1972 [21] Appl. No; 281,555
Werner Debray, Erlangen. Germany [30] Foreign Application Priority Data Aug 25, 1971 Germany 2142461] [52] US. Cl. 219/76; 117/50; 148/16 [51] Int. Cl 323k 1/20 I58] Field of Search 148/13. 16.5.14 15.5. 148/161), 19. 34, 127, 16, 6.14; 117/50 49 51; 219/76 156] References Cited UNITED STATES PATENTS 1185.814 5/1965 Russncr c1211. 219/76 June 24, 1975 3,406,047 10/1968 Magor ct a1. 148/16 3.4993103 3/1970 Hcnrickson cl a1 l 1 1 l 148/34 3.607.458 9/1971 Hunsaker or al l 1 148/16 3.694271 9/1972 Egncll n 148/34 Primary Examiner-Charles E. Van Horn Axxismn! Examiner-Jerome W. Massie Attorney, Agent, or Firm-Kenyon & Kenyon Reilly Carr 84 Chapin [57 1 ABSTRACT A steel base containing enough carbon to he heatlreatable or hardened is surface decarbonized prior to being weld-plated with another metal, such as austenilic stainless steel, to avoid cracking of the base from the welding heat.
4 Claims, No Drawings WELD-PLATING OF STEEL BACKGROUND OF THE INVENTION The present invention relates to the process of weldplating workpieces of one metal with another metal. In particular it is concerned with weld-plating non-rusting or stainless austenitic steels or high-alloy wear resistant metals on workpieces made of hardenable or heat treatable steels which therefore contain appreciable amounts of carbon. Such weld-platings are often needed to make certain surfaces, for example, the inner walls of boilers, resistant to corrosion or to wear. The chief fields of application are nuclear-reactor technology, processing technology in the chemical industry, and also the machine building industry.
DESCRIPTION OF THE PRIOR ART The weld-plating process itself is extensively used. However, particularly in the case of the hardenable or heat-treatable steels, it is possible for cracking of the part being plated to occur in the region subjected to the influence of the heat, or cracking may occur after the plating operation. Under certain conditions this can impair the utility of the part. Furthermore. problems are encountered when the basic material and the plating material cannot be welded to one another by normal practices; for example, a buffering welding prior to the actual welding-plating may be necessary.
SUMMARY OF THE INVENTION One object of the present invention is to avoid the cracking described above and, in general, to weldplated parts made of steel containing enough carbon to be hardenable, with metals of another type, such as austenitic stainless steel. in an improved manner.
According to this invention. this object is attained by first surface decarbonizing the steel part, and then weld-plating the part. The effect is that a relatively low carbon steel surface is weld-plated. Particularly, the weld-plating with austenitic stainless steel is facilitated. The cracking of the steel surface subjected to the weldplating heat is avoided.
DESCRIPTION OF THE PREFERRED EMBODIMENTS In accordance with the invention, a pre-treatment is used which consists of decarbonizing the steel surface to be plated, to a depth of approximately 1 to 5 mm. For example, this decarbonizing operation can be effected by a heat treatment of up to l,O00C. maximum, and preferably from 800 to 900C, in a decarbonizing gas atmosphere. Another possibility consists of coating the surface which is to be decarbonized with a l to 2 mm thick layer of a paste having a decarbonizing action, followed by a heat treatment in a protective-gas atmosphere at the aforesaid temperatures. with removal of the applied layer prior to the actual weld- 2 plating operation.
Gases effective in this process are the so-called forming gases, e.g., mixtures of nitrogen and 20% hydrogen, or a mixture of hydrogen, carbon dioxide and carbon monoxide, or a hydrogen-argon mixture or other combinations having the same effect. The time needed for the decarbonizing depends on the carbon content of the steel, on the temperature used and on the hydrogen content or the decarbonizing power of the gas. The higher the temperature, the shorter the necessary heat treatment time. Parts of the surface of the material that are not to be plated or decarbonized may be covered with suitable protective pastes, as is known from case-hardening technology.
The degree of decarbonization should be carried as far as possible. For example, a carbon-steel with 0.6% of carbon should have a surface layer containing less than 0.15% carbon. In order to obtain a decarbonization from 0.2% down to 0.6%, for a depth of about 3 mm. a heating time of 5 hours is needed at a temperature of 900C. The depth of decarbonization depends on the so-called penetration by burning during the plating process. The less this is, the less can be the decarbonizing depth, and the shorter the pre-treatment time.
Extensive experimentation and testing of this new process have shown that subsequent cracking can definitely be avoided, and that the material to be plated does not need to be pre-tested as to the possibility of weld-plating it. This process thus offers not only purely technological advantages, but offers also substantially greater freedom of choice as to the basic material of the workpieces to be plated.
Some parts to be weld-plated may be too large for the available decarbonizing furnace. Often these parts are fabricated from separate parts which are not individually too large. The separate parts may be processed as described hereinabove including the weld-plating, and the parts then welded together, the weld connections often being amenable to usual plating methods.
I claim:
1. A process for weld-plating austenitic stainless steel on the surface of a hardenable carbon steel part; wherein the improvement comprises decarbonizing said surface and thereafter weld-plating the stainless steel thereon.
2. The process ofclaim l in which said decarbonizing is extended into said surface for a depth at least equal to the penetration of the surface by burning during said weld-plating.
3. The process of claim 2 in which said depth is approximately from I to 5 mm.
4. The process of claim 3 in which by said decarbonizing the carbon content of said carbon steel is reduced to less than 0.15% substantially throughout said depth.

Claims (4)

1. A PROCESS FOR WELD-PLATING AUSTENITIC STAINLESS STEEL ON THE SURFACE OF A HARDENABLE CARBON STEEL PART; WHEREIN THE IMPROVEMENT COMPRISES DECARBONIZING SAID SURFACE AND THEREAFTER WELD-PLATING THE STAINLESS STEEL THEREON.
2. The process of claim 1 in which said decarbonizing is extended into said surface for a depth at least equal to the penetration of the surface by burning during said weld-plating.
3. The process of claim 2 in which said depth is approximately from 1 to 5 mm.
4. The process of claim 3 in which by said decarbonizing the carbon content of said carbon steel is reduced to less than 0.15% substantially throughout said depth.
US281555A 1971-08-25 1972-08-17 Weld-plating of steel Expired - Lifetime US3891820A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2142460A DE2142460A1 (en) 1971-08-25 1971-08-25 PRE-TREATMENT FOR WELD CLADDING OF STEEL

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US (1) US3891820A (en)
JP (1) JPS4830648A (en)
CH (1) CH581002A5 (en)
DE (1) DE2142460A1 (en)
FR (1) FR2151392A5 (en)
GB (1) GB1397799A (en)
IT (1) IT964219B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4159918A (en) * 1977-07-20 1979-07-03 Klockner-Werke Ag Method of manufacturing a compound steel material of a high corrosion resistance
WO1999002298A1 (en) * 1997-07-11 1999-01-21 Ruhr Oel Gmbh Method for welding shaped bodies made of carburized heat-resistant steel
EP2596902A1 (en) * 2011-11-28 2013-05-29 General Electric Company Method for decarburization of a rotor forging
CN103443299A (en) * 2011-04-22 2013-12-11 爱信艾达株式会社 Complex steel component and production method therefor
CN103442837A (en) * 2011-04-22 2013-12-11 爱信艾达株式会社 Complex steel component and production method therefor

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS499450A (en) * 1972-05-27 1974-01-28
JPS5427810Y2 (en) * 1974-09-10 1979-09-08
US4317669A (en) * 1980-08-18 1982-03-02 Libbey-Owens-Ford Company Glass melting furnace having a submerged weir
JPS59185567A (en) * 1983-04-08 1984-10-22 Usui Internatl Ind Co Ltd Pretreatment of cast iron member joined by adhering
FR2733706B1 (en) * 1995-05-05 1997-07-18 Cogifer WELDING WITHOUT METAL SUPPLY OF CARBON STEEL WITH ALLOY STEEL, METHODS OF OBTAINING AND APPLICATION TO RAILWAY APPARATUSES
US6127046A (en) * 1997-12-04 2000-10-03 Cummins Engine Company, Inc. Formation of a graphite-free surface in a ferrous material to produce an improved intermetallic bond

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3185814A (en) * 1961-12-30 1965-05-25 Siemens Ag Method and apparatus for overlay welding
US3406047A (en) * 1966-02-07 1968-10-15 Wilson Eng Co Inc Lee Vitreous enameling steel and method of making same
US3499803A (en) * 1967-02-13 1970-03-10 United States Steel Corp Method of treating stainless steel
US3607458A (en) * 1968-05-13 1971-09-21 Dayton Malleable Iron Co The Weldable and wear resistant magnetic ferritic malleable iron and method
US3694271A (en) * 1970-06-30 1972-09-26 Sandvikens Jernverks Ab Method of producing articles of composite material,and resulting products

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3185814A (en) * 1961-12-30 1965-05-25 Siemens Ag Method and apparatus for overlay welding
US3406047A (en) * 1966-02-07 1968-10-15 Wilson Eng Co Inc Lee Vitreous enameling steel and method of making same
US3499803A (en) * 1967-02-13 1970-03-10 United States Steel Corp Method of treating stainless steel
US3607458A (en) * 1968-05-13 1971-09-21 Dayton Malleable Iron Co The Weldable and wear resistant magnetic ferritic malleable iron and method
US3694271A (en) * 1970-06-30 1972-09-26 Sandvikens Jernverks Ab Method of producing articles of composite material,and resulting products

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4159918A (en) * 1977-07-20 1979-07-03 Klockner-Werke Ag Method of manufacturing a compound steel material of a high corrosion resistance
WO1999002298A1 (en) * 1997-07-11 1999-01-21 Ruhr Oel Gmbh Method for welding shaped bodies made of carburized heat-resistant steel
US6307178B1 (en) * 1997-07-11 2001-10-23 Ruhr Oel Gmbh Method for welding shaped bodies made of carburized heat-resistant steel
CN103443299A (en) * 2011-04-22 2013-12-11 爱信艾达株式会社 Complex steel component and production method therefor
CN103442837A (en) * 2011-04-22 2013-12-11 爱信艾达株式会社 Complex steel component and production method therefor
CN103442837B (en) * 2011-04-22 2016-02-10 爱信艾达株式会社 The manufacture method of clad steel parts
CN103443299B (en) * 2011-04-22 2016-03-16 爱信艾达株式会社 Clad steel parts and manufacture method thereof
EP2596902A1 (en) * 2011-11-28 2013-05-29 General Electric Company Method for decarburization of a rotor forging

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JPS4830648A (en) 1973-04-23
CH581002A5 (en) 1976-10-29
FR2151392A5 (en) 1973-04-13
DE2142460A1 (en) 1973-03-01
GB1397799A (en) 1975-06-18
IT964219B (en) 1974-01-21

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