US3823232A - Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate - Google Patents
Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate Download PDFInfo
- Publication number
- US3823232A US3823232A US00119921A US11992171A US3823232A US 3823232 A US3823232 A US 3823232A US 00119921 A US00119921 A US 00119921A US 11992171 A US11992171 A US 11992171A US 3823232 A US3823232 A US 3823232A
- Authority
- US
- United States
- Prior art keywords
- alkali metal
- hair
- uncurling
- carbonate
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 amino acid alkali metal carbonate Chemical class 0.000 title abstract description 12
- 239000000203 mixture Substances 0.000 title abstract description 11
- 229910000288 alkali metal carbonate Inorganic materials 0.000 title description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 18
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 18
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 17
- 150000001413 amino acids Chemical class 0.000 abstract description 15
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 abstract description 12
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 abstract description 12
- 229910021529 ammonia Inorganic materials 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 5
- 150000007513 acids Chemical class 0.000 abstract description 5
- 150000003863 ammonium salts Chemical class 0.000 abstract description 5
- 230000003113 alkalizing effect Effects 0.000 abstract description 4
- 235000001014 amino acid Nutrition 0.000 description 15
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 11
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002304 perfume Substances 0.000 description 9
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229940046307 sodium thioglycolate Drugs 0.000 description 6
- 229960000541 cetyl alcohol Drugs 0.000 description 5
- 239000006071 cream Substances 0.000 description 5
- 229960002449 glycine Drugs 0.000 description 5
- 239000004247 glycine and its sodium salt Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229940029258 sodium glycinate Drugs 0.000 description 5
- WUWHFEHKUQVYLF-UHFFFAOYSA-M sodium;2-aminoacetate Chemical compound [Na+].NCC([O-])=O WUWHFEHKUQVYLF-UHFFFAOYSA-M 0.000 description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- 150000008041 alkali metal carbonates Chemical class 0.000 description 4
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 description 4
- 229940075861 ammonium thioglycolate Drugs 0.000 description 4
- 230000000295 complement effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 4
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 150000007530 organic bases Chemical class 0.000 description 4
- 239000003352 sequestering agent Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- 239000004471 Glycine Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- VHFSMDHANDABQK-UHFFFAOYSA-N azane;2-sulfanylpropanoic acid Chemical compound [NH4+].CC(S)C([O-])=O VHFSMDHANDABQK-UHFFFAOYSA-N 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 3
- GNBVPFITFYNRCN-UHFFFAOYSA-M sodium thioglycolate Chemical compound [Na+].[O-]C(=O)CS GNBVPFITFYNRCN-UHFFFAOYSA-M 0.000 description 3
- KZLAYICWOGEOSV-UHFFFAOYSA-M sodium;2-sulfanylpropanoate Chemical compound [Na+].CC(S)C([O-])=O KZLAYICWOGEOSV-UHFFFAOYSA-M 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 description 2
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 2
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 2
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229930182817 methionine Natural products 0.000 description 2
- KRCMKUNIILUXPF-UHFFFAOYSA-N methyl 4-hydroxybenzoate;sodium Chemical compound [Na].COC(=O)C1=CC=C(O)C=C1 KRCMKUNIILUXPF-UHFFFAOYSA-N 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000010268 sodium methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004290 sodium methyl p-hydroxybenzoate Substances 0.000 description 2
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 2
- FFYRIXSGFSWFAQ-UHFFFAOYSA-N 1-dodecylpyridin-1-ium Chemical compound CCCCCCCCCCCC[N+]1=CC=CC=C1 FFYRIXSGFSWFAQ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010009696 Clumsiness Diseases 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- PBDAWQLIMPWEEF-JEDNCBNOSA-M sodium;(2s)-2,6-diaminohexanoate Chemical compound [Na+].NCCCC[C@H](N)C([O-])=O PBDAWQLIMPWEEF-JEDNCBNOSA-M 0.000 description 1
- IREPZTZSVPKCAR-WCCKRBBISA-M sodium;(2s)-2-amino-4-methylsulfanylbutanoate Chemical compound [Na+].CSCC[C@H](N)C([O-])=O IREPZTZSVPKCAR-WCCKRBBISA-M 0.000 description 1
- HSFQBFMEWSTNOW-UHFFFAOYSA-N sodium;carbanide Chemical group [CH3-].[Na+] HSFQBFMEWSTNOW-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000003664 tensile strength of the hair Effects 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-L tyrosinate(2-) Chemical compound [O-]C(=O)C(N)CC1=CC=C([O-])C=C1 OUYCCCASQSFEME-UHFFFAOYSA-L 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
Definitions
- ThepH value of these solutions ranges vfrom about 8.5 to about according to the specific formula employed, and according as the ammonia is converted or notfln' addition to these products, which are essential-tor obtaining the desired effect, the solutions comprise additives adapted to improve the technical prop erties and the facility of use.
- additives are sequesjftrant s, andmiscellaneous softeners, such as animal oils, vegetable oils,lanolidderivatives, perfumes, dyes, etc.
- the hair impregnated with the product are 'kept curled'on cylindricalcurlers during the time necessary for: enabling'the product to perform its action, ,t his timebeing selected as a function of the desired defigree of curling' g 'i'riicontras't thereto, for the uncurling opj ration" the hair impregnated with'the product is drawn r tens'ioned by combing, or flattened by hand or by brush- 'g, and subs'equentlyfpress'ed on the head in this drawn ex h sds p t tr A V I More particularly, the uncurling method consists in impregnating thehair to be uncurled with solutions of which the force 'denotirfg number may be selected as a function of the specific characteristics of the hair to be States Patent (3 "ice 3,823,232 Patented July
- the smoothing step becomes gradually more detrimental to the hair as the application time proceeds, for as a consequence of the disorganization of its structure the tensile strength of the hair decreases considerably and thus the combing or smoothing operation may cause more or less important local breakages if care is not taken to avoid this operation when about one-half of the application time has elapsed.
- the reducing uncurling solution in the form of a cream having a consistency suflicient to withstand the resilient action of treated, and notably its degree of curling or waving.
- the 7 .hairissoakedwith the. solution thencombedor flattened forfismogthed out so as to press the hair andremove the ztnaturalscurling therefrom.,The hair must be maintained in this pressed condition during the applicationtime.
- emulsions which have a cream consistency and contain to this end an emulsion base of a type known per se. It is obvious that the viscosity of these emulsions may range from the milk grade to a pasty one, the technological adaptation alone determining the choice of the viscosity and therefore the proper formulation.
- These emulsions or creams contain as a rule, like most permanent wave solutions. from 3% to 8% of thioglycolic or thiolactic acid, or of an ammonium salt or of an alkali metal salt of these acids.
- an alkali metal salt of an aminoacid consists preferably of v. glycine or glycocoll (aminoacetic acid) but lysine methionine, tyrosine, glutamic acid, leucine, valine, alanine may also be used to this end.'These aminoacids may be, used in the racemic form or in the form of one of their optical isomers.
- the alkali metal salt may be a' sodium salt, a
- This aminoacid alkali metal salt carbonate may be associated with an organic base such as morpholine, monoethanolamine, triethanolamine, etc.
- the carbonate of the aminoacid alkali metal salt such as sodium glycinate, is adapted to alkalize the curling or uncurling product without having the inconveniences of ammonia; in fact it is not volatile and eliminates the release of unpleasant and suffocating odors, does not attack or modify the perfumes added to said product and is less noxious to the users skin and to the skin of the person undergoing the treatment.
- the organic base possibly associated with the aminoacid alkali metal salt carbonate is advantageous in that it makes the hair considerably more pervious to the curling or uncurling product and permits, as a function of its proportion in the product, of graduating the strength thereof, i.e. the degree and rapidity of the curling and uncurling actions obtained with the product.
- the proportion of aminoacid alkali metal salt carbonate in the product may advantageously range from about 2 to about 12% by weight, and the proportion of the possible organic base may range preferably from about 1% to about by weight.
- the aminoacid alkali metal salt carbonate may be prepared extemporaneously, or even within the curling or uncurling product itself, and in either case without any isolation. This preparation consists in putting into mutual contact, in stoichiometric proportions, alkali metal carbonate and aminoacid, for example 1 mole of sodium carbonate and 2 moles of glycocoll or glycine or aminoacetic acid. From the economical point of view it is advantageous to perform this preparation extemporaneously in aqueous phase during the process of manufacturing the curling or uncurling product.
- EXAMPLE 2 Sodium glycinate carbonate, percent r 4 3:4 Sodium or ammonium thioglycolate or thiolactate (50% aqueous solution), percent 16. 0 16.0 Sequestrant (disodium salt of EDTA), percent 0.3 Methyl p-hydroxybenzoate, percent 0 05 Proteol SN," percent Perfume, percent Morpholine, percent Opaquing agent, percent Water (complement to make 100%), p
- the opaquing agent consists of synthetic latex giving a milky appearance to the solution for purely aesthetic reasons. i
- a composition for permanently-curling, waving or uncurling hair and keratinic fibres comprising 3% to 8% by weight of thioglycolic or thiolactic acid, or of an ammonium salt or an alkali metal salt of these acids, an aqueous carrier and an alkalizing agent, wherein said alkalizing agent consists of the carbonate of anaminogacid alkali metal salt, said aminoacid ,being selected from the group consisting of glycine, lysine, methionine, tyrosine, glutamic acid,,leucine, va'lineffand alanineQand said alkali metal being selected from the -gr0upconsistir'ig of sodium, potassium and lithium, the proportion of said aminoacid alkali metal salt carbonate is within the rang'e of about 2% to about 12% by weight, based on the' weight of the composition, and the pH of the composition is in the range of about 8.3
- a composition 'assetforth'in claim'l which also contains an organic base selected from the group consisting of morpholine, monoethanolamine'add'triethanolamine, in a proportion within the range of about 1% to about 5% by weight, based on the weight of the composition.
- composition as set forthin claim 1 which additionally contains free alkali metal carbonate or free aminoacid.
- composition asset forth in claim 1 in the form of an aqueous solution
- composition as set forth in claim 1 in the form of an emulsion. .7
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Glanulating (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7020797A FR2096687A1 (en) | 1970-06-05 | 1970-06-05 | Permanent waving cpsn for hair and keratinous fibres |
| FR7039392A FR2112095A2 (en) | 1970-11-02 | 1970-11-02 | Permanent waving cpsn for hair and keratinous fibres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3823232A true US3823232A (en) | 1974-07-09 |
Family
ID=26215784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00119921A Expired - Lifetime US3823232A (en) | 1970-06-05 | 1971-03-01 | Waving or uncurling hair with a composition containing an amino acid alkali metal carbonate |
Country Status (13)
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4010254A (en) * | 1974-07-08 | 1977-03-01 | Societe Anonyme Dite: L'oreal | Gels based on vinyl ether-maleic anhydride copolymer neutralized by a basic amino acid |
| US4078055A (en) * | 1975-04-11 | 1978-03-07 | Kao Soap Co., Ltd. | Deodorizing and smell-removing composition and method of using same |
| US4361157A (en) * | 1979-03-05 | 1982-11-30 | James Odie R | Method of curling negroid hair without rollers |
| US4459284A (en) * | 1980-07-10 | 1984-07-10 | Nikko Pharmaceutical Co., Ltd. | Permanent waving composition comprising amino acids |
| US5271926A (en) * | 1991-04-04 | 1993-12-21 | Kao Corporation | Two-pack hair treatment composition and process for treating hair |
| EP0722715A1 (en) * | 1994-12-20 | 1996-07-24 | Unilever Plc | Cosmetic compositions containing lactate dehydrogenase inhibitors |
| US6017519A (en) * | 1993-02-17 | 2000-01-25 | Goldwell Ag | Composition for permanent waving of human hair |
| US20180098928A1 (en) * | 2015-05-12 | 2018-04-12 | L'oreal | Hot reshaping process |
-
1971
- 1971-02-12 CH CH207471A patent/CH523685A/fr not_active IP Right Cessation
- 1971-02-17 BE BE763084A patent/BE763084A/xx not_active IP Right Cessation
- 1971-02-20 NO NO620/71A patent/NO134898C/no unknown
- 1971-03-01 US US00119921A patent/US3823232A/en not_active Expired - Lifetime
- 1971-03-24 ES ES71389860A patent/ES389860A1/es not_active Expired
- 1971-03-26 FI FI710874A patent/FI52809C/fi active
- 1971-04-08 SE SE7104679A patent/SE388772B/xx unknown
- 1971-04-09 IT IT68193/71A patent/IT1044218B/it active
- 1971-04-19 GB GB2229471A patent/GB1314625A/en not_active Expired
- 1971-04-19 NL NLAANVRAGE7105248,A patent/NL171324C/xx not_active IP Right Cessation
- 1971-04-28 DK DK204571AA patent/DK129625B/da unknown
- 1971-05-06 CA CA112,380A patent/CA959417A/en not_active Expired
- 1971-05-10 OA OA54243A patent/OA03833A/xx unknown
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4010254A (en) * | 1974-07-08 | 1977-03-01 | Societe Anonyme Dite: L'oreal | Gels based on vinyl ether-maleic anhydride copolymer neutralized by a basic amino acid |
| US4078055A (en) * | 1975-04-11 | 1978-03-07 | Kao Soap Co., Ltd. | Deodorizing and smell-removing composition and method of using same |
| US4361157A (en) * | 1979-03-05 | 1982-11-30 | James Odie R | Method of curling negroid hair without rollers |
| US4459284A (en) * | 1980-07-10 | 1984-07-10 | Nikko Pharmaceutical Co., Ltd. | Permanent waving composition comprising amino acids |
| US5271926A (en) * | 1991-04-04 | 1993-12-21 | Kao Corporation | Two-pack hair treatment composition and process for treating hair |
| US6017519A (en) * | 1993-02-17 | 2000-01-25 | Goldwell Ag | Composition for permanent waving of human hair |
| EP0722715A1 (en) * | 1994-12-20 | 1996-07-24 | Unilever Plc | Cosmetic compositions containing lactate dehydrogenase inhibitors |
| US5690944A (en) * | 1994-12-20 | 1997-11-25 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Cosmetic compositions containing lactate dehydrogenase inhibitors |
| US5853742A (en) * | 1994-12-20 | 1998-12-29 | Chesebrough-Pond's Usa Co., Division Of Conopco | Cosmetic compositions containing lactate dehydrogenase inhibitors |
| US20180098928A1 (en) * | 2015-05-12 | 2018-04-12 | L'oreal | Hot reshaping process |
| US10772814B2 (en) * | 2015-05-12 | 2020-09-15 | L'oreal | Hot reshaping process |
Also Published As
| Publication number | Publication date |
|---|---|
| DK129625B (da) | 1974-11-04 |
| IT1044218B (it) | 1980-03-20 |
| ES389860A1 (es) | 1974-02-16 |
| BE763084A (fr) | 1971-07-16 |
| NL171324B (nl) | 1982-10-18 |
| DE2111959A1 (de) | 1971-12-16 |
| GB1314625A (en) | 1973-04-26 |
| CA959417A (en) | 1974-12-17 |
| SE388772B (sv) | 1976-10-18 |
| OA03833A (fr) | 1971-12-24 |
| NO134898B (enrdf_load_stackoverflow) | 1976-09-27 |
| DE2111959B2 (de) | 1977-05-18 |
| CH523685A (fr) | 1972-06-15 |
| FI52809B (enrdf_load_stackoverflow) | 1977-08-31 |
| DK129625C (enrdf_load_stackoverflow) | 1975-05-05 |
| NO134898C (enrdf_load_stackoverflow) | 1977-01-05 |
| NL171324C (nl) | 1983-03-16 |
| NL7105248A (enrdf_load_stackoverflow) | 1971-12-07 |
| FI52809C (fi) | 1977-12-12 |
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