US3749578A - Image-receiving material for use in silver salt diffusion transfer photography - Google Patents
Image-receiving material for use in silver salt diffusion transfer photography Download PDFInfo
- Publication number
- US3749578A US3749578A US00178391A US3749578DA US3749578A US 3749578 A US3749578 A US 3749578A US 00178391 A US00178391 A US 00178391A US 3749578D A US3749578D A US 3749578DA US 3749578 A US3749578 A US 3749578A
- Authority
- US
- United States
- Prior art keywords
- image
- receiving
- receiving material
- hydroxyethyl
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract description 40
- 238000009792 diffusion process Methods 0.000 title description 11
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 title description 9
- -1 AMINE COMPOUND Chemical class 0.000 abstract description 18
- 150000001875 compounds Chemical class 0.000 abstract description 18
- 150000001412 amines Chemical class 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 36
- 229910052709 silver Inorganic materials 0.000 description 14
- 239000004332 silver Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000000523 sample Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 4
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 4
- 229930182490 saponin Natural products 0.000 description 4
- 150000007949 saponins Chemical class 0.000 description 4
- 125000000547 substituted alkyl group Chemical group 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 229910001864 baryta Inorganic materials 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 229920001747 Cellulose diacetate Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 101000795130 Homo sapiens Trehalase Proteins 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 102100029677 Trehalase Human genes 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 1
- AUIZLSZEDUYGDE-UHFFFAOYSA-L cadmium(2+);diacetate;dihydrate Chemical compound O.O.[Cd+2].CC([O-])=O.CC([O-])=O AUIZLSZEDUYGDE-UHFFFAOYSA-L 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229940031575 hydroxyethyl urea Drugs 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical compound NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229940116357 potassium thiocyanate Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulphite Substances [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- JGPSMWXKRPZZRG-UHFFFAOYSA-N zinc;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O JGPSMWXKRPZZRG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
- G03C8/06—Silver salt diffusion transfer
Definitions
- the amine compound serves to enhance the activity of a development nucleus contained in the receiving layer.
- This invention relates to an image-receiving material for use in a silver salt diffusion transfer photographic process.
- the photographic material is brought into contact with a processing liquid containing a solvent for the silver halide, such as sodium thiosulfate or potassium thiocyanate, whereupon the unexposed silver halide reacts with the solvent for the silver halide to form a water-soluble silver complex compound.
- a processing liquid containing a solvent for the silver halide such as sodium thiosulfate or potassium thiocyanate
- the unexposed silver halide reacts with the solvent for the silver halide to form a water-soluble silver complex compound.
- a receiving material that has a receiving layer comprising a catalyst (physical development nucleus) for the reduction of the water-soluble silver complex compound dispersed in the hydrophilic binder is brought into intimate contact with the photosensitive layer, the silver complex compound formed in the photosensitive layer diffuses together with the processing liquid containing the solvent for silver halide, and moves from the photosensitive layer to the receiving layer where it is reduced to silver by the action of the development nucleus.
- the development nuclei usually used in the silver salt diffusion transfer photographic process include, for example, sparingly water-soluble metal sulfides, metal selenides, or colloidal heavy metals or noble metals. Such a substance is dispersed in a polymeric material, such as gelatin or polyvinyl alcohol, which allows an alkaline liquid to penetrate, and the resulting dispersion is coated on a support such as paper, film or a metal plate to produce an image-receiving material.
- the development nucleus of the receiving material should have a high activity and receiving materials utilizing a highly active development nuclei can be used favorably as high speed diffusion transfer photographic materials.
- 2,698,237 discloses that when a water-soluble metal salt is mixed with a water-soluble sulfide in finely divided silicon dioxide, the precipitate of a water-soluble metal sulfide is obtained and this product has a very high activity as a development nucleus.
- This known development nucleus however, has the defect that during the storage of the receiving material it gradually loses its activity.
- an object of the present invention is to provide an image-receiving material in which the activity of a development nucleus contained therein is markedly enhanced and in which the enhanced activity hardly decreases during storage for long periods of time.
- the present invention provides an image-receiving material for use in a silver salt diffusion transfer photographic process which contains a compound of the following general formula in at least one of either its receiving layer or an adjacent layer:
- n is an integer of l to 5
- each of R and R is a member selected from the group consisting of a hydrogen atom, an alkyl group having not more than 5 carbon atoms, a substituted alkyl group having not more than 5 carbon atoms in which at least one of the hydrogen atoms is substituted with a hydroxyl group or a halogen atom, a substituted alkyl group having not more than 5 carbon atoms in which at least one of the hydrogen atoms is substituted with an amino group,
- -C(NH ) NH group, an acyl group and an allyl group, or R and R are bonded directly or through another atom to form a hetero ring together with the nitrogen atom.
- the above-described substance is incorporated in at least one of a receiving layer or an adjacent layer of the image-receiving material used in the silver salt diffusion transfer photographic process.
- the receiving material is composed of a support, a receiving layer provided thereon, and an adjacent layer including a sub layer for increasing the adhesion of the receiving layer to the support and a stripping layer (provided for rendering both the photographic material and the receiving layer separable from each other after the diffusion transfer treatment) or a protective layer (provided for preventing scratch injury or contamination of the image surface).
- Each of these layers contains as a binder a hydrophilic film-forming polymeric material such as gelatin, polyvinyl alcohol or polyvinyl pyrrolidone.
- the support which can be, for example, cellulose diacetate film, cellulose triacetate film, polystyrene paper, polyethylene laminate paper or baryta-coated paper.
- the above-mentioned compound aifects the action of the development nucleus.
- the amount of the compound to be incorporated in the receiving layer or adjacent layer is 1 to 200 moles por mole of the development nucleus, and best results are obtained when the amount is 10 to 100 moles per mole of the development nucleus.
- the compound is generally added to a solution or dispersion of the compound which forms the receiving layer or the adjacent layer at any stage until the coating of the solution. If desired, a solution of the compound may be applied before or after the coating of the receiving layer or the adjacent layer, so that the compound is caused to penetrate into the layer. In short, the requirement is that the compound is finally present in the a receiving layer or the adjacent layer.
- COMPARATIVE EXAMPLE Preparation of comparative sample Solution A of the following mixture was coated on the surface of baryta paper at the coating Weight of 25 cc./m.
- Aqueous solution of sodium sulfide (3% hy weight) o... 9.5
- Aqueous solution of saponin (6% by weight) cc 20
- the coating was dried, and on top of it, Solution B of the following mixture was coated, followed by drying.
- Solution B Distilled water or 1,000 Sodium salt of carboxymethyl cellulose -g 10 Aqueous solution of saponin (6% by weight) "cc-.. 20
- the resultant receiving material was used as a comparative sample.
- Sample 1 A receiving material (Sample 1) was prepared by the same procedure as set forth in the Comparative Example except that a solution of the following formulation was used instead of Solution A.
- the degree of forcible deterioration can be estimated by 1O0AD/D where AD is a difference between D which is the maximum density of the transfer image formed on the non-deteriorated sample, and D which is the maximum density of the transfer image of the forcibly deteriorated sample.
- the amine compound used in the present invention serves to prevent the processing composition from remaining attached to the surface of the receiving material when the receiving material was separated from the photosensitive material after the diffusion transfer process.
- An image-receiving material for use in the diffusion transfer process comprising a development nucleus material and an amine compound of the following general formula in at least one of either its receiving layer or an adjacent layer:
- n is an integer of 1 to 5
- An image-receiving material of claim 2 wherein the amount of the amine compound is 10 to 100 moles per mole of the development nucleus material.
- an image-receiving material of claim 1 wherein the amine compound is selected from the group consisting of fi-hydroxyethylamine, N-methyl-B-hydroxyethylamine, N,N-dimethyl-fl-hydroxyethylamine, N-ethyl-fl-hydroxyethylamine, N,N-diethyl-fi-hydroxyethylamine, N-methyl-N-ethyl-p-hydroxyethylamine, 'N-n-pentyl-B-hydroxyethylamine,
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45078373A JPS4913577B1 (enrdf_load_stackoverflow) | 1970-09-07 | 1970-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3749578A true US3749578A (en) | 1973-07-31 |
Family
ID=13660195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00178391A Expired - Lifetime US3749578A (en) | 1970-09-07 | 1971-09-07 | Image-receiving material for use in silver salt diffusion transfer photography |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3749578A (enrdf_load_stackoverflow) |
| JP (1) | JPS4913577B1 (enrdf_load_stackoverflow) |
| DE (1) | DE2144759C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2103383A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1338466A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3960569A (en) * | 1973-11-20 | 1976-06-01 | Fuji Photo Film Co., Ltd. | Diffusion transfer color film unit with hydroxy substituted alkylene amino development accelerators |
| US3963495A (en) * | 1973-03-20 | 1976-06-15 | Fuji Photo Film Co., Ltd. | Image-receiving element for silver salt diffusion transfer with layer of monoacrylates or monomethacrylates of polyhydric alcohols |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6262216B1 (en) | 1998-10-13 | 2001-07-17 | Affymetrix, Inc. | Functionalized silicon compounds and methods for their synthesis and use |
-
1970
- 1970-09-07 JP JP45078373A patent/JPS4913577B1/ja active Pending
-
1971
- 1971-08-31 FR FR7131445A patent/FR2103383A5/fr not_active Expired
- 1971-09-07 DE DE2144759A patent/DE2144759C3/de not_active Expired
- 1971-09-07 GB GB4173671A patent/GB1338466A/en not_active Expired
- 1971-09-07 US US00178391A patent/US3749578A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3963495A (en) * | 1973-03-20 | 1976-06-15 | Fuji Photo Film Co., Ltd. | Image-receiving element for silver salt diffusion transfer with layer of monoacrylates or monomethacrylates of polyhydric alcohols |
| US3960569A (en) * | 1973-11-20 | 1976-06-01 | Fuji Photo Film Co., Ltd. | Diffusion transfer color film unit with hydroxy substituted alkylene amino development accelerators |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2144759A1 (de) | 1972-03-16 |
| DE2144759C3 (de) | 1980-07-17 |
| GB1338466A (en) | 1973-11-21 |
| JPS4913577B1 (enrdf_load_stackoverflow) | 1974-04-01 |
| DE2144759B2 (de) | 1979-10-04 |
| FR2103383A5 (enrdf_load_stackoverflow) | 1972-04-07 |
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