US3832435A

US3832435A - Process for the manufacture of crimped fibers and filaments of linear high molecular weight polymers

Info

Publication number: US3832435A
Application number: US00158212A
Authority: US
Inventors: G Bauer; L Kramer; H Kuhn
Original assignee: Hoechst AG
Current assignee: Hoechst AG
Priority date: 1970-07-03
Filing date: 1971-06-30
Publication date: 1974-08-27
Anticipated expiration: 1991-08-27
Also published as: DE2032950A1; NL7108895A; FR2100236A5; CA966962A; GB1325939A; BE769431A; AT323312B; CH530477A

Abstract

Fibers and filaments of linear high molecular weight polyesters and copolyesters having a latent three-dimensional crimp are produced by passing the spun filaments after their exit from the spinneret, over a rotating cooled cylinder at a temperature at which they do no longer stick on to the cylinder but are not fully cooled down. The cylinder has a temperature in the range of from 15* to 90*C and rotates at a circumferential speed U of from Vf/50 to Vf-Vf/90, Vf being the draw off speed of the filaments. The filaments are in contact with a surface section of the cylinder the length of which is determined by a contact angle of 10* to 150*.

Description

Elite States Patent 1191 Bauer et al.

PROCESS FOR THE MANUFACTURE OF CRINIPED FIBERS AND FILANIENTS OF LINEAR HIGH MOLECULAR WEIGHT POLYNIERS Inventors: Gunther Bauer, Bobingen; Lothar Kramer, Bad Hersfeld; Helrnut Kuhn, Bobingen, all of Germany F arbwerke Hoechst Aktiengesellschaft vormals Meister Lucius & Bruning, Frankfurt/Main, Germany Filed: June 30, 1971 Appl. No.: 158,212

Assignee:

Foreign Application Priority Data July 3, 1970 Germany 2032950 US. Cl 264/168, 264/210 F Int. Cl D01d 5/22 Field of Search 264/176 F, 168, 210 F References Cited UNlTED STATES PATENTS Neal 264/290 3,458,890 8/1969 3,480,709 11/1969 Jacob et a1. 264/l76 2 3,499,953 3/1970 Stanley 264/210 2 3,511,905 5/1970 Martin 264/210 2 3,520,766 7/1970 Newman 264/210 Z 3,547,891 12/1970 Snead et a1. 264/237 3,629,386 12 1971 Knapp 264 176 2 FOREIGN PATENTS OR APPLICATICNS 809,273 2/1959 Great Britain 264 176 2 1,189,393 4/1970 Great Britain 264 210 Z Primary Examiner lay H. Woo Attorney, Agent, or FirmConnolly and Hutz 7] ABSTRACT Fibers and filaments of linear high molecular weight polyesters and copolyesters having a latent threedimensional crimp are produced by passing the spun filaments after their exit from the spinneret, over a rotating cooled cylinder at a temperature at which they do no longer stick on to the cylinder but are not fully cooleddown. The cylinder has a temperature in the range of from 15 to 90C and rotates at a circumferential speedU of from V/SOto V -V/90, V, being the draw off speed of the filaments. The filaments are in contact with a surface section of the cylinder the length of which is determined by a contact angle of 10 to 150.

7 Claims, 3 Drawing Figures PATENm w"? 7 20. 4

INVENTORS GUNTER BAUER HELMUT KUHN I TTORNEYS PROCFSS FOR THE MANUFA OF CRIMPED FIBERS AND FILAMENTS OF 51* h HIGH MOLECULAR WEIGHT POLYll/ERS The present invention relates to a process for the manufacture of fibers and filaments of linear, high molecular weight polyesters and copolyesters having a latent, three-dimensional crimp and to a device suitable for carrying out the said process.

It is especially easy to influence the crystallization and orientation of melt spun filaments of linear, high molecular weight polymers after they have left the spinneret and as long as they have not yet completely solidi fied. When the spun filament is unilaterally quenched or heated, the degree of orientation and crystallization varies over the cross section of the filament, which can be determined by measuring the different birefringence values on the opposite sides of the filament. In a later shrinking process the differences in orientation and crystallization thus produced cause the filament to shrink to different extentson the opposite sides of its cross section whereby a helical or spiral crimp of the filament is obtained.

It has been proposed to produce such an asymmetric crystallization and orientation by'unilaterally heating the filament (cf. British Patent 1,016,100). An analogous effect may be obtained'by unilateral quenching, for example by means of a liquid film on a porous support, into which film the filament immerses with part of its diameter only (cf. French Patent 1,145,727). Furthermore, it is possible to cool freshly spun filaments on one side by a gas current just below the spinneret (cf. French Patent 1,257,932). A three-dimensional crimp may also be brought about with the aid of a cooling body installed in the spinning shaft so as to be in contact with one side only of the filament (cf. French Patent 1,559,751).

It is known that in the manufacture of filaments from high melting substances, for example glass, a quenching below the spinneret by 1,000 to 1,500 centigrade sets the curvature produced thereby so that a strong visible crimp is obtained. To quench the glass filaments, thin cooling rods as well as two air currents directed one against the other are used (cf. British Patent 769,876). This process used for glass filaments is unsuitable in the manufacture of filaments from organic linear polymers of high molecular weight because the considerably smaller temperature difference between the plastic and the solid state is not sufficient to stabilize the geometric shape taken at the moment of quenching. Moreover, polyester filaments which have not been drawn after quenching, have too low a tensile strength and a poor elasticity, contrary to glass filaments.

The known methods permit, with more or less success, the manufacture of low titre, melt-spun filaments of linear, high molecular weight polymers having a spiral r helical crimp. With high titres, these methods do not yield filaments with satisfactory crimp.

The known modes of operation are not suitable to produce a sufficient gradient of birefringence over the cross section of the filament because the contact between the filament and the cooling device is not intense and effective enough.

The present invention provides a process and a device for the manufacture of fibers and filaments of high molecular weight polyesters and copolyesters, especially polyethylene terephthalate, which fibers and filaments have a latent three-dimensional crimp and a final titre in the range of from 4 to 300 dtex. Dtex is the weight of 10,000 m. of filament.

Fibers and filaments of this type are produced by passing the spun filaments, after they have left the spinneret, over a rotating cooled cylinder having a temperature of from 15 to C, preferably 20 to 40C and a circumferential speed U in the range of from U= V150 to U U V W/90, preferably U= V,/l0 to U= 6V,/1O V; being the draw off speed of the spun filaments, while being in contact with the cooled cylinder on a surface section the length of which is determined by a contact angle of 10 to 150, preferably 30 to To carry out the process of the invention a device is used comprising a first cooled, driven cylinder, and a second cooled driven cylinder which can be displaced on a semi-circular orbit preferably concentric with respect to the jacket of the first cylinder and locked at any point of this orbit, the distance in meters between the centers of the two cylinders being not larger than b =R +R 1 10 cos a in which R is the radius of the first cylinder, R4 is the radius of the second cylinder' in meters and 0: indicates the contact angle.

According to a preferred variant of the device of the invention the first cooled cylinder has a diameter of 0.3 10 to 20 10 mm, preferably 1.7 lO to 4.0 10 mm and the second cylinder has a diameter of 0.3 10 to 1 10 mm, preferably 0.3 10 to 0.9 10 mm. The circumferential speed of the second cylinder is preferably in the range of from 0 to l 10 m/min, more preferably 0 to 0.9 10 m/min.

The process of the invention yields especially valuable fibers and filaments from a high molecular weight linear polyester having a specific viscosity above 0.5, preferably above 0.8, measured with a l percent by weight solution of the polymer in phenol/tetrachloroethane in a weight ratio of 3 2 2. After drawing, the polyester filaments have a final titre of 4 to 300 dtex.

The manufacture of the filaments having a latent crimp according to the process of the invention is now described with reference to the accompanying drawing in which FIG. 1 is a side view of the device according to the invention,

FIG. 2 is a front view of the device and,

FIG. 3 is a cross sectional view of a filament with different zones of orientation and crystallization.

The polyester is melted in known manner with the aid of a melting grate or on an extruder and the melt is passed through a spinneret having such a number of orifices that the filaments 2, after having left the spinneret 1, lie side by side on cylinder 3 without disturbing each other, so that they cannot stick together while they travel over the surface of the cylinder. To this effect the orifices are preferably displaced with respect to one another. Their number thus depends on the diameter of the spinneret and the width of the cylinder. Further definitions are given in the examples.

Cylinder 3 is installed below spinneret 1 at such a distance (a) that the spun filaments 2 when striking the surface of cylinder 3 are cooled at a temperature at which they are no longer sticky but at which orientation and crystallization can still be influenced by quenching. As these two conditions do not always agree with one another, the cylinder should have a surface such that a good contact with the filaments is ensured as long as they are on the cylinder but that they readily detach when leaving it. For this purpose the cylinder preferably has a mat chromium plated surface. Distance (a) depends on the titre, the spinning temperature and the circumferential speed U of cylinder 3 in the manner described in the paragraph dealing with the influence of the spinning parameters and it can easily be adjusted empirically. It should be as small as possible.

To adjust the temperature of cylinder 3 a cooling medium is passed through which may be either liquid or gaseous. In most cases tap water or desalted water will be used, which is supplied and withdrawn centrically 7,8.

Cylinder 3 rotates in the direction indicated by the arrow in FIG. I and has a drive of its own. The circumferential speed U is adjusted to a value in the range of from U V,/50 to U V,V,/90, preferably U= V/IO to U= 6V,/l0, v being the draw off speed or the spun filaments.

An intense contact of the large cylinder 3 with the spun filaments 2 is brought about by a smaller cooled and driven cylinder 4. At the beginning of the spinning operation, small cylinder 4 the diameter of which is preferably in the range of from 0.5 10 to 0.7 10 mm is situated in position 4a. It can be displaced along a semi-circular orbit c which is preferably concentric with respect to cylinder 3. After the beginning of spinning it is swung into a position 4. Owing to the fact that it can be locked at any point of orbit c, contact angle a defined above of the spun filaments can be adjusted on cylinder 3 as desired. In FIG. 1, the contact angle a is shown as a sector of cylinder 3.

Cylinder 4 preferably has the same mat chromium plated surface as large cylinder 3 and is cooled by a cooling medium supplied and discharged centrically 9, l0. Cylinder 4 advantageously has approximately the same surface temperature as cylinder 3, is driven by its own drive in the direction of the arrow indicated in FIG. I. In the preferred variant it has a circumferential speed of to l 10 preferably 0 to 0.9 10 m/min.

Distance [2 between the centers of the two cylinders in meters should not be larger than b=R +R,+l+ l0cosa, R and R, being the respective radii of large cylinder 3 and small cylinder 4 in meters and (1 representing the contact angle. The distance is defined by the fact that with a position of cylinders 3 and 4 with respect to one another with a contact angle a of 90 a distance b which is larger as defined above causes the filaments to break. The distance between the two cylinders may be the larger the closer the direction of the filaments between the two cylinders comes to the perpendicular (a 0).

After having left small cylinder 4 the bundle of cooled filaments 5 is passed over a guide 6 or another deflection roll and wound up or laid down in a spinning pot without having passed a draw off shaft within a length of 10 to meters as otherwise necessary with coarse filaments, suitably after having been treated with a known antistatic and antiadhesive preparation.

The spinning tow obtained in this manner can be drawn as usual, for example between drawing elements with the aid of saturated vapor or superheated steam, warm water or hot air. It is also possible to heat part or all of the godets of the intake unit.

The three-dimensional crimp can be released either in the tow or in the cut fibers in the apparatus used in the manufacture of synthetic fibers for setting the crimp in the stuffing chamber and eliminating too large a shrinkage. The tow (with an advance of about 1 7) or the flock can be passed, for example, on a conveyor belt through a zone of hot air or superheated steam. As in the case of conventional processes for crimping fibers in the stuffing chamber, the heat treatment is carried out to avoid too large a shrinkage by anticipation, whereby asymmetrically oriented fibers acquire a spiral crimp.

The heat treatment is carried out at a temperature in the range of from to 230C, preferably to 160C. For the transmission of heat, air, steam, liquids or heated surfaces may be used.

in the process of the invention the various spinning parameters decisively influence the properties of the crimped fibers obtained. There must be taken into consideration not only the specific viscosity of the starting material, the number of orifices of the spinneret, the conveyed amount of spinning mass and the draw off speed of filaments, but also the distance a of large cylinder 3 from spinneret 1, the circumferential speed U of cylinder 3, the contact angle a of the spun filament around cylinder 3 and the circumferential speed Z of small cylinder 4.

Influence of the specific viscosity of the starting material A high specific viscosity of the starting material means a high melt viscosity and simultaneously a higher spinning tension (measured between guide 6 and the pull-off godet before the winding up. A higher spinning tension reduces the danger of sticking of the spun filaments on the cylinder 3 and thus permits a reduction of the distance a whereby, on the one hand, the filaments are quenched by cooling cylinder 3 while having a higher temperature so that the difference in temperature between the cooled and the uncooled side of the filament is greater and, on the other, the filaments are quenched at a earlier stage of pre-orientation, whereby the gradient of birefringence over the cross section of the filament becomes larger, i.e. a stronger crimp is fonned after release.

In the following Table l are compared the crimping properties of two types of filaments spun under identical conditions from two starting materials having different specific viscosities (the other parameters not mentioned are kept constant in this and the following experiments).

The abbreviations used in the table have the following meaning:

K (crimp) l 1 /1,. percent wherein l is the length of a crimped fiber loaded with a preliminary load of 1.8 mg/dtex,

I is the length of the same fiber in a de-crimped state.

The force necessary for de-crimping is determined with the aid of a force/elongation diagram of the respective fiber type to be tested.

K (residual crimp) I l /l 100 percent 3,832,435 6 wherein Table 2a 1,; is the same length of a crimped fiber loaded with a preliminary load of 1.8 mg/dtex as with l, with the I sole difference that fiber R is loaded prior to the if 313 AD 222?;

test for l minute with a load of 0.45 p/dtex and the 5 measurement is carried out after a subsequent re- 2 2? 3g g? covery of 1 minute, I is the length of the fiber R in the de-crim'ped state cf 1 a W ..h. a :4... i .H e) 1 o Influence of the draw off speed Table 1 An increase in the drawoff speed mainly increases the spinning tension whereby, as pointed out above in fixpeNrment K,.(%) R bends/cm connection with the specific viscosity, the distance a y between cooling cylinder 3 and spinneret 1 can be re- 1 0.8 42.9 1 0 4 duced and a more pronounced crimp can be produced 2 0 9s 53 0 34 s 10 4 (cf. Tables 3 and 4).

2. Table 3 m. Exp. final supply of draw off distance draw ratio K K R bends/ No. titre spinning speed a cm dtex mass g/min m/min mm Influence o ftlir 'humserardrtri'ces" irriiies siaaerr' Table zsirows mart an;fianhi ttmzmiat been With too high a number of orifices in the spinneret asymmetrically quenched according to the process of the distance between the spun filaments on the cooled the invention have a relatively high degree of preoriencylinder 3 and on the path from the spinneret l to said tation. The degree of preorientation may be further incooled cylinder is very small so that the individual filacreased by a high draw off speed and a high specific visments may stick together owing to vibration of the apcosity of the starting material. By an increasing degree paratus or a draft, whereby processing troubles arise as of preorientation, the difference in orientation caused in conventional spinning and drawing processes. by quenching is likewise increased, this being desirable. Influence of the conveyance of spinning mass The high degree of preorientation yields filaments Under constant conditions but with a higher amount which can be drawn to a small extent only. A draw ratio of spinning mass conveyed the titre of the spun filaof l :4 or there above, as generally used with polyester ments naturally increases. filaments, would cause the filaments to break and form With a low titre the spun filaments often come into laps on the drawing godets. Care should be taken, howcontact with the large cylinder after they have substan- 40 ever, that the highest possible draw ratio is used as the tially cooled down, since otherwise they do not support degree of shrinkage, the difference in shrinkage bethe tension exerted thereon. tween the cooled and the uncooled side of the filaments if too large a contact angle a is chosen, filaments of and consequently the crimp depend thereon. very low titre are cooled down over their entire cross Influence of distance a between spinneret 1 and cooled section so that crimping is not possible. ylind 3 Under identical conditions filaments having different final titres are cooled to a different extent over their cross section. In Table 2 there are indicated the differences in the birefringence as a measurement for the asymmetry of the spun filaments with respect to crystallization and orientation in different sections of their cross section in filaments of two different titres. FIG. 3 of the accompanying drawing illustrates the sections where the measurements were taken. The final titre is the titre of the filaments and fibres after drawing and development of the crimp.

lt is obvious mime greateEtheHistance a between spinneret l and cooled cylinder 3, the smaller the difference in the birefringence AD in the opposite sides of the cross section of the filament. The lower the temperature of the filament at the moment it strikes cooled cylinder 3, which depends on the distance between the spinneret and the cylinder, the smaller the temperature difference in the opposite sides of the filament after quenching. Hence, the intensity of the crimp diminishes, while the draw ratio possible without breaking the filaments, and consequently the tensile strength and Table 2 the bending-breaking-stress stability increase (cf. Table Y 4). Therefore, the smallest distance yields the best birefringence l0 Exp, final i 15 in i 3rd diff r crimp. In consideration of the above statements, this No. g ue smallest distance must be greater with higher titres, ex) 3,5,: 232 higher spinning temperatures and a higher circumferential speed U of cylinder 3 than with a fine titre, a 2 8 fig is? 2-2 v lower spinning temperature and a slower speed of rotation of cylinder 3. The most favorable distance a for the chosen combination of the other parameters is the dis- The influence of the difference in the birefringence tance at which the filaments just run off cylinder 3 (AD) on the crimp is shown in the following Table 2a). without sticking together or being entrained.

Table 4 Experiment No. 7 8 9 distance (mm) 400 600 900 tensile strength (p/dtex) 22.7 30.1 39.2 elongation at break 7!) 40.3 39.5 40.2 K ('71) 39.3 35.5 33.0 K (/r) 28.4 27.4 24.3 bends/cm 6.4 5.6 4.8 chafing-bending turns 960 1360 1500 until break The tensile strength and elongation at break were measured on a Fafegraph fiber breaking apparatus of Messrs. Textechno and the bending-breaking-stress stability was determined on a testing device as described in Chemiefasern, No. 12 (1962), page 853 by K.l-l. Grunewald. lnfl uence of the circumferential speed U of cylinder 3 The smaller the circumferential speed U of cylinder 3 with respect to the draw off speed V of the spun filaments, the higher the friction and the lower the degree of orientation of the molecules on the cooled side of the surface. On the other hand, by the friction a tension is built up towards the large cylinder which results in a higher preorientatipn and hence a lower draw ratio.

The above experiments show that with a circumferential speed U of cylinder 3 of less than V110, fibers Table 6 Exp. circumferential draw final tensile elonga- No. speed 2 m/min ratio titre strength tion at (dtex) (p/tex) break Influence of the contact angle a A larger contact angle a of the filaments round cylinder 3 results in a longer residence time of the filaments on the cooled surface. Hence, a larger portion of the cross section of the filament is cooled, the crimp becomes more stable (as the portion causing the crimp is Table 5 Experiment No. 10a 10b 1 1 12a 12b pull off V, (m/min) 1000 1000 1000 1000 1000 U (m/min) 50 200 270 340 700 final titre (dtex) 51 46 39 34 25 AD 73 60 32 18 4 draw ratio 1 1.26 121.39 1:1.64 111.89 112.47 tensile strength (p/tcx) 9 1 17.0 33.0 34.6 37.1 elongation at break /r) 23.2 31.9 34.6 39.6 38.9 K, (91) 69.4 61.5 32.0 28.0 22.3 K (61) 47.7 45.4 25.3 19.8 15.6 bends/cm 11 6 10.3 5.6 4.8 2.1 chafing-bending turns until break 7 130 1200 2070 2340 are obtained which have a poor tensile strength and abrasion resistance and are, therefore, not very suitable for practical purposes. With a circumferential speed.

greater) but the fineness of the bends is a little reduced. The difference in birefringence increases with an increasing angle while the draw ratio decreases to a small higher than 6 V110, fibers having large bends are 0b-- n )dcfincd in Example 1 below tained which are not very voluminous and of minor in-' terest only.

When in the spinning process the circumferential The following examples described fibers and filaments produced with the aid of the device of the invention. The indicated titres do not represent limits of the process of the invention, fibers and filaments having a speed of Cylinder 315 below 1 above I I finer or larger titre and a more intense latent threewith a contact angle within the indicated range, considerable spinning difficulties are encountered or uncrimped fibers are obtained. Influence of the circumferential speed 2 of cylinder 4 dimensional crimp can also be produced.

The filaments and fibers produced by the process of the invention and having medium or large titres have an excellent three-dimensional crimp of good stability. They are very suitable as upholstery filling or for the manufacture of tufted felt carpets.

EXAMPLE 1 Polyethylene terephthalate having a specific viscosity of 1.005, measured with a 1 percent by weight solution of the polymer in a 3 2 parts by weight mixture of phe- 1 nol and tetrachloroethane, was spun as described conveyance of p g mass 245 s/min above through a spinneret having 25 orifices in a line f Speed filaments 000 f28 C d h f n distance a of cylinder (3) at a spinning temperature 0 un er t e o owing f spinneret (1) 450 mm spinning conditions: 5 Contact angle 110 circumferential speed U of cylinder (3) 270 m/min circumferential speed Z of cylinder (4) 0.9 m/min radius of cylinder (3) 8.5 cm conveyance of spinning mass I 240 g/rnin temperature of Cylmder 3) 36 C draw off speed of filaments 550 m/miri distance a of cylinder (3) from s 't l 50 g'figgfl c The other conditions were identical with those of Exif g g Speed U V ample 1. The fibers obtained after drawing in a ratio of f g R Z 1 1.52 and a heat treatment under the conditions of cylinder 4 2.65 m/min specified in Example 1 had the following properties: diameter of cylinder (3) 19 cm diameter of cylinder (4) 7 cm temperature of cylinder (3) 27C temperature of cylinder (4) 27C '"dlvldual dtex tensile strength p/tex 28 elongation at break D 32.1 crimp K, 42.9 v I residual crimp K 3 l .l The tow was drawn in a ratio of 1 1.94 by blowing crimp slflbilily saturated steam onto it between godets having room e temperature and the crimps in the tow were developed I in the setting tube by means of hot air (300C). The fil- Flee much had been Spun from the same Polymer amems obtained had the following properties: by a conventional process, i.e., without the cooled cylinder, with a conveyance of 300 g/min and a draw off W a v. a speed of 425 m/min and drawn in a ratio of 1 4.03 had the following properties:

individual titre dtex l03 tensile strength p/tex 21.8 30

clon t'o tbre k D 7 38.7

crim? I n a a c 431 individual titre dtex 46.8

residual crimp 34A tensile strength p/tex 30.8

crimp ability 7L6 elongation at break D 64.4

crim stabilit =K K {00 resi ua crimp R o p y l crimp stability 1 35.8 bends/cm 4.8

EXAMPLE 2 The above values shown that fibers of high titre spun according to the process of the invention have an initial 40 crimp and residual crimp that are considerably higher than the crimp obtained in a conventional stuffing chamber for two-dimensional crimps.

Polyethylene terephthalate as defined in Example 1 was spun at 285C through a spinneret with 120 orifices in a row. With a conveyed amount of spinning mass of 205 g/min and a draw off speed of 1,800 m/min the following conditions were observed:

EXAMPLE 4 distance a of cylinder (3) from Spinner 150 mm Polyethylene terephthalate having a specific viscosity circumferential peed U of cylin er (3) 440 m/mln of 1.05 was spun through a spinneret with 43 trilobal orifices at a temperature of 291C. The cooled cylinder 3 had adiameter of 21 cm. In the present and in all following examples cylinder 4 had a diameter of 70 mm and was kept'at a'temperatuie of 25 to 35C.

The remaining conditions such as Z, diameter of cylinders and temperatures thereof were the same as in Example 1.

After drawing in a ratio of l 1.41 and development of the crimp in the manner described in Example 1, fi-

bers having the following properties were obtained: conveyance of spinning mass v 126 g/min draw off speed of filaments 1,100 m/min 5 distance a of cylinder (3) v from spinneret (I) 250 mm individual titrc dtex 9.0 Contact angle (a) tensile strength p/tex 25.3 circumferential Speed U elengenen at break of cylinder (3) 400 m/min p circumferential speed Z residual crimp 7r 23.9 of cylinder (4) 0 g r Mammy temperature of cylinder (3) 30C en s/cm temperature of cylinder (4) 30C cooling medium tap water EXAMPLE 3 The polyethylene terephthalate used had a specific The lobed fibers obtained were drawn in a ratio of 1 viscosity of 0.85. The polymer was spun through a plate 5 2.18 and the crimp was developed as described in Exnozzle having 43 orifices and a diameter of 134.5 mm ample l. The fibers obtained had the following properat a temperature of 287C. ties:

Polyethylene terephthalate having a specific viscosity of 1.0 was spun as described in Example 1 under the following conditions:

number of orifices 25 conveyance of spinning mass 240 g/min draw off speed of filaments 180 m/min' distance a of cylinder (3) from spinneret (1) 310 mm contact angle (a) 1 10 circumferential speed U of cylinder (3) 74 m/min circumferential speed 2 of cylinder (4) 2.7 m/min radius of cylinder (3) 105 mm temperature of cylinder (3) 25C temperature of cylinder (4) 25C The fibers were drawn in a ratio of l 3.53 and the crimp was developed as described in Example 1. The fibers obtained had the following properties:

individual titre dtex 198.0 tensile strength p/tex 30.4 elongation at break 7L 51.5 crimp K,,- 71 43.2 residual crimp K 71 31.0 crimp stability 71.5 bends/cm 3.8

EXAMPLE 6 A copolyester (as described in DOS 1,495,625 (German Application as laid open to public inspection)) consisting of ethylene glycol terephthalate units and percent of 2,Z-dimethyl-propanediol-l,3 units, calculated on dimethyl terephthalate, and having a specific viscosity of 0.625 was spun under the following conditrons:

spinning temperature 280C number of orifices in spinnerct 120 conveyance of spinning mass 225 g/min draw off speed of filaments 1.800 m/min distance a of cylinder (3) from spinneret (l) 450 mm contact angle (a) 55 circumferential speed U of cylinder (3) 470 m/min circumferential speed Z of cylinder (4) 1.5 m/min radius of cylinder (3) 8.5 cm temperature of cylinder (3) 32C temperature of cylinder (4) 30C After drawing in a ratio of l 1.58 and development of the crimp in the manner described in Example 1, fibers having the following properties were obtained:

individual titre dtex 6.7 tensile strength p/tex 31.1 elongation at break 29.6 crimp K 26.6 residual crimp K 18.0 bends/cm 8.0

What is claimed is:

1. A process for the manufacture of filaments of linear high molecular weight polyesters and copolyesters having a latent, three-dimensional crimp by asymmetrical cooling and a final titer of from about 4 to 300 dtex after drawing, which comprises passing the melt spun filaments, substantially immediately after they have left the spinneret when just cool enough to avoid sticking over a substantially dry smooth rotating cooled cylindrical zone having a temperature of from 20 to 40C and a circumferential speed U in the range of from U V,/5O to U V,- V,/ with U ranging from about 74 m/min. to 470 m/min., V; being the draw off speed of the spun filaments from the cylindrical zone, whereby the filaments are in contact with the cylindrical zone on a surface section, the length of which is determined by a contact angle of 10 to 150.

2. The process of claim 1, wherein the polyester is polyethylene terephthalate.

3. The process of claim 1, wherein the cooled cylindrical zone rotates at a circumferential speed 4. The process of claim 1,1wherein the contact angle determing the length of the filaments in contact with the cooled cylindrical zone is in the range of from 30 to 5. The process of claim 1, wherein the polyester has a specific viscosity above 0.5.

6. The process of claim 1,? wherein the polyester has a specific viscosity above 0.8.

7. A process as set forth in claim 1 wherein the circumferential speed U ranges approximately from 200 to 340 m/min.

Claims

2. The process of claim 1, wherein the polyester is polyethylene terephthalate.
3. The process of claim 1, wherEin the cooled cylindrical zone rotates at a circumferential speed U Vf/10 to U 6Vf/10
4. The process of claim 1, wherein the contact angle determing the length of the filaments in contact with the cooled cylindrical zone is in the range of from 30* to 115*.
5. The process of claim 1, wherein the polyester has a specific viscosity above 0.5.
6. The process of claim 1, wherein the polyester has a specific viscosity above 0.8.
7. A process as set forth in claim 1 wherein the circumferential speed U ranges approximately from 200 to 340 m/min.