US3764315A - Ambipolar electrophotographic plate - Google Patents

Ambipolar electrophotographic plate Download PDF

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US3764315A
US3764315A US00274141A US3764315DA US3764315A US 3764315 A US3764315 A US 3764315A US 00274141 A US00274141 A US 00274141A US 3764315D A US3764315D A US 3764315DA US 3764315 A US3764315 A US 3764315A
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binder
plate
ambipolar
active matrix
weight
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J Mort
I Chen
R Emerald
J Sharp
L Bean
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Xerox Corp
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Xerox Corp
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02—Charge-receiving layers
    • G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/08—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
    • G03G5/087—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic and being incorporated in an organic bonding material

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  • FIG. 3 POSITIVE CHARGING- NEGATIVE CHARGING ZTNF
  • An ambipolar, electrophotographic plate is disclosed of improved cyclic and discharge characteristics, having a photosensitive binder layer which comprises cadmium sulfoselenide particles, (Cd-S -Se dispersed in an ambipolar active matrix binder material in an amount of between about to by weight of said binder.
  • the cadmium sulfoselenide has a stoichiometric relationship of sulfur to selenium, where x is between about 0.1 to 0.6 and y is between about 0.9 to 0.4, to provide a pigment of panchromatic response, and the ambipolar active matrix binder material comprises a mixture of between about 6 to 14% by weight of 2,4,7 trinitro-9-fluorenone in polyvinylcarbazole, to support the injection and transport of photoexcited holes and electrons from the dispersed photosensitive particles through the active matrix binder upon imagewise exposure to radiation without substantial generation of charge carriers itself.
  • This invention relates to an improved ambipolar photoconductive insulating material which, when employed as the photoconductive layer for a xerographic plate and imaged, exhibits superior xerographic characteristics.
  • a xerographic plate comprising a layer of photoconductive insulating material on a conductive backing is given a uniform electric charge over its surface and is then exposed to a light and shadow image pattern of the subject matter, the original to be reproduced, usually by conventional projection techniques.
  • This exposure discharges the plate areas in accordance with the radiation intensity that reaches them and thereby creates an electrostatic latent image on or in the photoconductive layer corresponding to the light and shadow image pattern.
  • development of the latent image is effected by an electrostatically charged, finely divided material such as electroscopic powder, termed toner that is brought into surface contact with the photoconductive layer and is held thereon electrostatically in a pattern corresponding to the electrostatic latent image.
  • the developed toner image may be fixed or made permanent on the xerographic plate itself.
  • the developed image may be transferred from the xerographic plate to such a support surface to which it may be aflixed by any suitable means.
  • amorphous selenium is by far the most extensively used photoconductive insulating material in commercially available xerographic machines employing reusable xerographic plates, amorphous. selenium has certain characteristics which have prompted those skilled in the art to search for alternative materials. For example, amorphous selenium is sensitive only to radiation of wavelengths shorter than about 580 nanometers.
  • xerographic plates made with amorphous selenium are expensive to manufacture since the selenium itself is expensive and must be applied to the supporting substrate by vacuum evaporation under highly controlled temperature and other conditions, for example, as illustrated in Keck Patent 2,739,079.
  • amorphous selenium layers are only meta-stable because they are recrystallized into inoperative crystallized forms at temperatures only slightly in excess of those prevailing in conventional xerographic copy machines. Also, the surface of an amorphous selenium photoconductor layer is relatively soft and easily abraded which results in deterioration of the plate surface and subsequently, of image quality.
  • amorphous selenium photoconductors while producing line copy and other contrasting originals in an excellent fashion, have a relatively short dynamic range of about 0.6 density units when used in combination with conventional xerographic development processes, for example, cascade development.
  • amorphous selenium photoconductors are preferably imaged with positive charge in that such photoconductors have a longer charge transport range for holes and a shorter charge transport range for electrons. Accordingly, as set out herein, the photoconductors of the instant invention may be charged to either polarity, positive or negative, and still be useful in xerography. This desirable characteristic is termed ambipolarity.
  • zinc oxide pigment may comprise about one half (about 50%) of the layer by volume, the other half consisting of electrically insulating resin. This relatively high volume of pigment is required to insure that a series of unbroken chains of pigment particles are formed throughout the binder layer thickness to transport the charge carriers.
  • the photoconductive discharge characteristics change with cycling, and the plates exhibit residual conductivity patterns of previous images, as well as reduced charge acceptance levels.
  • An additional drawback to use of the zinc oxide type plates is that generally they can be sensitized only by negative and not by positive corona, because with this type of plate, the dark conductivity of positive charges is unacceptable.
  • a photoconductive member for xerographic applications which comprises a mixture of at least two photoconductive pigments capable of generating and injecting holes and electrons dispersed in an active matrix, charge transport binder material, capable of transporting either holes or electrons in response to imagewise radiation.
  • the active matrix binder material disclosed therein comprises very broadly a mixture of about 5 to 15%, preferably about by weight of 2,4,7 trinitro-9-fluorenone in polyvinyl carbazole, most broadly, the range of addition of the pigment mixture or total pigment content is between about 2 to 10 parts of pigment per 100 parts of binder by volume.
  • one of the pigments used in the binder layer in addition to selenium and phthalocyanine is cadmium sulfoselenide (Cd-S-Se) in a weight range of /2 to 5 parts per 100 parts of binder material.
  • CD-S-Se cadmium sulfoselenide
  • the present invention is an improvement over the above described unique photoconductive material and exhibits improved xerographic characteristics including high speed, recyclability and panchromatic response.
  • the instant invention comprises a photoconductive material utilizing these components within well defined critical limits to yield the above noted improved functional characteristics.
  • a novel photoconductive material comprising critically defined ranges of components to yield improved functional characteristics for xerography.
  • the components of the novel photoconductive material include an ambipolar active matrix binder material, capable of supporting the injection of holes or electrons and transporting the same under a broad range of operative conditions, consisting of a mixture of between about 6 to 14% by weight, preferably 8 to 12% by weight of 2,4,7 trinitro-9- fiuorenone in polyvinylcarbazole, and cadmium sulfoselenide (Cd-S -Se dispersed uniformly therein in an amount of between about 10 to 15% by weight of said binder, the cadmium sulfoselenide having a stoichiometric relationship of sulfur to selenium wherein x is between about 0.1 to 0.6 and y is between about 0.9 to 0.4.
  • the above defined critical ranges of components cooperate to yield an ambipolar photoconductive material and plate which is of faster, panchromatic response, and which is recyclable without a significant residual image pattern or sensitivity fatigue.
  • the former effect may also characterize a ghosting or retention of a residual latent or ghost image which corresponds to prior exposures of the plate and is a particular problem with extensive recycling of a photoconductive material.
  • the instant invention is free from ghosting with either polarity of charge and exhibits a wide range of operation, for line or continuous tone imaging.
  • Xerographic plates made with the improved photoconductive material set forth are easily fabricated because of a minimal number of components, the need for only a single layer of photoconductive material Without vacuum evaporation capabilities, and also because the photoconductive layer requires only a relatively low percentage of pigment loading with random distribution thereof, rather than precise or stringent geometric controls of the pigment particle loading.
  • the efiiciency of the photoconductive plate which permits a lower loading of photoconductive pigment is of course, related to the ability of the binder material to efficiently efiectively transport either holes or electrons without trapping thereof during imagewise exposure, and without significant functionality as an intrinsic photoconductive material because of a relatively small absorption of visible light thus contributing little to photogeneration of carriers.
  • FIG. 1 depicts the novel photosensitive member of the instant invention and its structure.
  • FIG. 2 illustrates the photoinduced discharge characteristics or speed of the photosensitive member of the instant invention as a function of the percentages of 2,4,7- trinitro-9-fiuorenone in the active matrix binder.
  • FIG. 3 depicts the initial charge acceptance of the photosensitive member of the instant invention as a function of the percentage of 2,4,7-trinitro-9-fiuorenone in the active matrix binder material.
  • FIGS. 4(a)(b), 5(a)(b) and 6(a) (b) illustrate the cycling properties of the photosensitive member of the instant invention as a function of the percentage of 2,4,7- trinitro-9-fluorenone in the binder material.
  • FIG. 7 depicts the charge acceptance properties of the photosensitive member of the instant invention as a function of the percentage of cadmium sulfoselenide in the binder material and as compared to similar prior art photosensitive members.
  • FIG. 8 illustrates the speed or discharge characteristics of the photosensitive member of the instant invention as fun tion of cadm um sulfoselen de in the b nder mate ial and as compared to similar prior art photosensitive members.
  • FIGS. 9(a) (b), 10(a) (b) and 11(a) (b) depict the cycling properties of the photosensitive member of the instant invention as a function of cadminum sulfoselenide in the binder material and as compared to similar prior are photosensitive members.
  • FIG. 12 graphically illustrates the dynamic range of the photosensitive member of the instant invention as compared to selenium.
  • FIG. 1 there is illustrated a xerographic plate comprising a layer of the novel photoconductive material of the instant invention 6 overlying electrically conductive layer 7.
  • the electrically conductive layer 7 is grounded during a charging step to facilitate application of a fairly uniform layer of charge on the layer of material 6.
  • Charging of the plate 5 can be accomplished in a variety of ways, including for example, the rubbing of layer 6 with soft brush or fur or preferably by corona charging techniques, as described in US. 'Patents 2,836,- 725 and 2,777,957.
  • the plate After charging by a corona charging technique or by the method of choice, the plate is exposed to a pattern of activating radiation in imagewise configuration to selectively discharge the applied charge from areas of the plate struck by the activating radiation, as compared to areas not struck by the activating radiation and thereby form an electrostatic latent image on layer 6.
  • the latent image is then made visible i.e. developed, by contacting the latent image with toner, generally electrostatically charged to a polarity opposite to the polarity of the electrostatic latent image, causing the material to be held thereon in the pattern corresponding to the latent image.
  • any suitable development system may be used to develop latent images on plates of this invention and many such systems exist in the art.
  • the system of cascade development has found extensive commercial acceptance and generally consists of gravitationally flowing developer material consisting of two component materials of the type disclosed in Walkup et al. Patent 2,638,- 416 over the xerographic plate bearing the latent image.
  • the two components consist of toner and a granular material called carrier and which by mixing acquire triboelectric charges of opposite polarities.
  • the toner component usually oppositely charged to the latent image is deposited on the latent electrostatic image to render that image visible.
  • Typical developing systems include for example, processes shown in Carlson Patents 2,221,776; 2,551,582; 2,690,394; 2,761,416; 2,928,575; Gundlach Patents 3,068,- 115 and 3,084,043; Mayo Patent 2,895,847; and others.
  • the powder image may then be transferred to another support surface 0t which it may be aflixed by solvent vapors, heat or other suitable means to render the image permanent or the powder image may be aflixed directly to the xerographic plate either as a result of developing or a separate step thereafter.
  • Layer 7 may be any suitable electrically conductive material, for example, most metals, and the present invention is not limited in this regard.
  • Aluminum has been extensively commercially used in an electrically conductive backing member in the preparation of xerographic plates.
  • suitable materials for this purpose include nickel, steel, brass, metallized tin oxide coated glass, plastics, semi-conductive plastic resins, paper or any other convenient material.
  • the rigid or flexible plate configuration as shown in FIG. 1 is for illustrative purposes only and the plate configuration may be extensively varied such as the form of a rigid or flexible drum configuration or the form of a flexible endless belt in loop of moebius strip form or any other suitable form.
  • the instant invention comprises an improved combination of components set forth within critically defined ranges to yield unexpected and surprising properties.
  • the components including an active matrix binder material capable of transporting both positive and negative charge carriers in response to actinic radiation in imagewise configuration, consisting of a mixture of between about 6 to 14% by weight preferably, 8 to 12% by weight of 2,4,7-trinitro-9-fluorenone in polyvinylcarbazole, and a finely divided cadmium sulfoselenide (Cd-S -Se photoconductive pigment uniformly dispersed in said active matrix in an amount of between about 10 to 15% by weight, the photoconductive mate rial being capable of generating and injecting holes and electrons into said active matrix binder, and having a stoichiometric relationship of sulfur to selenium wherein x is between about 0.1 and 0.6 and y is between about 0.9 to 0.4.
  • an active matrix binder material capable of transporting both positive and negative charge carriers in response to actinic radiation in imagewise configuration, consist
  • the use of a binder which is capable of transporting both types of charge carriers results in a highly recyclable plate, at either polarity, thus producing a plate with a broad operational range.
  • the components comprising the ambipolar active matrix binder of the instant invention include a critically defined mixture of between about 6 to 14% preferably 8 to 12% by weight of 2,4,7 trinitro-9-fluorenone which provides electron transport, in polyvinylcarbazole which itself will transport holes. It is this percentage range of 2,4,7 trinitro-9-fluorenone (TNF) which yields an active matrix of optimum ambipolarity without affecting speed or recyclability.
  • TNF 2,4,7 trinitro-9-fluorenone
  • the matrix functions to carry with maximum efficiency either polarity of charge, and without significant charge generation itself when exposed to a wide range of actinic radiation. Furthermore, within this range of TNF concentration the ambipolar matrix cooperates with the recited range of cadmium sulfoselenide (Cd-S -Se having the prescribed stiochiometric relationship of sulfur to selenium, wherein the composite photoconductor has good recyclability, with improved charge acceptance, and speed for either polarity of charge.
  • Cd-S -Se cadmium sulfoselenide
  • Cd-S Se the stoichiometric relation of the sulfur to selenium which is desired in the present invention, is where x is between about 0.1 and 0.6 and y is between about 0.9 to 0.4 and preferably where x is about 0.2 and y is about 0.8.
  • This stoichiometric relationship of sulfur to selenium provides a single photosensitive pigment, which has panchromatic response, thus when employed in an ambipolar active matrix binder material results in a photoconductive material of a wider operative spectral range. Furthermore, this particular stoichiometric relationship of sulfur to selenium also contributes to the speed of the photoconductive material when used in the described ambipolar active matrix binder material, since the described pigment, because of its panchromatic response, utilizes the white light from a constant light source much more effectively than a pigment or mixture of pigments having a narrow spectral range.
  • the particle size of the Cd-S -Se pigment as employed in the instant invention is not critical to its practice, although the particle size of the pigment should be less than the overall thickness of the photoconductive binder layer. In general, however, the preferred particle size for the pigment will be about 2 microns or less.
  • Th cadmium sulfoselenide pigment (Cd-S Se is added to the recited ambipolar mixture of polyvinylcarbazole and 6 to 14% by weight of 2,4,7 trinitro-9-fluorenone, in an amount of between about 10 to by weight of said mixture and uniformly dispersed therein.
  • the described mixture of polyvin'ylcarbazole and 2,4,7 trinitro-9-fluorenone is capable of efliciently supporting the injection and transport of charges of either polarity from the described photoconductive pigment through the mixture without significant generation of charge carriers itself.
  • This described percentage range of a single pigment further results in a photoconductive material of good mechanical and surficial properties, thus providing a highly functional and smooth photoconductive surface for latent image formation and development, with easy and efiicient removal of development material. If the percentage of the described photoconductive pigment is above the recited percentage range, not only are functional characteristics such as speed, and cyclic properties reduced, because of inefficient use of the active matrix binder material as a charge transport medium, but desirable mechanical properties such as stability and adhesion to the substrate are likewise diminished. On the other hand, if the percentage is below the recited range, a photoconductive binder material results of lower speed and cyclic properties than a binder material having the recited percentage of pigment.
  • the photoconductive binder material of the instant invention additionally yields a photosensitive member, with an extended dynamic range, especially as compared to amorphous selenium.
  • the extended dynamic range of the photosensitive member of the instant invention provides quality tone reproduction with a full latitude of contrast thus making the member eminently suitable for continuous tone imaging.
  • the dynamic range is graphically compared to amorphous selenium.
  • the dynamic range is drawn from the graphical representation by designation of the critical inflection points of the curves (E and E sometimes referred to as the shoulder (E and the toe (E thereof, then taking the log of this difference as a representation of the dynamic range.
  • curve A for amorphous selenium it may be seen that the dynamic range is approximately between .6 and .7 units, while if curve B for the photosensitive member of the instant invention is examined, it may be seen that the dynamic range of this member is about 1.5 units. It is therefore apparent from this comparison, that the member of the instant invention has a more dynamic range of operation than amorphous selenium and would be eminently suitable for continuous tone imaging.
  • the photoconductive binder material ofthe instant invention includes a com- 'bination of specific materials set forth within critically defined ranges to yield unexpected and surprising properties, including easy formulation in fabrication, relatively low pigment concentration having only random distribution, without stringent geometry controls being imposed, panchrom tic re pon e thr ugh variations in stoichiometry of the pigment, good speed, acceptable discharge characteristics with either polarity of charge, and improved cycling properties.
  • a 12% solution by weight of polyvinylcarbazole was prepared in a solvent solution comprising on a weight basis, toluene and 10% distilled cyclohexanone. This solution was then shaken for a period of about 6 hours, thus having a viscosity of about 750 centipoises. At this point, the desired weight percentage of 2,4,7 trinitro-9- fluorenone based on weight of PVK was added to the mixture and shaken for a further period of /2 hour.
  • the cadmium sulfoselenide pigment (Cd-S -Se was added to the mixture and shaken for an additional period of about 2 hours. After shaking is completed, the resultant dispersion was stirred to remove any entrapped air bubbles, at which time the solution was ready to be coated on a suitably prepared substrate.
  • a flexible substrate such as 6-mil thick ball grained aluminum plate or a 6-mil thick light brush grained, lithographic master plate was employed.
  • the substrate was first washed with acetone, wiped with lint free paper followed by heating to slightly above ambient temperature to remove residual solvent.
  • a Gardner doctor blade apparatus was used to provide a coating of the photoconductive material on the substrate which was found to vary between 20 to 25 microns in thickness.
  • the films were heated at about C. overnight to remove residual traces of solvents.
  • EXAMPLE 1 A series of seven plates were prepared as described above but with the percentage of 2,4,7 trinitro-9-fiuorenone being varied on a weight basis of the polyvinylcarbazole over a range of 2 to 20%, at 2, 5, 8, 10, 12, 15 and 20%. The percentage of cadmium sulfoselenide pigment Cd -Se was held constant at 12% by weight of the prepared binder material, with the thickness of the photoconductive layer being generally within the dimensions indicated above.
  • a single wire, grounded shield corotron charging device was employed with a high voltage power supply generating corona emission of the corotron wire, and all seven of the plates were charged to an approximately uniform surface potential (V at both positive and negative polarities.
  • each plate was exposed to a 1000- watt Xenon arc lamp through the entrance slit of a suitable monochromator having a quartz condensing lens, the light intensity of the system being in the order of 2x 10 photons/cm. sec. at 5400 A.
  • An electronic shutter is further provided to provide a timed exposure mode of operation, and each plate was illuminated for an equal period of time.
  • the initial change in voltage with respect to time was measured for each plate upon exposure to light and divided by the thickness of the photoconductive layer (d) to normalize the measured changes, making the discharge characteristics proportional to the quantum efliciency of the material.
  • An average reading of these normalized changes in voltage or (v) or for each polarity of charge are listed below for the varying percentages of 2,4,7 trinitro-9-fluorenone.
  • FIG. 3 the charge acceptance of plates containing the varying percentages of 2,4,7 trinitro- 9-fiuorenone are graphically depicted for either polarity of charge, the aim being to determine the optimum amount of charge acceptance equivalent for both positive and negative charging.
  • optimization of charge acceptance and equivalency for positive and negative charging occurs when the percent TNF is broadly between about 6 to 14%, although superior results occur when the percentage of TNF is between about 8 to 12% by weight, thus further illustrating the ambipolar characteristics of the active matrix binder of the instant invention which are maintained along with superior xerographic functional characteristics, such as charge acceptance.
  • EXAMPLE 3 To illustrate the optimum percentage of 2,4,7 trinitro- 9-fluorenone which is needed in the active matrix binder of the instant invention to provide ambipolarity as well 10 as desirable and improved cyclic properties, the seven plates described in Example 1 were subjected to a cycling evaluation for both positive and negative charging.
  • each plate was exposed to the source of illumination as described in Example 1, and was placed on a moving platen which had a velocity of about 3.5 cm./sec.
  • An elapsed time of about 18 seconds was used, in other words, from the first exposure to light until the second light exposure, a period elapsed of about 18 seconds.
  • FIGS. 4(a) (b), 5(a) (b) and 6(a) (b) the described measurements are graphically depicted for each percentage of 2,4,7 trinitro-9-fluorenone for each polarity or charge.
  • the y axis of the graph illustrates the surface voltage or potential of the plate and the x axis represents time.
  • the first, tenth and fiftieth cycle are graphically depicted. In those instances where no change in voltage over the measured period of time for up to 50 cycles has taken place, the first, tenth, and fiftieth cycles are superimposed as a single curve.
  • EXAMPLE 4 A series of six plates were then prepared in the recited procedure which proceeds Example 1 but with the percentage of 2,4,7 trinitro-9-fluorenone being held constant at 10% by weight of the polyvinylcarb-azole to yield an ambipolar active matrix material.
  • the percentage of cadmium sulfoselenide (Cd-S -Se was however, varied at concentrations of 2, 5, 8, 12, 15 and 20% by weight of the binder material with the thickness of the photoconductive layer for each plate being within the dimensions indicated above and having the respective optical densities listed below in the test data.
  • the described prior art plate comprises a mixture of about 10% by weight 2,4,7 trinitro-9-fluorenone in polyvinylcarbazole as the binder material, having dispersed therein as photoconductive pigments about 1% by weight of metal free phthalocyanine, which is prepared as shown in US. Pat. No. 3,357,989 to Byrne et al., 3% by weight amorphous selenium, and 5% by weight of cadmium sulfoselenide.
  • the photoconductive binder layer is prepared in a manner similar to that described in the procedure preceding Example 1 and as described in US. patent application, Ser. No. 94,072 to Bean and Gundlach and coated on an aluminum substrate.
  • FIG. 7 The results of this testing is graphically illustrated in FIG. 7 in which it may be seen that optimum charge acceptance occurs when the percentage of cadmium sulfoselenide is between about 10 and 15% by weight of said binder and specifically at 12% by weight. Likewise, referring to the prior art plate described above, the charge acceptance is much less at the same percentage of cadmium sulfoselenide and significantly less at the recited range of cadmium sulfoselenide of the instant invention. The improved charge acceptance properties of the plates of the instant invention over the prior art materials is therefore appropriately illustrated in FIG. 7.
  • EXAMPLE 5 The six plates referred to in Example 4 having a varying percentage of cadmium sulfoselenide in addition to the prior art plate described in Example 4, were then evaluated for photodischarge characteristics or speed as set forth in Example 1 for both polarities of charge. The measured initial normalized for layer thickness is expressed below for each plate along with its appropriate optical absorption.
  • FIG. 8 in which the above average readings are graphically depicted, it may be seen that optimum speed or discharge results when the percentage of cadmium sulfoselenide is within 10 to 15% by weight of the active matrix binder material for both polarities of charge. Furthermore, as to the prior art plate, it may be seen that a dramatic improvement in speed results even at the same percentage of cadmium sulfoselenide as the prior art plate, and that an even more significant result is achieved when the cadmium sulfoselenide is present in an amount of between about 10 to 15% by weight of said binder.
  • EXAMPLE 6 The six plates referred to in Example 4 having the varying percentage of cadmium sulfoselenide, as well as the prior art plate also described in Example 4 are then evaluated for their cyclic properties for both polarities of charge in a manner similar to that described in Example 3.
  • FIGS. 9(a) (b), 10(a) (b) and 11(a) (b) the results of the cycling testing is. graphically depicted in a manner similar to that which has been previously described in reference to Example 3. It is apparent from the depicted data that the optimum stability and sensitivity when the described plates are used in a cyclic mode, occurs when the percentage of cadmium sulfoselenide is between about 10 to 15%, particularly at 12%. Likewise, with reference to the prior art plate, it may be seen that while the first cycle shows good sensitivity, that as the number of cycles increases, the effect of this repetitive use on sensitivity is illustrated as a reduction in stability of the plate when recycled.
  • An ambipolar electrophotographic plate having a photosensitive binder layer comprising photosensitive particles dispersed in an electronically active organic matrix binder in an amount of from about 10 to 15% by weight of said binder, said photosensitive particles consisting essentially of Cd-S -Se wherein x is between about 0.1 to 0.6 and y is between about 0.9 to 0.4, said active matrix binder consisting essentially of a mixture of between about 6 to 14% by Weight 2,4,7 trinitro-9- fluorenone in polyvinylcarbazole, said active binder being capable of supporting the injection of photo-excited holes and electrons from said photosensitive particles and transporting them through said active matrix material.
  • An ambipolar electrophotographic plate as set forth in claim 1 wherien said photosensitive particles consist essentially of Cd-S -Se wherein x is about 0.2 and y is 0.8.
  • An ambipolar electrophotographic plate having a photosensitive binder layer compirsing photosensitive particles dispersed in an electronically active organic matrix binder in an amount of about 12% by weight of said binder, said photosensitive particles consisting essentially of Cd-S 'Se wherein x is between about 0.1 to 0.6 and y is between about 0.9 and 0.4, said active matrix binder consisting essentially of a mixture of between about 8 to 12% by weight of 2,4,7 trinitro-9-fluorenone in polyvinylcarbazole, said active binder being capable of supporting the injection of photo-excited holes and electrons from said photosensitive particles and transporting them through said active matrix material.
  • a method of imaging which comprises:
  • a xerographic plate having a photosensitive binder layer comprising photosensitive particles dispersed in an electronically active organic matrix binder in an amount of from about 10 to 15% by weight of said binder, said photosensitive particles consisting essentially of Cd-S -Se wherein x is between about 0.1 to 0.6 and y is between about 0.9 and 0.4, said active matrix binder consisting essentially of between about 6 to 14% by weight 2,4,7 trinitro-9-fiuorenone in polyvinylcarbazole, said active binder being capable of supporting the injection of photo-excited holes and electrons from said photosensitive particles and transporting them through said active matrix material;
  • said active matrix binder consists essentially of a mixture of between about 8 to 12% by weight of 2,4,7 trinitro-9-fluorenone in polyvinylcarbazole.
  • said active matrix binder consists essentially of a mixture of about 10% by weight of 2,4,7 trinitro-9-fiuorenone in polyvinylcarbazole.
  • said photosensitive particles consist essentially of Cd-S -Se wherein x is 0.2 and y is 0.8.

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3879201A (en) * 1972-12-18 1975-04-22 Xerox Corp Persistent photoconductive compositions
US3909261A (en) * 1970-09-25 1975-09-30 Xerox Corp Xerographic imaging member having photoconductive material in interlocking continuous paths
US3961954A (en) * 1972-12-27 1976-06-08 Xerox Corporation Acid sensitized charge transfer complexes and cyclic electrostatographic imaging
US3982938A (en) * 1973-02-13 1976-09-28 Fuji Photo Film Co., Ltd. Photoconductive toners which include photoconductive pigment particles in a charge-transporting insulating binder
US4052209A (en) * 1975-03-07 1977-10-04 Minnesota Mining And Manufacturing Company Semiconductive and sensitized photoconductive compositions
US4097277A (en) * 1973-01-31 1978-06-27 Canon Kabushiki Kaisha Photosensitive member having layer of vinyl carbazole polymer containing antimony chalcogen compound of antimony and sulfur
US4106934A (en) * 1976-06-14 1978-08-15 Eastman Kodak Company Photoconductive compositions and elements with charge transfer complexes
US4820846A (en) * 1982-07-29 1989-04-11 Minnesota Mining And Manufacturing Company Triarylmethane compounds, their preparation and use as photoconductive systems
US5336577A (en) * 1991-12-30 1994-08-09 Xerox Corporation Single layer photoreceptor
WO2015112158A1 (en) * 2014-01-24 2015-07-30 Brother International Corporation Quantum dot photoconductor for an electrophotographic printer

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4527886A (en) * 1981-05-12 1985-07-09 Kyoto Ceramic Co., Ltd. Electrophotographic recording apparatus having both functions of copying and printing

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA971796A (en) * 1970-12-01 1975-07-29 Robert W. Gundlach Xerographic binder plate

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3909261A (en) * 1970-09-25 1975-09-30 Xerox Corp Xerographic imaging member having photoconductive material in interlocking continuous paths
US3879201A (en) * 1972-12-18 1975-04-22 Xerox Corp Persistent photoconductive compositions
US3961954A (en) * 1972-12-27 1976-06-08 Xerox Corporation Acid sensitized charge transfer complexes and cyclic electrostatographic imaging
US4097277A (en) * 1973-01-31 1978-06-27 Canon Kabushiki Kaisha Photosensitive member having layer of vinyl carbazole polymer containing antimony chalcogen compound of antimony and sulfur
US3982938A (en) * 1973-02-13 1976-09-28 Fuji Photo Film Co., Ltd. Photoconductive toners which include photoconductive pigment particles in a charge-transporting insulating binder
US4052209A (en) * 1975-03-07 1977-10-04 Minnesota Mining And Manufacturing Company Semiconductive and sensitized photoconductive compositions
US4106934A (en) * 1976-06-14 1978-08-15 Eastman Kodak Company Photoconductive compositions and elements with charge transfer complexes
US4820846A (en) * 1982-07-29 1989-04-11 Minnesota Mining And Manufacturing Company Triarylmethane compounds, their preparation and use as photoconductive systems
US5336577A (en) * 1991-12-30 1994-08-09 Xerox Corporation Single layer photoreceptor
WO2015112158A1 (en) * 2014-01-24 2015-07-30 Brother International Corporation Quantum dot photoconductor for an electrophotographic printer

Also Published As

Publication number Publication date
JPS5238416B2 (en, 2012) 1977-09-29
FR2193997A1 (en, 2012) 1974-02-22
DE2316897A1 (de) 1974-02-07
IT993592B (it) 1975-09-30
CA995046A (en) 1976-08-17
FR2193997B1 (en, 2012) 1978-05-26
BR7304591D0 (pt) 1974-09-05
ES417020A1 (es) 1976-06-16
JPS4993020A (en, 2012) 1974-09-04
DE2316897B2 (de) 1977-09-15
NL7310021A (en, 2012) 1973-09-25
DE2316897C3 (de) 1978-05-03
BE802608A (fr) 1973-11-16
GB1421948A (en) 1976-01-21

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