US3823232A - Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate - Google Patents

Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate Download PDF

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Publication number
US3823232A
US3823232A US00119921A US11992171A US3823232A US 3823232 A US3823232 A US 3823232A US 00119921 A US00119921 A US 00119921A US 11992171 A US11992171 A US 11992171A US 3823232 A US3823232 A US 3823232A
Authority
US
United States
Prior art keywords
alkali metal
hair
uncurling
carbonate
percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00119921A
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English (en)
Inventor
J Galerne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eugene Gallia Sa fr
Gallia SA Eugene
Original Assignee
Gallia SA Eugene
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7020797A external-priority patent/FR2096687A1/fr
Priority claimed from FR7039392A external-priority patent/FR2112095A2/fr
Application filed by Gallia SA Eugene filed Critical Gallia SA Eugene
Application granted granted Critical
Publication of US3823232A publication Critical patent/US3823232A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur

Definitions

  • ThepH value of these solutions ranges vfrom about 8.5 to about according to the specific formula employed, and according as the ammonia is converted or notfln' addition to these products, which are essential-tor obtaining the desired effect, the solutions comprise additives adapted to improve the technical prop erties and the facility of use.
  • additives are sequesjftrant s, andmiscellaneous softeners, such as animal oils, vegetable oils,lanolidderivatives, perfumes, dyes, etc.
  • the hair impregnated with the product are 'kept curled'on cylindricalcurlers during the time necessary for: enabling'the product to perform its action, ,t his timebeing selected as a function of the desired defigree of curling' g 'i'riicontras't thereto, for the uncurling opj ration" the hair impregnated with'the product is drawn r tens'ioned by combing, or flattened by hand or by brush- 'g, and subs'equentlyfpress'ed on the head in this drawn ex h sds p t tr A V I More particularly, the uncurling method consists in impregnating thehair to be uncurled with solutions of which the force 'denotirfg number may be selected as a function of the specific characteristics of the hair to be States Patent (3 "ice 3,823,232 Patented July
  • the smoothing step becomes gradually more detrimental to the hair as the application time proceeds, for as a consequence of the disorganization of its structure the tensile strength of the hair decreases considerably and thus the combing or smoothing operation may cause more or less important local breakages if care is not taken to avoid this operation when about one-half of the application time has elapsed.
  • the reducing uncurling solution in the form of a cream having a consistency suflicient to withstand the resilient action of treated, and notably its degree of curling or waving.
  • the 7 .hairissoakedwith the. solution thencombedor flattened forfismogthed out so as to press the hair andremove the ztnaturalscurling therefrom.,The hair must be maintained in this pressed condition during the applicationtime.
  • emulsions which have a cream consistency and contain to this end an emulsion base of a type known per se. It is obvious that the viscosity of these emulsions may range from the milk grade to a pasty one, the technological adaptation alone determining the choice of the viscosity and therefore the proper formulation.
  • These emulsions or creams contain as a rule, like most permanent wave solutions. from 3% to 8% of thioglycolic or thiolactic acid, or of an ammonium salt or of an alkali metal salt of these acids.
  • an alkali metal salt of an aminoacid consists preferably of v. glycine or glycocoll (aminoacetic acid) but lysine methionine, tyrosine, glutamic acid, leucine, valine, alanine may also be used to this end.'These aminoacids may be, used in the racemic form or in the form of one of their optical isomers.
  • the alkali metal salt may be a' sodium salt, a
  • This aminoacid alkali metal salt carbonate may be associated with an organic base such as morpholine, monoethanolamine, triethanolamine, etc.
  • the carbonate of the aminoacid alkali metal salt such as sodium glycinate, is adapted to alkalize the curling or uncurling product without having the inconveniences of ammonia; in fact it is not volatile and eliminates the release of unpleasant and suffocating odors, does not attack or modify the perfumes added to said product and is less noxious to the users skin and to the skin of the person undergoing the treatment.
  • the organic base possibly associated with the aminoacid alkali metal salt carbonate is advantageous in that it makes the hair considerably more pervious to the curling or uncurling product and permits, as a function of its proportion in the product, of graduating the strength thereof, i.e. the degree and rapidity of the curling and uncurling actions obtained with the product.
  • the proportion of aminoacid alkali metal salt carbonate in the product may advantageously range from about 2 to about 12% by weight, and the proportion of the possible organic base may range preferably from about 1% to about by weight.
  • the aminoacid alkali metal salt carbonate may be prepared extemporaneously, or even within the curling or uncurling product itself, and in either case without any isolation. This preparation consists in putting into mutual contact, in stoichiometric proportions, alkali metal carbonate and aminoacid, for example 1 mole of sodium carbonate and 2 moles of glycocoll or glycine or aminoacetic acid. From the economical point of view it is advantageous to perform this preparation extemporaneously in aqueous phase during the process of manufacturing the curling or uncurling product.
  • EXAMPLE 2 Sodium glycinate carbonate, percent r 4 3:4 Sodium or ammonium thioglycolate or thiolactate (50% aqueous solution), percent 16. 0 16.0 Sequestrant (disodium salt of EDTA), percent 0.3 Methyl p-hydroxybenzoate, percent 0 05 Proteol SN," percent Perfume, percent Morpholine, percent Opaquing agent, percent Water (complement to make 100%), p
  • the opaquing agent consists of synthetic latex giving a milky appearance to the solution for purely aesthetic reasons. i
  • a composition for permanently-curling, waving or uncurling hair and keratinic fibres comprising 3% to 8% by weight of thioglycolic or thiolactic acid, or of an ammonium salt or an alkali metal salt of these acids, an aqueous carrier and an alkalizing agent, wherein said alkalizing agent consists of the carbonate of anaminogacid alkali metal salt, said aminoacid ,being selected from the group consisting of glycine, lysine, methionine, tyrosine, glutamic acid,,leucine, va'lineffand alanineQand said alkali metal being selected from the -gr0upconsistir'ig of sodium, potassium and lithium, the proportion of said aminoacid alkali metal salt carbonate is within the rang'e of about 2% to about 12% by weight, based on the' weight of the composition, and the pH of the composition is in the range of about 8.3
  • a composition 'assetforth'in claim'l which also contains an organic base selected from the group consisting of morpholine, monoethanolamine'add'triethanolamine, in a proportion within the range of about 1% to about 5% by weight, based on the weight of the composition.
  • composition as set forthin claim 1 which additionally contains free alkali metal carbonate or free aminoacid.
  • composition asset forth in claim 1 in the form of an aqueous solution
  • composition as set forth in claim 1 in the form of an emulsion. .7

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Glanulating (AREA)
US00119921A 1970-06-05 1971-03-01 Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate Expired - Lifetime US3823232A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7020797A FR2096687A1 (en) 1970-06-05 1970-06-05 Permanent waving cpsn for hair and keratinous fibres
FR7039392A FR2112095A2 (en) 1970-11-02 1970-11-02 Permanent waving cpsn for hair and keratinous fibres

Publications (1)

Publication Number Publication Date
US3823232A true US3823232A (en) 1974-07-09

Family

ID=26215784

Family Applications (1)

Application Number Title Priority Date Filing Date
US00119921A Expired - Lifetime US3823232A (en) 1970-06-05 1971-03-01 Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate

Country Status (13)

Country Link
US (1) US3823232A (no)
BE (1) BE763084A (no)
CA (1) CA959417A (no)
CH (1) CH523685A (no)
DK (1) DK129625B (no)
ES (1) ES389860A1 (no)
FI (1) FI52809C (no)
GB (1) GB1314625A (no)
IT (1) IT1044218B (no)
NL (1) NL171324C (no)
NO (1) NO134898C (no)
OA (1) OA03833A (no)
SE (1) SE388772B (no)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4010254A (en) * 1974-07-08 1977-03-01 Societe Anonyme Dite: L'oreal Gels based on vinyl ether-maleic anhydride copolymer neutralized by a basic amino acid
US4078055A (en) * 1975-04-11 1978-03-07 Kao Soap Co., Ltd. Deodorizing and smell-removing composition and method of using same
US4361157A (en) * 1979-03-05 1982-11-30 James Odie R Method of curling negroid hair without rollers
US4459284A (en) * 1980-07-10 1984-07-10 Nikko Pharmaceutical Co., Ltd. Permanent waving composition comprising amino acids
US5271926A (en) * 1991-04-04 1993-12-21 Kao Corporation Two-pack hair treatment composition and process for treating hair
EP0722715A1 (en) * 1994-12-20 1996-07-24 Unilever Plc Cosmetic compositions containing lactate dehydrogenase inhibitors
US6017519A (en) * 1993-02-17 2000-01-25 Goldwell Ag Composition for permanent waving of human hair
US20180098928A1 (en) * 2015-05-12 2018-04-12 L'oreal Hot reshaping process

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4010254A (en) * 1974-07-08 1977-03-01 Societe Anonyme Dite: L'oreal Gels based on vinyl ether-maleic anhydride copolymer neutralized by a basic amino acid
US4078055A (en) * 1975-04-11 1978-03-07 Kao Soap Co., Ltd. Deodorizing and smell-removing composition and method of using same
US4361157A (en) * 1979-03-05 1982-11-30 James Odie R Method of curling negroid hair without rollers
US4459284A (en) * 1980-07-10 1984-07-10 Nikko Pharmaceutical Co., Ltd. Permanent waving composition comprising amino acids
US5271926A (en) * 1991-04-04 1993-12-21 Kao Corporation Two-pack hair treatment composition and process for treating hair
US6017519A (en) * 1993-02-17 2000-01-25 Goldwell Ag Composition for permanent waving of human hair
EP0722715A1 (en) * 1994-12-20 1996-07-24 Unilever Plc Cosmetic compositions containing lactate dehydrogenase inhibitors
US5690944A (en) * 1994-12-20 1997-11-25 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Cosmetic compositions containing lactate dehydrogenase inhibitors
US5853742A (en) * 1994-12-20 1998-12-29 Chesebrough-Pond's Usa Co., Division Of Conopco Cosmetic compositions containing lactate dehydrogenase inhibitors
US20180098928A1 (en) * 2015-05-12 2018-04-12 L'oreal Hot reshaping process
US10772814B2 (en) * 2015-05-12 2020-09-15 L'oreal Hot reshaping process

Also Published As

Publication number Publication date
DK129625B (da) 1974-11-04
CH523685A (fr) 1972-06-15
NO134898B (no) 1976-09-27
NL171324B (nl) 1982-10-18
DK129625C (no) 1975-05-05
DE2111959B2 (de) 1977-05-18
NL7105248A (no) 1971-12-07
IT1044218B (it) 1980-03-20
NO134898C (no) 1977-01-05
CA959417A (en) 1974-12-17
FI52809C (fi) 1977-12-12
DE2111959A1 (de) 1971-12-16
NL171324C (nl) 1983-03-16
SE388772B (sv) 1976-10-18
OA03833A (fr) 1971-12-24
GB1314625A (en) 1973-04-26
FI52809B (no) 1977-08-31
ES389860A1 (es) 1974-02-16
BE763084A (fr) 1971-07-16

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