US38589A - Improvement in dyeing and printing a black color on fabrics with aniline compounds - Google Patents
Improvement in dyeing and printing a black color on fabrics with aniline compounds Download PDFInfo
- Publication number
- US38589A US38589A US38589DA US38589A US 38589 A US38589 A US 38589A US 38589D A US38589D A US 38589DA US 38589 A US38589 A US 38589A
- Authority
- US
- United States
- Prior art keywords
- printing
- fabrics
- dyeing
- improvement
- black color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 title description 14
- 238000004043 dyeing Methods 0.000 title description 8
- 150000001448 anilines Chemical class 0.000 title 2
- 150000003839 salts Chemical class 0.000 description 22
- 239000011780 sodium chloride Substances 0.000 description 22
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical class NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N Hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 241000405147 Hermes Species 0.000 description 2
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 2
- 241001149655 Rubia tinctorum Species 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/10—Amino derivatives of triarylmethanes
Definitions
- aniline or-anyaualog'ous homologous or isomeric matters using by preference aniline in the proportion of eight ounces, previously combining it with eight ounces of hydrochloric acid at 32 Twaddle.
- I add one pintof acetic acid a and eight ounces, measupe, of perchloride of atv from 609 to 70v Fahrenheit for two or thre days.
- the goods are now passed through water alone or a solution containing" alkaline or metallic salts, (which developthe black much sooner and better.)
- the alkalies and alkaline I earths may be used for raising the blackysuch,
- the goods may be passed, after printing and dyeing, through a box containing rollers supplied with ammoniacal gas,. (which I prefer when the black is printed along with steam ,colors prior to steaming the goods.)
- a box containing rollers supplied with ammoniacal gas which I prefer when the black is printed along with steam ,colors prior to steaming the goods.
- metallic Salts such as sulphate of copper, chloride 0 copper, chloride of antimony, nitrate of nickel, nitrate of bismuth, 8E0.
- the vsalts of several other metals may also be substituted for those of copper for producing a black dye or printing material for black, such as soluble compounds of antimony, bismuth-,.chroni ium,
- Patehtutgents 20 019,30 Street, Manchester.
Description
To all whom it may concern:
UNITED i STATES PATENT OFFICE:
Joan LIGHIFOOT, or Aoonmeron, ENGLAND.-
. IMPROYEMENT'IN DYEING A ND PRIilTING A BLACK COLOR ON ,FABRICS- WITH Amuse COMPOUNDS.
Specification forming part df Letters PatentN0.-38,9, dated May 19,1863.
Be it knownjthat I, JOHN Lrencrroor, ot
' Accrington in the county of Lancaster :and
Kingdom of England, chemist, have invented or discovered new anduseful Improvements in Printing and Dyeing Te'xtile Fabrics and Yarns; and I do hereby declare that the following is afull and-exact description thereofthat is to say Thesedmprovem-ents consist in the production of a black dye on textile fabrics or yarns by printing or staining them with a salt or salts of aniline or any analogous homologous or isomeric com-pounds mixed with certain me-- tallic salts or their oxides as a mordant, as hereinafter described. I takeonegallon ofv water and dissolvein it four ounces chlorate of potash. To this I add aniline or-anyaualog'ous homologous or isomeric matters, using by preference aniline in the proportion of eight ounces, previously combining it with eight ounces of hydrochloric acid at 32 Twaddle. After stirring well I add one pintof acetic acid a and eight ounces, measupe, of perchloride of atv from 609 to 70v Fahrenheit for two or thre days. The goods are now passed through water alone or a solution containing" alkaline or metallic salts, (which developthe black much sooner and better.) The alkalies and alkaline I earths may be used for raising the blackysuch,
'as-causticlsoda, caustic potash, caustic ammonia, caustic lime in solution in water; orthe goods may be passed, after printing and dyeing, through a box containing rollers supplied with ammoniacal gas,. (which I prefer when the black is printed along with steam ,colors prior to steaming the goods.) When --.the blackiis printed along with madder or gara'ncine colors theyare aged or exposed in'a room at from 60 to 70 Fahrenheit for three days, and dunged, dyed, washed, and
passed through a, solution'of soap or dilute hypochlorite of lime, whereby'an intense black is produced. 7
, For printing on fabrics or yarns, Ltakej one gallon of starch-paste (containing one pound,
weight, starch per gallon) or'other suitable thickening ingredient and dissolve 'in it four ounces chlorate, of potash and eight ounces "aniline previously combined with eight ounces. I
hydrochloric acid. 1 I then add four ounces,
-. measure, of perchloride of copper at 88 Twaddie and two ounces 'sal-ammpniac or. an equivalentiquantity of other suitable' alkaline chlor1de. After printing this color I age for three nights and raise in water alone, or weak alkali,
the same result. Neither do I confine myself to the use of alkaline chlorides, for they can. 1
be dispensed with when certain metallic Salts are used, such as sulphate of copper, chloride 0 copper, chloride of antimony, nitrate of nickel, nitrate of bismuth, 8E0. The vsalts of several other metals may also be substituted for those of copper for producing a black dye or printing material for black, such as soluble compounds of antimony, bismuth-,.chroni ium,
iron, manganese, nickel; and in some cases I pad the cloth I in a solution of any of the metallic salts named, either separately or mixed together, dry, and print or paid ona thickened salt of aniline in combination with-chlorate of potash, age three to four nights, and finish as previously stated; or I pad the cloth in a solution of any of the metallic salts named, as before. I then precipitate the oiride ofthe metal or metals used in the cloth by passing through a solution of alkali suitable to the metal used, wash, dry, and print or pad on a thickened 'acid' salt of. aniline in combination with chlorate of-potash, age three to four nights, and finish as before.
I do not confine myself to the precise details herein mentioned, nor totheexact quantities herein stated, as they may be slightly modified without departing from the spirit of my invention; but What I claim'as my invention is-- Y I The use of certain metallic'salts'or their oxides,-as hrein stated, either alone or combined with chlorate of potash and then mixed with a saltor salts of; aniline or anyanalogous homologous or isomeric compounds, either singly or mixed together, aswell as the process or series of processes,- as previously described, for the production of a black dye or tain. I v
one at.-the city of Manchester, England, this 21st day of February, 1863.
JOHN LIGHTFOOL In presence of- EDWARD JOSEPH Hermes,
JOHN Bnoonwon'rn;
Patehtutgents, 20 019,30 Street, Manchester.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US38589A true US38589A (en) | 1863-05-19 |
Family
ID=2108160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US38589D Expired - Lifetime US38589A (en) | Improvement in dyeing and printing a black color on fabrics with aniline compounds |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US38589A (en) |
-
0
- US US38589D patent/US38589A/en not_active Expired - Lifetime
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