US3870531A - Optical flint glass with relatively low refractive indices and high dispersion - Google Patents
Optical flint glass with relatively low refractive indices and high dispersion Download PDFInfo
- Publication number
- US3870531A US3870531A US272628A US27262872A US3870531A US 3870531 A US3870531 A US 3870531A US 272628 A US272628 A US 272628A US 27262872 A US27262872 A US 27262872A US 3870531 A US3870531 A US 3870531A
- Authority
- US
- United States
- Prior art keywords
- weight
- glass
- flint glass
- optical
- tio2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 21
- 239000006185 dispersion Substances 0.000 title claims abstract description 19
- 239000005308 flint glass Substances 0.000 title claims abstract description 19
- 239000011521 glass Substances 0.000 claims description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000004040 coloring Methods 0.000 claims description 5
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims 2
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims 2
- 229910052681 coesite Inorganic materials 0.000 claims 1
- 229910052906 cristobalite Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 229910052682 stishovite Inorganic materials 0.000 claims 1
- 229910052905 tridymite Inorganic materials 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 18
- 239000010955 niobium Substances 0.000 description 14
- 238000007792 addition Methods 0.000 description 8
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 230000009471 action Effects 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 229910000484 niobium oxide Inorganic materials 0.000 description 3
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 3
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 3
- 239000005368 silicate glass Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- 229910001936 tantalum oxide Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- LSIXBBPOJBJQHN-UHFFFAOYSA-N 2,3-Dimethylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C(C)=C(C)C1C2 LSIXBBPOJBJQHN-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000000223 arsonoyl group Chemical group [H][As](*)(*)=O 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 239000005385 borate glass Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S501/00—Compositions: ceramic
- Y10S501/90—Optical glass, e.g. silent on refractive index and/or ABBE number
- Y10S501/901—Optical glass, e.g. silent on refractive index and/or ABBE number having R.I. at least 1.8
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S501/00—Compositions: ceramic
- Y10S501/90—Optical glass, e.g. silent on refractive index and/or ABBE number
- Y10S501/903—Optical glass, e.g. silent on refractive index and/or ABBE number having refractive index less than 1.8 and ABBE number less than 70
Definitions
- the invention relates to an optical flint glass, which has relatively low refractive indices from nd 1.65 to rid 1.87, high dispersions from vd 32 to vd 21 and varying relative partial dispersions.
- Such glasses are frequently referred to as low flints. They usually contain large quantities of titanium dioxide, which in known manner contributes to a particularly high degree to increasing the dispersion with relatively low refractive indices.
- silicate glasses with a low flint character are based on'the ternary systems SiO Na O TiO and SiO K TiO The higher their content of TiO the more their optical values differ from those of the conventional flint glasses based on lead silicate.
- the glasses according to the invention can contain additions of up to altogether 6% by weight of W0 AS203 and Bi O3.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712137748 DE2137748C (de) | 1971-07-28 | Titandioxidhaltiges, optisches Flintglas mit relativ niedrigen Brech werten von n tief d = 1,65 bis n tief d = 1,87 und hoher Dispersion von ny tief d = 32bisnytiefd = 21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3870531A true US3870531A (en) | 1975-03-11 |
Family
ID=5815084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US272628A Expired - Lifetime US3870531A (en) | 1971-07-28 | 1972-07-17 | Optical flint glass with relatively low refractive indices and high dispersion |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3870531A (enrdf_load_stackoverflow) |
| JP (1) | JPS4834913A (enrdf_load_stackoverflow) |
| FR (1) | FR2161890B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1347830A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4149895A (en) * | 1977-07-01 | 1979-04-17 | Corning Glass Works | Glass with high refractive index and low density |
| US4734389A (en) * | 1985-02-11 | 1988-03-29 | Schott Glaswerke | Highly refractive optical glass with refractive indices >1.83 and Abbe numbers <25, and with very good chemical stability |
| US4996173A (en) * | 1988-02-29 | 1991-02-26 | Hoya Corporation | Optical glass |
| US5952256A (en) * | 1997-03-25 | 1999-09-14 | Kabushiki Kaisha Ohara | Optical glass having a negative anomalous dispersion |
| US20030191008A1 (en) * | 2002-04-02 | 2003-10-09 | Susumu Uehara | Optical glass |
| US20040220040A1 (en) * | 2002-04-02 | 2004-11-04 | Susumu Uehara | Optical glass |
| US20090197755A1 (en) * | 2008-01-31 | 2009-08-06 | Ohara Inc. | Optical glass |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7528083B2 (en) | 2003-06-10 | 2009-05-05 | Kabushiki Kaish Ohara | Optical glass |
| CZ2009373A3 (cs) * | 2009-06-10 | 2010-10-13 | Preciosa, A. S. | Vysoceolovnaté sklo |
| JP6675772B2 (ja) * | 2014-10-29 | 2020-04-01 | 株式会社オハラ | 光学ガラス、プリフォーム及び光学素子 |
| CN106630594B (zh) | 2016-09-05 | 2019-12-03 | 成都光明光电股份有限公司 | 光学玻璃和光学元件 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3446638A (en) * | 1964-02-13 | 1969-05-27 | Leitz Ernst Gmbh | Optical flint glasses |
| US3460954A (en) * | 1964-05-21 | 1969-08-12 | Bendix Corp | Bao-nb2o5-sio2 glass compositions for use in fiber-optics |
| US3536504A (en) * | 1965-09-04 | 1970-10-27 | Jenaer Glaswerk Schott & Gen | Optical glasses |
| US3589918A (en) * | 1967-11-14 | 1971-06-29 | Jenaer Glaswerk Schott & Gen | Optical glass and process for its manufacture |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1502602A (fr) * | 1961-06-20 | 1967-11-24 | Jenaer Glas Schott Gen Veb | Verre d'optique de réfringence relativement faible et à grand pouvoir dispersif |
| FR1415326A (fr) * | 1964-12-01 | 1965-10-22 | Leitz Ernst Gmbh | Flint-glass à usages optiques |
| FR2056248A5 (enrdf_load_stackoverflow) * | 1969-08-14 | 1971-05-14 | Leitz Ernst Gmbh |
-
1972
- 1972-07-17 US US272628A patent/US3870531A/en not_active Expired - Lifetime
- 1972-07-21 JP JP47072663A patent/JPS4834913A/ja active Pending
- 1972-07-25 GB GB3475272A patent/GB1347830A/en not_active Expired
- 1972-07-25 FR FR7226750A patent/FR2161890B1/fr not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3446638A (en) * | 1964-02-13 | 1969-05-27 | Leitz Ernst Gmbh | Optical flint glasses |
| US3460954A (en) * | 1964-05-21 | 1969-08-12 | Bendix Corp | Bao-nb2o5-sio2 glass compositions for use in fiber-optics |
| US3536504A (en) * | 1965-09-04 | 1970-10-27 | Jenaer Glaswerk Schott & Gen | Optical glasses |
| US3589918A (en) * | 1967-11-14 | 1971-06-29 | Jenaer Glaswerk Schott & Gen | Optical glass and process for its manufacture |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4149895A (en) * | 1977-07-01 | 1979-04-17 | Corning Glass Works | Glass with high refractive index and low density |
| US4734389A (en) * | 1985-02-11 | 1988-03-29 | Schott Glaswerke | Highly refractive optical glass with refractive indices >1.83 and Abbe numbers <25, and with very good chemical stability |
| US4996173A (en) * | 1988-02-29 | 1991-02-26 | Hoya Corporation | Optical glass |
| US5952256A (en) * | 1997-03-25 | 1999-09-14 | Kabushiki Kaisha Ohara | Optical glass having a negative anomalous dispersion |
| US20030191008A1 (en) * | 2002-04-02 | 2003-10-09 | Susumu Uehara | Optical glass |
| US20040220040A1 (en) * | 2002-04-02 | 2004-11-04 | Susumu Uehara | Optical glass |
| US6828265B2 (en) * | 2002-04-02 | 2004-12-07 | Kabushiki Kaisha Ohara | Optical glass |
| US7320949B2 (en) * | 2002-04-02 | 2008-01-22 | Kabushiki Kaisha Ohara | Optical glass |
| US20090197755A1 (en) * | 2008-01-31 | 2009-08-06 | Ohara Inc. | Optical glass |
| US8030233B2 (en) * | 2008-01-31 | 2011-10-04 | Ohara Inc. | Optical glass |
| US8664133B2 (en) | 2008-01-31 | 2014-03-04 | Ohara Inc. | Optical glass |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2137748B2 (de) | 1972-11-23 |
| DE2137748A1 (enrdf_load_stackoverflow) | 1972-11-23 |
| FR2161890A1 (enrdf_load_stackoverflow) | 1973-07-13 |
| FR2161890B1 (enrdf_load_stackoverflow) | 1976-03-26 |
| JPS4834913A (enrdf_load_stackoverflow) | 1973-05-23 |
| GB1347830A (en) | 1974-02-27 |
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