US3854518A - Melt extrusion method for producing wire from steel alloys - Google Patents
Melt extrusion method for producing wire from steel alloys Download PDFInfo
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- US3854518A US3854518A US00429333A US42933373A US3854518A US 3854518 A US3854518 A US 3854518A US 00429333 A US00429333 A US 00429333A US 42933373 A US42933373 A US 42933373A US 3854518 A US3854518 A US 3854518A
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- 238000001125 extrusion Methods 0.000 title abstract description 14
- 229910000851 Alloy steel Inorganic materials 0.000 title abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000001257 hydrogen Substances 0.000 claims abstract description 65
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 65
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000000155 melt Substances 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims description 54
- 238000002485 combustion reaction Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 16
- 230000000087 stabilizing effect Effects 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 2
- 239000002826 coolant Substances 0.000 abstract description 13
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 238000010791 quenching Methods 0.000 abstract description 8
- 230000000171 quenching effect Effects 0.000 abstract description 8
- 238000010924 continuous production Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 6
- 239000001307 helium Substances 0.000 description 6
- 229910052734 helium Inorganic materials 0.000 description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 3
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
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- 230000009467 reduction Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- -1 e.g. Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011551 heat transfer agent Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/005—Continuous casting of metals, i.e. casting in indefinite lengths of wire
Definitions
- ABSTRACT A method is provided which permits the effective utilization of gaseous hydrogen as a quenching medium in the continuous production of steel alloy wire by extrusion from the melt.
- hydrogen could not be used as a coolant to solidify the extruded stream of molten metal because of its tendency to cause a lowering of the tensile properties of the wire product formed which in turn created great difficulties in takeup.
- This problem has now been overcome by controlling the time of exposure of the extruded wire to the hydrogen coolant. The time in which the wire is in contact with hydrogen is controlled by burning the spent hydrogen after an appropriate predetermined interval of contact.
- the melt In the production of filaments and wire from steel alloys by the process of melt extrusion, the melt is forced through a small orifice and into an oxygen-containing medium as a continuous molten stream. This results in an instantaneous reaction causing the formation of an oxide skin or film about the periphery of the hot jet immediately upon issue from the extrusion orifice.
- the purpose of the film referred to as the stabilizing film, is to protect the liquid stream against surface tension break-up until solidification can be effected by cooling
- the oxide formed In order that the stabilizing film be capable of functioning in the intended manner, the oxide formed must be stable and insoluble in the melt.
- a second'alloying metal be added to the melt before steel can be satisfactorily processed by this method. That is, a second metal is added whose oxide is stable and insoluble in the molten charge.
- Aluminum and silicon have been most commonly used for this purpose, although various other metals, e.g., magnesium, beryllium, chromium, lanthanum and titanium are likewise capable of forming the desired oxide film.
- the second metal is present in only very minor amounts, say from about 0.3 to. 5.0 percent on the weight of the alloy, with from 1.0 to 2.0 percent being most generally used.
- Any gas used for this purpose must possess, as does helium, a high coefficient of heat transfer and be chemically inert to the liquid stream under the conditions of the quenching operation.
- Hydrogen which is relatively inexpensive when compared with helium, is known to have such properties.
- hydrogen has been found to perform even more efficiently than does helium as a heat transfer agent in the quenching operation.
- the hot molten jet issuing from an extrusion unit enters a first cooling zone where initial contact is made with the gaseous hydrogen coolant.
- the hydrogen which is continuously supplied into the entrance of the zone at a predetermined flow rate passes through the zone in cocurrent flow with the free-streaming molten jet.
- the jet and enveloping flow of hydrogen exit directly into a second cooling zone into which air is continuously supplied.
- the air is admitted proximate to the entrance of this second zone at a predetermined flow rate and flows in a direction co-current with that of the extruded jet and the hydrogen coolant.
- the flow of hydrogen and air into the system is adjusted such that upon admixture in the second cooling zone, the hydrogen present in the resulting mixture exceeds the stoichiometric quantity for total combustion with the amount of air present by from about 18 percent.
- ignition of the gaseous mixture is caused to occur within the second cooling zone at a point proximate to its entrance with the products of combustion being swept through the zone and exhausted at the terminal end.
- FIGURE is a schematic sectional view of the presently preferred embodiment of the apparatus of this invention.
- the assembly includes a crucible 11 for containing the melt enclosed within a pressure vessel 12.
- the crucible is provided with an orifice 13 through which is extruded a continuous stream or jet of molten metal generally denoted 14.
- the crucible rests upon a supporting insulating pedestal 15 of pyrolytic graphite construction which in turn rests upon pedestals l6 and 17 supported by the assembly base plate 18.
- the nascent molten jet passes through a reactive gaseous atmosphere contained within cavity 19 of pedestals l5 and 16 where a stabilizing film is formed about the peripheral surface of the molten stream or jet.
- first vertically disposed elongated cooling chamber 20 Positioned immediately beneath the conical stabilization zone formed by cavity 19 is a first vertically disposed elongated cooling chamber 20.
- the upper portion of chamber 20 extends into extrusion assembly 10 through cavity 21 in base plate 18 and terminates in cavity 22 of pedestal 17; while the lower portion extends into a second elongated cooling chamber or column 23 and terminates proximate to the entrance thereof.
- cooling column 23 is of greater length and cross-sectional area than cooling chamber 20.
- the extruded molten stream upon emerging from the stabilizing zone 19 enters cooling chamber 20 and passes through it together with a cocurrent flow of gaseous hydrogen which effects an initial rapid cooling.
- the hydrogen coolant is metered through apertures 24 and 25 in flange member 26 from a supply source (not shown) and is continuously admitted into the entrance of cooling chamber 20 via a flow path through cavity 22 in base plate 18 and pedestal 17 as indicated by arrows 27 and 28.
- a supply source not shown
- the downward descending molten stream 14 and enveloping flow of hydrogen are immediately brought into contact with a metered flow of air.
- the air which may be supplied by a blower or other means (not shown) is introduced proximate to the entrance of cooling column 23 through ports 29 and 30 and flows in a downward direction cocurrently with the hydrogen flow as indicated by arrows 31 and 32.
- the intermingling of hydrogen with air forms a combustible gas mixture which is ignited by passage through a continuously burning hydrogen flame.
- Burning of the gaseous hydrogen-air mixture is preferably conducted proximate to the exit of cooling chamber 20.
- the flame may be produced by an electrically activated spark plug 33 or other suitable means.
- the combustion products are swept downward through cooling column 23 and are utilized as co-current gas to provide necessary aerodynamic drag on the descending metal stream and additional cooling.
- the combustion products Upon exiting from cooling column 23, the combustion products enter exhaust chamber 34 and are exhausted through conduit 35 as indicated by arrow 36 while the molten stream 14 now cooled to a solid wire product is continuously advanced to a take-up device.
- a second ignition system 37 positioned at the exit of cooling column 23 is optional but provides a number of advantages. For example, it provides for the safe disposal of any hydrogen present in the combustion products exhausted at the exit of cooling column 23. Moreover, it provides an alternative site for an initial combustion of the hydrogen-air gas mixture. That is, in some instances it may be desirable and advantageous to effect combustion solely at the exit of cooling column 23, in which case, ignition system 33 would not be placed in operation.
- the hydrogen coolant is metered into the entrace at the top of the first and shorter chamber 20 for initial rapid cooling of the freestreaming molten jet and is burned at the exit thereof after passing through in co-current flow with the molten wire stream.
- Air for combustion is admitted through the top of the cooling chamber 23.
- the combustion products are swept downward through chamber 23 to provide additional cooling and the necessary aerodynamic drag on the wire stream.
- the gaseous hydrogen may be burned at the exit of cooling chamber 23.
- the effective length of hydrogen cooling chamber 20 will vary depending for the most part upon the ejection velocity under which the molten metal is extruded. For extrusion rates up to 1400 feet per minute, a length of about 16 inches has been found satisfactory. Chamber 23 into which the air for combustion is admitted should be of a greater relative length. That is, in the instance when the length of hydrogen cooling chamber 20 is about 16 inches, a length of from about to inches has been found suitable for the chamber 23. Generally speaking, the effective total length of hydrogen cooling chamber 20 and chamber 23 should be at least about 42 inches. A cylindrical or tubular configuration is usually preferred for both chambers 20 and 23, although it is not critical and other configurations could be used if desired.
- the hydrogen quenching medium is continuously introduced into cooling chamber 20 to present a fresh cool supply along the path of the molten stream as it is extruded.
- the minimum effective flow rate of the hydrogen coolant is dependent upon the length of the chamber into which it is introduced, the
- the air flow rate into chamber 23 controls the degree of combustion of the hydrogen exiting from chamber 20. Since the temperature level required to accelerate diffusion of hydrogen out of the wire tends to promote the oxidation of the wire in the presence of air, it is generally desirable to adjust the air flow rate to provide less than the stoichiometric quantities required to effect total combustion of the hydrogen present. The purpose is to exclude oxygen from the combustion products being swept downwardly in chamber 23. Although not required, it is generally preferred that the hydrogen present exceed the stoichiometric quantity for combustion with the amount of air introduced into the system by from about -18 percent.
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Abstract
A method is provided which permits the effective utilization of gaseous hydrogen as a quenching medium in the continuous production of steel alloy wire by extrusion from the melt. Previously, hydrogen could not be used as a coolant to solidify the extruded stream of molten metal because of its tendency to cause a lowering of the tensile properties of the wire product formed which in turn created great difficulties in take-up. This problem has now been overcome by controlling the time of exposure of the extruded wire to the hydrogen coolant. The time in which the wire is in contact with hydrogen is controlled by burning the spent hydrogen after an appropriate predetermined interval of contact.
Description
United States Patent [191 Junker 1 Dec. 17, 1974 22 Filed:
[ MELT EXTRUSION METHOD FOR PRODUCING WIRE FROM STEEL ALLOYS [75] Inventor: Bernhard T. Junker, Raleigh, NC. [73] Assignee: Monsanto Company, St. Louis, Mo.
Dec. 28, 1973 [21] Appl. No.: 429,333
Dobo 164/82 X 3,811,850 5/1974 Dobo 164/82 X Primary ExaminerR. Spencer Annear l 5 7] ABSTRACT A method is provided which permits the effective utilization of gaseous hydrogen as a quenching medium in the continuous production of steel alloy wire by extrusion from the melt. Previously, hydrogen could not be used as a coolant to solidify the extruded stream of molten metal because of its tendency to cause a lowering of the tensile properties of the wire product formed which in turn created great difficulties in takeup. This problem has now been overcome by controlling the time of exposure of the extruded wire to the hydrogen coolant. The time in which the wire is in contact with hydrogen is controlled by burning the spent hydrogen after an appropriate predetermined interval of contact.
4 Claims, 1 Drawing Figure MELT EXTRUSION METHOD FOR PRODUCING WIRE FROM STEEL ALLOYS FIELD OF THE INVENTION This invention relates to the manufacture of fine diameter wire directly from the melt of steel alloys by extruding a free-streaming molten jet which upon solidification yields a solid filamentary product. More specifically, the invention is concerned with an improved method and apparatus for cooling the extruded molten stream to effect solidification. Fine diameter wire is defined as wire having a diameter of less than about 35 mils.
BACKGROUND OF THE INVENTION In the production of filaments and wire from steel alloys by the process of melt extrusion, the melt is forced through a small orifice and into an oxygen-containing medium as a continuous molten stream. This results in an instantaneous reaction causing the formation of an oxide skin or film about the periphery of the hot jet immediately upon issue from the extrusion orifice. The purpose of the film, referred to as the stabilizing film, is to protect the liquid stream against surface tension break-up until solidification can be effected by cooling In order that the stabilizing film be capable of functioning in the intended manner, the oxide formed must be stable and insoluble in the melt. Because the oxide of iron does not possess these required properties, it is necessary that a second'alloying metal be added to the melt before steel can be satisfactorily processed by this method. That is, a second metal is added whose oxide is stable and insoluble in the molten charge. Aluminum and silicon have been most commonly used for this purpose, although various other metals, e.g., magnesium, beryllium, chromium, lanthanum and titanium are likewise capable of forming the desired oxide film. The second metal is present in only very minor amounts, say from about 0.3 to. 5.0 percent on the weight of the alloy, with from 1.0 to 2.0 percent being most generally used.
After the extruded molten stream or jet has been film stabilized, it is rapidly quenched to effect solidification. Previously, this has been accomplished by causing the stabilized stream as it emerges from the extrusion unit to pass through a chamber which is continuously supplied with a quenching medium of helium gas. Although this cooling system has been reasonably effective, the high cost of helium has had an adverse impact on over-all process economics. Consequently, there has been a need and a desire for a more economic gaesous cooling medium which could be satisfactorily substituted for high cost helium.
Any gas used for this purpose must possess, as does helium, a high coefficient of heat transfer and be chemically inert to the liquid stream under the conditions of the quenching operation. Hydrogen, which is relatively inexpensive when compared with helium, is known to have such properties. Moreover, in actual trial runs hydrogen has been found to perform even more efficiently than does helium as a heat transfer agent in the quenching operation.
Despite these advantages, it has not been previously practical or even feasible to utilize hydrogen gas as a cooling medium in continuous production operations.
The reason for this has been its tendency to cause a temporary reduction in the tensile properties of the wire product at the time of solidification, i.e., the wire exhibits a tensile strength when formed which is from 30-40 percent below normal levels. This phenomenon is believed to be caused by the presence of interstitial hydrogen which has diffused into the wire during the cooling procedure. Apparently, the hydrogen slowly diffuses out of the wire product when at ambient temperatures, since the tensile properties generally recover to normal levels in from about 24-36 hours at room temperature. Nevertheless, the drastic reduction in tensile strength at the time the wire is formed causes great difficulty in take-up. That is, the low strength, embrittled wire can not be handled as required for continuous collection on take-up devices.
It is, therefore, an object of this invention to provide a procedure which permits the effective utilization of gaseous hydrogen as a quenching medium in the continuous production of steel alloy wire by extrusion from the melt.
It is a further object of the invention to provide a method and apparatus for hydrogen cooling in the manufacture of steel alloy wire by melt extrusion wherein the tensile properties of the wire product at the time of formation are at levels compatible with continuous take-up.
SUMMARY OF THE INVENTION The afore-mentioned objects are achieved by a procedure wherein the accumulation of interstitial hydrogen in the extruded wire prior to take-up is substantially eliminated. As a result, the tensile strength of the solidified wire is relatively unimpaired and collection on take-up devices can be conducted in the normal manner.
This is accomplished by a controlled exposure of the extruded wire to the hydrogen quenching medium while cooling to effect solidification. The time in which the wire is in contact with hydrogen is controlled by burning the spent hydrogen after an appropriate predetermined interval of contact. By limiting the extent of exposure to the coolant, diffusion of the hydrogen into the interstices of the wire is greatly reduced. Moreover, such control permits cooling of the wire to a temperature level which is still high enough to cause any interstitial hydrogen present therein to diffuse out at an accelerated rate before reaching the take-up mechanisms.
In practicing the present invention, the hot molten jet issuing from an extrusion unit enters a first cooling zone where initial contact is made with the gaseous hydrogen coolant. The hydrogen which is continuously supplied into the entrance of the zone at a predetermined flow rate passes through the zone in cocurrent flow with the free-streaming molten jet. From this first cooling zone, the jet and enveloping flow of hydrogen exit directly into a second cooling zone into which air is continuously supplied. The air is admitted proximate to the entrance of this second zone at a predetermined flow rate and flows in a direction co-current with that of the extruded jet and the hydrogen coolant. Comingling of the gaseous hydrogen coolant with the flow of air causes a combustible gas mixture to form which is ignited by passage through a continuous flame. The products of combustion are exhausted from the second cooling zone at its terminal end'while the solid wire product exiting therefrom is continuously forwarded to take-up devices.
In a preferred embodiment the flow of hydrogen and air into the system is adjusted such that upon admixture in the second cooling zone, the hydrogen present in the resulting mixture exceeds the stoichiometric quantity for total combustion with the amount of air present by from about 18 percent. In addition, ignition of the gaseous mixture is caused to occur within the second cooling zone at a point proximate to its entrance with the products of combustion being swept through the zone and exhausted at the terminal end.
The afore-described procedure may be carried out in an apparatus having a design as illustrated in the accompanying drawing. This novel apparatus can best be understood by the following description of the drawing.
DESCRIPTION OF THE DRAWING The single FIGURE is a schematic sectional view of the presently preferred embodiment of the apparatus of this invention. There is shown, as generally represented by the numeral 10, a typical assembly for extruding a free-streaming molten jet from the melt of a steel alloy. The assembly includes a crucible 11 for containing the melt enclosed within a pressure vessel 12. The crucible is provided with an orifice 13 through which is extruded a continuous stream or jet of molten metal generally denoted 14. The crucible rests upon a supporting insulating pedestal 15 of pyrolytic graphite construction which in turn rests upon pedestals l6 and 17 supported by the assembly base plate 18. Upon emerging from orifice 13, the nascent molten jet passes through a reactive gaseous atmosphere contained within cavity 19 of pedestals l5 and 16 where a stabilizing film is formed about the peripheral surface of the molten stream or jet.
Positioned immediately beneath the conical stabilization zone formed by cavity 19 is a first vertically disposed elongated cooling chamber 20. The upper portion of chamber 20 extends into extrusion assembly 10 through cavity 21 in base plate 18 and terminates in cavity 22 of pedestal 17; while the lower portion extends into a second elongated cooling chamber or column 23 and terminates proximate to the entrance thereof. As shown in the drawing, cooling column 23 is of greater length and cross-sectional area than cooling chamber 20.
.In operation, the extruded molten stream upon emerging from the stabilizing zone 19 enters cooling chamber 20 and passes through it together with a cocurrent flow of gaseous hydrogen which effects an initial rapid cooling. The hydrogen coolant is metered through apertures 24 and 25 in flange member 26 from a supply source (not shown) and is continuously admitted into the entrance of cooling chamber 20 via a flow path through cavity 22 in base plate 18 and pedestal 17 as indicated by arrows 27 and 28. Upon exiting from chamber 20 directly into cooling column 23, the downward descending molten stream 14 and enveloping flow of hydrogen are immediately brought into contact with a metered flow of air. The air which may be supplied by a blower or other means (not shown) is introduced proximate to the entrance of cooling column 23 through ports 29 and 30 and flows in a downward direction cocurrently with the hydrogen flow as indicated by arrows 31 and 32. The intermingling of hydrogen with air forms a combustible gas mixture which is ignited by passage through a continuously burning hydrogen flame. Burning of the gaseous hydrogen-air mixture is preferably conducted proximate to the exit of cooling chamber 20. The flame may be produced by an electrically activated spark plug 33 or other suitable means. The combustion products are swept downward through cooling column 23 and are utilized as co-current gas to provide necessary aerodynamic drag on the descending metal stream and additional cooling. Upon exiting from cooling column 23, the combustion products enter exhaust chamber 34 and are exhausted through conduit 35 as indicated by arrow 36 while the molten stream 14 now cooled to a solid wire product is continuously advanced to a take-up device.
A second ignition system 37 positioned at the exit of cooling column 23 is optional but provides a number of advantages. For example, it provides for the safe disposal of any hydrogen present in the combustion products exhausted at the exit of cooling column 23. Moreover, it provides an alternative site for an initial combustion of the hydrogen-air gas mixture. That is, in some instances it may be desirable and advantageous to effect combustion solely at the exit of cooling column 23, in which case, ignition system 33 would not be placed in operation.
DETAILED DESCRIPTION OF THE INVENTION As has been noted in describing the drawing, a novel apparatus which may be employed in the practice of this invention comprises a first elongated cooling chamber 20 which communicates with a second chamber 23-- the second chamber being of the greater length and cross-sectional area. The hydrogen coolant is metered into the entrace at the top of the first and shorter chamber 20 for initial rapid cooling of the freestreaming molten jet and is burned at the exit thereof after passing through in co-current flow with the molten wire stream. Air for combustion is admitted through the top of the cooling chamber 23. The combustion products are swept downward through chamber 23 to provide additional cooling and the necessary aerodynamic drag on the wire stream. Optionally, the gaseous hydrogen may be burned at the exit of cooling chamber 23.
The effective length of hydrogen cooling chamber 20 will vary depending for the most part upon the ejection velocity under which the molten metal is extruded. For extrusion rates up to 1400 feet per minute, a length of about 16 inches has been found satisfactory. Chamber 23 into which the air for combustion is admitted should be of a greater relative length. That is, in the instance when the length of hydrogen cooling chamber 20 is about 16 inches, a length of from about to inches has been found suitable for the chamber 23. Generally speaking, the effective total length of hydrogen cooling chamber 20 and chamber 23 should be at least about 42 inches. A cylindrical or tubular configuration is usually preferred for both chambers 20 and 23, although it is not critical and other configurations could be used if desired.
As has been noted, the hydrogen quenching medium is continuously introduced into cooling chamber 20 to present a fresh cool supply along the path of the molten stream as it is extruded. The minimum effective flow rate of the hydrogen coolant is dependent upon the length of the chamber into which it is introduced, the
diameter of wire being extruded and the ejection velocity under which the molten metal is extruded. For any given set of such conditions, the appropriate flow rate The air flow rate into chamber 23 controls the degree of combustion of the hydrogen exiting from chamber 20. Since the temperature level required to accelerate diffusion of hydrogen out of the wire tends to promote the oxidation of the wire in the presence of air, it is generally desirable to adjust the air flow rate to provide less than the stoichiometric quantities required to effect total combustion of the hydrogen present. The purpose is to exclude oxygen from the combustion products being swept downwardly in chamber 23. Although not required, it is generally preferred that the hydrogen present exceed the stoichiometric quantity for combustion with the amount of air introduced into the system by from about -18 percent.
The following table presents data on a series of experimental runs in which either the hydrogen or air as delivered into the system was in stoichiometric excess for combustion. The notations under wire appearance indicate whether or not some oxidation occurred during the cooling operation.
Flow Rates It is seen that undesirable oxidation was essentially avoided in runs 2, 3 and 5 where excess hydrogen was employed. However in run number 3 brittleness in the wire occurred when too great of an excess of hydrogen was employed. In conducting the runs reported in the above table the extrusion velocity was 1,200 feet per minute. The cooling chamber into which the hydrogen was injected had a length of 16 inches and the downstream chamber into which the flow of air was introduced had a length of 60 inches.
It is seen from the above description that the objects of this invention are well fulfilled by the method and apparatus of this invention. The description is intended to be illustrative only and it is to be understood that changes and variations may be made without departing from the spirit and scope of the invention as defined by the appended claims.
I claim:
1. In the method for forming fine diameter wire directly from the melt of an alloy of steel by extruding said melt as a free-streaming molten jet into an oxygencontaining medium to form a stabilizing film about the peripheral surface of the jet and thereafter cooling the film stabilized molten jet to produce a solid wire product, the improvement which comprises effecting said cooling by:
a. leading said film stabilized molten jet through a first cooling zone in which gaseous hydrogen is continuously admitted into the entrance thereof at a predetermined flow rate, the direction of said hydrogen flow being cocurrent with that of said molten jet;
b. causing the jet together with said hydrogen flow to enter a second cooling zone being provided with a continuous supply of air introduced proximate to the entrance thereof at a predetermined rate of flow, the direction of said air flow being co-current with that of said jet and said hydrogen whereby a combustible gas mixture of air and hydrogen is caused to form;
c. igniting said combustible gas mixture to cause combustion thereof; and
d. exhausting the products of said combustion at the terminal end of said second cooling zone while continuously forwarding the resulting solidified wire product to a take-up device.
2. The method of claim 11, wherein the combustible gas mixture of hydrogen and air contains an amount of hydrogen which exceeds the stoichiometric quantity for combustion with the amount of air present in said mixture by about from about 10 to 18 percent.
3. The method of claim 1, wherein igniting of said combustible gas mixture occurs proximate to the entrance of said second cooling zone.
4. The method of claim 1, wherein igniting of said combustible gas mixture occurs at the exit of said second cooling zone.
Claims (4)
1. In the method for forming fine diameter wire directly from the melt of an alloy of steel by extruding said melt as a freestreaming molten jet into an oxygen-containing medium to form a stabilizing film about the peripheral surface of the jet and thereafter cooling the film stabilized molten jet to produce a solid wire product, the improvement which comprises effecting said cooling by: a. leading said film stabilized molten jet through a first cooling zone in which gaseous hydrogen is continuously admitted into the entrance thereof at a predetermined flow rate, the direction of said hydrogen flow being cocurrent with that of said molten jet; b. causing the jet together with said hydrogen flow to enter a second cooling zone being provided with a continuous supply of air introduced proximate to the entrance thereof at a predetermined rate of flow, the direction of said air flow being co-current with that of said jet and said hydrogen whereby a combustible gas mixture of air and hydrogen is caused to form; c. igniting said combustible gas mixture to cause combustion thereof; and d. exhausting the products of said combustion at the terminal end of said second cooling zone while continuously forwarding the resulting solidified wire product to a take-up device.
2. The method of claim 1, wherein the combustible gas mixture of hydrogen and air contains an amount of hydrogen which exceeds the stoichiometric quantity for combustion with the amount of air present in said mixture by about from about 10 to 18 percent.
3. The method of claim 1, wherein igniting of said combustible gas mixture occurs proximate to the entrance of said second cooling zone.
4. The method of claim 1, wherein igniting of said combustible gas mixture occurs at the exit of said second cooling zone.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00429333A US3854518A (en) | 1973-12-28 | 1973-12-28 | Melt extrusion method for producing wire from steel alloys |
AU76699/74A AU479109B2 (en) | 1973-12-28 | 1974-12-20 | Improved melt extrusion method for producing wire from steel alloys and apparatus therefor |
GB55091/74A GB1487770A (en) | 1973-12-28 | 1974-12-20 | Manufacture of fine diameter wire |
DE19742460662 DE2460662A1 (en) | 1973-12-28 | 1974-12-20 | MELT EXTRUDING STEEL ALLOYS FOR THE MANUFACTURE OF WIRE |
IT7430874A IT1027927B (en) | 1973-12-28 | 1974-12-20 | PERFECTLY PERFECTED FUSION EXTRUSION PROCESS TO PRODUCE WIRES |
FR7442417A FR2255981B1 (en) | 1973-12-28 | 1974-12-20 | |
SE7416140A SE398308B (en) | 1973-12-28 | 1974-12-20 | IMPROVED MELTING EXTRACTION PROCEDURE FOR PRODUCING WIRE FROM STABLE ALLOYS |
JP49147523A JPS5097524A (en) | 1973-12-28 | 1974-12-20 | |
CA216,977A CA983428A (en) | 1973-12-28 | 1974-12-27 | Melt extrusion method for producing wire from steel alloys and apparatus therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00429333A US3854518A (en) | 1973-12-28 | 1973-12-28 | Melt extrusion method for producing wire from steel alloys |
Publications (1)
Publication Number | Publication Date |
---|---|
US3854518A true US3854518A (en) | 1974-12-17 |
Family
ID=23702793
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00429333A Expired - Lifetime US3854518A (en) | 1973-12-28 | 1973-12-28 | Melt extrusion method for producing wire from steel alloys |
Country Status (1)
Country | Link |
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US (1) | US3854518A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4020891A (en) * | 1974-11-11 | 1977-05-03 | Brunswick Corporation | Melt spinning process and machine |
US6585151B1 (en) | 2000-05-23 | 2003-07-01 | The Regents Of The University Of Michigan | Method for producing microporous objects with fiber, wire or foil core and microporous cellular objects |
US20080047736A1 (en) * | 2006-08-25 | 2008-02-28 | David Levine | Lightweight composite electrical wire |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2976590A (en) * | 1959-02-02 | 1961-03-28 | Marvalaud Inc | Method of producing continuous metallic filaments |
US3216076A (en) * | 1962-04-30 | 1965-11-09 | Clevite Corp | Extruding fibers having oxide skins |
US3771982A (en) * | 1972-06-28 | 1973-11-13 | Monsanto Co | Orifice assembly for extruding and attenuating essentially inviscid jets |
US3788786A (en) * | 1972-08-30 | 1974-01-29 | Monsanto Co | Orifice assembly for extruding low-viscosity melts |
US3811850A (en) * | 1972-12-29 | 1974-05-21 | Monsanto Co | High speed production of filaments from low viscosity melts |
-
1973
- 1973-12-28 US US00429333A patent/US3854518A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2976590A (en) * | 1959-02-02 | 1961-03-28 | Marvalaud Inc | Method of producing continuous metallic filaments |
US3216076A (en) * | 1962-04-30 | 1965-11-09 | Clevite Corp | Extruding fibers having oxide skins |
US3771982A (en) * | 1972-06-28 | 1973-11-13 | Monsanto Co | Orifice assembly for extruding and attenuating essentially inviscid jets |
US3788786A (en) * | 1972-08-30 | 1974-01-29 | Monsanto Co | Orifice assembly for extruding low-viscosity melts |
US3811850A (en) * | 1972-12-29 | 1974-05-21 | Monsanto Co | High speed production of filaments from low viscosity melts |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4020891A (en) * | 1974-11-11 | 1977-05-03 | Brunswick Corporation | Melt spinning process and machine |
US6585151B1 (en) | 2000-05-23 | 2003-07-01 | The Regents Of The University Of Michigan | Method for producing microporous objects with fiber, wire or foil core and microporous cellular objects |
US20080047736A1 (en) * | 2006-08-25 | 2008-02-28 | David Levine | Lightweight composite electrical wire |
US7626122B2 (en) | 2006-08-25 | 2009-12-01 | David Levine | Lightweight composite electrical wire |
US20100071931A1 (en) * | 2006-08-25 | 2010-03-25 | David Levine | Lightweight composite electrical wire with bulkheads |
US8697998B2 (en) | 2006-08-25 | 2014-04-15 | David Levine | Lightweight composite electrical wire with bulkheads |
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