US3793219A - Anionic liquid detergent composition - Google Patents
Anionic liquid detergent composition Download PDFInfo
- Publication number
- US3793219A US3793219A US00157728A US3793219DA US3793219A US 3793219 A US3793219 A US 3793219A US 00157728 A US00157728 A US 00157728A US 3793219D A US3793219D A US 3793219DA US 3793219 A US3793219 A US 3793219A
- Authority
- US
- United States
- Prior art keywords
- percent
- liquid detergent
- carbon atoms
- water
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract description 25
- 239000003599 detergent Substances 0.000 title abstract description 24
- 239000007788 liquid Substances 0.000 title abstract description 14
- 125000000129 anionic group Chemical group 0.000 title description 8
- 239000004094 surface-active agent Substances 0.000 abstract description 9
- 150000001768 cations Chemical class 0.000 abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 229910017053 inorganic salt Inorganic materials 0.000 abstract description 4
- -1 alkylbenzene sulfonate Chemical class 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000006260 foam Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000011734 sodium Substances 0.000 description 7
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 229940043237 diethanolamine Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 239000003752 hydrotrope Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- YHGREDQDBYVEOS-UHFFFAOYSA-N [acetyloxy-[2-(diacetyloxyamino)ethyl]amino] acetate Chemical compound CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O YHGREDQDBYVEOS-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- WZEMSIKSCALWJZ-UHFFFAOYSA-N azane;ethanol Chemical compound N.CCO.CCO WZEMSIKSCALWJZ-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-O bis(2-hydroxyethyl)azanium Chemical compound OCC[NH2+]CCO ZBCBWPMODOFKDW-UHFFFAOYSA-O 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 1
- 150000001940 cyclopentanes Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Definitions
- a transparent anionic liquid detergent composition comprising 5 to 30% by weight of an anionic surface active agent having S radical or SO, radical, to 45% by weight of a water-softening builder, 5 to 25% by weight of an alkaline inorganic salt, wherein more than 70% of the total amount of cations (in terms of the number of ions) in said three compounds is alkanol ammonium ion.
- the present invention relates to an anionic liquid detergent composition containing a water-softenig builder and an alkaline builder.
- nonionic liquid detergent development of various hydrotropes and stabilizers has been promoted, and there have so far been produced fairly stable detergents of this kind.
- the nonionic detergent is poor in foam producing power on account of properties of the nonionic surface active agent contained therein, thereby leading to a tendency to use it excessively on the part of the consumer.
- its high viscosity causes much adhesion of detergent onto a receptacle, etc., thereby making it inconvenient to handle and uneconomical. Such being the case, it has not yet been recognized as a completely acceptable detergent.
- the object of the present invention is to provide an anionic liquid detergent composition which is free from separation and change in quality even when preserved at a low temperature or a high temperature, not to mention at room temperature, and is capable of always maintaining a satisfactory transparency, low viscosity, high detergency and good foaming property.
- the detergent composition according to the present invention comprises 5 to 30 wt. percent preferably 15 to 25 wt. percent-of an anionic surfactant having 80;, radical or SO, radical, 5 to 45 wt. percentpreferably 15 to 30 wt. percent-of a water-softening builder, 5 to 25 wt. percentpreferably 7 to 15 wt. percentof an alkaline inorganic salt and is characterized by that or more-preferably 70 to percent-of the total amount of cations (in terms of the number of ions) in said three compounds is alkanol ammonium.
- the anionic surfactant applicable in the present inventio is one having S0 or SO, radical and includes preferably straight-chain alkylbenzene sulfonate (the alkyl radical having 10-20 carbon atoms), alkyl sulfate having 10 20 carbon atoms, a-olefin sulfonate having l020 carbon atoms, alkane sulfonate having 10-20 carbon atoms, and alkyl ether sulfate (the alkyl radical having 10-20 carbon atoms; an adduct with 2-5 mols of ethylene oxide), and more preferably straight-chain alkyl-benzene sulfonate (the alkyl radical ha-ving 10-14 carbon atoms).
- the alkanol amine preferable for use in the present invention includes diethanol amine and triethanol amine.
- the water-softening builder applicable in the present invention includes nitrilotriacetate (NTA), ethylene diamine tetraacetate (EDTA), salt of tetracarboxy cyclopentane, etc., and the alkaline inorganic salt suitable for use in the present invention includes carbonate, phosphate, b0- rate, etc.
- composition under the present invention can be also mixed with some nonionic surfactant as well as amphoteric active agent, and further mixed with such additives as the optical brightener, germicide, anti-redeposition agent, preventing agent for skin irritation, colorant, perfumer, foam booster, anti-foaming agent, etc.
- composition according to the present invention when compared with conventional powdery or granular detergents, proves to be equal or rather superior to them in detergency and has good stability in separation at higher and lower temperature, and also has high foam producing power.
- Example 7 Example Composition (percent) Comggliition 1(fpt21'celg) 2O Straight-chain alkylbenzene sulfonate Y 12) Ethylene-diamine tetracetate 20 0 2 ate 17 Tripolyphosphate 10 O e 5 Optical brightener 0.5 ptlcal bnghtener Ethanol 3 Ethfmol 7 Ratio of diethanolamine/Na 90/10 Pro 23?? methanolamme/Na 92/8 Properties: 8.
- Example 11 Composition (percent) Examp 1e 8 a-Olefin sulfonate '17 Composition (percent) gyrgphosphate 10 Straight-chain alkylbenzene sulfonate (alkyl: (mate. 7
- Viscosity o 1 140 Method of measurement: Collective judgment 0 1C b 1 need b water Stability at low temperature: Stability upon storage were a y at 10 C., for 100 hrs. The result was expressed Example 9 as follows: composition showing freezing or separation was marked with x; composition retaining uni- Composition (percent) form transparency was marked with o.
- Ethanol 5 Viscosity by T-type viscosimeter No. 2; 20 C.
- a transparent anionic liquid detergent composition consisting essentially of (A) 15 to 25 wt. percent of an anionic surface active agent selected from the group consisting of sulfonate and sulfate anionic surface active agents, (B) 15 to 30 wt. percent of water-softening builder selected from the group consisting of nitrilotriacetate, ethylene diamine tetraacetate and cyclopentane tetracarboxylate, (C) 7 to 15 wt.
- anionic surface active agent selected from the group consisting of sulfonate and sulfate anionic surface active agents
- B 15 to 30 wt. percent of water-softening builder selected from the group consisting of nitrilotriacetate, ethylene diamine tetraacetate and cyclopentane tetracarboxylate
- C 7 to 15 wt.
- water-soluble alkaline inorganic builder salt selected from the group consisting of carbonates, phosphates and borates, and the balance is water, wherein more than 70% of the total number of cations in said three compounds (A), (B) and (C) is alkanol ammonium ion selected from the group consisting of diethanol ammonium ion and triethanol ammonium ion.
- composition according to claim 1 wherin said surface active agent is selected from the group consisting of alkylbenzene sulfonate in which the alkyl radical has from 10 to 20 carbon atoms, alkyl sulfate having from 10 to 20 carbon atoms, a-olefin sulfonate having from 10 to 20 carbon atoms, alkane sulfonate having from 10 to 20 carbon atoms and alkyl ether sulfate containing from 2 to 5 mols of ethylene oxide and in which the alkyl has from 10 to 20 carbon atoms.
- composition according to claim 1 wherein 70 to 80% of the total number of cations is alkanol ammonium ion.
- a transparent temperature-stable liquid detergent composition consisting essentially of a three-component composition consisting of (A) to 25 wt. percent of a member of the group consisting of an (a) alkylbenzene sulfonate having 10 to carbon atoms in the alkyl chain,
- water-soluble inorganic builder salt selected from the group consisting of carbonates, phosphates and borates; and further, wherein 3 to 7 wt. percent is ethanol and the balance is water, the cations present are sodium and alkanol ammonium ions, at least molar percent of said cations being alkanol ammonium ions.
- composition of claim 4 wherein (A) is a straight-chain alkylbenzene sulfonate having 10 to 14 carbon atoms in the alkyl chain, and the alkanol ammonium ions constitute 70 to molar percent of said cations and are selected from the group consisting of diethanol ammonium and triethanol ammonium ions.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45057169A JPS496524B1 (enrdf_load_stackoverflow) | 1970-06-30 | 1970-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3793219A true US3793219A (en) | 1974-02-19 |
Family
ID=13048038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00157728A Expired - Lifetime US3793219A (en) | 1970-06-30 | 1971-06-28 | Anionic liquid detergent composition |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3793219A (enrdf_load_stackoverflow) |
| JP (1) | JPS496524B1 (enrdf_load_stackoverflow) |
| DE (1) | DE2128500A1 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4056113A (en) * | 1973-09-04 | 1977-11-01 | The Procter & Gamble Company | Liquid detergent compositions for removal of cooked-on food soils |
| US4107095A (en) * | 1973-04-11 | 1978-08-15 | Colgate-Palmolive Company | Liquid olefin sulfonate detergent compositions containing anti-gelling agents |
-
1970
- 1970-06-30 JP JP45057169A patent/JPS496524B1/ja active Pending
-
1971
- 1971-06-08 DE DE19712128500 patent/DE2128500A1/de active Pending
- 1971-06-28 US US00157728A patent/US3793219A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107095A (en) * | 1973-04-11 | 1978-08-15 | Colgate-Palmolive Company | Liquid olefin sulfonate detergent compositions containing anti-gelling agents |
| US4056113A (en) * | 1973-09-04 | 1977-11-01 | The Procter & Gamble Company | Liquid detergent compositions for removal of cooked-on food soils |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS496524B1 (enrdf_load_stackoverflow) | 1974-02-14 |
| DE2128500A1 (de) | 1972-01-05 |
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