US3844848A - Production of low alloy steel wire - Google Patents
Production of low alloy steel wire Download PDFInfo
- Publication number
- US3844848A US3844848A US00416203A US41620373A US3844848A US 3844848 A US3844848 A US 3844848A US 00416203 A US00416203 A US 00416203A US 41620373 A US41620373 A US 41620373A US 3844848 A US3844848 A US 3844848A
- Authority
- US
- United States
- Prior art keywords
- rod
- wire
- low alloy
- alloy steel
- drawn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000851 Alloy steel Inorganic materials 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229910001562 pearlite Inorganic materials 0.000 claims abstract description 11
- 238000005482 strain hardening Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 238000005275 alloying Methods 0.000 claims description 4
- 238000010622 cold drawing Methods 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 230000035882 stress Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- 229910019582 Cr V Inorganic materials 0.000 description 4
- 229910008458 Si—Cr Inorganic materials 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000010962 carbon steel Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000000171 quenching effect Effects 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000011651 chromium Substances 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- HBXWYZMULLEJSG-UHFFFAOYSA-N chromium vanadium Chemical compound [V][Cr][V][Cr] HBXWYZMULLEJSG-UHFFFAOYSA-N 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
Definitions
- the present invention relates to low alloy steel wire.
- the mechanical properties of drawn carbon-steel wire can be manipulated and controlled by subjecting the wire to oil quench hardening and tempering. It would be desirable to be able to treat low alloy steel so as to'produce wire which has better mechanical'properties than oil quench hardened and tempered wire, espe- 2 (preferably 28 percent); heating the wire leaving the die to 300450C (preferably 420C and forcibly cooling the wire.
- the heat treatment to produce the pearlite structure lower relaxation- 10 preferably comprises heating above the AC point
- Great Britain Pat. No. 748,357 describes a method ofli to d h ldi t a temperature b tw 550 treating cold drawn wire, in which the wire is drawn to d 700C h preferred temperature b i 50C f its final Size in a die and, as 1631/65 the 118,15 heated lowed by cooling in air.
- the material is first given a heat treatment involving heating to a temperature 50-150C above the AC point, air cooling to just above the Ms point, and reheating to 450-650C, followed by air cooling. Then follows multi-hole cold drawing to the finished size, with a reduction in area of at least 40 percent.
- the finished wire is tempered, preferably at 440C or higher, without tensile stress or quenching.
- the steel has a high silicon content.
- the present invention provides a method of producing low alloy steel wire from low alloy steel rod, the method comprising heat treating the rod to produce a pearlite structure; cold drawing the rod to initiate work hardening and thereby raise the tensile strength; drawing the part-drawn rod through a drawing die to reduce As-rolled rod (5 mm diameter) of each steel composition was initially austenitised, cooled to 650C and held at this temperature, and then allowed to cool in air; this provided a pearlite structure. The rod was cleaned, provided with a drawing coat, and drawn to a diameter of 4.4 mm; this initiated work hardening and raised the tensile strength.
- the part-drawn rod was then further drawn, during which operation it was subjected to a reduction in area of 25 percent, to finish at 3.85 mm diameter. As soon as the wire emerged from the die, it was heated to 420C and then quenched from this temperature by forcible cooling using an air blast or water spray.
- the resulting wire had a tensile strength ranging from 158 to 175 kgf/mm
- the mechanical properties of the wire obtained from each steel composition are shown in Table 11.
- the properties of the as drawn wire (not the cross-sectional area by between 10 and 40 percent heated after drawing) are shown for comparison.
- low temperature heat treatment under tension may promote a dislocation locking mechanism involving interstitial carbon and nitrogen atoms, creating a condition similar to strain ageing.
- Additions of such alloying elements as chromium, silicon, and vanadium may promote an interaction between dislocations and alloy carbides, resulting in a further increase in flow stress.
- the rod can be given the pearlite structure by a heat treatment comprising controlled cooling of the rod as it leaves the hot rolling mill.
- a method of producing low alloy steel wire from low alloy steel rod comprising heat treating the rod to produce a pearlite structure; cold drawing the rod to initiate work hardening and thereby raise the tensile strength; drawing the part-drawn rod through a drawing die to reduce the cross-sectional area by between 10 and 40 percent; heating the wire leaving the die to 300450C; and forcibly cooling the wire.
- a method as claimed in claim 1, in which the heat treatment to produce a pearlite structure comprises heating above the AC point, cooling to and holding at a temperature between 550 and 700C, and then cooling in air.
- alloying elements selected from the following elements in the following ranges: Mn 0.20-l.50%, Si 0.l0-4.00%, Cr 0.l04.00%, S 0.050% maximum, P 0.050% maximum, Mo 0.l02.00%, Cu 0.l0-3.00%, Ni 0.l0-5.00%, Ti
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Heat Treatment Of Steel (AREA)
- Metal Extraction Processes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5280572A GB1400872A (en) | 1972-11-15 | 1972-11-15 | Production of low alloy steel wire |
Publications (1)
Publication Number | Publication Date |
---|---|
US3844848A true US3844848A (en) | 1974-10-29 |
Family
ID=10465383
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00416203A Expired - Lifetime US3844848A (en) | 1972-11-15 | 1973-11-15 | Production of low alloy steel wire |
Country Status (5)
Country | Link |
---|---|
US (1) | US3844848A (enrdf_load_stackoverflow) |
JP (1) | JPS5046511A (enrdf_load_stackoverflow) |
DE (1) | DE2356791A1 (enrdf_load_stackoverflow) |
GB (1) | GB1400872A (enrdf_load_stackoverflow) |
SE (1) | SE387369B (enrdf_load_stackoverflow) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3900347A (en) * | 1974-08-27 | 1975-08-19 | Armco Steel Corp | Cold-drawn, straightened and stress relieved steel wire for prestressed concrete and method for production thereof |
US4040688A (en) * | 1973-12-08 | 1977-08-09 | Industriewerk Schaeffler Ohg | Novel cylindrical rollers |
US4046600A (en) * | 1973-12-17 | 1977-09-06 | Kobe Steel Ltd. | Method of producing large diameter steel rods |
US4123296A (en) * | 1973-12-17 | 1978-10-31 | Kobe Steel, Ltd. | High strength steel rod of large gauge |
US4390377A (en) * | 1981-01-12 | 1983-06-28 | Hogg James W | Novel continuous, high speed method of galvanizing and annealing a continuously travelling low carbon ferrous wire |
EP1524323A4 (en) * | 2002-07-22 | 2006-02-01 | Suzuki Metal Industry Co Ltd | PROCESS FOR PRODUCING AN OIL-DAMED YARN |
EP1698712A1 (en) * | 2005-03-03 | 2006-09-06 | Kabushiki Kaisha Kobe Seiko Sho | Steels for high-strength springs excellent in cold workability and quality stability |
US20120091663A1 (en) * | 2009-03-26 | 2012-04-19 | Laszlo Pelsoeczy | Nitriding Grade Steel Material Composition for Manufacturing Piston Rings and Cylinder Liners |
CN109023123A (zh) * | 2018-10-12 | 2018-12-18 | 石横特钢集团有限公司 | 一种840MPa级热轧锚杆钢筋的生产方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5848017B2 (ja) * | 1977-12-16 | 1983-10-26 | 日「鉄」溶接工業株式会社 | 溶接用鋼線材の中間焼鈍方法 |
US4448617A (en) * | 1980-08-05 | 1984-05-15 | Aichi Steel Works, Ltd. | Steel for a vehicle suspension spring having good sag-resistance |
JP2802155B2 (ja) * | 1990-09-21 | 1998-09-24 | 株式会社神戸製鋼所 | 耐疲労性および耐摩耗性に優れた熱処理省略型高張力鋼線材の製造方法 |
CN112126850B (zh) * | 2020-08-24 | 2022-02-22 | 上海衍衡新材料科技有限公司 | 一种耐蚀针布钢及制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2756169A (en) * | 1950-10-19 | 1956-07-24 | John A Roebling S Sons Corp | Method of heat treating hot rolled steel rods |
US3011928A (en) * | 1960-01-18 | 1961-12-05 | Morgan Construction Co | Method for heat treating hot rolled steel rods |
US3574000A (en) * | 1968-02-15 | 1971-04-06 | Huettenwerk Oberhausen Ag | High flexibility steel wire and method of treating same |
US3584494A (en) * | 1968-05-21 | 1971-06-15 | Huettenwerk Oberhausen Ag | High-flexibility steel wire and method of treating same |
US3645805A (en) * | 1969-11-10 | 1972-02-29 | Schloemann Ag | Production of patented steel wire |
US3711338A (en) * | 1970-10-16 | 1973-01-16 | Morgan Construction Co | Method for cooling and spheroidizing steel rod |
-
1972
- 1972-11-15 GB GB5280572A patent/GB1400872A/en not_active Expired
-
1973
- 1973-11-13 SE SE7315320A patent/SE387369B/xx unknown
- 1973-11-14 DE DE2356791A patent/DE2356791A1/de active Pending
- 1973-11-15 US US00416203A patent/US3844848A/en not_active Expired - Lifetime
- 1973-11-15 JP JP48128675A patent/JPS5046511A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2756169A (en) * | 1950-10-19 | 1956-07-24 | John A Roebling S Sons Corp | Method of heat treating hot rolled steel rods |
US3011928A (en) * | 1960-01-18 | 1961-12-05 | Morgan Construction Co | Method for heat treating hot rolled steel rods |
US3574000A (en) * | 1968-02-15 | 1971-04-06 | Huettenwerk Oberhausen Ag | High flexibility steel wire and method of treating same |
US3584494A (en) * | 1968-05-21 | 1971-06-15 | Huettenwerk Oberhausen Ag | High-flexibility steel wire and method of treating same |
US3645805A (en) * | 1969-11-10 | 1972-02-29 | Schloemann Ag | Production of patented steel wire |
US3711338A (en) * | 1970-10-16 | 1973-01-16 | Morgan Construction Co | Method for cooling and spheroidizing steel rod |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4040688A (en) * | 1973-12-08 | 1977-08-09 | Industriewerk Schaeffler Ohg | Novel cylindrical rollers |
US4046600A (en) * | 1973-12-17 | 1977-09-06 | Kobe Steel Ltd. | Method of producing large diameter steel rods |
US4123296A (en) * | 1973-12-17 | 1978-10-31 | Kobe Steel, Ltd. | High strength steel rod of large gauge |
US3900347A (en) * | 1974-08-27 | 1975-08-19 | Armco Steel Corp | Cold-drawn, straightened and stress relieved steel wire for prestressed concrete and method for production thereof |
US4390377A (en) * | 1981-01-12 | 1983-06-28 | Hogg James W | Novel continuous, high speed method of galvanizing and annealing a continuously travelling low carbon ferrous wire |
EP1524323A4 (en) * | 2002-07-22 | 2006-02-01 | Suzuki Metal Industry Co Ltd | PROCESS FOR PRODUCING AN OIL-DAMED YARN |
EP1698712A1 (en) * | 2005-03-03 | 2006-09-06 | Kabushiki Kaisha Kobe Seiko Sho | Steels for high-strength springs excellent in cold workability and quality stability |
US20060196584A1 (en) * | 2005-03-03 | 2006-09-07 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Steels for high-strength springs excellent in cold workability and quality stability |
US7618498B2 (en) | 2005-03-03 | 2009-11-17 | (Kobe Steel, Ltd.) | Steels for high-strength springs excellent in cold workability and quality stability |
US20120091663A1 (en) * | 2009-03-26 | 2012-04-19 | Laszlo Pelsoeczy | Nitriding Grade Steel Material Composition for Manufacturing Piston Rings and Cylinder Liners |
US9650702B2 (en) * | 2009-03-26 | 2017-05-16 | Federal-Mogul Burscheid Gmbh | Nitridable piston rings |
CN109023123A (zh) * | 2018-10-12 | 2018-12-18 | 石横特钢集团有限公司 | 一种840MPa级热轧锚杆钢筋的生产方法 |
Also Published As
Publication number | Publication date |
---|---|
GB1400872A (en) | 1975-07-16 |
DE2356791A1 (de) | 1974-05-16 |
JPS5046511A (enrdf_load_stackoverflow) | 1975-04-25 |
SE387369B (sv) | 1976-09-06 |
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