US3864903A - Synthetic fibrous unit which is three-dimensionally crimped and twisted - Google Patents

Synthetic fibrous unit which is three-dimensionally crimped and twisted Download PDF

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US3864903A
US3864903A US26263572A US3864903A US 3864903 A US3864903 A US 3864903A US 26263572 A US26263572 A US 26263572A US 3864903 A US3864903 A US 3864903A
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fibrous
stem
film
rollers
branches
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Isao Maki
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Soko Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/423Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/47Processes of splitting film, webs or sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S57/00Textiles: spinning, twisting, and twining
    • Y10S57/907Foamed and/or fibrillated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T225/00Severing by tearing or breaking
    • Y10T225/30Breaking or tearing apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T225/00Severing by tearing or breaking
    • Y10T225/30Breaking or tearing apparatus
    • Y10T225/307Combined with preliminary weakener or with nonbreaking cutter
    • Y10T225/321Preliminary weakener
    • Y10T225/325With means to apply moment of force to weakened work

Definitions

  • ABSTRACT A three-dimensionally crimped and twisted synthetic fibrous unit formed by a stem having a relatively large width. Branches randomly extend from the stem and have a width less than the stern width. and fine hairs randomly extend from the branches. Numerous peripherally and internally formed crevices are provided in the fibrous unit.
  • FIG. 4 FIG.5
  • PATENTEB FEB 1 1 I975 SHEET 0F 7 I DO PATENTED 1 I975 1864.903
  • the present invention relates to a synthetic fibrous unit of novel configuration.
  • This invention more particularly relates to a synthetic fibrous unit having diverse form of branched hairy configuration produced from one or more synthetic resinous films of a thermoplastic nature by utilizing a draft-fibrillation.
  • a method of splitting a given synthetic filmy band into a mass of fine fibrous units was recently developed.
  • the given synthetic filmy band or strip is subjected to a rubbing action by suitable rubbing means or to a splitting action by suitable splitting means such as an inflicting roller or a peripherally screw grooved roller.
  • suitable rubbing means such as an inflicting roller or a peripherally screw grooved roller.
  • suitable splitting means such as an inflicting roller or a peripherally screw grooved roller.
  • the material filmy band has a relatively large width, it is usual to preliminary slit the band into a plurality of strips of smaller width.
  • the obtained fibrous mass is composed of a plurality of randomly split fine-fibrous units connected to each other in a network configuration.
  • this already developed splitting technique has, to some extent, solved the problem of the superficial smoothness and the lengthwise evenness in the fineness of the filaments obtained.
  • the obtained fibrous unit does not fully meet the general requirement for the configurational diversity thereof.
  • the fibrous units manufactured by the conventional splitting method are not so fine as is suitable for yarns of finer thickness and fabrics of light and thin construction.
  • the lateral width of the fibrous units now on the market is at smallest 0.5 mm.
  • any of the convention'ally developed synthetic filaments and split fibers cannot assure the provision of the fabric made thereof with sufficient softness, resiliency, warmth retainability, handling quality, bulkiness and hygroscopic property such as inherent in the fabrics made of natural fibers.
  • a principal object of the present invention is to provide a synthetic fibrous unit having a remarkably diverse form of configuration and considerably fine construction.
  • Another object of the present invention is to provide a synthetic fibrous unit having an enhanced inter-fibers frictional property.
  • a still other object of the present invention is to provide a synthetic fibrous unit capable of assuring an excellent capillary attraction to the fibrous mass composed thereof.
  • a further object of the present invention is to provide a synthetic fibrous unit capable of assuring a desirable softness, resiliency, warmth retainability, handling quality, bulkiness and hygroscopic property which is inherent to the natural fibers of a fabric made thereof.
  • the synthetic fibrous unit of the present invention is composed of a stem of relatively large width, a plurality of branches randomly integral of the stern and a plurality of hairs extending at random from the stem and the branches, The entire configuration is three-dimensionally crimped and twisted.
  • the fibrous unit is further provided with polygonally-profiled transverse cross section together with both internally and superficially formed numerous fine crevices.
  • one or more synthetic resinous films of a thermoplastic nature are firstly subjected to a uniaxial thermal pre-drawing. Thereafter, the uniaxially pre-drawn film or films are passed through a draft zone for a draft fibrillation.
  • the draft zone is formed by two or more pairs of rotational rollers located apart in a prescribed distance and the superficial speed of the downstream rollers is made larger than that of the supstream rollers to such an extent so as to efi'ectuate the purposed draft fibrillation of the given film.
  • the system includes three pairs of rollers and a particular mechanical modification may be applied to the intermediate roller pair as later described in detail.
  • FIG. IA is an enlarged diagrammatic representation of a fibrous unit of the present invention
  • FIGS. 18 and 1C are microscopically enlarged photographical representations of the fibrous unit of the present invention.
  • FIG. 2 is a photographical representation of fibrous units of the present invention taken in a slackened massed disposition
  • FIGS. 3A and 3B are photographical representations of the transverse cross sections of the fibrous units of the present invention.
  • FIG. 4 is an enlarged photographical representation of the transverse cross sections of the fibrous units of the present invention.
  • FIG. 5 is an enlarged photographical representation of the transverse cross sections of split fibers manufactured by the conventional film splitting method
  • FIG. 6 is a partly sectional diagrammatic side view of a basic embodiment of the apparatus of the present invcntion.
  • FIG. 7 is a diagrammatic side view of another embodiment of the apparatus of the present invention whereon some example tests were performed.
  • FIGS. 8A to 8C are some examples of the staple diagram characteristic of the fibrous unit of the present invention.
  • FIG. 9 is a diagrammatic side view of a modified embodiment of the apparatus of the present invention, wherein a two-stage draft fibrillation is performed,
  • FIG. I0 is a diagrammatic side view of a practical em bodiment of the apparatus shown in FIG. 9 whereon some example tests were performed,
  • FIGS. IIA to C are some examples of the staple diagram characteristic of the fibrous units of the present invention manufactured on an apparatus shown in FIG. 10,
  • FIG. I2A is a diagrammatic side view of a practical embodiment of the apparatus of the present invention having three stage successive draft zones,
  • FIG. I28 is a staple diagram of the fibrous units obtained on the apparatus shown in FIG. 12A,
  • FIG. 13 is a diagrammatic side view of another modilied embodiment of the apparatus of the present invention.
  • FIG. 14 is a diagrammatic side view ofa practical embodiment of the with-apron arrangement shown in FIG. 13, whereon an example test was performed,
  • FIG. 15 presents staple diagrams of the fibrous units manufactured on the apparatus shown in FIG. 14,
  • FIG. 16 is a diagrammatic plan view of a still another modification of the apparatus shown in FIG. 9.
  • the fibrous unit of the present invention is diagrammatically and photographically shown in an enlarged illustration.
  • the fibrous unit of the present invention is provided with a stem 1 of relatively large width, a plurality of branches 2 randomly integral of the stem I and a plurality of fine hairs 3 extending at random from the stem 1 and the branches 2.
  • the stem I, the branches 2 and the hairs 3 are randomly and independently crimped and twisted in portions.
  • the diverse form of the entire configuration of the fibrous unit of the present invention can be fairly confirmed by the photographs shown in FIGS. IB and IC. It was confirmed through the experimental observation by the inventor of the present invention that the fineness of the hair 3 in its finest portion was smaller than 0.2 denier.
  • the randomly crimped configuration of the branches 2 causes a sufficient extent of entanglement between the fibrous units when they are massed together.
  • This mutually entangled condition will be understood from the graphical illustration shown in FIG. 2, wherein the fibrous units are massed together in a relatively slackened condition. Due to this considerably entangled condition, the coherency of the fibrous units composing the mass is remarkably enhanced and the enhanced coherency of the fibrous units in the mass assures the production of a fine yarn of increased tensile strength and a relatively thin silver or web of increased tearing strength.
  • the randomly twisted configuration of the fibrous unit brings about a desirable increase in the bulkiness of the fibrous mass made thereof. This fairly satisfies the recent public preference for bulky apparel.
  • the fibrous unit of the present invention is provided with the obvious diverse form of configuration such as variation in fineness, length, crimp and twist, a textile product made thereof can be accompanied with functional properties almost the same with those possessed by the products made of natural fibers while maintaining the advantages of the syn thetic fibers such as, for example, an excellent resistance against chemical attack.
  • the fibrous unit of the present invention should be evaluated from a view point of its internal configuration. more particularly from its transverse cross-sectional features.
  • transverse cross-sectional fea ture of the synthetic fibrous unit of the present inven tion are shown in FIGS. 3A and 38, wherein it is observed that the transverse cross section of the fibrous unit is characterized by a variety of polygonal profiles. It is microscopically confirmed that the transverse cross-sectional profile varies from stem to stem, from branch to branch, from hair to hair, from stem to branch or hairs and from branch to hairs. This profile having a diverse form in the transverse cross section also, to a great extent, contributes to the enhancement in the inter-fibers frictional property to be possessed by the resultant fibrous unit.
  • Stem I as particularly illustrated in FIG. 1A has a predetermined cross-sectional dimension of a relatively large size as compared to the branches and the fine hairs.
  • Branches 2 extend from stem 1 and are seen to have a decreased cross-sectional dimension as compared to the width of stem 1.
  • Fine hairs 3 extend from both the stem and the branches and are seen to be greatly decreased in cross-sectional dimension as compared with the widths of both the stem and branches.
  • the term fine hair is well understood in the art to represent a most minute cross-sectional dimension as both fine and hair” have well understood meanings of very small, slender elements, and this contrast of widths is clearly shown in the FIG. IA illustration.
  • FIG. 4 an enlarged photographical illustration of the transverse cross sections of the fibrous units of the present invention is given.
  • the transverse cross section is provided with numerous peripherally and internally formed crevices.
  • the given illustration should be compared with the illustration given in FIG. 5, wherein an enlarged photographical illustration of the transverse cross sections of the split fibers manufactured by the conventional splitting process provided with suitable film inflicting means is shown.
  • FIG. 5 an enlarged photographical illustration of the transverse cross sections of the split fibers manufactured by the conventional splitting process provided with suitable film inflicting means is shown.
  • the numerous fine crevices in the fibrous unit of the present invention assures an enhanced inter-fibers coherency and capillary attraction when the fibrous units are massed together to form a textile product.
  • one or more films of such synthetic resinous substances such as polypropylene, polyethylene, polyamide, polyacryl, polyester, polyvinylchloride, polyvinylidenechloride and polyvinylalcohol can be advantageously used.
  • the acquired fibrous units of the present invention are, in a massed disposition, advantageously used for such textile products as woven or knitted fabrics, nonwoven fabrics, synthetic papers, fishing nets, shock absorbers, heat insulators, noise absorbers and warmth retainers.
  • the apparatus includes a pair of back rollers 11 and a pair of front rollers 12 located apart from the pair of back rollers 11 at a prescribed distance.
  • the respective pairs 11 and 12 are composed of axially rotational top rollers 11a and 12a and axially rotational bottom rollers 11! and 12b disposed in a pressure contact with the corresponding top rollers 110 and 12a.
  • the top rollers lla and [2a are peripherally covered by elastic layers lie and 12c for exerting a stable nip on the film and the fibrous units processed through the apparatus.
  • the surface speed of the front rollers 12 is designed as larger than that of the back rollers I1 and is, to such an extent, sufficiently capable of causing a draft fibrillation of the given film. That is, a draft zone 13 is formed in between the pairs of rollers 11 and 12.
  • a draft zone 13 is formed in between the pairs of rollers 11 and 12.
  • one or more uniaxially predrawn film 14 is processed through the nips by the roller pairs I1 and 12 and, within the draft zone 13, the film 14 is randomly fibrillated into a mass of numerous fine fibrous units 15.
  • the film composing polymeric chains are connected randomly to each other by partial chemical links.
  • a uniaxial pre'drawing operation which is usually performed at a drawing ratio up to 7 or 8
  • the film 14 is introduced into the draft zone 13 and the film 14 is subjected to a uniaxial stretching force, which force causes a stress distribution in the film configuration.
  • This distribution extends three-dimensionally throughout the films internal configuration.
  • breakage of the chemical links takes place at random location in the film configuration.
  • the breakage propagates one by one throughout the entire film configuration. Further, at the moment of film breakage at a particular location of the film, the stress distribution near that particular location is suddenly unbalanced and the momentary residual stress in film portions adjacent to that broken location tends to cause a random crimping and/or twisting in those film portions.
  • the resultant fibrous unit of the present invention can be provided with both a diverse form of branched hairy configuration of randomly and partially crimped and/or twisted nature and diverse form of profiled transverse cross section having numerous fine crevices.
  • polypropylene was used as the material polymer.
  • the material polypropylene was extruded into a film of 40 p. thickness and 650 mm width. After extrusion, the film was subsequently subjected to a uniaxial drawing at a drawing ratio of l0 and temperatures from to l20C in order to form a uniaxially drawn film of 10 p. thickness and 210 mm width.
  • EXAMPLE 1 A uniaxially drawn film of the above-described nature was processed through an arrangement shown in FIG. 7, wherein the back and front rollers were somewhat modified in their combination and arrangement Table 1 Average length of the fibrous units in mm I650 Effective length of the fibrous units in mm I260 Content of short fibrous units in 4l.5
  • EXAMPLE 2 A uniaxially drawn film used in Example I was also processed through the arrangement shown in FIG. 7. In this case. however. the draft ratio was selected as 2.5. The obtained fibrous units were provided with desirably diverse form of configurational features and the result of the staple diagram analysis were as shown in Table 2.
  • FIGS. 8A to SC some examples of the staple diagram sampled from the mass of the fibrous units of the present invention are shown.
  • the one shown in FIG. 8A corresponds to the fibrous units of Example I. the one in FIG. 88 to Example 2 and the one in FIG. BC to Example 3. From these illustrations, it is observed that the fibrous units of the present invention have a staple diagram very similar to those characteristics of natural fibers such as wool. This means that the fibrous unit of the present invention is perfectly distinguished and advanced from the conventional synthetic fibers in its fiber length characteristics, also.
  • EXAMPLE 4 Material polypropylene was formed into a film of IO pt thickness by uniaxially drawing an extruded film at a draw ratio from 7 to 8. Next. the uniaxially drawn film was supplied to the arrangement shown in FIG. 6, wherein the draft zone length was selected as 200 mm and the draft ratio was selected as 2.0. The obtained fibrous unit was provided with a configuration like that shown in FIG. IA, the maximum fiber length being about 200 mm the average fiber length being about I I0 mm and the minimum fiber length being 30 mm. The fineness of the stem was about [5 denier and that of the finest hair was smaller than 0.1 denier. Further, the stem was provided with. in average, from l5 to 20 crimps per l inch length and the branches or hairs with, in average. from 25 to 30 crimps per 1 inch length.
  • FIG. 9 a modification of the basic arrangement of the apparatus shown in FIG. 6 is diagrammatically shown, wherein two-stage draft fibrillation is carried out.
  • three pairs of rollers II, 12 and I6 are disposed in a mutually spaced apart relationship.
  • the first draft zone 17 is formed in between the back rollers ll and the intermediate rollers 16 and the second draft zone 18 is formed in between the intermediate rollers 16 and the front rollers 12.
  • the surface speed of the back rollers II is given by V that of the intermediate rollers I6 by V and that of the front rollers I2 by V the following relationship is employed in the mechanical designing of the arrangement.
  • the supplied uniaxially pre-drawn film 14 is firstly fibrillated to some extent in the first draft zone 17 and next. being introduced into the second draft zone 18, the partly fibrillated fibrous mass is now subjected to a complete fibrillation so as to be delivered through the nip by the front rollers 12 in the form of a mass of numerous fine fibrous units 15.
  • numerous crevices are developed in the internal configuration of the film and thusly developed crevices assist, to a great extent. the second zone fibrillation.
  • V A surface speed of the i th rollers (counted from the back rollers).
  • V A surface speed of the i l th rollers (counted from the back rollers).
  • L, l A length of the j 1 th draft zone, which is formed in between the i+ i th and the i 2 th rollers.
  • EXAMPLE 5 The first draft zone length was selected as 170 mm and the second draft zone length as 130 mm. The first draft ratio was selected as 2.5 and the second as l.7. A mass of fibrous units having various configurational features was obtained and the staple diagram analysis resulted as shown in Table 4.
  • the first draft zone length was selected as 270 mm and the second as 130 mm.
  • the first draft ratio was selected as 2.0 and the second as 1.7.
  • the result was as is shown in Table 5.
  • EXAMPLE 7 The first draft zone length was selected as 270 mm and the second as I mm. The first draft ratio was selected as 3.2 and the second as l.l. The result was as shown in Table 6.
  • FIGS. 11A, 11B and 11C The staple diagrams sampled as to the fibrous units of Examples 5 to 7 are shown in FIGS. 11A, 11B and 11C in the order of the Examples. It will be understood that the fibrous units of the present invention are accompanied with staple diagrams almost resembling those of natural fibers such as wool.
  • EXAMPLE 8 A uniaxially pre-drawn film used in the preceding examples was processed through the arrangement shown in H0. 12A and the mechanical setting was as follows:
  • the first draft zone length in mm 170 The second draft zone length in mm 130
  • the third draft zone length in mm The first draft ratio 2.4
  • the obtained staple diagram is shown in H08. 128 and the result of the analysis of the obtained staple dia gram is as shown in Table 7.
  • FIG. 13 a modification of the apparatus shown in FIG. 9 is shown, in which modification a pair of apron rollers 19 replaces the intermediate rollers 16.
  • the surface speed of the apron rollers 19 is also so designed as to satisfy the above-presented relationship (3).
  • the maximum length of the resul tant fibrous units are greatly dependent upon the distance L between the axial line of the main roller of the apron l9 and the front nip. So, as a sideeffect of using this arrangement, the maximum length of the fibrous units can be changed as desired by only adjusting the location disposition of the apron rollers 19 while maintaining the location relationship between the back and front rollers 11 and 12.
  • EXAMPLE 9 A uniaxially pre-drawn film used in the preceding examples was processed through the arrangement shown in FIG. 14, wherein the distance between the back nip and the apron main roller's axial line was selected as ISO mm the total draft zone length was selected as 240 mm and the total draft ratio was selected as 1.9.
  • the same type of film was also processed through the same arrangement under the same processing conditions with the only exception being that the apron rollers were removed.
  • the staple diagrams of the obtained fibrous units are shown in FIG. 15, wherein the curve a is for the withapron case and the curve b is for the without-apron case.
  • the result of the staple diagram analysis is illustrated in Table 8. From this result, it is fairly confirmed that insertion of the apron roller mechanism has a remarkable effect on the length of the fibrous units ob tained.
  • FIG. 16 another modification of the apparatus shown in FIG. 9 is illustrated, in which modification a pair of cone roller 20 replaces the intermediate rollers 16.
  • a cone roller axially rotates, its surface speed at the larger diametral portion is greater than that at the smaller diametral portion.
  • the mechanical arrangement must be so designed that the smallest surface speed of the cone roller 20 is greater than the surface speed of the back roller 11 and that the largest surface speed of the cone roller 20 is smaller than the surface speed of the front roller 12.
  • the film portion corresponding to the smaller siametral portion of the cone roller 20 starts to fibrillate. This is because of the relatively large difference in the surface speed between the small diametral portion of the cone roller 20 and the front rollers 12. Because the largest surface speed of the cone roller 20 is designed as smaller than the surface speed of the front rollers 12, the firstly fibrillated film portion is also subjected to an additional draft fibrillation while passing through the zone. Thus, a con siderable variation in the fibrillating action can be obtained along the transversal direction of the film.
  • EXAMPLE A polypropylene film was pre-drawn at a draw ratio from 7 to 8 and a uniaxially pre-drawn filament of 0.053 g/cm linear density and about 900 mm width was obtained.
  • This film was processed through the arrangement shown in FIG. 16. The distances between the three pairs of rollers were settled as 200 mm.
  • the surface speed of the cone rollers 20 were so selected that the draft ratio between the back roller and the largest diametral end of the cone roller was 2, that the draft ratio between the back roller and the smallest diame tral end of the cone roller was 1, that the draft ratio between the largest diametral end of the cone roller and the front roller was 1 and that the draft ratio between the smallest diametral end of the cone roller and the front roller was 2.
  • a synthetic fibrous unit made of a polyolefin consisting of a single stem having a predetermined crosssectional width, a plurality of branches randomly formed integral of said stem, and a plurality of numerous fine hairs extending at random from said stern and said branches, the entire configuration of said fibrous unit being three-dimensionally crimped and twisted at random, said branches having a decreased crosssectional width as compared with said predetermined cross-sectional width, said fine hairs having a crosssectional width greatly decreased as compared with the cross-sectional widths of said stem and said branches, and numerous crevices are formed peripherally and internally throughout said fibrous unit.
  • a synthetic fibrous unit according to claim 1 made from a polyethylene.

Abstract

A three-dimensionally crimped and twisted synthetic fibrous unit formed by a stem having a relatively large width. Branches randomly extend from the stem and have a width less than the stem width, and fine hairs randomly extend from the branches. Numerous peripherally and internally formed crevices are provided in the fibrous unit.

Description

United States Patent [191 Maki [451 Feb. 11, 1975 1 SYNTHETIC FIBROUS UNIT WHICH IS THREE-DIMENSIONALLY CRIMPED AND TWISTED [75] inventor: Isao Maki, Tokyo, Japan [73] Assignee: Soko Co., Ltd., Tokyo. Japan [22] Filed: June 14, 1972 [21] Appl. No.: 262,635
Related U.S. Application Data [63] Continuation in-part of Ser. No. 24,658. April 1,
1970, abandoned.
[52] U.S. C1 57/140 ,1, 161/173, 161/177, 161/179, 161/180, 225/93, 225/965.
264/Dig. 47, 264/D1G. 147, ZS/Dig. 1 F
[51] Int. Cl 002g 3/00, D02g 3/02 [58] Field of Search 161/172, 173, 177, 179, 161/180, 169; 57/140 .1
[561 References Cited UNITED STATES PATENTS 3,423,284 1/1969 Marek et a1. 162/157 3,506,535 4/1970 Prevorsek et a1. 161/177 3,551,275 12/1970 Teng, .1. 161/179 3,645,085 2/1972 Rassarl 161/180 3,649,404 3/1972 Waterhouse, G. 161/180 Primary E.raminerGeorge F. Lesmes Assistant Examiner-Kendell, Lorraine T.
[57] ABSTRACT A three-dimensionally crimped and twisted synthetic fibrous unit formed by a stem having a relatively large width. Branches randomly extend from the stem and have a width less than the stern width. and fine hairs randomly extend from the branches. Numerous peripherally and internally formed crevices are provided in the fibrous unit.
3 Claims, 24 Drawing Figures PATENTEB 1 sum 1 0F 7 3.864.903
PATENTED 1 3, 864,903
SHEET 2 0F 7 PATENTEDFEHI 1 I975 3,864,903
SHEET 3 BF 7 FIG.3B
FIG. 4 FIG.5
PATENTEB FEB 1 1 I975 SHEET 0F 7 I DO PATENTED 1 I975 1864.903
SHEET 7 OF 7 1 SYNTHETIC FIBROUS UNIT WHICH IS THREE-DIMENSIONALLY CRIMPED AND TWISTED This is a continuation-in-part of an earlier filed copending application Ser. No. 24,658 filed Apr. l, I970 and now abandoned.
The present invention relates to a synthetic fibrous unit of novel configuration. This invention more particularly relates to a synthetic fibrous unit having diverse form of branched hairy configuration produced from one or more synthetic resinous films of a thermoplastic nature by utilizing a draft-fibrillation.
Most of the conventional synthetic fibers are produced by extruding material polymer solutions or molten material polymers in a filamentary form through, a spinneret having fine spinning holes of given crosssectional profiles. Both internally and externally, various types of cross-sectional features of the filament can be given as desired through modification in the extrusion mechanism and the spinning holes cross-sectional profile. But, once the mechanical design is settled, no appreciable variation in the cross-sectional features along the filament length can be expected, except indispensable accidental variation in the fineness of relatively minor extent. In addition, unless any particular later-staged treatment is applied thereto, the produced filaments are in most cases provided with a remarkably smooth surface when compared with natural fibers. Such evenness in the cross-sectional feature and smooth surface leads to degraded inter-fibers frictional property and such a poor inter-fibers frictional property inevitably causes relatively poor coherency between the fibers composing a yarn.
Further, in the practical mill-production of the synthetic filaments by the extrusion technique, it is difficult to provide the resultant filaments with a fineness smaller than approximately 1.0 denier. This is firstly because of the flow characteristic inherent to the material polymer solution or molten material polymer at the time of extrusion and secondly because of the probable filament breakage after extrusion which oftentimes takes place due to excessively narrowed spinning holes. Because of this lower limit in the fineness of the produced filament, one cannot so much expect an excellent capillary attraction by the fibrous mass composing, for example, a fabric.
As an attempt to give the filament a threedimensional diversity, there is the well-known crimping technique. However, even this technique cannot give a perfect solution to the problem of the superficial smoothness and the lengthwise evenness in the fineness inherent to the individual filament.
In order to mitigate the disadvantage encountered in the prior art, a method of splitting a given synthetic filmy band into a mass of fine fibrous units was recently developed. In this method, the given synthetic filmy band or strip is subjected to a rubbing action by suitable rubbing means or to a splitting action by suitable splitting means such as an inflicting roller or a peripherally screw grooved roller. In case the material filmy band has a relatively large width, it is usual to preliminary slit the band into a plurality of strips of smaller width. The obtained fibrous mass is composed of a plurality of randomly split fine-fibrous units connected to each other in a network configuration. It is true that this already developed splitting technique has, to some extent, solved the problem of the superficial smoothness and the lengthwise evenness in the fineness of the filaments obtained. However, as is more apparently proved by the later description, the obtained fibrous unit does not fully meet the general requirement for the configurational diversity thereof. Further, in order to practice this manufacturing, it is necessary to furnish the manufacturing equipment with particular film slitting and/or splitting means such as abovementioned. It is also assuredly known that the fibrous units manufactured by the conventional splitting method are not so fine as is suitable for yarns of finer thickness and fabrics of light and thin construction. For example, the lateral width of the fibrous units now on the market is at smallest 0.5 mm.
Therefore, it can be concluded that any of the convention'ally developed synthetic filaments and split fibers cannot assure the provision of the fabric made thereof with sufficient softness, resiliency, warmth retainability, handling quality, bulkiness and hygroscopic property such as inherent in the fabrics made of natural fibers.
A principal object of the present invention is to provide a synthetic fibrous unit having a remarkably diverse form of configuration and considerably fine construction.
Another object of the present invention is to provide a synthetic fibrous unit having an enhanced inter-fibers frictional property.
A still other object of the present invention is to provide a synthetic fibrous unit capable of assuring an excellent capillary attraction to the fibrous mass composed thereof.
A further object of the present invention is to provide a synthetic fibrous unit capable of assuring a desirable softness, resiliency, warmth retainability, handling quality, bulkiness and hygroscopic property which is inherent to the natural fibers of a fabric made thereof.
In view of the above-mentioned objects, the synthetic fibrous unit of the present invention is composed of a stem of relatively large width, a plurality of branches randomly integral of the stern and a plurality of hairs extending at random from the stem and the branches, The entire configuration is three-dimensionally crimped and twisted. The fibrous unit is further provided with polygonally-profiled transverse cross section together with both internally and superficially formed numerous fine crevices.
In the manufacturing of the fibrous unit, one or more synthetic resinous films of a thermoplastic nature are firstly subjected to a uniaxial thermal pre-drawing. Thereafter, the uniaxially pre-drawn film or films are passed through a draft zone for a draft fibrillation. The draft zone is formed by two or more pairs of rotational rollers located apart in a prescribed distance and the superficial speed of the downstream rollers is made larger than that of the supstream rollers to such an extent so as to efi'ectuate the purposed draft fibrillation of the given film. [n a preferred embodiment. the system includes three pairs of rollers and a particular mechanical modification may be applied to the intermediate roller pair as later described in detail.
Further features and advantages of the present invention will be made more apparent from the following description, reference being made to the accompanying drawings; wherein FIG. IA is an enlarged diagrammatic representation of a fibrous unit of the present invention,
FIGS. 18 and 1C are microscopically enlarged photographical representations of the fibrous unit of the present invention,
FIG. 2 is a photographical representation of fibrous units of the present invention taken in a slackened massed disposition,
FIGS. 3A and 3B are photographical representations of the transverse cross sections of the fibrous units of the present invention,
FIG. 4 is an enlarged photographical representation of the transverse cross sections of the fibrous units of the present invention,
FIG. 5 is an enlarged photographical representation of the transverse cross sections of split fibers manufactured by the conventional film splitting method,
FIG. 6 is a partly sectional diagrammatic side view of a basic embodiment of the apparatus of the present invcntion.
FIG. 7 is a diagrammatic side view of another embodiment of the apparatus of the present invention whereon some example tests were performed,
FIGS. 8A to 8C are some examples of the staple diagram characteristic of the fibrous unit of the present invention,
FIG. 9 is a diagrammatic side view of a modified embodiment of the apparatus of the present invention, wherein a two-stage draft fibrillation is performed,
FIG. I0 is a diagrammatic side view of a practical em bodiment of the apparatus shown in FIG. 9 whereon some example tests were performed,
FIGS. IIA to C are some examples of the staple diagram characteristic of the fibrous units of the present invention manufactured on an apparatus shown in FIG. 10,
FIG. I2A is a diagrammatic side view of a practical embodiment of the apparatus of the present invention having three stage successive draft zones,
FIG. I28 is a staple diagram of the fibrous units obtained on the apparatus shown in FIG. 12A,
FIG. 13 is a diagrammatic side view of another modilied embodiment of the apparatus of the present invention,
FIG. 14 is a diagrammatic side view ofa practical embodiment of the with-apron arrangement shown in FIG. 13, whereon an example test was performed,
FIG. 15 presents staple diagrams of the fibrous units manufactured on the apparatus shown in FIG. 14,
FIG. 16 is a diagrammatic plan view of a still another modification of the apparatus shown in FIG. 9.
Referring to FIGS. 1A to IC, the fibrous unit of the present invention is diagrammatically and photographically shown in an enlarged illustration. As is diagrammatically shown in FIG. 1A, the fibrous unit of the present invention is provided with a stem 1 of relatively large width, a plurality of branches 2 randomly integral of the stem I and a plurality of fine hairs 3 extending at random from the stem 1 and the branches 2. The stem I, the branches 2 and the hairs 3 are randomly and independently crimped and twisted in portions. The diverse form of the entire configuration of the fibrous unit of the present invention can be fairly confirmed by the photographs shown in FIGS. IB and IC. It was confirmed through the experimental observation by the inventor of the present invention that the fineness of the hair 3 in its finest portion was smaller than 0.2 denier.
This particular diverse form of external configuration cannot be found in any of the conventional synthetic and natural fibers and it provides a great many advantages when the fibrous units are formed into yarns or fabrics.
In the first place, the randomly crimped configuration of the branches 2 causes a sufficient extent of entanglement between the fibrous units when they are massed together. This mutually entangled condition will be understood from the graphical illustration shown in FIG. 2, wherein the fibrous units are massed together in a relatively slackened condition. Due to this considerably entangled condition, the coherency of the fibrous units composing the mass is remarkably enhanced and the enhanced coherency of the fibrous units in the mass assures the production of a fine yarn of increased tensile strength and a relatively thin silver or web of increased tearing strength.
Secondly, the randomly twisted configuration of the fibrous unit brings about a desirable increase in the bulkiness of the fibrous mass made thereof. This fairly satisfies the recent public preference for bulky apparel.
Thirdly, the presence of the numerous fine hairs leads to an enhanced capillary attraction of the fibrous mass made thereof, which capillary attraction promises a better hygroscopic property. Therefore, an improved wearing comfort results by using the fibrous units of the present invention as a material for fabrics.
Further, because the fibrous unit of the present invention is provided with the obvious diverse form of configuration such as variation in fineness, length, crimp and twist, a textile product made thereof can be accompanied with functional properties almost the same with those possessed by the products made of natural fibers while maintaining the advantages of the syn thetic fibers such as, for example, an excellent resistance against chemical attack.
In addition to the above-mentioned external configurational features, the fibrous unit of the present invention should be evaluated from a view point of its internal configuration. more particularly from its transverse cross-sectional features.
Some examples of the transverse cross-sectional fea ture of the synthetic fibrous unit of the present inven tion are shown in FIGS. 3A and 38, wherein it is observed that the transverse cross section of the fibrous unit is characterized by a variety of polygonal profiles. It is microscopically confirmed that the transverse cross-sectional profile varies from stem to stem, from branch to branch, from hair to hair, from stem to branch or hairs and from branch to hairs. This profile having a diverse form in the transverse cross section also, to a great extent, contributes to the enhancement in the inter-fibers frictional property to be possessed by the resultant fibrous unit.
As shown most clearly in FIG. 1A the widths or crosssectional dimensions involved show a substantial variation in size when comparing the stem, the branches and the fine hairs. Stem I as particularly illustrated in FIG. 1A has a predetermined cross-sectional dimension of a relatively large size as compared to the branches and the fine hairs. Branches 2 extend from stem 1 and are seen to have a decreased cross-sectional dimension as compared to the width of stem 1. Fine hairs 3 extend from both the stem and the branches and are seen to be greatly decreased in cross-sectional dimension as compared with the widths of both the stem and branches. The term fine hair" is well understood in the art to represent a most minute cross-sectional dimension as both fine and hair" have well understood meanings of very small, slender elements, and this contrast of widths is clearly shown in the FIG. IA illustration.
Further, referring to FIG. 4, an enlarged photographical illustration of the transverse cross sections of the fibrous units of the present invention is given. As is clearly observed in the drawing, the transverse cross section is provided with numerous peripherally and internally formed crevices. The given illustration should be compared with the illustration given in FIG. 5, wherein an enlarged photographical illustration of the transverse cross sections of the split fibers manufactured by the conventional splitting process provided with suitable film inflicting means is shown. By this comparison, it will be understood that, although the conventional split fibers are provided with some peripherally and internally formed crevices also, their transverse cross-sectional profiles are remarkably smoother than those possessed by the fibrous units of the present invention.
The numerous fine crevices in the fibrous unit of the present invention assures an enhanced inter-fibers coherency and capillary attraction when the fibrous units are massed together to form a textile product.
The reason for the formation of the diverse form of transverse cross-sectional profile will be made apparent in the following description.
As a material for the fibrous unit of the present invention, one or more films of such synthetic resinous substances such as polypropylene, polyethylene, polyamide, polyacryl, polyester, polyvinylchloride, polyvinylidenechloride and polyvinylalcohol can be advantageously used.
The acquired fibrous units of the present invention are, in a massed disposition, advantageously used for such textile products as woven or knitted fabrics, nonwoven fabrics, synthetic papers, fishing nets, shock absorbers, heat insulators, noise absorbers and warmth retainers.
Referring to H6. 6, a principal arrangement of a preferred embodiment of the apparatus of the present invention is shown diagrammatically. The apparatus includes a pair of back rollers 11 and a pair of front rollers 12 located apart from the pair of back rollers 11 at a prescribed distance. The respective pairs 11 and 12 are composed of axially rotational top rollers 11a and 12a and axially rotational bottom rollers 11!) and 12b disposed in a pressure contact with the corresponding top rollers 110 and 12a. Preferably, the top rollers lla and [2a are peripherally covered by elastic layers lie and 12c for exerting a stable nip on the film and the fibrous units processed through the apparatus. The surface speed of the front rollers 12 is designed as larger than that of the back rollers I1 and is, to such an extent, sufficiently capable of causing a draft fibrillation of the given film. That is, a draft zone 13 is formed in between the pairs of rollers 11 and 12. On the apparatus designed as above, one or more uniaxially predrawn film 14 is processed through the nips by the roller pairs I1 and 12 and, within the draft zone 13, the film 14 is randomly fibrillated into a mass of numerous fine fibrous units 15.
The draft-fibrillating mechanism on the apparatus of the present invention will now be explained in detail in relation to the resultant diversity in the configurational features of the fibrous unit obtained.
in the material undrawn film, the film composing polymeric chains are connected randomly to each other by partial chemical links. By subjecting the film of this internal configuration to a uniaxial pre'drawing operation, which is usually performed at a drawing ratio up to 7 or 8, there takes place a compulsive interchains slippage and the chemical links connecting the chains are partially and randomly broken by this compulsive slippage. In this situation, the film 14 is introduced into the draft zone 13 and the film 14 is subjected to a uniaxial stretching force, which force causes a stress distribution in the film configuration. This distribution extends three-dimensionally throughout the films internal configuration. As is above-mentioned, breakage of the chemical links takes place at random location in the film configuration. That is, there must be a random distribution of weak-points throughout the films internal configuration. As is well-known, when an article having weak-points is subjected to a force application, the stress caused by the applied force tends to concentrate upon the weak-points resulting in the breakage thereof. Once the breakage takes place at the weakest points, the balance of the stress distribution is disturbed and the stress tends to concentrate on the second weakest points. Breakage of the weakest points is observed externally as a locational tearing of the film, in other words, a locational fibrillation of the film. Due to the random distribution of the weak-points throughout the three-dimensional configuration of the film, the above-explained fibrillation takes place at random locations in the film configuration. With proceeding of the draft action, that is, as the film is transported downstreamly under the above-mentioned compulsive stretch, the breakage propagates one by one throughout the entire film configuration. Further, at the moment of film breakage at a particular location of the film, the stress distribution near that particular location is suddenly unbalanced and the momentary residual stress in film portions adjacent to that broken location tends to cause a random crimping and/or twisting in those film portions. Thus, the resultant fibrous unit of the present invention can be provided with both a diverse form of branched hairy configuration of randomly and partially crimped and/or twisted nature and diverse form of profiled transverse cross section having numerous fine crevices.
For confirmation of the advantages of the present invention, several mill-scale tests were performed by the inventor of the present invention and some examples are given as follows.
In all the examples, polypropylene was used as the material polymer. The material polypropylene was extruded into a film of 40 p. thickness and 650 mm width. After extrusion, the film was subsequently subjected to a uniaxial drawing at a drawing ratio of l0 and temperatures from to l20C in order to form a uniaxially drawn film of 10 p. thickness and 210 mm width.
EXAMPLE 1 A uniaxially drawn film of the above-described nature was processed through an arrangement shown in FIG. 7, wherein the back and front rollers were somewhat modified in their combination and arrangement Table 1 Average length of the fibrous units in mm I650 Effective length of the fibrous units in mm I260 Content of short fibrous units in 4l.5
Measurement of the values listed in the table was achieved by the analysis of the obtained staple diagram in a manner generally employed in the cotton mill testing.
EXAMPLE 2 A uniaxially drawn film used in Example I was also processed through the arrangement shown in FIG. 7. In this case. however. the draft ratio was selected as 2.5. The obtained fibrous units were provided with desirably diverse form of configurational features and the result of the staple diagram analysis were as shown in Table 2.
Table 2 Average length of the fibrous units in mm 84.0 Effective length of the fibrous units in mm 1320 Content of short fibrous units in l 565 EXAMPLE 3 A uniaxially drawn film used in Example I was also processed through the arrangement shown in FIG. 7. In this case. however, the draft zone length was selected as 270 mm and the draft ratio was selected as 3.2. The configurational features of the fibrous units obtained were considerably diverse in form and the result of the staple diagram analysis were as shown in Table 3.
Table 3 Average length of the fibrous units in mm 930 Effective length of the fibrous units in mm 168.0 Content of the short fibrous units in 70 56.5
Referring to FIGS. 8A to SC, some examples of the staple diagram sampled from the mass of the fibrous units of the present invention are shown. The one shown in FIG. 8A corresponds to the fibrous units of Example I. the one in FIG. 88 to Example 2 and the one in FIG. BC to Example 3. From these illustrations, it is observed that the fibrous units of the present invention have a staple diagram very similar to those characteristics of natural fibers such as wool. This means that the fibrous unit of the present invention is perfectly distinguished and advanced from the conventional synthetic fibers in its fiber length characteristics, also.
EXAMPLE 4 Material polypropylene was formed into a film of IO pt thickness by uniaxially drawing an extruded film at a draw ratio from 7 to 8. Next. the uniaxially drawn film was supplied to the arrangement shown in FIG. 6, wherein the draft zone length was selected as 200 mm and the draft ratio was selected as 2.0. The obtained fibrous unit was provided with a configuration like that shown in FIG. IA, the maximum fiber length being about 200 mm the average fiber length being about I I0 mm and the minimum fiber length being 30 mm. The fineness of the stem was about [5 denier and that of the finest hair was smaller than 0.1 denier. Further, the stem was provided with. in average, from l5 to 20 crimps per l inch length and the branches or hairs with, in average. from 25 to 30 crimps per 1 inch length.
Referring to FIG. 9, a modification of the basic arrangement of the apparatus shown in FIG. 6 is diagrammatically shown, wherein two-stage draft fibrillation is carried out. In the arrangement, three pairs of rollers II, 12 and I6 are disposed in a mutually spaced apart relationship. The first draft zone 17 is formed in between the back rollers ll and the intermediate rollers 16 and the second draft zone 18 is formed in between the intermediate rollers 16 and the front rollers 12. Assuming that the surface speed of the back rollers II is given by V that of the intermediate rollers I6 by V and that of the front rollers I2 by V the following relationship is employed in the mechanical designing of the arrangement.
V. v. v.
As to the length of the respective draft zones, it was confirmed that the following relationship is established in the mechanical arrangement of the rollers. provided that the length of the first draft zone I7 is given by 1, and that of the second draft zone by L In the above mechanical arrangement. the supplied uniaxially pre-drawn film 14 is firstly fibrillated to some extent in the first draft zone 17 and next. being introduced into the second draft zone 18, the partly fibrillated fibrous mass is now subjected to a complete fibrillation so as to be delivered through the nip by the front rollers 12 in the form of a mass of numerous fine fibrous units 15. During the first draft zone fibrillation. numerous crevices are developed in the internal configuration of the film and thusly developed crevices assist, to a great extent. the second zone fibrillation.
Although, only the two-stage draft fibrillation is mentioned in the foregoing description, the abovepresented mathematical relationships (I) and (2) can be well extended to cases wherein three or more staged fibrillation is performed in succession as follows.
L, L +l wherein V, A surface speed of the i th rollers (counted from the back rollers).
V, A surface speed of the i l th rollers (counted from the back rollers).
L, A length of thej th draft zone, which is formed in between the i th and the i+ l th rollers.
L, l A length of the j 1 th draft zone, which is formed in between the i+ i th and the i 2 th rollers.
Further, through the repeated mill-tests by the inventor, it was emphatically confirmed that a desirable draft fibrillation effect can be obtained when the following mathematical relationships are mechanically satisfied in the arrangement of the apparatus.
EXAMPLE 5 The first draft zone length was selected as 170 mm and the second draft zone length as 130 mm. The first draft ratio was selected as 2.5 and the second as l.7. A mass of fibrous units having various configurational features was obtained and the staple diagram analysis resulted as shown in Table 4.
Table 4 Average length of the fibrous units in mm 60.5 Effective length of the fibrous units in mm 93.0 Content of the short fibrous units in 52.0
EXAMPLE 6 The first draft zone length was selected as 270 mm and the second as 130 mm. The first draft ratio was selected as 2.0 and the second as 1.7. The result was as is shown in Table 5.
Table 5 Average length of the fibrous units in mm 68.0 Effective length of the fibrous units in mm l2l.0 Content of the short fibrous units in 64.5
EXAMPLE 7 The first draft zone length was selected as 270 mm and the second as I mm. The first draft ratio was selected as 3.2 and the second as l.l. The result was as shown in Table 6.
Table 6 Average length of the fibrous units in mm 72.0 Effective length of the fibrous units in mm I340 Content of the short fibrous units in 68.0
10 The staple diagrams sampled as to the fibrous units of Examples 5 to 7 are shown in FIGS. 11A, 11B and 11C in the order of the Examples. It will be understood that the fibrous units of the present invention are accompanied with staple diagrams almost resembling those of natural fibers such as wool.
EXAMPLE 8 A uniaxially pre-drawn film used in the preceding examples was processed through the arrangement shown in H0. 12A and the mechanical setting was as follows:
The first draft zone length in mm 170 The second draft zone length in mm 130 The third draft zone length in mm The first draft ratio 2.4 The second draft ratio 1.7 The third draft ratio 2.0
The obtained staple diagram is shown in H08. 128 and the result of the analysis of the obtained staple dia gram is as shown in Table 7.
Referring to FIG. 13, a modification of the apparatus shown in FIG. 9 is shown, in which modification a pair of apron rollers 19 replaces the intermediate rollers 16. The surface speed of the apron rollers 19 is also so designed as to satisfy the above-presented relationship (3). By inserting this apron rollers l9, whipping of the fibrous units at the moment of fibrillation can be effectively prevented and an abrasional contract of the apron surfaces with the partly fibrillated film, which advances downwardly at a speed approximately similar to the surface speed of the front rollers 12, assures further propagated fibrillation of the film. It was further empirically determined that the maximum length of the resul tant fibrous units are greatly dependent upon the distance L between the axial line of the main roller of the apron l9 and the front nip. So, as a sideeffect of using this arrangement, the maximum length of the fibrous units can be changed as desired by only adjusting the location disposition of the apron rollers 19 while maintaining the location relationship between the back and front rollers 11 and 12.
EXAMPLE 9 A uniaxially pre-drawn film used in the preceding examples was processed through the arrangement shown in FIG. 14, wherein the distance between the back nip and the apron main roller's axial line was selected as ISO mm the total draft zone length was selected as 240 mm and the total draft ratio was selected as 1.9. For the purpose of comparison, the same type of film was also processed through the same arrangement under the same processing conditions with the only exception being that the apron rollers were removed.
The staple diagrams of the obtained fibrous units are shown in FIG. 15, wherein the curve a is for the withapron case and the curve b is for the without-apron case. The result of the staple diagram analysis is illustrated in Table 8. From this result, it is fairly confirmed that insertion of the apron roller mechanism has a remarkable effect on the length of the fibrous units ob tained.
fibrous units in 7;
Referring to FIG. 16, another modification of the apparatus shown in FIG. 9 is illustrated, in which modification a pair of cone roller 20 replaces the intermediate rollers 16. As is commonly known, when a cone roller axially rotates, its surface speed at the larger diametral portion is greater than that at the smaller diametral portion. So, in the present embodiment, the mechanical arrangement must be so designed that the smallest surface speed of the cone roller 20 is greater than the surface speed of the back roller 11 and that the largest surface speed of the cone roller 20 is smaller than the surface speed of the front roller 12. Once a film 14 is supplied to this designed apparatus, the film portion corresponding to the larger diametral portion of the cone roller 20 starts to fibrillate first. This is because of the relatively large difference in the surface speed between the back roller and the large diametral portion of the cone roller 20. Next, in the zone between the cone rollers 20 and the front rollers 12, the film portion corresponding to the smaller siametral portion of the cone roller 20 starts to fibrillate. This is because of the relatively large difference in the surface speed between the small diametral portion of the cone roller 20 and the front rollers 12. Because the largest surface speed of the cone roller 20 is designed as smaller than the surface speed of the front rollers 12, the firstly fibrillated film portion is also subjected to an additional draft fibrillation while passing through the zone. Thus, a con siderable variation in the fibrillating action can be obtained along the transversal direction of the film.
EXAMPLE A polypropylene film was pre-drawn at a draw ratio from 7 to 8 and a uniaxially pre-drawn filament of 0.053 g/cm linear density and about 900 mm width was obtained. This film was processed through the arrangement shown in FIG. 16. The distances between the three pairs of rollers were settled as 200 mm. The surface speed of the cone rollers 20 were so selected that the draft ratio between the back roller and the largest diametral end of the cone roller was 2, that the draft ratio between the back roller and the smallest diame tral end of the cone roller was 1, that the draft ratio between the largest diametral end of the cone roller and the front roller was 1 and that the draft ratio between the smallest diametral end of the cone roller and the front roller was 2.
It was clearly observed that the fibrillation was firstly commenced in the film portion corresponding to the larger diametral portion of the cone rollers in the first draft zone and the fibrillation propagated to the remaining film portion in the second draft zone. The film was perfectly fibrillated into a mass of numerous fine fibrous units of diverse form of configurational features.
What I claim is:
l. A synthetic fibrous unit made of a polyolefin consisting of a single stem having a predetermined crosssectional width, a plurality of branches randomly formed integral of said stem, and a plurality of numerous fine hairs extending at random from said stern and said branches, the entire configuration of said fibrous unit being three-dimensionally crimped and twisted at random, said branches having a decreased crosssectional width as compared with said predetermined cross-sectional width, said fine hairs having a crosssectional width greatly decreased as compared with the cross-sectional widths of said stem and said branches, and numerous crevices are formed peripherally and internally throughout said fibrous unit.
2. A synthetic fibrous unit according to claim 1, made from a polyethylene.
3. A synthetic fibrous unit according to claim 1,
made from a polypropylene.

Claims (3)

1. SYNTHETIC FIBROUS UNIT MADE OF A POLYOLEFIN CONSISTING OF A SINGLE STEM HAVING A PREDETERMINED CROSS-SECTIONAL WIDTH, A PLURALITY OF BRANCHES RANDOMLY FORMED INTERGRAL OF SAID STEM, AND A PLURALITY OF NUMEROUS FINE HAIRS EXTENDING AT RANDOM FROM SAID STEM AND SAID BRANCHES, THE ENTIRE CONFIGURATION OF SAID FIBROUS UNIT BEING THREE-DIMENSIONALLY CRIMPED AND TWISTED AT RANDOM, SAID BRANCHES HAVING A DECREASED CROSSSECTIONAL WIDTH AS COMPARED WITH SAID PREDETERMINED CROSSSECTIONAL WIDTH, SAID FINE HAIRS HAVING A CROSS-SECTIONAL WIDTH GREATLY DECREASED AS COMPARED WITH THE CROSS-SECTIONAL WIDTHS OF SAID STEM AND SAID BRANCHES, AND NUMEROUS CREVICES ARE FORMED PERIPHERALLY AND INTERNALLY THROUGHOUT SAID FIBROUS UNIT.
2. A synthetic fibrous unit according to claim 1, made from a polyethylene.
3. A synthetic fibrous unit according to claim 1, made from a polypropylene.
US26263572 1970-04-01 1972-06-14 Synthetic fibrous unit which is three-dimensionally crimped and twisted Expired - Lifetime US3864903A (en)

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US4274251A (en) * 1973-01-16 1981-06-23 Hercules Incorporated Yarn structure having main filaments and tie filaments
US4331724A (en) * 1978-05-22 1982-05-25 Milliken Research Corporation Fibrillated polyester textile materials
US4364998A (en) * 1981-07-20 1982-12-21 E. I. Du Pont De Nemours And Company Spunlike yarns
US5807633A (en) * 1994-10-04 1998-09-15 Daikin Industries, Ltd. Polytetrafluoroethylene composite fiber, cotton-like materials obtained therefrom and processes for production thereof
US20040038027A1 (en) * 2001-02-21 2004-02-26 Lovett Jeffrey B. Fiber reinforcement material, products made thereform, and method for making the same
US6753081B1 (en) * 2001-02-21 2004-06-22 Forta Corporation Fiber reinforcement material, products made therefrom, and method for making the same
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US3506535A (en) * 1967-11-06 1970-04-14 Allied Chem Method of fibrillation and product
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US3551275A (en) * 1967-02-23 1970-12-29 James Teng Branched fiber and fibrous composition formed therefrom
US3506535A (en) * 1967-11-06 1970-04-14 Allied Chem Method of fibrillation and product
US3649404A (en) * 1968-07-24 1972-03-14 Scragg & Sons Making filaments with fibrils bonded thereto
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Publication number Priority date Publication date Assignee Title
US4274251A (en) * 1973-01-16 1981-06-23 Hercules Incorporated Yarn structure having main filaments and tie filaments
US4331724A (en) * 1978-05-22 1982-05-25 Milliken Research Corporation Fibrillated polyester textile materials
WO1980000960A1 (en) * 1978-11-03 1980-05-15 Eternit Fab Dansk As A fiber-reinforced composite material and a fibrillated tow and a reinforcing web for use therein
US4364998A (en) * 1981-07-20 1982-12-21 E. I. Du Pont De Nemours And Company Spunlike yarns
US5807633A (en) * 1994-10-04 1998-09-15 Daikin Industries, Ltd. Polytetrafluoroethylene composite fiber, cotton-like materials obtained therefrom and processes for production thereof
US5998022A (en) * 1994-10-04 1999-12-07 Daikin Industries, Ltd. Polytetrafluoroethylene cotton-like materials
US20040038027A1 (en) * 2001-02-21 2004-02-26 Lovett Jeffrey B. Fiber reinforcement material, products made thereform, and method for making the same
US6753081B1 (en) * 2001-02-21 2004-06-22 Forta Corporation Fiber reinforcement material, products made therefrom, and method for making the same
US7168232B2 (en) 2001-02-21 2007-01-30 Forta Corporation Fiber reinforcement material, products made thereform, and method for making the same
US20110020629A1 (en) * 2008-01-22 2011-01-27 Tesa Se Film made of polypropylene, use thereof, and method for the production of the film
US8048514B2 (en) * 2008-01-22 2011-11-01 Tesa Se Film made of polypropylene, use thereof, and method for the production of the film

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