US3806460A - Cleaner compositions - Google Patents

Cleaner compositions Download PDF

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Publication number
US3806460A
US3806460A US00216826A US21682672A US3806460A US 3806460 A US3806460 A US 3806460A US 00216826 A US00216826 A US 00216826A US 21682672 A US21682672 A US 21682672A US 3806460 A US3806460 A US 3806460A
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United States
Prior art keywords
weight
composition
compositions
monophenyl ether
oven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US00216826A
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English (en)
Inventor
C Mukai
B Weinstein
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt and Colman Subsidiary Corp
Original Assignee
American Home Products Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE793854D priority Critical patent/BE793854A/xx
Application filed by American Home Products Corp filed Critical American Home Products Corp
Priority to US00216826A priority patent/US3806460A/en
Priority to JP48004488A priority patent/JPS5747238B2/ja
Priority to AT1109972A priority patent/AT322701B/de
Priority to GB52873A priority patent/GB1411032A/en
Priority to CA160,654A priority patent/CA989696A/en
Priority to AU50847/73A priority patent/AU468520B2/en
Priority to DE2300744A priority patent/DE2300744C3/de
Priority to IE28/73A priority patent/IE37089B1/xx
Priority to NL7300288A priority patent/NL7300288A/xx
Priority to ZA730157A priority patent/ZA73157B/xx
Priority to FR7300598A priority patent/FR2331943A7/fr
Priority to CH29673A priority patent/CH584752A5/xx
Application granted granted Critical
Publication of US3806460A publication Critical patent/US3806460A/en
Assigned to BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP. OF DE. reassignment BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP. OF DE. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: AMERICAN HOME PRODUCTS CORPORATION, A DE. CORP.
Assigned to RECKITT & COLMAN SUBSIDIARY CORPORATION reassignment RECKITT & COLMAN SUBSIDIARY CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP OFF DE
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0057—Oven-cleaning compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

Definitions

  • the present invention relates to cleaning compositions useful for cleaning oven, pots, barbecue equipment, tiles, walls, etc.
  • One aspect of the present invention is to provide cleaning compositions, particularly oven-cleaning compositions, which effectively remove grease, fat, etc. from oven surfaces at temperatures as low as 150 F. and which do not fume.
  • Another aspect of the present invention is to provide an oven-cleaner composition which is caustic alkali free, thereby eliminating many of the hazards associated with known prior art caustic alkali compositions.
  • a further aspect of the present invention relates to the use of an amide in oven cleaner formulations to facilitate removal of grease and fat deposits.
  • the cleaning compositions of this invention comprise 1) about 1 to about 'by weight of an inorganic cleaner, (2) ammonia and/or an organic amine compound, (3) about 0.7 to about by weight of a water soluble mono or di-substituted amide, preferably about 2 to about 10% by weight, (4) 0 to about by weight of a Water-insoluble or partially soluble solvent, preferably about 6 to 20% by weight, (5) 0 to about 7% by weight of at least one surfactant, preferably from about .01 to 3% by weight. Water is present in the composition in an amount from 60 to 90% by weight of the total composition.
  • compositions of the present invention may contain one or more additional ingredients useful in oven cleaning compositions such as thickening agents, humectants, abrasives, foam stabilizers (surfactants), viscosity modifier, perfumes, etc.
  • additional ingredients useful in oven cleaning compositions such as thickening agents, humectants, abrasives, foam stabilizers (surfactants), viscosity modifier, perfumes, etc.
  • the inorganic cleaners (builders) useful in the compositions described herein are selected from the alkali metal or ammonium salts of carbonic, phosphoric, boric and silicic acid.
  • Illustrative compounds are sodium, potassium or ammonium carbonates, phosphates such as trisodium phosphate, tripotassium phosphate, trilithium phosphate, sodium metapolyphosphate etc.; silicates such as sodium disilicate, potassium disilicate, lithium disilicate, and the corresponding orthosilicates, sesquisilicates and metasilicates.
  • the corresponding borates are also useful such as sodium borate, etc.
  • the amines useful in the compositions are non-toxic primary or secondary amines, preferably primary amines which may be either aliphatic, aromatic or heterocyclic. Illustrative of these amines are N-2-hydroxyethyl diethylene triamine, monoethanolamine, diethanolamine, propanolamine, ethylamine, benzylamine, but-ylisopropanolamine, isopropanolamine and 2 [2 (3 aminopropoxy) ethoxy]ethanol.
  • the preferred amines are the aliphatic 3,806,460 Patented Apr. 23, 1974 primary amines having at least one amine group on a terminal carbon atom and having a molecular weight below about 300.
  • the preferred specific amines are N-2 hydroxy ethyl diethylene triamine and 2-[2-(3-aminopropoxy)ethoxy]ethanol.
  • the amines, when present in the compositions of the present invention may be used in an amount of about 1 to about 20% by weight of the total composition, preferably between about 2 and 10% by weight.
  • Ammonia can be used in place of the amine or these materials may be used in combination. It is present in the composition as ammonia in solution.
  • the ammonia may be added to the formulation as ammonia water, or as gaseous ammonia, or in the form of a neutral salt or other compound of ammonia which upon reaction with the inorganic cleaner in the composition yields free ammonia to provide ammonia water.
  • Illustrative of ammonium salts are ammonium acetate, ammonium sulfate, ammonium chloride, etc.
  • the total weight of ammonia expressed as NH in the composition may vary but is about 0.1 to about 10% based on the weight of the water in the composition. Larger quantities may be used but offer no advantages and result in loss of ammonia through vaporization.
  • the preferred quantity of ammonia is about 0.1 to about 4% by weight.
  • the surfactant used in the present compositions is chosen to provide a stable foam which helps to maintain a deposit of the composition upon the site sought to be cleaned.
  • the surfactant may be a anionic material (eg a soap) which may be used alone but preferably in combination with a non-ionic surface active agent or another anionic agent.
  • a soap e.g. a soap
  • Illustrative of soaps which may be used in the present invention are the well-known salts of fatty acids having up to twenty-two carbon atoms.
  • These may include the Na, K, Li and ammonium or amine salts of myristic, palmitic, stearic, behinic, oleic, lauric, abietic, capric, caproic, caprylic, ricinoleic, linoleic, hydrogenated and dehydrogenated abietic acids, the surface active bydrolysis products of tallow, coconut oil, cottonseed oil, soybean oil, peanut oil, sesame oil, linseed oil, olive oil, corn oil, castor oil and the like.
  • the soap not only aids in removal of oven grime but also opacifies the composition.
  • the nonionic and anionic surfactants are low foaming materials in the following classes: aliphatic polyethers; polyoxyethylene esters of fatty acids; sulfated esters; alkylarylpolyglycol ethers; aliphatic ester sulfates; alkali metal salts of alcohol sulfates; organic phosphate esters; an alkylphenoxypolyethyleneoxyethanol; ether terminated polyethoxy ethanols such as described in U.S. Pat. 3,281,475, the disclosure of which incorporated herein by reference.
  • R selected from the class consistingof a C -C2 alkyl radical, either straight chain or branch chain and an alkyl phenyl radical wherein the alkyl radical is C C straight or branch chain.
  • R is selected from the class consisting of tertiary C C alkyl groups and an acyclic radical of the formula C H derived from monoterpenes.
  • R is t-butylisobornyl; x is a number from about 7 to 50, preferably 9 to 35. R is preferably p-nonylphenyl. Preferably about 0.5 to 4% by weight of the non-ionic or anionic surfactant is used in addition to the use of a soap as previously described.
  • the solvent used in the compositions of the present invention is one which is capable of dissolving animal fats deposited on oven surfaces.
  • the solvent is no more than about 20% soluble in water at room temperature and atmospheric pressure and has a boiling point above 250 F.
  • suitable solvents are diphenyl ether, 2- ethylhexanol-l,2-ethylhexanediol-l,3; 2 phenoxyethanol, diethylene glycol monophenyl ether, phenylmethylcarbinol, benzyl alcohol, phenylglycol ethers (e.g.
  • the mixture of phenyl glycol ethers is the preferred solvent.
  • amides useful in the compositions of the present invention are represented by the formula:
  • ii-N-n' are characterized by high solubility in water at ambient temperatures.
  • R is selected from the class consisting of hydrogen and (lower)alkyl: R is (lower) alkyl; R is selected from the class consisting of hydrogen and an alkyl radical (straight or branch chain) having C to C carbon atoms; R and R may be joined together to form with the N-atom a saturated heterocyclic ring containing four to seven ring carbons with the proviso that when R and R are not joined together, R is (lower) alkyl.
  • (lower)alkyl includes methyl, ethyl, propyl, isobutyl, n-butyl, pentyl, etc.
  • Illustrative of C to C alkyl radicals are methyl, ethyl, butyl, isobutyl, hexyl, etc.
  • the preferred amides within the scope of the present invention are N-methyl pyrrolidinone-2(N-methyl pyrrolidone-2) and pyrrolidinone-2(pyrrolidone-2).
  • Illustrative of other amides are N,N-dimethylformamide, N,N- dimethylacetamide, N,N-dimethylcaproamide, N-methyl piperidone-Z and piperidone-Z.
  • Optional ingredients may be present in the compositions.
  • thickening agents provide body to the composition, allowing it to remain in contact with the oven surface without running.
  • Exemplary of useful thickening agents are colloidal magnesium aluminum silicate, alginates, carboxymethyl cellulose, carboxyethyl cellulose bentonite and other well-known materials such as described in US. Pat. 3,296,147.
  • Humectants are present in the composition to aid in slowing the evaporation of the water present in the composition and some provide a solvent effect in removing grease.
  • Exemplary of useful humectants are the glycols (propylene glycol and polyethylene glycol) and glycerol.
  • abrasives are added to provide additional cleaning power to aid in removing stubborn stains; additionally, certain abrasives serve to increase viscosity and to absorb the emulsifier and propellant in pressurized aerosol systems, providing a superior product.
  • abrasives producing all the above properties is a silica such as CabO-Sil M or Aerosil 200.
  • a foam stabilizer may be added to increase the adherence of the composition to the walls of the oven and is preferably a wax having a softening point in the range of 100 to 200 F.
  • the wax may be added in pellet or powder form to the mixture of the composition and propellant.
  • suitable waxes are beeswax, microcrystalline wax, etc.
  • compositions are useful in cleaning ovens when applied to cold (ambient room temperature) or hot (up to 300 F.) soiled ovens and allowed to remain on the soiled surfaces until the grime is softened, followed by wiping away the composition, preferably with a damp cloth or sponge. Extremey high temperatures impede cleaning action, due to the fast evaporation of the water present in the composition. However, the most efiicient method of using the disclosed compositions is to apply them to an oven preheated of 150-2 00 R, which is ideally maintained at that temperature range during the entire cleaning procedure (i.e. not turned 01f). The composition is allowed to remain on the heated oven surfaces for about ten to about thirty minutes, depending on degree of soiling, followed by removal with a damp cloth or sponge.
  • the oven cleaning compositions are supplied in self-contained valve-controlled aerosol units which provide a fine spray or foam upon activation of the valve.
  • the aerosol container unit consists of a pressure-tight aerosol container having a valve-controlled opening and containing a composition as set forth herein and from about 2.00% to about 25.00% of a propellant.
  • Propellants are selected from the well-known compatible propellants such as isobutane, isobutane/propane, dichlorodifluoromethane Freon 12), trichlorofluoromethane (Freon ll), dichlorotetrafluoroethane (Freon 114) and l,1,2-trichlorotrifluoroethane (Freon 113) or mixtures thereof.
  • the propellant should be effective at atmospheric temperature and not adversely react with any components of the composition.
  • compositions of the present invention are illustrative of the compositions of the present invention:
  • EXAMPLE 2 Ingredients: Percent by weight Composition of Example 1 81.60 N-methyl pyrrolidinone-2 6.05 Ammonium hydroxide (28% NH 2.17 2-et-hylhexanol-1 10.18
  • This composition is prepared as follows:
  • Example 1 To the composition of Example 1 there is added consecutively N-methyl pyrrolidinone 2, ammonium hydroxide and 2-ethyl hexanol-l with mechanical agitation, the Z-ethyl hexanol-l being added slowly.
  • the resulting homogenous mixture has a pH of 12.3.
  • cleaner-compositions are prepared in the same manner as described in Example 2.
  • EXAMPLE 4 Ingredients: Percent by weight Composition of Example 1 81.60 N-methyl pyrrolidinone-2 6.05 Ammonium hydroxide 2.17 Octauol-Z 10.18
  • EXAMPLE 6 10 Ingredients: Percent by weight Composition of Example 1 82.90 N-methyl pyrrolidinone-2 4.74 Ammonium hydroxide (28% NH 2.17 Mixture of 30% diethylene glycol monophenyl ether and 70% ethylene glycol monophenyl ether 10.19
  • EXAMPLE7 Ingredients: Percent by weight Composition of Example 1 81.60 N-methyl pynrolidinone-Z 6.05 Ammonium hydroxide (28% NH 2.17 Mixture of 30% diethylene glycol monophenyl ether and 70% ethylene glycol monophenyl ether 10.18
  • EXAMPLE 8 Ingredients: 'Percent by weight Composition of Example 1 81.60 N,N-dimethyl formamide 6.05 Ammonium hydroxide (28% NH 2.17 Mixture of 30% diethylene glycol monophenyl ether and 70% ethylene glycol monophenyl ether 10.18
  • EXAMPLE9 Ingredients: Percent by weight Composition of Example 1 81.60 N,N-dimethyl acetamide 6.05 Ammonium hydroxide (28% NH 2.17 Mixture of 30% diethylene glycol monophenyl ether and 70% ethylene glycol monophenyl ether 10.18
  • EXAMPLE 10 Ingredients: Percent by weight Composition of Example 1 81.00 Hallcomid M6 6.05 Ammonium hydroxide (28% NH 2.17 Mixture of 30% diethylene glycol monophenyl ether and 70% ethylene glycol monophenyl ether 10.18
  • EXAMPLE 12 Ingredients: Percent by weight Composition of Example 1 80.90 N-methyl pyrrolidinone-2 6.00 N-Z-hydroxyethyldiethylene triamine 3.00
  • EXAMPLE 13 Ingredients: Percent by weight Composition of Example 1 80.90 N-methyl pyrrolidinone-Z 6.00 Monoethanolamine 3.01
  • Example 2 through 14 can be applied by a brush to surfaces to 'be cleaned or they may be incorporated into aerosol packages as exemplified by Example 15 to be used as sprays or they may be incorporated into squeeze containers.
  • the efiiciency of the cleaning compositions within the scope of the present invention was tested by spraying an aerosol preparation containing the cleaning composition onto panels upon which was baked an oven soil composition composed of 84% by weight beef tallow, 8% flour and 8% powdered sugar.
  • the panels used were of varying size including 4" x 8" which were white in color.
  • the oven soil composition was brushed on plates at the rate of 0.04 g./sq. inch and the plates baked in an oven at 500 F. for seventy-five minutes.
  • the soiled panels are placed in an oven maintained at a temperature between 150200 F. 'for about ten minutes.
  • One half of each panel is sprayed with a standard cleaning composition using a shield to confine the spray from the other half of the panel.
  • a non-caustic cleaner composition for removing baked on food residues from a solid surface consisting essentially of (a) at least 60% water, (b) about 1 to about 15% by weight of an inorganic cleaner wherein said cleaner is an alkali metal or ammonium salt whose anionic portion is selected from the class consisting of a carbonate, a phosphate, a borate and a silicate, (c) up to about 4% by weight of ammonia based on the total weight of water in said cleaner composition, (d) about 1 to about 20% by weight of a non-toxic primary amine having a primary amino moiety on a terminal carbon atom and having a molecular weight below 300, (e) about 6 to about 20% by weight of an organic solvent which is no more than 20% soluble in water at room temperature and atmospheric pressure, said solvent having a boiling point about 250 F.
  • an inorganic cleaner wherein said cleaner is an alkali metal or ammonium salt whose anionic portion is selected from the class consisting of a carbonate, a
  • said solvent being selected from the class consisting of diphenyl ether, Z-ethyl-hexanol-l, 2-ethylhexanediol-1,3, phenylmethylcarbinol, a phenyl glycol ether, benzyl alcohol, octanol-Z, n-octanol, decanol, isodecanol and dodeca- 1101 and mixtures thereof, (f) about 0.1 to 4% by weight of a soap and about 0.5% to about 4% by weight of a non-ionic surfactant, and (g) about 2 to about by weight of an amide selected from the class consisting of N,N-dimethylcaproamide, N-methyl pyrrolidinone-Z and pyrrolidinone-2.
  • R is selected from the class consisting of a C C alkyl radical and a C C alkyl phenyl radical; R is selected from the class consisting of a tertiary C -C alkyl radical and isobornyl; and x is a number from 9 to 35.
  • a non-caustic composition for cleanng soiled solid surfaces consisting essentially of (a) at least 60% water, (b) about 1 to about by weight of an inorganic cleaner wherein said cleaner is an alkali metal or ammonium salt whose anionic portion is selected from the class consisting of a carbonate, a phosphate, a boratc and a silicate, (c) about 0.1 to about 4% by weight of ammonia based on the total weight of water is said non-caustic composition, (d) about 2 to about 10% by weight of monoethanolamine, (e) about 6 to about 20% by weight of a mixture of diethylene glycol monophenyl ether and ethylene glycol monophenyl ether, (f) about 0.1 to about 4% by weight of a soap and about 0.5% to about 4% by weight of a non-ionic surfactant and (g) about 2 to about 10% by weight of a material selected from the class consisting of N-methyl pyrrolidinone-Z, pyrrolidinone
  • component (g) is N-methyl pyrrolidinone-2.
  • composition according to claim 7 wherein the weight ratio of diethylene glycol monophenyl ether to ethylene glycol monophenyl ether is about 3:7.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
US00216826A 1972-01-10 1972-01-10 Cleaner compositions Expired - Lifetime US3806460A (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
BE793854D BE793854A (fr) 1972-01-10 Compositions de nettoyage
US00216826A US3806460A (en) 1972-01-10 1972-01-10 Cleaner compositions
JP48004488A JPS5747238B2 (enrdf_load_stackoverflow) 1972-01-10 1972-12-22
AT1109972A AT322701B (de) 1972-01-10 1972-12-28 Reinigungsmittelmischung
GB52873A GB1411032A (en) 1972-01-10 1973-01-04 Cleaner compositions
CA160,654A CA989696A (en) 1972-01-10 1973-01-05 Cleaner compositions
DE2300744A DE2300744C3 (de) 1972-01-10 1973-01-08 Ätzalkalienfreie Ofenreinigungsmittel
AU50847/73A AU468520B2 (en) 1972-01-10 1973-01-08 Cleaner compositions
IE28/73A IE37089B1 (en) 1972-01-10 1973-01-09 Cleaning compositions
NL7300288A NL7300288A (enrdf_load_stackoverflow) 1972-01-10 1973-01-09
ZA730157A ZA73157B (en) 1972-01-10 1973-01-09 Cleaner compositions
FR7300598A FR2331943A7 (fr) 1972-01-10 1973-01-09 Compositions detergentes non-caustiques
CH29673A CH584752A5 (enrdf_load_stackoverflow) 1972-01-10 1973-01-10

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00216826A US3806460A (en) 1972-01-10 1972-01-10 Cleaner compositions

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US3806460A true US3806460A (en) 1974-04-23

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US00216826A Expired - Lifetime US3806460A (en) 1972-01-10 1972-01-10 Cleaner compositions

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US (1) US3806460A (enrdf_load_stackoverflow)
JP (1) JPS5747238B2 (enrdf_load_stackoverflow)
AT (1) AT322701B (enrdf_load_stackoverflow)
AU (1) AU468520B2 (enrdf_load_stackoverflow)
BE (1) BE793854A (enrdf_load_stackoverflow)
CA (1) CA989696A (enrdf_load_stackoverflow)
CH (1) CH584752A5 (enrdf_load_stackoverflow)
DE (1) DE2300744C3 (enrdf_load_stackoverflow)
FR (1) FR2331943A7 (enrdf_load_stackoverflow)
GB (1) GB1411032A (enrdf_load_stackoverflow)
IE (1) IE37089B1 (enrdf_load_stackoverflow)
NL (1) NL7300288A (enrdf_load_stackoverflow)
ZA (1) ZA73157B (enrdf_load_stackoverflow)

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928065A (en) * 1973-12-19 1975-12-23 Lever Brothers Ltd Composition for cleaning metal cookware
US3939101A (en) * 1972-10-04 1976-02-17 Rockwell International Corporation Composition for ultrasonic inspection of objects and method for employing same
US3963560A (en) * 1972-11-01 1976-06-15 Gaf Corporation Composition for deinking waste paper
US4055515A (en) * 1975-12-31 1977-10-25 Borden, Inc. Developer for printing plates
US4085059A (en) * 1974-05-02 1978-04-18 Bunker Ramo Corporation Foam type coating remover
US4130674A (en) * 1977-08-17 1978-12-19 Detrex Chemical Industries, Inc. Process of controlling organic coatings in aqueous spray booth systems
DE2807329A1 (de) * 1978-02-21 1979-08-23 Boehringer Sohn Ingelheim Mittel und verfahren zur feuerungsseitigen reinigung von heizanlagen auf schaumbasis
US4212759A (en) * 1979-01-22 1980-07-15 Cherry Donald G Acidic hydrocarbon-in-water emulsions
US4263179A (en) * 1979-08-09 1981-04-21 Basf Wyandotte Corporation Heavy-duty liquid detergent compositions containing alkoxylated alkylene diamines
US4269630A (en) * 1979-10-01 1981-05-26 George M. Stephenson Two-step process and composition for cleaning polished surfaces
US4407741A (en) * 1978-08-28 1983-10-04 Life Industries Corporation Hydrotropic cleaner
US4409116A (en) * 1982-08-18 1983-10-11 Richard Lodico Windshield wiper cleaning product
US4507155A (en) * 1983-07-08 1985-03-26 Cheek Robert H Cleaning composition and method
US4509989A (en) * 1983-03-25 1985-04-09 United States Steel Corporation Cleaning method for removing sulfur containing deposits from coke oven gas lines
US4617251A (en) * 1985-04-11 1986-10-14 Olin Hunt Specialty Products, Inc. Stripping composition and method of using the same
US4664721A (en) * 1981-12-07 1987-05-12 Intercontinental Chemical Corporation Printing screen cleaning and reclaiming compositions
US4774015A (en) * 1986-02-28 1988-09-27 Cherokee Chemical Co., Inc. Carburetor cleaner
US4780235A (en) * 1987-04-16 1988-10-25 E. I. Du Pont De Nemours And Company Paint remover
US4921629A (en) * 1988-04-13 1990-05-01 Colgate-Palmolive Company Heavy duty hard surface liquid detergent
US5102573A (en) * 1987-04-10 1992-04-07 Colgate Palmolive Co. Detergent composition
AU624357B2 (en) * 1988-01-26 1992-06-11 Hans-Gerd Kaiser Cleaning agent and process
US5254175A (en) * 1988-01-26 1993-10-19 Kaiser Hans Gerd Process for removing contaminants, in particular material residues, in poorly accessible machine parts
US5380454A (en) * 1993-07-09 1995-01-10 Reckitt & Colman Inc. Low temperature non-caustic oven cleaning composition
US5503778A (en) * 1993-03-30 1996-04-02 Minnesota Mining And Manufacturing Company Cleaning compositions based on N-alkyl pyrrolidones having about 8 to about 12 carbon atoms in the alkyl group and corresponding methods of use
US5569410A (en) * 1994-11-17 1996-10-29 Elf Atochem North America, Inc. Ammonium bicarbonate/ammonium carbamate activated benzyl alcohol paint stripper
US5573710A (en) * 1993-03-30 1996-11-12 Minnesota Mining And Manufacturing Company Multisurface cleaning composition and method of use
US5637559A (en) * 1993-03-30 1997-06-10 Minnesota Mining And Manufacturing Company Floor stripping composition and method
US5650001A (en) * 1995-12-01 1997-07-22 Howell; Bradley Compositions and methods for treating compact discs
US5922665A (en) * 1997-05-28 1999-07-13 Minnesota Mining And Manufacturing Company Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal
US6150320A (en) * 1994-07-21 2000-11-21 3M Innovative Properties Company Concentrated cleaner compositions capable of viscosity increase upon dilution
US20030021887A1 (en) * 2001-03-08 2003-01-30 Shipley Company, L.L.C. Compositions containing heterocylcic nitrogen compounds and glycols for texturing resinous material and desmearing and removing resinous material
US6849589B2 (en) 2001-10-10 2005-02-01 3M Innovative Properties Company Cleaning composition
US20070117730A1 (en) * 1997-05-23 2007-05-24 Bowsman Shelba F Piston cleaning compositions
CN100575401C (zh) * 2003-09-05 2009-12-30 三星电机株式会社 棕色氧化物预处理组合物及改进聚酰亚胺表面粘合性的方法
US20110318494A1 (en) * 2010-06-25 2011-12-29 Donate Felipe Augusto Coalescent for aqueous compositions
KR20210065630A (ko) * 2019-11-27 2021-06-04 애경산업(주) 의류용 액체 세제 조성물
WO2021222083A1 (en) * 2020-04-30 2021-11-04 Stepan Company Concentrated liquid esterquat compositions

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DE2910402A1 (de) * 1979-03-16 1980-09-25 Basf Ag Farbstabilisierte, nichtionische tenside und alkalische reinigerformulierungen, die diese tenside enthalten
US4372788A (en) * 1981-08-17 1983-02-08 Colgate-Palmolive Company Grill and oven cleaner
JPS62165101U (enrdf_load_stackoverflow) * 1986-03-11 1987-10-20
NZ224148A (en) * 1987-04-10 1991-02-26 Colgate Palmolive Co Pre-spotting composition for food residue removal
RU2767942C1 (ru) * 2021-07-19 2022-03-22 Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский государственный аграрный университет - МСХА имени К.А. Тимирязева" (ФГБОУ ВО РГАУ - МСХА имени К.А. Тимирязева) Маслорастворимый ингибитор коррозии

Cited By (42)

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US3939101A (en) * 1972-10-04 1976-02-17 Rockwell International Corporation Composition for ultrasonic inspection of objects and method for employing same
US3963560A (en) * 1972-11-01 1976-06-15 Gaf Corporation Composition for deinking waste paper
US3928065A (en) * 1973-12-19 1975-12-23 Lever Brothers Ltd Composition for cleaning metal cookware
US4085059A (en) * 1974-05-02 1978-04-18 Bunker Ramo Corporation Foam type coating remover
US4055515A (en) * 1975-12-31 1977-10-25 Borden, Inc. Developer for printing plates
US4130674A (en) * 1977-08-17 1978-12-19 Detrex Chemical Industries, Inc. Process of controlling organic coatings in aqueous spray booth systems
DE2807329A1 (de) * 1978-02-21 1979-08-23 Boehringer Sohn Ingelheim Mittel und verfahren zur feuerungsseitigen reinigung von heizanlagen auf schaumbasis
US4407741A (en) * 1978-08-28 1983-10-04 Life Industries Corporation Hydrotropic cleaner
US4212759A (en) * 1979-01-22 1980-07-15 Cherry Donald G Acidic hydrocarbon-in-water emulsions
US4263179A (en) * 1979-08-09 1981-04-21 Basf Wyandotte Corporation Heavy-duty liquid detergent compositions containing alkoxylated alkylene diamines
US4321167A (en) * 1979-08-09 1982-03-23 Basf Wyandotte Corporation Heavy duty liquid detergent compositions containing alkoxylated alkylene diamines and fatty acids
US4269630A (en) * 1979-10-01 1981-05-26 George M. Stephenson Two-step process and composition for cleaning polished surfaces
US4664721A (en) * 1981-12-07 1987-05-12 Intercontinental Chemical Corporation Printing screen cleaning and reclaiming compositions
US4409116A (en) * 1982-08-18 1983-10-11 Richard Lodico Windshield wiper cleaning product
US4509989A (en) * 1983-03-25 1985-04-09 United States Steel Corporation Cleaning method for removing sulfur containing deposits from coke oven gas lines
US4507155A (en) * 1983-07-08 1985-03-26 Cheek Robert H Cleaning composition and method
US4617251A (en) * 1985-04-11 1986-10-14 Olin Hunt Specialty Products, Inc. Stripping composition and method of using the same
US4774015A (en) * 1986-02-28 1988-09-27 Cherokee Chemical Co., Inc. Carburetor cleaner
US5102573A (en) * 1987-04-10 1992-04-07 Colgate Palmolive Co. Detergent composition
US4780235A (en) * 1987-04-16 1988-10-25 E. I. Du Pont De Nemours And Company Paint remover
AU624357B2 (en) * 1988-01-26 1992-06-11 Hans-Gerd Kaiser Cleaning agent and process
US5254175A (en) * 1988-01-26 1993-10-19 Kaiser Hans Gerd Process for removing contaminants, in particular material residues, in poorly accessible machine parts
US4921629A (en) * 1988-04-13 1990-05-01 Colgate-Palmolive Company Heavy duty hard surface liquid detergent
US5503778A (en) * 1993-03-30 1996-04-02 Minnesota Mining And Manufacturing Company Cleaning compositions based on N-alkyl pyrrolidones having about 8 to about 12 carbon atoms in the alkyl group and corresponding methods of use
US5573710A (en) * 1993-03-30 1996-11-12 Minnesota Mining And Manufacturing Company Multisurface cleaning composition and method of use
US5637559A (en) * 1993-03-30 1997-06-10 Minnesota Mining And Manufacturing Company Floor stripping composition and method
US5744440A (en) * 1993-03-30 1998-04-28 Minnesota Mining And Manufacturing Company Hard surface cleaning compositions including a very slightly water-soluble organic solvent
WO1995002033A1 (en) * 1993-07-09 1995-01-19 Reckitt & Colman Inc. Low temperature non-caustic oven cleaning composition
US5380454A (en) * 1993-07-09 1995-01-10 Reckitt & Colman Inc. Low temperature non-caustic oven cleaning composition
US6150320A (en) * 1994-07-21 2000-11-21 3M Innovative Properties Company Concentrated cleaner compositions capable of viscosity increase upon dilution
US5569410A (en) * 1994-11-17 1996-10-29 Elf Atochem North America, Inc. Ammonium bicarbonate/ammonium carbamate activated benzyl alcohol paint stripper
US5744438A (en) * 1994-11-17 1998-04-28 Elf Atochem North America, Inc. Ammonium bicarbonate/ammonium carbamate activated benzyl alcohol paint stripper
US5650001A (en) * 1995-12-01 1997-07-22 Howell; Bradley Compositions and methods for treating compact discs
US20070117730A1 (en) * 1997-05-23 2007-05-24 Bowsman Shelba F Piston cleaning compositions
US5922665A (en) * 1997-05-28 1999-07-13 Minnesota Mining And Manufacturing Company Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal
US20030021887A1 (en) * 2001-03-08 2003-01-30 Shipley Company, L.L.C. Compositions containing heterocylcic nitrogen compounds and glycols for texturing resinous material and desmearing and removing resinous material
US6849589B2 (en) 2001-10-10 2005-02-01 3M Innovative Properties Company Cleaning composition
CN100575401C (zh) * 2003-09-05 2009-12-30 三星电机株式会社 棕色氧化物预处理组合物及改进聚酰亚胺表面粘合性的方法
US20110318494A1 (en) * 2010-06-25 2011-12-29 Donate Felipe Augusto Coalescent for aqueous compositions
EP2399960A3 (en) * 2010-06-25 2015-04-01 Dow Global Technologies LLC Coalescent for aqueous compositions
KR20210065630A (ko) * 2019-11-27 2021-06-04 애경산업(주) 의류용 액체 세제 조성물
WO2021222083A1 (en) * 2020-04-30 2021-11-04 Stepan Company Concentrated liquid esterquat compositions

Also Published As

Publication number Publication date
DE2300744B2 (de) 1981-07-30
CA989696A (en) 1976-05-25
JPS4880607A (enrdf_load_stackoverflow) 1973-10-29
IE37089B1 (en) 1977-04-27
GB1411032A (en) 1975-10-22
CH584752A5 (enrdf_load_stackoverflow) 1977-02-15
AT322701B (de) 1975-06-10
FR2331943A7 (fr) 1977-06-10
AU468520B2 (en) 1976-01-15
NL7300288A (enrdf_load_stackoverflow) 1973-07-12
DE2300744C3 (de) 1982-04-29
IE37089L (en) 1973-07-10
ZA73157B (en) 1973-09-26
JPS5747238B2 (enrdf_load_stackoverflow) 1982-10-07
AU5084773A (en) 1974-07-11
DE2300744A1 (de) 1973-07-19
BE793854A (fr) 1973-07-10

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