US3811883A - Photoelectrophoretic imaging process employing napthofuranediones - Google Patents
Photoelectrophoretic imaging process employing napthofuranediones Download PDFInfo
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- US3811883A US3811883A US00207179A US20717971A US3811883A US 3811883 A US3811883 A US 3811883A US 00207179 A US00207179 A US 00207179A US 20717971 A US20717971 A US 20717971A US 3811883 A US3811883 A US 3811883A
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G17/00—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process
- G03G17/04—Electrographic processes using patterns other than charge patterns, e.g. an electric conductivity pattern; Processes involving a migration, e.g. photoelectrophoresis, photoelectrosolography; Processes involving a selective transfer, e.g. electrophoto-adhesive processes; Apparatus essentially involving a single such process using photoelectrophoresis
Definitions
- R denotes an arylene radical
- X and Y denote hydrogen or halogen atoms or alkyl or alkoxy groups
- X and Y together with two adjacent C atoms of the 'base substance can form a benzene ring, or
- An essential component of the system are the suspended particles which must be electricallyphotosensitive. These particles evidently undergo a change in charge during irradiation with an activating electromagnet radiation, and in particulardo so through interaction with one of the electrodes.
- particles of a single colour are used, whereby a single-colourimage is produced which is equivalent to a customary black and white image.
- the images are produced in a natural colour, since mixtures of particles of two or more different colours eachsensitive to light of a specific wavelength or of a narrow wavelengthrange, are used.
- the 4,4-diaminodianthraquinonyl is known amongst the series of the naphthofuranediones, the dyestuffs of the formula wher ein X and Y denote chlorine atoms or alkyl 5 groups, or the dyestuff of the formula CONH may especially ,be mentioned. These dyestuffs are known. Their manufacture is described in German Pat. No. 1,209,683.
- the dyestuffs are preferably in a finely divided form, the average particle size appropriately being less than 10 n and advantageously between 0.1 and 5 11.. It is advantageous if the particles are of uniform size.
- the toners appropriately contain a binder which permits the pigment particles to be fixed to the final image carrier.
- the specific resistance of the binder should be greater than Ohm.cm, and appropriately greater than 10 Ohm.cm.
- Natural, semi-synthetic or synthetic resins such as abietic acid esters, tetrahydroabietic acid esters, cellulose esters, cellulose ethers, chlorinated rubber, vinyl resins, such as, for example, polyvinyl chloride, polyvinyl acetate, copolymers of vinyl chloride and vinyl acetate, polyvinyl acetals, polyvinyl alcohols, polyvinyl ethers, polyvinylcarbazole, polyisobutylene, polybutadiene, polyacrylic esters or polymethacrylic esters, polystyrene, polyacrylonitrile or silicone resins are suitable for this purpose.
- the proportion of binder in the toner is appropriately between 10 and 60 percent. It proves to be advantageous to achieve as intimate a mixing of the toner with the binder as possible, for example, on grinding or kneading the two materials together. In doing so, the desired reduction in particle size can be achieved simultaneously if a crude pigment is employed.
- the drawing shows a transparent electrode 1 which in this case consists of a layer of an optically transparent glass 2 which is coated with a thin optically transparent layer 3 of tin oxide.
- This material is commercially available under the description. NESA-glass.”
- This electrode is subsequently described as the injector electrode.”
- a thin layer 4 of finely divided, lightsensitive particles, dispersed in an insulating liquid carrier, is coated onto the surface of the injector electrode 1.
- the term light-sensitive is to be understood, according to the invention, as indicating the property of a particle that, once it has been attracted by the injector electrode, it migrates away from the electrode under the influence of an applied electrical field if an irradiation with an actinic electromagnetic radiation is carried out.
- the liquid suspension 4 can furthermore contain a sensitising agent and/or a binder for the pigment particles, these agents being at least partially soluble in the suspending liquid or carrier liquid, as will still be described in more detail below.
- a projector consisting of a light source 8, a diapositive 9 and a lens 10 irradiates the dispersion 4 with a light image of the diapositive 9 which is to be reproduced.
- the electrode 5 is constructed in the form of a roller with a conducting central core 11 connected to the potential source 6.
- the core is covered with a layer of a blocking electrode material 12, which can be baryte paper.
- the pigment suspension is irradiated with the image to be reproduced, whilst applying a potential at right angles to the blocking electrode and injector electrode by closing the switch 7.
- the roller 5 is rolled over the upper surface of the injector electrode 1 during the image irradiation, whilst the switch 7 is closed.
- the irradiation withlig ht is that exposed pigment particles, which have originally been attracted by the electrode I, migrate through the liquid and adhere to the surfaces of the blocking electrode, leaving, on the injector electrode surface, a pigment image which is a duplicate of the diapositive 9.
- the relatively volatile carrier liquid evaporates, leaving the pigment image.
- This pigment image can subsequently be fixed in situ, for example by applying a coating layer to the upper surface, or by means of a binder, such as, for example, paraffin wax, dissolved in the carrier liquid.
- a binder such as, for example, paraffin wax
- Other suitable binders which are obtainedfroiii the solution when the carrier liquid evaporates can also be used. About 3 6 per cent .by weight of the paraffin binder in the carrier give good results.
- the carrier liquid itself can be a liquid paraffin wax or some other suitable binder.
- the pigment image which is left on the injector electrode can be transferred to another surface and fixed thereon.
- this system can produce either monochromatic or polychromatic images, depending on the type and number of the pigments which are suspended in the carrier liquid and depending on the colour of the light with which this suspension is irradiated when carrying out the process.
- any suitable insulating liquid can be used as a carrier for the pigment particles in this system.
- Typical carrier liquids are decane, dodecane, N-tetradecane, paraffin, wax or other thermoplastic materials, Sohio Odorless Solvent 3440 (a kerosene fraction marketed by Standard Oil Company, Ohio) and lsopar-E (a branched saturated aliphatic hydrocarbon marketed by Esso Oil Company, New Jersey). Images of good qualityare obtained at voltages of between 300 and 5,000 volt, which are applied when using the device described in the attached drawing. The proportion of pigment in the solvent is appropriately 2 10 percent. The addition of smaller amounts, for example 0.5 5 mol percent, of electron donors or'electron acceptors to the suspensions results in a marked improvement of the light sensitivity of the system.
- a monochromatic system particles of the same composition are dispersed in the carrier liquid and irradiated with a black and white image. Thereby, a single colour is obtained, analogous to a customary black and white image.
- the particles are so chosen that the particles with different colours respond to the various wavelengths in the visible spectrum, in accordance with their main absorption bands.
- the pigments should be so chosen that their spectral response curves do not significantly overlap, so that a colour separation and a subtractive multi-colour image production is possible.
- the dispersion of particles should contain particles of cyan colour, which are mainly sensitive to'red light, particles of magenta colour, which are mainly sensitive to green light, and particles of yellow colour, which are mainly sensitive to blue light.
- these particles produce a liq uid of black appearance. If one or more of these particles migrate from the electrode 11 in the direction of the upper'electrode, particles are left which produce a colour which is equivalent to the colour of the incident light.
- the result of an irradiation with red light is that the pigments of cyan colour migrate, leaving the pigments of magenta colour and the pigments of yellow colour.
- the combination of these colours gives a final red image.
- blue and green colours are reproducedby removal of pigments of yelgood spectral response and their high light sensitivity result in the formation of dense and brilliant images.
- the examples which follow are carried out in a device which corresponds to the type illustrated by the attached drawing.
- the image production mixture 4 is applied to an NESA-glass substrate.
- the irradiation takes place through this glass.
- the NESA-glass surface is wired in series with a switch, a potential source and the conducting core of a roller which has a baryte paper covering on its surface.
- the roller has a diameter of about 63 mm (2% inches) and is moved over the surface of the plate at a speed of about 1.45 cm per second.
- the plate used is about 19.3 cm (3 square inches) in size and is irradiated with a light intensity of 8,000 foot candles, measured on the uncoated NESA-glass surface.
- the magnitude of the potential applied is 2,500 volt.
- the irradiation is carried out with a 3,200 K lamp through a neutral dense wedge filter to measure the sensitivity of the suspensions to white light, and through Wratten filters 29, 61 and 47b, each placed by themselves in front of the light source, in order to measure the sensitivity of the suspensions to red, green and blue light, respectively, in separate tests.
- the dyestuffs according to the invention are also suitable for other photoelectrophoretic reproduction processes.
- EXAMPLE 1 10g of 4,4'-'diamino-l,l'-dianthraquinonyl of average particle size maximally l u are suspended in g of lsopar E, a saturated aliphatic hydrocarbon obtainable from ESSO Standard. The resulting paste is employed, either as such or diluted with further lsopar E, for the process described above. Brilliant, red images of excellent transparency and fastness to light are obtained.
- EXAMPLE 2 The procedure in Example 1 is followed, but the dyestuffs of the formula particles of at least one colordispersed in an electrically insulating liquid carrier, said particles comprising a photosensitive pigment selected from the group consisting of naphthofuranediones of the formula cami 'nmaea" p wherein R denotes an arylene radical,
- N H I -1 (H) CONH- are used as toners, thus yielding brilliant yellow images- C ONE- K/K I is used as photosensitive pigment.
Abstract
Use of 4,4''-diamino-1,1''-dianthraquinonyl, naphthofuran-diones, quinophthalones and phthalimidopyrazolones in the photoelectrophoretic production of images.
Description
United States Patent 119 Zographos et a1.
1111 3,811,883 [451 May 21, 1974 I 1 PHOTOELECTROPI'IORETIC IMAGING PROCESS EMPLOYING NAP'IHQFURANEDIONES [75] Inventors: Georg Zographos, Zurich; Christoph Frey, Oberwil, both of Switzerland [73] Assignee: Ciba-Geigy AG, Basel, Switzerland [22] Filed: Dec. 13, 1971 21] Appl. No.: 207,179
[30] Foreign Application Priority Data I Dec. 16, 1970 Switzerland 18616/70 [52] US. Cl 96/l.3, 96/1 PE, 96/1 PC, 96/1.2,96/1.5, 204/181 PE [51] Int. Cl. G03g-l7/00, 003g 5/00 [58] Field of Search 96/1.5, 1,3,1 PE, 1 PC; 252/501 [56] References Cited UNITED STATES PATENTS 3,448,029 6/1969 Weinberge r ..96/1.5X
3,448,030 6/1969 Weinbcrger ct a1. 96/l.5 X 3,445,227 5/1969 Weinhergcr 96/l.5 3.384.566 5/1968 X 3,448,028 6/1969 Weinberger 96/].5 X 3,447,922 6/1969 96/].5 X 3,301,676 1/1967 Tomanek 96/1.5
FOREIGN PATENTS OR APPLICATIONS 6,41 1,488 4/1965 Netherlands 96/1.5 2,018,611 5/1970 France ..,96/1.5
OTHER PUBLICATIONS Chemical Abstracts, Vol. 63, 1965, p. 10909g. Chemical Abstracts, Vol. 74, 1971, p, 149220g.
Primary ExaminerNorman G. Torchin Assistant Examiner-John R. Miller [57] ABSTRACT Use of 4,4-diamino-1,'1 -dianthraquinony1, naphthofuran-diones, quinophthaloncs and phthalimidopyrazolones in the photoelectrophoretic production of images.
4 Claims, 1 Drawing Figure wherein R denotes an aryleue radical, or the quinophthalones of the formula 4 It is known that single-colour and multi-colour reproductions can be produced electrophoretically by the use of photoconducting organic pigments. This system employs photoconducting particles and is described,
OHi
wherein R denotes an arylene radical, X and Y denote hydrogen or halogen atoms or alkyl or alkoxy groups, or X and Y together with two adjacent C atoms of the 'base substance can form a benzene ring, or
for example, in us. Pat. Nos. 3,384,565, 3,384,566 phthalimidopyrazolones or the formula and 3,3 85,480. In such a system forproducing images, wherein R denotes an arylene radical, X and Y, denote light-absorbing particles of different colours are suspended in a non-conducting liquid carrier. The suspension isintroduced between electrodes, after which a potential is applied and an image is projected. Thereafthrough migration of dyestuff particles in the electric field.
An essential component of the system are the suspended particles which must be electricallyphotosensitive. These particles evidently undergo a change in charge during irradiation with an activating electromagnet radiation, and in particulardo so through interaction with one of the electrodes. In a monochromatic system, particles of a single colour are used, whereby a single-colourimage is produced which is equivalent to a customary black and white image. In a polychromatic system, the images are produced in a natural colour, since mixtures of particles of two or more different colours eachsensitive to light of a specific wavelength or of a narrow wavelengthrange, are used.
Hitherto, only few pigments are known which meet the high demands of the electrophoretic reproduction technique. This is because the dyestuffs in question must be distinguished by the following properties: pure colour shade, high colour strength and fastness to light,.
o ooNH-R-NHuo o I Ell-Z? hydrogen or halogen atomsor alkoxy, carbonamide or nitro groups and R denotes a benzene radical.
The 4,4-diaminodianthraquinonyl is known amongst the series of the naphthofuranediones, the dyestuffs of the formula wher ein X and Y denote chlorine atoms or alkyl 5 groups, or the dyestuff of the formula CONH may especially ,be mentioned. These dyestuffs are known. Their manufacture is described in German Pat. No. 1,209,683.
Amongst the series of the quinophthalone dyestuffs, those of the formula 1 \JO Q wherein X and Y denote hydrogen or halogen atoms or alkyl or alkoxy groups and 2, denotes a chlorine atom or an alkoxy group, may especially be mentioned. These dyestuffs are known. Their manufacture is described in German Patent No. 1,279,258.
Finally, amongst the series of the phthalimidopyrazolones, those of the formula wherein, in the formulae shown, X, and Y denote hydrogen or halogen atoms or nitro or alkoxy groups and X and Y Z and Z denote hydrogen or halogen atoms or alkyl or alkoxy groups may especially be mentioned. These dyestufis are known. Their manufacture is described in US. Pat. application Ser. No. 65332.
The dyestuffs are preferably in a finely divided form, the average particle size appropriately being less than 10 n and advantageously between 0.1 and 5 11.. It is advantageous if the particles are of uniform size.
The toners appropriately contain a binder which permits the pigment particles to be fixed to the final image carrier. The specific resistance of the binder should be greater than Ohm.cm, and appropriately greater than 10 Ohm.cm. Natural, semi-synthetic or synthetic resins, such as abietic acid esters, tetrahydroabietic acid esters, cellulose esters, cellulose ethers, chlorinated rubber, vinyl resins, such as, for example, polyvinyl chloride, polyvinyl acetate, copolymers of vinyl chloride and vinyl acetate, polyvinyl acetals, polyvinyl alcohols, polyvinyl ethers, polyvinylcarbazole, polyisobutylene, polybutadiene, polyacrylic esters or polymethacrylic esters, polystyrene, polyacrylonitrile or silicone resins are suitable for this purpose. Amongst the series of the condensation resins, phenol-formaldehyde resins, urea-formaldehyde resins, melaminefonnaldehyde resins, aldehyde or ketone resins, polyamides, polyurethanes or epoxy resins may be mentioned as examples. The proportion of binder in the toner is appropriately between 10 and 60 percent. It proves to be advantageous to achieve as intimate a mixing of the toner with the binder as possible, for example, on grinding or kneading the two materials together. In doing so, the desired reduction in particle size can be achieved simultaneously if a crude pigment is employed.
The use of the dyestuffs according to the invention in photoelectrophoretic systems for producing images is presented in more detail in the subsequent text, with reference to the attached drawing which shows an example of such a system.
The drawing shows a transparent electrode 1 which in this case consists of a layer of an optically transparent glass 2 which is coated with a thin optically transparent layer 3 of tin oxide. This material is commercially available under the description. NESA-glass." This electrode is subsequently described as the injector electrode." A thin layer 4 of finely divided, lightsensitive particles, dispersed in an insulating liquid carrier, is coated onto the surface of the injector electrode 1. The term light-sensitive is to be understood, according to the invention, as indicating the property of a particle that, once it has been attracted by the injector electrode, it migrates away from the electrode under the influence of an applied electrical field if an irradiation with an actinic electromagnetic radiation is carried out. A more detailed theoretical explanation of the mechanism which probably occurs is to be found in US. Pat. Nos. 3,384,565, 3,384,566 and 3,385,488. The liquid suspension 4 can furthermore contain a sensitising agent and/or a binder for the pigment particles, these agents being at least partially soluble in the suspending liquid or carrier liquid, as will still be described in more detail below. Adjoining the liquid suspension there is a second electrode 5 subsequently described as the blocking electrode. This electrode is connected via a switch 7 to one side of the potential source 6. The opposite side of the potential source 6 is connected to the injector electrode 1 so that if the switch 7 is closed an electrical field is applied between the electrodes 1 and 5 at right angles to the liquid suspension 4. A projector consisting of a light source 8, a diapositive 9 and a lens 10 irradiates the dispersion 4 with a light image of the diapositive 9 which is to be reproduced. The electrode 5 is constructed in the form of a roller with a conducting central core 11 connected to the potential source 6. The core is covered with a layer of a blocking electrode material 12, which can be baryte paper. The pigment suspension is irradiated with the image to be reproduced, whilst applying a potential at right angles to the blocking electrode and injector electrode by closing the switch 7. The roller 5 is rolled over the upper surface of the injector electrode 1 during the image irradiation, whilst the switch 7 is closed. The consequence of the irradiation withlig ht is that exposed pigment particles, which have originally been attracted by the electrode I, migrate through the liquid and adhere to the surfaces of the blocking electrode, leaving, on the injector electrode surface, a pigment image which is a duplicate of the diapositive 9. After the irradiation, the relatively volatile carrier liquid evaporates, leaving the pigment image. This pigment image can subsequently be fixed in situ, for example by applying a coating layer to the upper surface, or by means of a binder, such as, for example, paraffin wax, dissolved in the carrier liquid. Other suitable binders which are obtainedfroiii the solution when the carrier liquid evaporates can also be used. About 3 6 per cent .by weight of the paraffin binder in the carrier give good results. The carrier liquid itself can be a liquid paraffin wax or some other suitable binder. According to another embodiment, the pigment image which is left on the injector electrode can be transferred to another surface and fixed thereon. As will still be explained in more detail below, this system can produce either monochromatic or polychromatic images, depending on the type and number of the pigments which are suspended in the carrier liquid and depending on the colour of the light with which this suspension is irradiated when carrying out the process.
Any suitable insulating liquid can be used as a carrier for the pigment particles in this system. Typical carrier liquids are decane, dodecane, N-tetradecane, paraffin, wax or other thermoplastic materials, Sohio Odorless Solvent 3440 (a kerosene fraction marketed by Standard Oil Company, Ohio) and lsopar-E (a branched saturated aliphatic hydrocarbon marketed by Esso Oil Company, New Jersey). Images of good qualityare obtained at voltages of between 300 and 5,000 volt, which are applied when using the device described in the attached drawing. The proportion of pigment in the solvent is appropriately 2 10 percent. The addition of smaller amounts, for example 0.5 5 mol percent, of electron donors or'electron acceptors to the suspensions results in a marked improvement of the light sensitivity of the system.
In a monochromatic system, particles of the same composition are dispersed in the carrier liquid and irradiated with a black and white image. Thereby, a single colour is obtained, analogous to a customary black and white image. In a polychromatic system the particles are so chosen that the particles with different colours respond to the various wavelengths in the visible spectrum, in accordance with their main absorption bands. Furthermore, the pigments should be so chosen that their spectral response curves do not significantly overlap, so that a colour separation and a subtractive multi-colour image production is possible. In a typical multi-colour system, the dispersion of particles should contain particles of cyan colour, which are mainly sensitive to'red light, particles of magenta colour, which are mainly sensitive to green light, and particles of yellow colour, which are mainly sensitive to blue light. On mixing in a carrier liquid, these particles produce a liq uid of black appearance. If one or more of these particles migrate from the electrode 11 in the direction of the upper'electrode, particles are left which produce a colour which is equivalent to the colour of the incident light. For example, the result of an irradiation with red light is that the pigments of cyan colour migrate, leaving the pigments of magenta colour and the pigments of yellow colour. The combination of these colours gives a final red image. In vthe same way, blue and green colours are reproducedby removal of pigments of yelgood spectral response and their high light sensitivity result in the formation of dense and brilliant images.
The examples which follow illustrate the invention. The parts and percentages indicated are by weight, unless otherwise stated. These examples illustrate various embodiments of the electrophoretic image production process, without however restricting theinvention thereto.
The examples which follow are carried out in a device which corresponds to the type illustrated by the attached drawing. The image production mixture 4 is applied to an NESA-glass substrate. The irradiation takes place through this glass. The NESA-glass surface is wired in series with a switch, a potential source and the conducting core of a roller which has a baryte paper covering on its surface. The roller has a diameter of about 63 mm (2% inches) and is moved over the surface of the plate at a speed of about 1.45 cm per second. The plate used is about 19.3 cm (3 square inches) in size and is irradiated with a light intensity of 8,000 foot candles, measured on the uncoated NESA-glass surface. The magnitude of the potential applied is 2,500 volt. The irradiation is carried out with a 3,200 K lamp through a neutral dense wedge filter to measure the sensitivity of the suspensions to white light, and through Wratten filters 29, 61 and 47b, each placed by themselves in front of the light source, in order to measure the sensitivity of the suspensions to red, green and blue light, respectively, in separate tests.
The dyestuffs according to the invention are also suitable for other photoelectrophoretic reproduction processes.
EXAMPLE 1 10g of 4,4'-'diamino-l,l'-dianthraquinonyl of average particle size maximally l u are suspended in g of lsopar E, a saturated aliphatic hydrocarbon obtainable from ESSO Standard. The resulting paste is employed, either as such or diluted with further lsopar E, for the process described above. Brilliant, red images of excellent transparency and fastness to light are obtained.
EXAMPLE 2 The procedure in Example 1 is followed, but the dyestuffs of the formula particles of at least one colordispersed in an electrically insulating liquid carrier, said particles comprising a photosensitive pigment selected from the group consisting of naphthofuranediones of the formula cami 'nmaea" p wherein R denotes an arylene radical,
0H 9: ii H0 g I c I CONH-R-NHOC CH\ N Y N \XY 0 0 ll ll X1 1 X1 Yr 0: ?C=C--CCONHRNHCOC- C=C 0:0 /o= It It e=o\ g \N/ N H 1'1, in
l a 2 a A 3 2. Method according to claim] in which a naphthofuranedione of the formula 00 C=C--CCONH a- I a 1 06 X: I
N H I -1 (H) CONH- are used as toners, thus yielding brilliant yellow images- C ONE- K/K I is used as photosensitive pigment.
4. Method according to claim 1, characterised in that the pigments have a particle size of 0.1 to 5 .L.
Claims (3)
- 2. Method according to claim 1 in which a naphthofuranedione of the formula
- 3. Method according to claim 1 in which the naphthofuranedione of the formula
- 4. Method according to claim 1, characterised in that the pigments have a particle size of 0.1 to 5 Mu .
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1861670A CH558209A (en) | 1970-12-16 | 1970-12-16 | USE OF ORGANIC PIGMENTS IN ELECTROPHORETIC IMAGE GENERATION. |
Publications (1)
Publication Number | Publication Date |
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US3811883A true US3811883A (en) | 1974-05-21 |
Family
ID=4434187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00207179A Expired - Lifetime US3811883A (en) | 1970-12-16 | 1971-12-13 | Photoelectrophoretic imaging process employing napthofuranediones |
Country Status (5)
Country | Link |
---|---|
US (1) | US3811883A (en) |
JP (1) | JPS5427734B1 (en) |
CH (1) | CH558209A (en) |
DE (1) | DE2162296C3 (en) |
GB (1) | GB1357974A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3966466A (en) * | 1974-12-17 | 1976-06-29 | Xerox Corporation | Photoelectrophoretic imaging process using dark charge injecting agent on blocking electrode |
US4017311A (en) * | 1974-07-29 | 1977-04-12 | Xerox Corporation | Photoelectrophoretic imaging suspension |
US4104064A (en) * | 1974-07-29 | 1978-08-01 | Xerox Corporation | Photoelectrophoretic imaging method employing dinaphtho-furan-dione pigments |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1115578A (en) * | 1977-07-25 | 1982-01-05 | Frank G. Webster | Electrophotosensitive materials for migration imaging processes |
US4165985A (en) * | 1978-05-24 | 1979-08-28 | Eastman Kodak Company | Electrophotosensitive materials for migration imaging processes |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3448028A (en) * | 1964-12-28 | 1969-06-03 | Xerox Corp | N-substituted - 8,13-dioxodinaphtho (2,1-b; 2',3'-d)-furan - 6 - carboxamides as electrically photosensitive materials in electrophotographic processes |
GB1316667A (en) * | 1969-05-26 | 1973-05-09 | Xerox Corp | Benzobrazanquinone pigments |
US3484029A (en) * | 1968-11-12 | 1969-12-16 | John E Gaydos | Wire hanger clip |
-
1970
- 1970-12-16 CH CH1861670A patent/CH558209A/en not_active IP Right Cessation
-
1971
- 1971-12-13 US US00207179A patent/US3811883A/en not_active Expired - Lifetime
- 1971-12-15 DE DE2162296A patent/DE2162296C3/en not_active Expired
- 1971-12-16 JP JP10222471A patent/JPS5427734B1/ja active Pending
- 1971-12-16 GB GB5846271A patent/GB1357974A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4017311A (en) * | 1974-07-29 | 1977-04-12 | Xerox Corporation | Photoelectrophoretic imaging suspension |
US4104064A (en) * | 1974-07-29 | 1978-08-01 | Xerox Corporation | Photoelectrophoretic imaging method employing dinaphtho-furan-dione pigments |
US3966466A (en) * | 1974-12-17 | 1976-06-29 | Xerox Corporation | Photoelectrophoretic imaging process using dark charge injecting agent on blocking electrode |
Also Published As
Publication number | Publication date |
---|---|
GB1357974A (en) | 1974-06-26 |
DE2162296B2 (en) | 1981-06-11 |
JPS5427734B1 (en) | 1979-09-12 |
CH558209A (en) | 1975-01-31 |
DE2162296C3 (en) | 1982-02-11 |
DE2162296A1 (en) | 1972-06-22 |
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