US3772173A - Electroconductive paper - Google Patents
Electroconductive paper Download PDFInfo
- Publication number
- US3772173A US3772173A US00080549A US3772173DA US3772173A US 3772173 A US3772173 A US 3772173A US 00080549 A US00080549 A US 00080549A US 3772173D A US3772173D A US 3772173DA US 3772173 A US3772173 A US 3772173A
- Authority
- US
- United States
- Prior art keywords
- paper
- electroconductive
- potential
- support
- resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 claims abstract description 21
- 230000000694 effects Effects 0.000 claims description 8
- 230000015556 catabolic process Effects 0.000 abstract description 9
- 239000000758 substrate Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 description 8
- 238000013459 approach Methods 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- -1 polytetrachloroethylene Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/02—Sensitising, i.e. laying-down a uniform charge
Definitions
- This invention relates to a method of preparing electroconductive paper and more specifically to a process for producing paper adaptable for use in electrophotography, and in electrostatic and electroconductive recording.
- Ordinary paper which consists primarily of cellulose fibers, fillers such as clay, and hydrophobic sizing agents such as rosin, generally exhibits a relatively high electrical resistance.
- the value of this resistance generally varies considerably with ambient conditions, specifically the relative humidity of the atmosphere. However, in most instances the resistance value is considered too high to utilize the paper for electroconductive purposes.
- Electroconductive short circuit paths are made throughout the paper support by making pinholes at equal intervals on a sheet of paper and filling the resulting pin holes with a carbon paint.
- a further object of this invention is to provide an expedient, readily adaptable technique for converting an ordinarily prepared and available paper substrate for use where low electrical resistance is required.
- Still a further object of this invention is to pro vide a process for producing electroconductive paper adapted for use as an electrostatic and electroconductive recording material.
- Another object of this invention is to provide an electroconductive paper support having sufficiently high electroconductivity in the thickness direction.
- FIG. 1 represents a schematic drawing demonstrating a specific embodiment of the present invention.
- FIG. 2 is a schematic drawing representing an alternate process implementing the concept of the present invention.
- rollers 22 and 23 are driven by any suitable driving means in the direction indicated by the arrows 27 to transport the paper support 21 in the direction indicated by the arrow 26.
- the roller 22 is electrocon ductive and is generally made up of a metallic material such as aluminum, steel, copper or other similar material.
- the roller 23 is also composed of an electroconductive component such as is described above.
- a semi-conductive peripheral portion 24 comprising a semi-conductive material, such as semiconductive rubber, polystyrene, polytetrachloroethylene, polyvinylfluoride, polyethyleneterephthalate, and cellulose acetate is provided.
- a semi-conductive material such as semiconductive rubber, polystyrene, polytetrachloroethylene, polyvinylfluoride, polyethyleneterephthalate, and cellulose acetate.
- any suitable semi-conductive material having a resistivity of about 10 ohms-centimeter or greater is desired.
- a resistivity between about 10 to 10 ohms-centimeter is preferred to assure obtaining the desired effect.
- Power source 25 supplies the potential necessary to bring about the dielectric breakdown of the paper support which generally will be in the magnitude of from about I to 5 kilovolts.
- the high electrical potential is applied across the roller configuration to bring about local dielectric breakdown of the respective paper support material thereby producing the above discussed black dots.
- the presence of the semi-conductive material has been observed to prevent the lowering of potential during the formation of the selective black dots or the dielectric breakdown of the paper support material.
- the passing of the paper support through the rotating roller electrodes allows for the uniform production of the carbonized areas throughout the entire paper support.
- the high potential source 25 may supply either direct or alternating current.
- the amount of potential applied and final value of resistance obtained will be determined by the particular species of paper worked on and the translating speed at which the paper passes through the rollers.
- a paper support 31 is subjected to a high electric potential by a group of lever electrodes 33.
- the paper. support 31 is translated by means of a roller system (not shown) in the direction of arrow 38.
- the electrodes 33 are preferably provided in the transversal direction with respect to the paper support with spacing intervals between about 0.2 to 3 centimeters.
- the electrodes 33 are pressed against the paper support 31 by means of a flexible elctroconductive support means 34 which are in turn mounted on an insulating support 35 and connected to a high potential source 37 through a resistance 36.
- the circuit is completed by connecting power source 37 to a rear electrode 32 which, in combination with electrodes 33, holds the paper support in position and produces the desired effect.
- Dielectric breakdown caused by the applied electric potential to the paper support forms the characteristic black dots.
- the resistance element 36 present in the system are utilized as a control.
- the resistance values are increased when the potential supply from the electric source is high and conversely it is lowered when necessary such as when the potential applied is decreased or when the translating speed for the paper support is rapid.
- the potential of the power source 37 and the resistance values 36 will be determined appropriately according to the quality of the support paper being treated as well as the translating speed of the support paper since excessively high potential or excessively low resistance will result in the formation of a hole in the support.
- the potential is excessively low or resistance excessively high the effect desired from the discharge will not be realized or the density produced by thedischarge will be lowered to an undesirable level. Resistance levels ranging from about 10 to about 10 ohms-centimeter have produced satisfactory results.
- a method for preparing electroconductive paper adapted for use as an electrostatic and electroconduc' tive recording material comprising providing a paper substrate, and applying a potential of from 1-5 kv to said paper substrate in the form of an electrical discharge thereby bringing about a local dielectric breakdown and the formation of densely distributed microscopic carbonized electroconductive paths manifested in the form of black dots which penetrate through said paper in the thickness direction.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Paper (AREA)
- Electrostatic Charge, Transfer And Separation In Electrography (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP44097341A JPS4828697B1 (enrdf_load_stackoverflow) | 1969-12-04 | 1969-12-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3772173A true US3772173A (en) | 1973-11-13 |
Family
ID=14189761
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00080549A Expired - Lifetime US3772173A (en) | 1969-12-04 | 1970-10-14 | Electroconductive paper |
US93316A Expired - Lifetime US3689767A (en) | 1969-12-04 | 1970-11-27 | Method and apparatus for uniformly charging the surface of an insulating member |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US93316A Expired - Lifetime US3689767A (en) | 1969-12-04 | 1970-11-27 | Method and apparatus for uniformly charging the surface of an insulating member |
Country Status (3)
Country | Link |
---|---|
US (2) | US3772173A (enrdf_load_stackoverflow) |
JP (1) | JPS4828697B1 (enrdf_load_stackoverflow) |
CA (1) | CA925929A (enrdf_load_stackoverflow) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4028551A (en) * | 1975-10-17 | 1977-06-07 | Champion International Corporation | Apparatus and method for corona discharge priming a dielectric web |
US6007784A (en) * | 1997-07-11 | 1999-12-28 | 3Dt, Inc. | Electric discharge surface treating electrode and system |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4937541B1 (enrdf_load_stackoverflow) * | 1970-12-30 | 1974-10-09 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2453484A (en) * | 1946-05-31 | 1948-11-09 | Rca Corp | Electrolytic signal recording |
US2662803A (en) * | 1949-06-29 | 1953-12-15 | Faximile Inc | Recording method and apparatus |
US2707744A (en) * | 1953-08-05 | 1955-05-03 | Meaker John Wesley | Apparatus for perforating paper and other sheet materials |
US2977475A (en) * | 1958-04-30 | 1961-03-28 | Inst Textile De France | Method of and apparatus for processing textile fibre materials |
US3008888A (en) * | 1957-07-04 | 1961-11-14 | Fujimoto Shigenobu | Method for the production of processed papers |
US3285696A (en) * | 1960-08-25 | 1966-11-15 | Tokai Denkyoku Seizo Kabushiki | Method for the preparation of flexible carbon fibre |
US3399252A (en) * | 1966-04-15 | 1968-08-27 | Air Force Usa | Method and apparatus for manufacture of high strength and high modulus carbon filaments |
US3540848A (en) * | 1967-07-12 | 1970-11-17 | Hitco | Continuous process for preparing electrically conductive carbonaceous fibers |
US3553000A (en) * | 1969-07-01 | 1971-01-05 | Deering Milliken Res Corp | Process for durably setting a desired configuration in a cellulosic material |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL294832A (enrdf_load_stackoverflow) * | 1962-07-20 | |||
US3335322A (en) * | 1966-05-06 | 1967-08-08 | Borg Warner | Charge head array for electrostatic printing system |
-
1969
- 1969-12-04 JP JP44097341A patent/JPS4828697B1/ja active Pending
-
1970
- 1970-10-14 US US00080549A patent/US3772173A/en not_active Expired - Lifetime
- 1970-11-27 US US93316A patent/US3689767A/en not_active Expired - Lifetime
- 1970-12-03 CA CA099742A patent/CA925929A/en not_active Expired
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2453484A (en) * | 1946-05-31 | 1948-11-09 | Rca Corp | Electrolytic signal recording |
US2662803A (en) * | 1949-06-29 | 1953-12-15 | Faximile Inc | Recording method and apparatus |
US2707744A (en) * | 1953-08-05 | 1955-05-03 | Meaker John Wesley | Apparatus for perforating paper and other sheet materials |
US3008888A (en) * | 1957-07-04 | 1961-11-14 | Fujimoto Shigenobu | Method for the production of processed papers |
US2977475A (en) * | 1958-04-30 | 1961-03-28 | Inst Textile De France | Method of and apparatus for processing textile fibre materials |
US3285696A (en) * | 1960-08-25 | 1966-11-15 | Tokai Denkyoku Seizo Kabushiki | Method for the preparation of flexible carbon fibre |
US3399252A (en) * | 1966-04-15 | 1968-08-27 | Air Force Usa | Method and apparatus for manufacture of high strength and high modulus carbon filaments |
US3540848A (en) * | 1967-07-12 | 1970-11-17 | Hitco | Continuous process for preparing electrically conductive carbonaceous fibers |
US3553000A (en) * | 1969-07-01 | 1971-01-05 | Deering Milliken Res Corp | Process for durably setting a desired configuration in a cellulosic material |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4028551A (en) * | 1975-10-17 | 1977-06-07 | Champion International Corporation | Apparatus and method for corona discharge priming a dielectric web |
US6007784A (en) * | 1997-07-11 | 1999-12-28 | 3Dt, Inc. | Electric discharge surface treating electrode and system |
Also Published As
Publication number | Publication date |
---|---|
CA925929A (en) | 1973-05-08 |
US3689767A (en) | 1972-09-05 |
JPS4828697B1 (enrdf_load_stackoverflow) | 1973-09-04 |
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