US3808329A - Liquid shampoo - Google Patents
Liquid shampoo Download PDFInfo
- Publication number
- US3808329A US3808329A US00305741A US30574172A US3808329A US 3808329 A US3808329 A US 3808329A US 00305741 A US00305741 A US 00305741A US 30574172 A US30574172 A US 30574172A US 3808329 A US3808329 A US 3808329A
- Authority
- US
- United States
- Prior art keywords
- fatty acid
- shampoo
- triethanolamine
- coconut
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002453 shampoo Substances 0.000 title abstract description 49
- 239000007788 liquid Substances 0.000 title description 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 51
- 239000000194 fatty acid Substances 0.000 abstract description 51
- 229930195729 fatty acid Natural products 0.000 abstract description 51
- -1 FATTY ACID ESTER Chemical class 0.000 abstract description 46
- 150000004665 fatty acids Chemical class 0.000 abstract description 30
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000000344 soap Substances 0.000 abstract description 10
- 229920001214 Polysorbate 60 Polymers 0.000 abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- 235000013162 Cocos nucifera Nutrition 0.000 description 16
- 244000060011 Cocos nucifera Species 0.000 description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- 229920001213 Polysorbate 20 Polymers 0.000 description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 9
- 239000002085 irritant Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 5
- 230000007794 irritation Effects 0.000 description 5
- 125000006353 oxyethylene group Chemical group 0.000 description 5
- 239000002304 perfume Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 description 1
- BBFCZCZRPXGONA-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCO.OCCN(CCO)CCO BBFCZCZRPXGONA-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- WWHZEXDIQCJXSV-UHFFFAOYSA-N aluminum;trihypochlorite Chemical compound [Al+3].Cl[O-].Cl[O-].Cl[O-] WWHZEXDIQCJXSV-UHFFFAOYSA-N 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SKDZEPBJPGSFHS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)tetradecanamide Chemical compound CCCCCCCCCCCCCC(=O)N(CCO)CCO SKDZEPBJPGSFHS-UHFFFAOYSA-N 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4993—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
Definitions
- the present invention relates to novel liquid shampoo compositions having highly desirable properties of mildness, conditioning, cleaning and foaming.
- Each constituent of the present shampoo is known in the prior art as a shampoo ingredient, but heretofore no one has combined the present constituents to formulate a shampoo of the present invention.
- a recently marketed shampoo contained triethnolamine alkyl sulfate, triethanolamine coconut fatty acid soap and coconut ethanolamide, but this shampoo was not as mild as the shampoos of this invention.
- Applicants have discovered that the addition of a polyoxyethylene fatty acid ester to a shampoo of the same or similar components results in a shampoo which is unexpectedly mild and which has a highly desirable lather.
- polyoxyethylene fatty acid ester in a shampoo is not novel, having been disclosed as early as 1953 in A Guide to Cosmetic and Pharmaceutical Formulation With Atlas Products, Atlas Powder Company, 47 (1953).
- polyoxyethylene fatty acid ester when used in shampoos of the present invention, exerts an anti-irritant effect on the other shampoo ingredients. This reduces the irritation potential of the shampoo, resulting in a mild shampoo.
- the addition of polyoxyethylene fatty acid ester also increases the desirability of the lather of the shampoo. Further, these unexpected results are not obtained at the cost of reduced cleaning or conditioning.
- the ratio of polyoxyethylene fatty acid ester to other surfactants is from about 1:1 to about 1:5 and the pH of the solution is from about 7.0 to about 8.4.
- the shampoo is surprisingly mild and produces voluminous rich lather when used on both soiled and unsoiled hair.
- the ratio of (A) to the total of (B), (C) and (D) is from about 1:1 to about 1:5 and the pH of the composition in aqueous solution is from 7.0 to 8.4. It is advantageous to control the pH by the addition of triethanolamine as this comopund also prevents contamination of the solution by bacteria.
- polyoxyethylene fatty acid ester decreases the irritation potential of the other components of the above shampoo and results in a shampoo with increased mildness.
- the polyoxyethylene fatty acid ester apparently acts not only as an anti-irritant, but also acts to incease the desirability of the lather feel.
- the lather of the shampoo of the present invention is preferred for its rich, smooth, creamy qualities.
- Shampoos made in accordance with the present invention combine the qualities of excellent mildness and feel with qualities of excellent cleaning, conditioning of hair, and similar loaded and unloaded foam heights. Similar foam heights means that similar quantities of foam are obtained whether the hair is clean or is heavily soiled.
- the ratio of (A) to the total of (B), (C) and (D) is about 5:18 and the pH of the composition in aqueous solution is from about 7.2 to about 8.0.
- the triethanolamine alkyl sulfate may be replaced by an equivalent amount of sodium alkyl sulfate.
- the ratio of (A) to the total of (B), (C) and (D) is 5 :18 and the pH of the composition in aqueous solution is from about 7.2 to about 8.
- the triethanolamine alkyl sulfate may be replaced by an equivalent amount of sodium ethanolamine alkyl sulfate.
- the use of coconut alkyls and fatty acids not only results in an excellent shampoo, but is also economical since they are commercially available.
- a shampoo made in accordance with the present invention can, of course, contain other common shampoo ingredients, for example, a thickening agent, an antioxidant, ancl/or a perfume.
- Triethanolamine alkyl (coconut middle cut sulfate 10.00 Polyoxyethylene (20) sorbitan monolaurate 5.00 Triethanolamine 4.00 Coconut 2 fatty acid 3.00 Coconut 2 monoethanolamide 2.00
- a coconut middle cut consists essentially of about 67% Cu; about 25% C11. and about 8% C16.
- a first shampoo was made as in Example I and was compared to a second shampoo made without polyoxyethylene (20) sorbitan monolaurate but otherwise containing all of the components of Example I.
- Four twoinch square patches of gauze were soaked in the first shampoo and four were soaked in the second shampoo.
- the patches were applied for 24 hours to the upper arms of four human subjects.
- Each subject was exposed to one first shampoo patch and one second shampoo patch. At the end of 24 hours, the patches were removed; and the subjects were graded then and graded again 24 hours later. No irritation was observed under any of the Example I patches while mild irritation was observed under every second shampoo patch by the time of the second grading.
- a mild shampoo consisting essentially of:
- (C) from about 1% to about 10% of triethanolamine coconut fatty acid soap wherein said fatty acid contains from about 10 to about 18 carbon atoms;
- a mild shampoo as recited in claim 6 consisting essentially of from about 4% to about 15% of polyoxyethylene sorbitan fatty acid ester; from about 5% to about of triethanolamine alkyl sulfate; from about 2% to about 5% of triethanolamine coconut fatty acid soap; and from about 2% to about 5% of fatty acid ethanolamide.
- a mild shampoo as recited in claim 1 consisting essentially of about 10% of triethanolamine alkyl sulfate; about 5% 0f polyoxyethylene sorbitan monolaurate; about 4% of triethanolamine; about 3% of coconut fatty acid; about 2% of coconut monoethanolamide; and the balance, water.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00305741A US3808329A (en) | 1972-11-13 | 1972-11-13 | Liquid shampoo |
| PH15154A PH10112A (en) | 1972-11-13 | 1973-10-26 | Liquid shampoo |
| AU62166/73A AU479862B2 (en) | 1972-11-13 | 1973-11-05 | Liquid shampoo |
| CA185,093A CA1017251A (en) | 1972-11-13 | 1973-11-06 | Liquid shampoo |
| FR7340194A FR2206080B1 (enExample) | 1972-11-13 | 1973-11-12 | |
| DE2356475A DE2356475A1 (de) | 1972-11-13 | 1973-11-12 | Fluessiges shampoo |
| IT31200/73A IT1048157B (it) | 1972-11-13 | 1973-11-12 | Shampoo liquido |
| NL7315427A NL7315427A (enExample) | 1972-11-13 | 1973-11-12 | |
| JP48127614A JPS505A (enExample) | 1972-11-13 | 1973-11-13 | |
| BE137669A BE807232A (fr) | 1972-11-13 | 1973-11-13 | Shampooing liquide |
| GB5258973A GB1393639A (en) | 1972-11-13 | 1973-11-13 | Liquid shampoo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00305741A US3808329A (en) | 1972-11-13 | 1972-11-13 | Liquid shampoo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3808329A true US3808329A (en) | 1974-04-30 |
Family
ID=23182143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00305741A Expired - Lifetime US3808329A (en) | 1972-11-13 | 1972-11-13 | Liquid shampoo |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3808329A (enExample) |
| JP (1) | JPS505A (enExample) |
| BE (1) | BE807232A (enExample) |
| CA (1) | CA1017251A (enExample) |
| DE (1) | DE2356475A1 (enExample) |
| FR (1) | FR2206080B1 (enExample) |
| GB (1) | GB1393639A (enExample) |
| IT (1) | IT1048157B (enExample) |
| NL (1) | NL7315427A (enExample) |
| PH (1) | PH10112A (enExample) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988438A (en) * | 1975-01-10 | 1976-10-26 | American Cyanamid Company | Hair conditioning shampoo |
| US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
| EP0018717A1 (en) * | 1979-03-27 | 1980-11-12 | Unilever Plc | Shampoo |
| US4438096A (en) | 1982-05-27 | 1984-03-20 | Helene Curtis Industries, Inc. | Pearlescent shampoo |
| US4774016A (en) * | 1983-01-24 | 1988-09-27 | Crinos Industria Farmacobiologica Spa | Skin cleaning preparations containing an HLB 10-19 nonionic emulsifier and a thickening agent |
| US4777038A (en) * | 1985-05-28 | 1988-10-11 | Henkel Kommanditgesellschaft Auf Aktien | Free-flowing pearlescent concentrate |
| US5246613A (en) * | 1990-07-20 | 1993-09-21 | The Procter & Gamble Company | Aqueous isotropic personal liquid cleansing composition with triethanol amine soap, selected electrolyte and synthetic surfacant |
| US5573756A (en) * | 1995-01-25 | 1996-11-12 | Banner Pharmacaps Inc. | Shampoo conditioner and softgel filled therewith |
| FR2897777A1 (fr) * | 2006-02-28 | 2007-08-31 | Oreal | Article cosmetique a usage unique, comprenant un support impregne d'une lotion contenant un ester d'acide gras et de sorbitan oxyalkylene. |
| US20070212401A1 (en) * | 2006-02-28 | 2007-09-13 | Virginie Masse | Single-use cosmetic article comprising a support impregnated with a lotion containing oxyethylenated sorbitan monolaurate comprising 4 OE |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5182738A (ja) * | 1975-01-13 | 1976-07-20 | Kao Corp | Shanpuusoseibutsu |
| US4154706A (en) * | 1976-07-23 | 1979-05-15 | Colgate-Palmolive Company | Nonionic shampoo |
| GB2204319A (en) * | 1987-05-08 | 1988-11-09 | Unilever Plc | Liquid dishwashing composition for aluminium pans |
| FR2889661B1 (fr) † | 2005-08-11 | 2007-10-05 | Oreal | Procede de coloration des fibres keratiniques comprenant une etape de traitement du cuir chevelu a partir d'un ester de sorbitan particulier |
-
1972
- 1972-11-13 US US00305741A patent/US3808329A/en not_active Expired - Lifetime
-
1973
- 1973-10-26 PH PH15154A patent/PH10112A/en unknown
- 1973-11-06 CA CA185,093A patent/CA1017251A/en not_active Expired
- 1973-11-12 IT IT31200/73A patent/IT1048157B/it active
- 1973-11-12 NL NL7315427A patent/NL7315427A/xx not_active Application Discontinuation
- 1973-11-12 FR FR7340194A patent/FR2206080B1/fr not_active Expired
- 1973-11-12 DE DE2356475A patent/DE2356475A1/de not_active Withdrawn
- 1973-11-13 JP JP48127614A patent/JPS505A/ja active Pending
- 1973-11-13 BE BE137669A patent/BE807232A/xx unknown
- 1973-11-13 GB GB5258973A patent/GB1393639A/en not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
| US3988438A (en) * | 1975-01-10 | 1976-10-26 | American Cyanamid Company | Hair conditioning shampoo |
| EP0018717A1 (en) * | 1979-03-27 | 1980-11-12 | Unilever Plc | Shampoo |
| US4438096A (en) | 1982-05-27 | 1984-03-20 | Helene Curtis Industries, Inc. | Pearlescent shampoo |
| US4774016A (en) * | 1983-01-24 | 1988-09-27 | Crinos Industria Farmacobiologica Spa | Skin cleaning preparations containing an HLB 10-19 nonionic emulsifier and a thickening agent |
| US4897214A (en) * | 1983-01-24 | 1990-01-30 | Crinos Industria Farmacobiologica Spa. | Skin cleaning preparations containing a HLB 10-19 non-ionic emulsifier and a thickening agent |
| US4777038A (en) * | 1985-05-28 | 1988-10-11 | Henkel Kommanditgesellschaft Auf Aktien | Free-flowing pearlescent concentrate |
| US5246613A (en) * | 1990-07-20 | 1993-09-21 | The Procter & Gamble Company | Aqueous isotropic personal liquid cleansing composition with triethanol amine soap, selected electrolyte and synthetic surfacant |
| US5573756A (en) * | 1995-01-25 | 1996-11-12 | Banner Pharmacaps Inc. | Shampoo conditioner and softgel filled therewith |
| FR2897777A1 (fr) * | 2006-02-28 | 2007-08-31 | Oreal | Article cosmetique a usage unique, comprenant un support impregne d'une lotion contenant un ester d'acide gras et de sorbitan oxyalkylene. |
| US20070212401A1 (en) * | 2006-02-28 | 2007-09-13 | Virginie Masse | Single-use cosmetic article comprising a support impregnated with a lotion containing oxyethylenated sorbitan monolaurate comprising 4 OE |
| EP1837011A1 (fr) * | 2006-02-28 | 2007-09-26 | L'Oréal | Article cosmétique à usage unique, comprenant un support imprégné d'une lotion contenant du mono-laurate de sorbitan oxyéthylène à 4 OE. |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2206080B1 (enExample) | 1978-09-29 |
| NL7315427A (enExample) | 1974-05-15 |
| PH10112A (en) | 1976-08-26 |
| AU6216673A (en) | 1975-05-08 |
| BE807232A (fr) | 1974-05-13 |
| FR2206080A1 (enExample) | 1974-06-07 |
| DE2356475A1 (de) | 1974-05-16 |
| IT1048157B (it) | 1980-11-20 |
| CA1017251A (en) | 1977-09-13 |
| JPS505A (enExample) | 1975-01-06 |
| GB1393639A (en) | 1975-05-07 |
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