US3843357A - High strength aluminum alloy - Google Patents
High strength aluminum alloy Download PDFInfo
- Publication number
- US3843357A US3843357A US00392480A US39248073A US3843357A US 3843357 A US3843357 A US 3843357A US 00392480 A US00392480 A US 00392480A US 39248073 A US39248073 A US 39248073A US 3843357 A US3843357 A US 3843357A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- alloy
- weight
- high strength
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000838 Al alloy Inorganic materials 0.000 title description 14
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 24
- 239000000956 alloy Substances 0.000 claims abstract description 24
- 238000005266 casting Methods 0.000 claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 17
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011651 chromium Substances 0.000 claims abstract description 9
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- 239000011701 zinc Substances 0.000 claims abstract description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000010936 titanium Substances 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- -1 aluminum-zinc-magnesium Chemical compound 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910009369 Zn Mg Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- WPPDFTBPZNZZRP-UHFFFAOYSA-N aluminum copper Chemical compound [Al].[Cu] WPPDFTBPZNZZRP-UHFFFAOYSA-N 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
Definitions
- the present invention relates to high strength aluminum alloy for casting having a tensile strength not less than 50 kg/mm. at high temperatures and an elongation not less than 1.5%.
- the alloy consists of 3.0- 6.0% zinc, 2.0-4.0% magnesium, 01-04% titamum, 0.1-0.4% chromium, 0.020.2% lithium and the balance aluminum and inevitable impurities.
- copper may be added but not more than 2.0%.
- aluminum alloy castings having a high tensile strength at room as well as high temperatures are being increasingly required. These alloys are replacing iron materials such as iron castings.
- aluminumzinc-magnesium alloys have been developed, but they must contain a very large amount of zinc or magnesium in order to attain a tensile strength not less than 50 kg./mrn. 0n the other hand, the alloys containing a large amount of zinc or magnesium are subject to hot cracking during casting or reduction of the stress corrosion resistance. Obviously, such defects render these materials unacceptable.
- the high strength aluminum alloy of the present invention is used for casting purposes and is directed to and improving the strength of the casting during heating. Hot cracking is prevented, and the weight of casting is reduced.
- the high strength aluminum casting alloy of the present invention is based on an aluminum-zinc-magnesium alloy to which various elements are added with their amounts being limited as follows.
- the high strength aluminum casting alloy of the present invention is composed of, by weight, 3.0-6.0% zinc, 2.0-4.0% magnesium, 0.l-0.4% titanium, (Ll-0.4% chromium, 0.02-0.2% lithium, copper not more than 2.0%, and the remainder of aluminum and inevitable impurities.
- the alloy compositions are indicated in Table 1.
- high strength aluminum casting alloy of the present invention was not limited to those described and the series of numbers used in the composition of this alloy are referred to in the following experimental examples.
- the above aluminum alloys with Nos. 1 to 8 were retained, after casting, at 470 C. for 16 hours, immediately followed by quenching (in water at room temperature), and then subjected to an artificial aging at C. for 24 hours, corresponding to H8 T -Temper, and their room temperature tensile strength, high temperature tensile strength and elongation were determined.
- the T -tempered materials were machined into test pieces having a parallel portion of 8 x 40 mm.
- test pieces were preheated at the respective temperatures of C., 250 C., and 350 C. for 100 hours, and thereafter the pieces were set to a test machine and retained therein at the respective temperatures for 15 additional minutes before the tension test.
- test pieces were preheated at the respective temperatures of 150 C., 250 C., and 350 C. for 100 hours prior to the measurement of tensile strength at the respective temperatures.
- the hot crack test is generally described as follows.
- the material to be tested is cast into an annular metal mold and its contraction upon solidfying is restricted by a core.
- the total length of cracks generated thereby is determined. The results are indicated in Table 4.
- a content of zinc less than 3.0% does not provide a tensile strength not less than 50 kg./mm. while its content exceeding 6.0% adversely affects the castability and the stress corrosion resistance of the material.
- a content of magnesium less than 2.0% does not provide a tensile strength not less than 50 kg./mm. while its content exceeding adversely affects the castability and the stress corrosion resistance of the material.
- a content of lithium less than 0.02% decreases the tensile strength at both room temperature and high temperatures, while a content exceeding 0.2% reduces the tensile strength at both room temperature and high temperatures. With more than 0.2% lithium elongation is reduced as well as the eifect for preventing hot cracks. Also, more than 0.2% lithium deteriorates the surface condition of casting.
- a content of titanium and chromium less than 0.1% each does not produce the effect for preventing the hot crack, while their respective contents exceeding 0.4% lowers the elongation.
- a high strength aluminum casting alloy having a tensile strength of not less than 50 kg./mm. at room temperatures and an elongation of not less than 1.5%, the alloy consisting substantially of 3.0-6.0% by weight zinc, 2.0-4.0% by weight magnesium, 0.10.4% by weight titanium, 01-04% by weight chromium, 0.02-0.2% by weight lithium, and the balance aluminum and inevitable impurities.
- a high strength aluminum casting alloy as in claim 1 additionally including not more than 2.0% by weight copper.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP47109098A JPS5222610B2 (enrdf_load_html_response) | 1972-10-31 | 1972-10-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3843357A true US3843357A (en) | 1974-10-22 |
Family
ID=14501519
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00392480A Expired - Lifetime US3843357A (en) | 1972-10-31 | 1973-08-29 | High strength aluminum alloy |
Country Status (2)
Country | Link |
---|---|
US (1) | US3843357A (enrdf_load_html_response) |
JP (1) | JPS5222610B2 (enrdf_load_html_response) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4172181A (en) * | 1977-05-10 | 1979-10-23 | Furukawa Aluminum Co., Ltd. | Composite material for vacuum brazing |
US6368427B1 (en) | 1999-09-10 | 2002-04-09 | Geoffrey K. Sigworth | Method for grain refinement of high strength aluminum casting alloys |
US6645321B2 (en) | 1999-09-10 | 2003-11-11 | Geoffrey K. Sigworth | Method for grain refinement of high strength aluminum casting alloys |
US20140251511A1 (en) * | 2013-03-09 | 2014-09-11 | Alcoa Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
EP2959029A4 (en) * | 2013-02-19 | 2016-10-05 | Alcoa Inc | HEAT-TREATABLE ALUMINUM ALLOYS WITH MAGNESIUM AND ZINC AND METHOD FOR THE PRODUCTION THEREOF |
CN107815569A (zh) * | 2017-09-29 | 2018-03-20 | 宁波优适捷传动件有限公司 | 一种汽车转向节及其制备方法 |
US12123078B2 (en) | 2019-02-20 | 2024-10-22 | Howmet Aerospace Inc. | Aluminum-magnesium-zinc aluminum alloys |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110629084B (zh) * | 2019-09-23 | 2021-01-15 | 山东南山铝业股份有限公司 | 一种高导热变形铝合金的制备方法及产品 |
-
1972
- 1972-10-31 JP JP47109098A patent/JPS5222610B2/ja not_active Expired
-
1973
- 1973-08-29 US US00392480A patent/US3843357A/en not_active Expired - Lifetime
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4172181A (en) * | 1977-05-10 | 1979-10-23 | Furukawa Aluminum Co., Ltd. | Composite material for vacuum brazing |
US6368427B1 (en) | 1999-09-10 | 2002-04-09 | Geoffrey K. Sigworth | Method for grain refinement of high strength aluminum casting alloys |
US6645321B2 (en) | 1999-09-10 | 2003-11-11 | Geoffrey K. Sigworth | Method for grain refinement of high strength aluminum casting alloys |
EP2959029A4 (en) * | 2013-02-19 | 2016-10-05 | Alcoa Inc | HEAT-TREATABLE ALUMINUM ALLOYS WITH MAGNESIUM AND ZINC AND METHOD FOR THE PRODUCTION THEREOF |
EP2964799A4 (en) * | 2013-03-09 | 2016-12-21 | Alcoa Inc | HEAT-TREATABLE ALUMINUM ALLOYS WITH MAGNESIUM AND ZINC AND METHOD FOR THE PRODUCTION THEREOF |
US9315885B2 (en) * | 2013-03-09 | 2016-04-19 | Alcoa Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
US20140251511A1 (en) * | 2013-03-09 | 2014-09-11 | Alcoa Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
US9580775B2 (en) * | 2013-03-09 | 2017-02-28 | Arconic Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
US9850556B2 (en) * | 2013-03-09 | 2017-12-26 | Arconic Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
US20180094339A1 (en) * | 2013-03-09 | 2018-04-05 | Arconic Inc. | Heat treatable aluminum alloys having magnesium and zinc and methods for producing the same |
CN107815569A (zh) * | 2017-09-29 | 2018-03-20 | 宁波优适捷传动件有限公司 | 一种汽车转向节及其制备方法 |
CN107815569B (zh) * | 2017-09-29 | 2019-05-10 | 宁波优适捷传动件有限公司 | 一种汽车转向节及其制备方法 |
US12123078B2 (en) | 2019-02-20 | 2024-10-22 | Howmet Aerospace Inc. | Aluminum-magnesium-zinc aluminum alloys |
Also Published As
Publication number | Publication date |
---|---|
JPS5222610B2 (enrdf_load_html_response) | 1977-06-18 |
JPS4965915A (enrdf_load_html_response) | 1974-06-26 |
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