US3795510A - Valve components - Google Patents
Valve components Download PDFInfo
- Publication number
- US3795510A US3795510A US00777557A US3795510DA US3795510A US 3795510 A US3795510 A US 3795510A US 00777557 A US00777557 A US 00777557A US 3795510D A US3795510D A US 3795510DA US 3795510 A US3795510 A US 3795510A
- Authority
- US
- United States
- Prior art keywords
- alloys
- iron
- valve components
- titanium
- valve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052742 iron Inorganic materials 0.000 abstract description 8
- 150000002611 lead compounds Chemical class 0.000 abstract description 7
- 229910052759 nickel Inorganic materials 0.000 abstract description 7
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011651 chromium Substances 0.000 abstract description 5
- 239000010936 titanium Substances 0.000 abstract description 5
- 229910052719 titanium Inorganic materials 0.000 abstract description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052804 chromium Inorganic materials 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000005486 sulfidation Methods 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 description 19
- 239000000956 alloy Substances 0.000 description 19
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- 235000019687 Lamb Nutrition 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910001090 inconels X-750 Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229910002059 quaternary alloy Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/058—Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
Definitions
- FIG. 4 has been presented to demonstate that the iron content of the claimed alloys can be increased to about 14% without loss of resistance to lead compound attack. This is economically important as it enables the alloy to be fabricated from more economical alloys such as ferrochromium and ferro-titanium. Iron is, of course, per se the cheapest constituent of the alloy. ABSTRACT OF THE DISCLOSURE It is important that these alloys have the maximum.
- This invention relates to internal combustion engine possible amount of gamma prime dissolved in a gamma valve system components which are exposed to exhaust matrix at operating temperature; The amount of gamma gas and must be resistant to oxidation, sulfidation and prime should be at least twenty percent. The presence of the effects of lead compounds at high temperatures.
- a the titanium in this alloy permits this particular structure typical composition of such a component is chroto be obtained. mium, 5.5% aluminum, 2.5% titanium, 7.5% iron, 0.15%
- the following table is presented to illustrate the resistcarbon, remainder nickel. ance of a variety of alloys to attack by molten lead oxide.
- This invention is predicated upon the discovery that 20 certain quaternary alloys of nickel, chromium, aluminum and titanium possess a combination of qualities highly TABLE 11 desirable in internal combustion engine valve components Composition wt percent Ba1ance Ni which are exposed to exhaust gas and must be resistant to oxidation, sufidation and the efiects of lead compounds 5,235?) at high temperatures. Cr e Al Ti dc l s- Attention is invited to a scholarly thesis upon the 20 7,1 267 properties of this general type of alloys published in Journal of Metals, October 1956 at pages 1356 to 136 2 2 2 2 2 by A. Taylor.
- V270 a typical such alloy designated V270 has been compared in detail with four other commercially We claim as our invention: popular and available high temperature alloys, one an 1.
- valve system component consisting essentially of 20%
- the chemical composition of these alloys are given on the chromium, 5.5% aluminum, 2.5% titanium, 7.5 iron, following table. 0.15% carbon, remainder nickel.
- FIG. 2 is a comparable showing and relates to the stress required for rupture in 100 hours at 1600" F.
- the superior properties of the claimed alloys are clearly apparent insofar as creep rupture is concerned.
- FIG. 3 relates to the resistance of the alloys to attack by hot lead compounds and is reported in weight loss of a standard specimen in grams per dcm. per hour of expo- References Cited UNITED STATES PATENTS 2,515,185 7/1950 Bieber et al. -171 2,766,455 10/1956 Betteridge et al. 75-171 X 3,145,124 8/1964 Hignett et a1 148-162 3,147,155 9/1964 Lamb 148-162 X FOREIGN PATENTS 493,718 6/1953 Canada 75-171 CHARLES N. LOVELL, Primary Examiner U.S. Cl. X.R.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Lift Valve (AREA)
- Heat Treatment Of Steel (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77755768A | 1968-11-21 | 1968-11-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3795510A true US3795510A (en) | 1974-03-05 |
Family
ID=25110579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00777557A Expired - Lifetime US3795510A (en) | 1968-11-21 | 1968-11-21 | Valve components |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3795510A (enExample) |
| JP (1) | JPS5415248B1 (enExample) |
| DE (1) | DE1957823A1 (enExample) |
| GB (1) | GB1227730A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4741080A (en) * | 1987-02-20 | 1988-05-03 | Eaton Corporation | Process for providing valve members having varied microstructure |
| US4783966A (en) * | 1987-09-01 | 1988-11-15 | Aldrich Clare A | Multi-staged internal combustion engine |
| EP0639652A1 (en) * | 1993-07-27 | 1995-02-22 | Ngk Insulators, Ltd. | Ni-based alloys |
| USH1869H (en) * | 1998-12-18 | 2000-10-03 | Caterpillar Inc. | Valve train components having an oxidation and corrosion-resistant thermal spray coating |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2648145B1 (fr) * | 1989-06-08 | 1991-10-04 | Inst Francais Du Petrole | Utilisation d'alliages a base de nickel dans un procede de craquage thermique d'une charge petroliere et reacteur pour la mise en oeuvre du procede |
-
1968
- 1968-11-21 US US00777557A patent/US3795510A/en not_active Expired - Lifetime
-
1969
- 1969-09-25 GB GB1227730D patent/GB1227730A/en not_active Expired
- 1969-10-02 JP JP7818169A patent/JPS5415248B1/ja active Pending
- 1969-11-18 DE DE19691957823 patent/DE1957823A1/de active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4741080A (en) * | 1987-02-20 | 1988-05-03 | Eaton Corporation | Process for providing valve members having varied microstructure |
| US4783966A (en) * | 1987-09-01 | 1988-11-15 | Aldrich Clare A | Multi-staged internal combustion engine |
| EP0639652A1 (en) * | 1993-07-27 | 1995-02-22 | Ngk Insulators, Ltd. | Ni-based alloys |
| USH1869H (en) * | 1998-12-18 | 2000-10-03 | Caterpillar Inc. | Valve train components having an oxidation and corrosion-resistant thermal spray coating |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1957823A1 (de) | 1970-06-04 |
| JPS5415248B1 (enExample) | 1979-06-13 |
| GB1227730A (enExample) | 1971-04-07 |
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