US3811919A - New process for improving the resistance of surfaces against erosion - Google Patents
New process for improving the resistance of surfaces against erosion Download PDFInfo
- Publication number
- US3811919A US3811919A US00149016A US14901671A US3811919A US 3811919 A US3811919 A US 3811919A US 00149016 A US00149016 A US 00149016A US 14901671 A US14901671 A US 14901671A US 3811919 A US3811919 A US 3811919A
- Authority
- US
- United States
- Prior art keywords
- coating
- fibers
- boron
- resistance
- improving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000003628 erosive effect Effects 0.000 title abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 31
- 238000000576 coating method Methods 0.000 claims abstract description 31
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000004033 plastic Substances 0.000 claims abstract description 12
- 229920003023 plastic Polymers 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 239000011159 matrix material Substances 0.000 claims abstract description 11
- 238000005488 sandblasting Methods 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000011527 polyurethane coating Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract description 13
- 229910052580 B4C Inorganic materials 0.000 abstract description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 12
- 229910010271 silicon carbide Inorganic materials 0.000 abstract description 12
- 229910052796 boron Inorganic materials 0.000 abstract description 11
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 abstract description 11
- 239000004814 polyurethane Substances 0.000 abstract description 5
- 229920002635 polyurethane Polymers 0.000 abstract description 5
- 239000011236 particulate material Substances 0.000 abstract description 2
- 239000008199 coating composition Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- LFVLUOAHQIVABZ-UHFFFAOYSA-N Iodofenphos Chemical compound COP(=S)(OC)OC1=CC(Cl)=C(I)C=C1Cl LFVLUOAHQIVABZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
- Y10T428/249948—Fiber is precoated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
Definitions
- ABSTRACT There is disclosed a process for improving the resistance of the surface of a substrate against erosion and wear.
- the process includes coating the substrate with a coating consisting of fibers in a plastic matrix, the fibers being selected from materials wherein at least thesurfaces thereof are coated with boron, boron carbide, or silicon carbide. At least a portion of the plastic matrix is removed from the surface, thereby exposing some of the embedded fibers.
- the surface is then coated with a polyurethane material containing a quantity of particulate material wherein at least the surfaces thereof are of boron, boron carbide, or silicon carbide.
- the present invention relates to a process for applying an erosion resistant coating to a substrate.
- the present invention is directed to a process for improving the resistance to erosion of surfaces either metallic or non metallic, which are subjected to friction or particulate impact.
- the process of the present invention comprises coating the surfaces or portions of surfaces subjected to erosion with at least one layer of a composite coating material containing fibers dispersed in a plastic binding agent.
- the surfaces of the fibers are either boron, boron carbide, or silicon carbide.
- the surface is sandblasted to remove the plastic binding material, and a coating of polyurethane containing particles having a surface of boron, boron carbide, or silicon carbide is applied.
- the surface to be protected is first coated with one or more layers of threads or fibers contained in an organic resin.
- These threads or fibers have boron, boron carbide, or silicon carbide surfaces.
- the threads or fibers may be oriented in a preferred direction; in the case where more than one layer is used, the orientation may differ from one layer to the next.
- the amount of threads or fibers contained in the coating composition may range from 30 percent to 70 percent by volume.
- the orientation of the threads in the coating is determined by the degree and orientation of the flexion, traction, or torsion stresses which the pieces may receive in use, as such oriented threads may advantageously enhance the resistance to stress of the entire piece.
- the coating of the present invention to a substrate, two methods could be used. Where the substrate had a non-metallic surface, such as the case of a glass or carbon laminate, the coating would be effected at the time the laminate was is preeroded by dry or humid sandblasting with the aid of an abrasive such as alumina of low granulometry. This treatment preferably eliminates the organic ma trix, leaving a coating solely of the threads or fibers.
- this second coating comprises an elastomeric binder and a charge of 15 to 60 percent fine particles intrinsically resistant to erosion.
- This charge is based on micronized powders having a boron, boron carbide, or silicon carbide surface. A silicon carbide surface is preferred.
- the outer carbon layers of the above-described compressor blade are replaced by one or more unidirectional layers of boron or silicon carbide threads, which may have angles of intersection provided so as either to not change or to improve the characteristics of the blade.
- the blade is sandblasted dry with alumina. This sandblasting operation eliminates on the surface and between each thread the epoxide resin whose behavior to erosion is poor.
- a finishing coating is then applied.
- it is a polyurethane based paint charged with a micronized silicon carbide powder.
- the paint penetrates the intermolded.
- the coating would be first molded and then attached to the metal surface by means of a suitable adhesive.
- the coating resulting from the abovedescribed methods generally proves to be inadequate in preventing erosion due to the wear of the organic resin forming the matrix between the fibers of the coating.
- the method of the present invention alleviates this problem by removing the organic matrix between the fibers and then applying a second coating containing fine particles.
- One or more layers of a first coating composition are applied to the surface to be protected.
- This coating composition comprises an organic plastic matrix containing from 30 percent to 70 percent by volume of threads or fibers having a coating of boron, boron carbide, or silicon carbide. After this coating is applied, it
- the process of the present invention may also be used to make helicopter blades.
- the blades are coated with threads or fibers suspended'in a matrix, which coating is treated by sandblasting and then overcoated as in the process described above.
- a process for applying an improved erosion resistance coating to a substrate comprising coating the substrate with a composition comprising a plastic material containing fibers having a surface of a material selected from the group consisting of boron, boron carbide, and silicon carbide; sandblasting said coating; thereafter coating the surface thus obtained with a coating of polyurethane containing micronized particles having a surface of a material selected from the group consisting 3 4 60% by volume of the polyurethane coating composiapplied.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7020826A FR2093228A5 (enrdf_load_stackoverflow) | 1970-06-05 | 1970-06-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3811919A true US3811919A (en) | 1974-05-21 |
Family
ID=9056785
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00149016A Expired - Lifetime US3811919A (en) | 1970-06-05 | 1971-06-01 | New process for improving the resistance of surfaces against erosion |
Country Status (3)
Country | Link |
---|---|
US (1) | US3811919A (enrdf_load_stackoverflow) |
FR (1) | FR2093228A5 (enrdf_load_stackoverflow) |
GB (1) | GB1349383A (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5757334A (en) * | 1989-08-29 | 1998-05-26 | Hughes Electronics Corporation | Graphite composite structures exhibiting electrical conductivity |
FR2980487A1 (fr) * | 2011-09-23 | 2013-03-29 | Snecma | Piece de turbomachine, telle qu'un turboreacteur ou un turbopropulseur d'avion |
US10441968B2 (en) | 2011-08-24 | 2019-10-15 | United Technologies Corporation | Substrates coated with wear resistant layers and methods of applying wear resistant layers to same |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3151413A1 (de) * | 1981-12-24 | 1983-07-14 | MTU Motoren- und Turbinen-Union München GmbH, 8000 München | "schaufel einer stroemungsmaschine, insbesondere gasturbine" |
GB2118459B (en) * | 1982-03-25 | 1986-03-26 | Koop Wijnbouers Zuid Afrika | Coating of a surface |
AUPR373901A0 (en) * | 2001-03-14 | 2001-04-12 | Leach Aero Services Pty Ltd | An article having an erodynamic surface |
-
1970
- 1970-06-05 FR FR7020826A patent/FR2093228A5/fr not_active Expired
-
1971
- 1971-06-01 US US00149016A patent/US3811919A/en not_active Expired - Lifetime
- 1971-06-04 GB GB1909471*[A patent/GB1349383A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5757334A (en) * | 1989-08-29 | 1998-05-26 | Hughes Electronics Corporation | Graphite composite structures exhibiting electrical conductivity |
US10441968B2 (en) | 2011-08-24 | 2019-10-15 | United Technologies Corporation | Substrates coated with wear resistant layers and methods of applying wear resistant layers to same |
FR2980487A1 (fr) * | 2011-09-23 | 2013-03-29 | Snecma | Piece de turbomachine, telle qu'un turboreacteur ou un turbopropulseur d'avion |
Also Published As
Publication number | Publication date |
---|---|
GB1349383A (en) | 1974-04-03 |
FR2093228A5 (enrdf_load_stackoverflow) | 1972-01-28 |
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