US3855019A - Processing for high permeability silicon steel comprising copper - Google Patents
Processing for high permeability silicon steel comprising copper Download PDFInfo
- Publication number
- US3855019A US3855019A US00357973A US35797373A US3855019A US 3855019 A US3855019 A US 3855019A US 00357973 A US00357973 A US 00357973A US 35797373 A US35797373 A US 35797373A US 3855019 A US3855019 A US 3855019A
- Authority
- US
- United States
- Prior art keywords
- steel
- hot rolled
- rolled band
- silicon
- annealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1266—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest between cold rolling steps
Definitions
- ABSTRACT A process for producing silicon steel having a cubeon-edge orientation and a permeability of at least 1850 (G/O at 10 oersteds, which includes the steps of: annealing a hot rolled band of silicon steel at a temperature of from 1400 to 1700F for a period of from 15 seconds to 2 hours; cooling the annealed hot rolled band at a rate substantially equivalent to a still air cool; and cold rolling the cooled steel at a reduction of at least 80 percent in a single cold rolling.
- the present invention relates to a process for producing electromagnetic silicon steel having a cube-on-edge orientation and a permeability of at least 1850 (6/0 at oersteds.
- Oriented silicon steels containing 2.60 to 4.0 percent silicon are generally produced by processes which involve hot rolling, a double cold reduction, an anneal before each cold roll and a high temperature texture anneal. Characterizing these steels are permeabilities at 10 oersteds of from 1790 to 1840 (G/O In recent years a number of patents have disclosed silicon steels with permeabilities in excess of 1850 (6/0,) at 10 oersteds. Of these, U.S. Pat. Nos. 3,287,183, 3,632,456 and 3,636,579 appear to be the most interesting from a processing standpoint. U.S. Pat. No. 3,287,183 which issued on Nov.
- 3,632,456 anneals a hot rolled band at a temperature of from l382 to 2l92F depending upon its silicon content, rapidly cools the annealed band and then proceeds to subject it to at least two cold rollings.
- Another patent of interest is U.S. Pat. No. 3,159,511, which issued on Dec. 1, 1964.
- Described herein is another, and improved method for producing silicon steel having a cube-on-edge orientation and a permeability of at least 1850 (6/0,) at 10 oersteds, from steel of a particular chemistry.
- the method includes the steps of: annealing a hot rolled band of silicon steel at a temperature of from 1400 to 1700F for a period of from seconds to 2 hours; cooling the hot rolled band at a rate substantially equivalent to a still air cool; and cold rolling the cooled steel at a reduction of at least 80 percent in a single cold rolling. It differs from and is contradictory to the methods of heretofore referred to U.S. Pat. Nos.
- U.S. Pat. No. 3,159,51 1 does not disclose a process for producingsilicon steel witha permeability as high as 1850 (6/0 at 10 oersteds nor the step of annealing a hot rolled band at a temperature of from 1400 to 1700F for a period of from 15 seconds to 2 hours;
- U.S. Pat. No. 3,287,183 discloses a minimum annealing temperature of l742F and not a maximum annealing temperature of 1700F;
- 3,632,456 calls for an anneal and two cold rollings subsequent to the hot rolled band anneal, which is in fact at a temperature in excess of 1742F for steels containing at least 2.5% Si, and does not cool the annealed hot rolled band at a rate substantially equivalent to a still air cool; and U.S. Pat. No. 3,636,579 discloses a minimum annealing temperature of 1742F for steels containing at least 2.5% Si and a rapid cool from said annealing temperature. Moreover, the chemistry of the steel being processed in accordance with the present invention differs from that being processed in said heretofore referred to patents.
- the present invention provides a method for producing silicon steel having a cube-on-edge orientation and a permeability of at least 1850 (6/0,) at 10 oersteds.
- Involved therein are the steps of: preparing a melt of silicon steel having, by weight, up to 0.07% carbon, from 2.60 to 4.0% silicon, from 0.03 to 0.24% manganese, from 0.01 to 0.07% sulfur, from 0.015 to 0.04% aluminum, up to 0.02% nitrogen, and from 0.1 to 0.5% copper, casting the steel; hot rolling the steel into a hot rolled band; annealing the hot rolled hand; cold rolling the annealed hot rolled band; decarburizing the steel; and final texture annealing the steel.
- annealing the hot rolled band at a temperature of from l400 to 1700F for a period of from 15 seconds to 2 hours; cooling the annealed hot rolled band at a rate substantially equivalent to a still air cool; and cold rolling the cooled steel at a reduction of at least percent in a single cold rolling.
- Preferred conditions include annealing the hot rolled bandat a temperature of from 1450 to 1650F and cold rolling at a reduction of at least percent.
- still air cools in clude those wherein the steel is cooled in a static atmosphere as well as those wherein there is relative motion between the atmosphere and the steel, as in a continuous processing line, so long as there is no deliberate intention to cause the motion for cooling purposes.
- all gaseous atmospheres are considered to have the same cooling effect asair.
- all open cools are at a rate substantially equivalent to a still air cool unless a liquid quenching medium or forced gaseous atmosphere is employed, and a forced gaseousatmosphere is one in which motion is deliberately imparted to the atmosphere for cooling purposes.
- Annealing of the hot rolled band at a temperature of from 1400 to 1700F is, however, believed-to be particularly beneficial in that it conditions the steel for cold rolling, provides an operation during which inhibitors can form, and mostrimportantly, increases the uniformity in which the inhibitors are distributed as essentially only ferrite phase is present in the steel at temperatures below 1700F, contrasted to the presence of austenite and ferrite phases and different solubilites for the inhibiting elements in each phase at somewhat higher temperature.
- the invention primarily pertains to aluminum nitride, and manganese sulfide and/or manganese copper sulfide, which are discussed in greater detail hereinbelow.
- Illustrative atmospheres therefore include nitrogen; reducing gases such as hydrogen; inert gases such as argon; air; and mixtures thereof.
- reducing gases such as hydrogen
- inert gases such as argon
- air and mixtures thereof.
- cold rolling it should be pointed out that several roll passes can constitute a single cold rolling operation, and that plural cold rolling operations exist only when cold rolling passes are separated by an anneal.
- the steel melt must include silicon, aluminum, manganese, sulfur and copper. Silicon is necessary as it increases the ste els resistivity, decreases its magnetostriction, decreases its magnetocrystalline anisotropy and hence decreases its core loss.
- Aluminum, manganese and sulfur are necessary as they form inhibitors which are essential to controlling the steels orientation and its properties which are dependent thereon. More specifically, aluminum combines with nitrogen, in the steel or from the atmosphere, to form aluminum nitride, and manganese combines with sulfur to form manganese sulfide and/or manganese copper sulfide; and these compounds act so as to.
- Copper in addition to possibly forming manganese copper sulfide, is believed to be beneficial in that it is hypothesized that copper'can lower the annealing temperature, improve rollability, simplify melting and relax annealing atmospheres requirements.
- a steel in which the process of the present invention is particularly adaptable to consists essentially of, by weight, from 0.02 to 0.07% carbomfrom 2.60 to 3.5% silicon, a manganese equivalent of from 0.05 to 0.24% as expressed by an equivalency equation of %Mn (0.1 to 0.25) X %Cu, from 0.01 to 0.05% sulfur, from 0.015 to 0.04% aluminum, from 0.0030 to 0.0090% nitrogen, from 0.1 to 0.3% copper, balance iron and residuals; and wherein the ratio of manganese equivalent to sulfur is in the range of from 2.0 to 4.75.
- the steel has its chemistry balanced so as to produce a highly beneficial structurewhen processed according to the present invention.
- samples 1 Three samples (Samples 1 3) of silicon steel were cast and processed into silicon steel having a cube-onedge orientation from a heat of BOF silicon steel.
- the steel consisted essentially of, by weight, 0.049% carbon, 2.91% silicon, 0.094% manganese, 0.032% sulfur, 0.036% aluminum, 0.0046% nitrogen, 0.22% copper, balance iron and residuals.
- Processing for the three samples involved soaking at an elevated temperature for several hours, blooming, hot rolling to a gage of approximately 92 mils, annealing at 1475F for 1 hour in nitrogen, cooling by one of three methods, cold rolling to final gage of approximately 13 mils, decarburizing for 2 minutes at 1475F in a mixture of nitrogen and wet hydrogen, and final annealing for 8 hours in hydrogen at a maximumtemperature of 2150F.
- the three cooling methods were a furnace cool, an air cool and a brine quench. Sample 1 "was furnace cooled, sample 2 was air cooled and the brine quench was applied to sample 3.
- samples 2 and 3 displayed very high permeabilities, that is permeabilities in excess of 1850 (G/Q.) at 10 oersteds.
- Sample 2 was processed in accordance with the present invention and sample 3 illustrated an embodiment of another invention claimed inv copending, application Ser. No. 357,974, filed concurrently herewith.
- Sample 2 was annealed in hydrogen for'l hour at 1475F, air cooled therefrom and cold rolled at a reduction of 86 percent in a single cold rolling. Similar processing was applied to samples 3 and l with the exception that they were respectively brine quenched and furnace cooled from their annealing temperature.
- sample 1 had a relatively low permeability. 1t also had a core loss which was substantially higher than that for samples 2 and 3.
- a process for producing electromagnetic silicon steel having a cube-on-edge orientation and a permeability of at least 1850 which process includes the steps of: preparing a melt of silicon steel consisting essentially of, by weight, up to 0.07% carbon, from 2.60 to 4.0% silicon, from 0.03 to 0.24% manganese, from 0.01 to 0.07% sulfur, from 0.015 to 0.04% aluminum, up to 0.02% nitrogen, from 0.1 to 0.5% copper and the balance iron; casting said steel; hot rolling said steel into a hot rolled band; annealing said hot rolled band; cold rolling said annealed hot rolled band; decarburizing said steel; and final texture annealing said steel; the improvement comprising the steps of annealing the hot rolled band at a temperature of from l400 to 1700F for a period of from 15 seconds to 2 hours; cooling said annealed hot rolled band at a rate equivalentto a steel air cool, said cool including those
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electromagnetism (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Soft Magnetic Materials (AREA)
- Metal Rolling (AREA)
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00357973A US3855019A (en) | 1973-05-07 | 1973-05-07 | Processing for high permeability silicon steel comprising copper |
AU67432/74A AU479508B2 (en) | 1973-05-07 | 1974-04-02 | Processing for high permeability silicon steel |
CA198,057A CA1010347A (en) | 1973-05-07 | 1974-04-18 | Processing for high permeability silicon steel |
FR7413792A FR2228854A1 (en) | 1973-05-07 | 1974-04-19 | Silicon steel with high magnetic permeability - prepd. by casting, hot-rolling, annealing and cooling |
BE143470A BE814023A (fr) | 1973-05-07 | 1974-04-22 | Procede pour produire de l'acier au silicium a permeabilite elevee et pertes faibles |
IT50770/74A IT1011366B (it) | 1973-05-07 | 1974-05-03 | Procedimento per la produzione di acciaio al silicio ad elevata permeabilita |
GB1980474A GB1428902A (en) | 1973-05-07 | 1974-05-06 | Processing for high permeability silicon steel |
BR362774A BR7403627D0 (pt) | 1973-05-07 | 1974-05-06 | Processo para a producao de aco silicio eletro-magnetico |
PL17087574A PL89829B1 (en) | 1973-05-07 | 1974-05-06 | Silicon steel with high magnetic permeability - prepd. by casting, hot-rolling, annealing and cooling[FR2228854A1] |
JP49049839A JPS5813605B2 (ja) | 1973-05-07 | 1974-05-07 | 磁気的珪素鋼の製造方法 |
ES426047A ES426047A1 (es) | 1973-05-07 | 1974-05-07 | Perfeccionamientos en los procesos para producir acero al silicio electromagnetico de permeabilidad elevada. |
SE7406094A SE415196B (sv) | 1973-05-07 | 1974-05-07 | Framstellning av kiselstal med hog permeabilitet |
RO7478693A RO69739A (ro) | 1973-05-07 | 1974-05-07 | Procedeu de obtinere a benzilor din otel silicios,cu permeabilitate magnetica ridicata |
DE2422073A DE2422073B2 (de) | 1973-05-07 | 1974-05-07 | Verfahren zum Herstellen von Silicium-Stahl mit hoher Permeabilität |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00357973A US3855019A (en) | 1973-05-07 | 1973-05-07 | Processing for high permeability silicon steel comprising copper |
Publications (1)
Publication Number | Publication Date |
---|---|
US3855019A true US3855019A (en) | 1974-12-17 |
Family
ID=23407791
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00357973A Expired - Lifetime US3855019A (en) | 1973-05-07 | 1973-05-07 | Processing for high permeability silicon steel comprising copper |
Country Status (8)
Country | Link |
---|---|
US (1) | US3855019A (it) |
JP (1) | JPS5813605B2 (it) |
BE (1) | BE814023A (it) |
CA (1) | CA1010347A (it) |
DE (1) | DE2422073B2 (it) |
ES (1) | ES426047A1 (it) |
GB (1) | GB1428902A (it) |
IT (1) | IT1011366B (it) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3925115A (en) * | 1974-11-18 | 1975-12-09 | Allegheny Ludlum Ind Inc | Process employing cooling in a static atmosphere for high permeability silicon steel comprising copper |
US3929522A (en) * | 1974-11-18 | 1975-12-30 | Allegheny Ludlum Ind Inc | Process involving cooling in a static atmosphere for high permeability silicon steel comprising copper |
US4054470A (en) * | 1976-06-17 | 1977-10-18 | Allegheny Ludlum Industries, Inc. | Boron and copper bearing silicon steel and processing therefore |
US4078952A (en) * | 1976-06-17 | 1978-03-14 | Allegheny Ludlum Industries, Inc. | Controlling the manganese to sulfur ratio during the processing for high permeability silicon steel |
US4168189A (en) * | 1977-05-20 | 1979-09-18 | Armco Inc. | Process of producing an electrically insulative film |
US4319936A (en) * | 1980-12-08 | 1982-03-16 | Armco Inc. | Process for production of oriented silicon steel |
US4411714A (en) * | 1981-08-24 | 1983-10-25 | Allegheny Ludlum Steel Corporation | Method for improving the magnetic properties of grain oriented silicon steel |
US4581080A (en) * | 1981-03-04 | 1986-04-08 | Hitachi Metals, Ltd. | Magnetic head alloy material and method of producing the same |
US4592789A (en) * | 1981-12-11 | 1986-06-03 | Nippon Steel Corporation | Process for producing a grain-oriented electromagnetic steel sheet or strip |
US5711825A (en) * | 1993-04-05 | 1998-01-27 | Thyssen Stahl Ag | Process for the production of grain oriented magnetic steel sheets having improved remagnetization losses |
US7204894B1 (en) | 2004-03-18 | 2007-04-17 | Nucor Corporation | Annealing of hot rolled steel coils with clam shell furnace |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105956274B (zh) * | 2016-05-04 | 2019-06-07 | 武汉钢铁有限公司 | 通过织构指数评价无取向硅钢磁性能的方法 |
Citations (11)
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US2209686A (en) * | 1938-07-25 | 1940-07-30 | Electro Metallurg Co | Sheared electrical steel sheet |
US2867558A (en) * | 1956-12-31 | 1959-01-06 | Gen Electric | Method for producing grain-oriented silicon steel |
US3151005A (en) * | 1959-07-09 | 1964-09-29 | United States Steel Corp | Method of producing grain-oriented electrical steel |
US3159511A (en) * | 1956-11-08 | 1964-12-01 | Yawata Iron & Steel Co | Process of producing single-oriented silicon steel |
US3287184A (en) * | 1963-10-22 | 1966-11-22 | Bethlehem Steel Corp | Method of producing low carbon electrical sheet steel |
US3345219A (en) * | 1960-05-04 | 1967-10-03 | Vacuumschmelze Ag | Method for producing magnetic sheets of silicon-iron alloys |
US3575739A (en) * | 1968-11-01 | 1971-04-20 | Gen Electric | Secondary recrystallization of silicon iron with nitrogen |
US3632456A (en) * | 1968-04-27 | 1972-01-04 | Nippon Steel Corp | Method for producing an electromagnetic steel sheet of a thin sheet thickness having a high-magnetic induction |
US3671337A (en) * | 1969-02-21 | 1972-06-20 | Nippon Steel Corp | Process for producing grain oriented electromagnetic steel sheets having excellent magnetic characteristics |
US3764406A (en) * | 1971-11-04 | 1973-10-09 | Armco Steel Corp | Hot working method of producing cubeon edge oriented silicon iron from cast slabs |
US3770517A (en) * | 1972-03-06 | 1973-11-06 | Allegheny Ludlum Ind Inc | Method of producing substantially non-oriented silicon steel strip by three-stage cold rolling |
-
1973
- 1973-05-07 US US00357973A patent/US3855019A/en not_active Expired - Lifetime
-
1974
- 1974-04-18 CA CA198,057A patent/CA1010347A/en not_active Expired
- 1974-04-22 BE BE143470A patent/BE814023A/xx not_active IP Right Cessation
- 1974-05-03 IT IT50770/74A patent/IT1011366B/it active
- 1974-05-06 GB GB1980474A patent/GB1428902A/en not_active Expired
- 1974-05-07 ES ES426047A patent/ES426047A1/es not_active Expired
- 1974-05-07 JP JP49049839A patent/JPS5813605B2/ja not_active Expired
- 1974-05-07 DE DE2422073A patent/DE2422073B2/de not_active Ceased
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
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US2209686A (en) * | 1938-07-25 | 1940-07-30 | Electro Metallurg Co | Sheared electrical steel sheet |
US3159511A (en) * | 1956-11-08 | 1964-12-01 | Yawata Iron & Steel Co | Process of producing single-oriented silicon steel |
US2867558A (en) * | 1956-12-31 | 1959-01-06 | Gen Electric | Method for producing grain-oriented silicon steel |
US3151005A (en) * | 1959-07-09 | 1964-09-29 | United States Steel Corp | Method of producing grain-oriented electrical steel |
US3345219A (en) * | 1960-05-04 | 1967-10-03 | Vacuumschmelze Ag | Method for producing magnetic sheets of silicon-iron alloys |
US3287184A (en) * | 1963-10-22 | 1966-11-22 | Bethlehem Steel Corp | Method of producing low carbon electrical sheet steel |
US3632456A (en) * | 1968-04-27 | 1972-01-04 | Nippon Steel Corp | Method for producing an electromagnetic steel sheet of a thin sheet thickness having a high-magnetic induction |
US3575739A (en) * | 1968-11-01 | 1971-04-20 | Gen Electric | Secondary recrystallization of silicon iron with nitrogen |
US3671337A (en) * | 1969-02-21 | 1972-06-20 | Nippon Steel Corp | Process for producing grain oriented electromagnetic steel sheets having excellent magnetic characteristics |
US3764406A (en) * | 1971-11-04 | 1973-10-09 | Armco Steel Corp | Hot working method of producing cubeon edge oriented silicon iron from cast slabs |
US3770517A (en) * | 1972-03-06 | 1973-11-06 | Allegheny Ludlum Ind Inc | Method of producing substantially non-oriented silicon steel strip by three-stage cold rolling |
Non-Patent Citations (3)
Title |
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Kussmann, A., et al., Gekupferter Stahl Fur . . . Transform., in Stahl und Eisen, 50, (1930), pp. 1194 1197, (T5300 S7). * |
Lyman, T., Metals Handbook, ASM, Cleveland, 1948, p. 628, (TA472 A3). * |
Saito, A., Effect of Minor Elements . . . in Silicon Steel, in Nippon Kinzoku, 27, (1963), pp. 191 195. * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3925115A (en) * | 1974-11-18 | 1975-12-09 | Allegheny Ludlum Ind Inc | Process employing cooling in a static atmosphere for high permeability silicon steel comprising copper |
US3929522A (en) * | 1974-11-18 | 1975-12-30 | Allegheny Ludlum Ind Inc | Process involving cooling in a static atmosphere for high permeability silicon steel comprising copper |
US4054470A (en) * | 1976-06-17 | 1977-10-18 | Allegheny Ludlum Industries, Inc. | Boron and copper bearing silicon steel and processing therefore |
US4078952A (en) * | 1976-06-17 | 1978-03-14 | Allegheny Ludlum Industries, Inc. | Controlling the manganese to sulfur ratio during the processing for high permeability silicon steel |
US4168189A (en) * | 1977-05-20 | 1979-09-18 | Armco Inc. | Process of producing an electrically insulative film |
US4319936A (en) * | 1980-12-08 | 1982-03-16 | Armco Inc. | Process for production of oriented silicon steel |
US4581080A (en) * | 1981-03-04 | 1986-04-08 | Hitachi Metals, Ltd. | Magnetic head alloy material and method of producing the same |
US4411714A (en) * | 1981-08-24 | 1983-10-25 | Allegheny Ludlum Steel Corporation | Method for improving the magnetic properties of grain oriented silicon steel |
US4592789A (en) * | 1981-12-11 | 1986-06-03 | Nippon Steel Corporation | Process for producing a grain-oriented electromagnetic steel sheet or strip |
US5711825A (en) * | 1993-04-05 | 1998-01-27 | Thyssen Stahl Ag | Process for the production of grain oriented magnetic steel sheets having improved remagnetization losses |
US5759294A (en) * | 1993-04-05 | 1998-06-02 | Thyssen Stahl Ag | Process for the production of grain oriented magnetic steel sheets having improved remagnetization losses |
US7204894B1 (en) | 2004-03-18 | 2007-04-17 | Nucor Corporation | Annealing of hot rolled steel coils with clam shell furnace |
Also Published As
Publication number | Publication date |
---|---|
ES426047A1 (es) | 1976-07-01 |
JPS5813605B2 (ja) | 1983-03-15 |
IT1011366B (it) | 1977-01-20 |
CA1010347A (en) | 1977-05-17 |
GB1428902A (en) | 1976-03-24 |
JPS5015726A (it) | 1975-02-19 |
DE2422073B2 (de) | 1975-12-11 |
BE814023A (fr) | 1974-10-22 |
DE2422073A1 (de) | 1974-11-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: ALLEGHENY LUDLUM CORPORATION Free format text: CHANGE OF NAME;ASSIGNOR:ALLEGHENY LUDLUM STEEL CORPORATION;REEL/FRAME:004779/0642 Effective date: 19860805 |
|
AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: SECURITY INTEREST;ASSIGNOR:ALLEGHENY LUDLUM CORPORATION;REEL/FRAME:004855/0400 Effective date: 19861226 |
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AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. RECORDED ON REEL 4855 FRAME 0400;ASSIGNOR:PITTSBURGH NATIONAL BANK;REEL/FRAME:005018/0050 Effective date: 19881129 |
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