US3741716A - Heater for use in the manufacture of plastics filaments - Google Patents
Heater for use in the manufacture of plastics filaments Download PDFInfo
- Publication number
- US3741716A US3741716A US00238846A US3741716DA US3741716A US 3741716 A US3741716 A US 3741716A US 00238846 A US00238846 A US 00238846A US 3741716D A US3741716D A US 3741716DA US 3741716 A US3741716 A US 3741716A
- Authority
- US
- United States
- Prior art keywords
- heater
- internal surface
- filaments
- portions
- spun
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/084—Heating filaments, threads or the like, leaving the spinnerettes
Definitions
- the present invention relates to a heater for use in the manufacture of macromolecular plastics filaments having a low degree of pre-orientation for the production of high strength threads.
- High strength threads can only be produced when the material spun to make the threads is drawn to a very high degree. A high degree of drawing can only be obtained, however, with material which, when spun, has a low pre-orientation.
- the spinning process has to be carried out in such a manner that the spun filaments should have as low a preorientation as possible.
- a further problem arises in achieving the necessary uniformity, because the filaments can only be drawn to a high degree when, in the spinning process, each of the many capillaries has been uniformly treated. irregularities which may, for example, occur by unsuitable cooling cannot be remedied by further processing and detrimentally affect the quality of the finished thread.
- British Pat. No. 580,832 describes a process and a device for heating freshly spun filaments produced by the dry spinning process.
- the spun filament is drawn off in a direction parallel to the axis of a tube having a vertical axis and heated by means of horizontal radiation.
- the tube is ellitical in cross section and the inner wall of the tube has good reflecting properties.
- the source of heat radiation is situated at one principal focus of the ellipse while the filament is at the other principal focus.
- French Pat. No. 1,347,986 provides a process according to which the freshly spun polyester or polyamide filaments pass through a cylindrical heated tube the gas temperature around the filaments being determined according to the following condition T gas temperature directly on the spinneret in C with 270 C s T 700 C T gas temperature in C at distance L vertically below the spinneret T temperature of spinneret in C D distance from the spinneret in meters V draw-off speed of the spun filaments in m/sec After having left the cylinder the filaments are rapidly cooled by a horizontal air current. Subsequently,
- the invention provides a heater for use in the manufacture of spun plastics filaments which comprises two portions each of which has a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the perimeters of the larger ends of the'internal surfaces being congruent and the two portions meeting at their larger ends with the perimeters of the larger ends of the internal surfaces in register with one another, wherein the internal surface of one of the portions is heated and the internal surface of the other portion is thermally reflective.
- each of the said portions is, preferably, a truncated right conical surface.
- FIG. 1 is a perspective view of the heater
- FIG. 2 is an axial cross-section of the heater shown in FIG. 1;
- FIG. 3 illustrates the variation in temperature along the axis of the heater.
- a heater comprises two parts 1 and 2, each of which has the shape of a hollow truncated cone, which are attached to each other at their larger circular openings.
- the lower part 2 is heated while the inside wall of the upper part 1 reflects the heat emitted by the lower part.
- part 1 has the function of a reflector while part 2 has the function of a radiator.
- the lower opening 3 of the heater is protected by an annular screen 4 preventing air blown onto filaments after they have left the heater entering the space below the spinneret and disturbing the course of the capillaries while they are still plastic.
- the diameter d, of the opening in the screen is larger by only 5 to 30 millimeters than the diameter dp of a bundle of capillaries, that is to say,
- the diameter d, of the upper opening of upper part 1 is larger than the diameter of the bundle of capillaries.
- the height L of the radiator is in the range of from 1.0 to 2.5 times the diameter d, of the opening of the upper part. That is to say:
- the cross sectional area of flow should be as large as possible so that the compensation of air can take place at a low speed.
- the largest cross sectional area of the heater should be at least twice the cross sectional area of the bundle of capillaries, that is to say,
- the side line H of the heated part 2 of the heater and the cone angle 4) should be chosen in such a manner that the said perpendicular 5 drawn on the wall of part 2 points to the opposite wall of part I; and arcsin H/2d, l2 arcsin (H/Z s/(d, +d /2 L,) arccot d,+d /2 L
- the biconical shape of the heating radiator allows concentric thermal radiation. The reason why this shape was chosen is that only a minor part of the thermal rays hits the spinneret while the major part is reflected by the conical reflector into the space below the spinneret.
- the reflector I is, therefore, provided with a highly polished surface or coated with a reflecting foil.
- the heating elements of radiator 2 preferably consist of ceramic plates with inserted heating spirals.
- the device according to the invention can be used in melt spinning, preferably spinning of high molecular weight polyesters, more preferably polyethylene terephthalate, and copolyesters, the acid components of which preponderantly consist of terephthalic acid.
- spun filaments of a very low degree of pre-orientation can be obtained, which permit the production of high strength threads. It is likewise possible to increase the throughput of molten polyester since the higher pre-orientation resulting from a higher draw-off speed of the spun filaments can be compensated for in the heater.
- the device according to the invention is also suitable for the continuous spin drawing of filaments from highly viscous material.
- the short biconical heating radiator With the aid of the short biconical heating radiator according to the invention a narrow temperature variation with respect to time and space as indicated in FIG. 3 can be obtained below the spinneret in the solidification zone of the filaments, whereby the solidification is very favourably influenced.
- the temperature is within the indicated limits ll0- 1.7 X 10 l BIL-0.4 T T,, 2 X10 (D/L 0.5)
- the spun filaments produced in this manner have a double refraction DR of (1.6 2.0). 10', measured according to the compensation method of Ehringhous with quartz or calcite compensators. The DR value is calcu-' lated from the ratio of the path difference and the capillary diameter.
- the filaments had a very good uniformity over their length.
- U the average linear deviation of the titer T from the means titer value T:
- the titer T is measured as a function of the filament length l.
- L is the total filament length measured.
- the mean titer value is With the use of the heating radiator according to the invention filaments were produced having a titer nonuniformity U of 0.8%. The spun filaments did not stick together.
- the spun filaments obtained in this manner could be drawn in a ratio of l 6.5, their strength then being 82 g/tex.
- a heater according to the invention was used in the spinning process of high strength filaments from a material having an intrinsic viscosity of 0.73. In this case it can be used either for reducing the molecule orientation with the same draw-off speed of the spun filaments or for maintaining the degree of molecule orientation with an increased draw-off speed.
- the present example is intended to illustrate the former possibility.
- the positions of the heater and spinning chamber were the same as in Example 1.
- a heater for use in the manufacture of spun plastics filaments which comprises two portions each of which has a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the perimeters of the larger ends of the internal surfaces being congruent and the two portions meeting at their larger ends with the perimeters of the larger ends of the internal surfaces in register with one another, wherein the internal surface of one of the portions is heated and the internal surface of the other portion is thermally reflective.
- a heater as claimed in claim 1 wherein there is provided at the smaller end of the said one portion a screen arranged to reduce the effective area of the said smaller opening.
- a heater as claimed in claim I wherein the internal surface of each of the said portions is a truncated right conical surface.
- L is the total height of the heater
- d is the largest diameter of the heater taken at right angles to the axis
- d is the diameter of the smaller opening in the said other portion.
- a heater as claimed in claim I wherein the internal surface of the said other portion is highly polished or coated with a reflective foil.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
A heater for use in the manufacture of spun plastics filaments which comprises two portions each having a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the internal surface of one of the portions is heated while the internal surface of the other portion is thermally reflective and at the smaller end of the heated portion a screen is arranged to reduce the effective area of the said smaller opening. With the use of the heater spun filaments can be produced having a low degree of preorientation and a satisfactory uniformity.
Description
United States Patent 1191 Jolme et a1.
[ June 26, 1973 HEATER FOR USE IN THE MANUFACTURE 3,174,537 3/1965 Meyer 165/133 x 0 PLASTICS FILAMENTS 3,285,333 11/1966 Johnson, Jr 165/133 [75] inventors: Rudolf Johue, Haunstetten; Max
Bechter, Bobmgen, both of Germany Primary Examiner John L Camby [73] Assignee: Farbwerke Hoechst Attorney-Arthur G. Connolly, Jacob C. Kellen,
Aktiengesellschalt vormais Meister Rudolf E. Hutz et a1. Lucius & Brunlng, Frankfurt/Main, Germany 221 Filed: Mar. 28, 1972 [571 ABSTRACT Appl' 238846 A heater for use in the manufacture of spun plastics filaments which comprises two portions each having a [30] Foreign Application Priority Data truncated right polygonal pyramidal or truncated right Mar, 30, 1971 Germany p 21 5 3 23 conical internal surface that is open ended, the internal surface of one of the portions is heated while the inter- 52 U.S. c1. 432/59 nal surface of the other Portion is themally reflective 51 m. (:1 F271: 9/28 n at the smaller end of the heated Portion a screen [58] Field of Search 432/8, 59,64; is arranged to reduce the effective area of h aid 165/133 smaller opening. With the use of the heater spun filaments can be produced having a low degree of preo- [56] Reference; Cit d rientation and a satisfactory uniformity.
UNITED STATES PATENTS 1,881,331 10/1932 Smith et a1 432/59 7 Claims, 3 Drawing Figures -Z- l 1 V d 1 d2 --1 i d 3 HEATER FOR USE IN THE MANUFACTURE OF PLASTICS FILAMENTS The present invention relates to a heater for use in the manufacture of macromolecular plastics filaments having a low degree of pre-orientation for the production of high strength threads.
High strength threads can only be produced when the material spun to make the threads is drawn to a very high degree. A high degree of drawing can only be obtained, however, with material which, when spun, has a low pre-orientation. In the manufacture of high strength threads, as used, for example, for tire cord, the spinning process has to be carried out in such a manner that the spun filaments should have as low a preorientation as possible. A further problem arises in achieving the necessary uniformity, because the filaments can only be drawn to a high degree when, in the spinning process, each of the many capillaries has been uniformly treated. irregularities which may, for example, occur by unsuitable cooling cannot be remedied by further processing and detrimentally affect the quality of the finished thread.
It has been discovered that the pre-orientation of the filaments during spinning can be reduced when a heating zone is provided below the spinneret to retard cooling of the filaments. British Pat. No. 580,832 describes a process and a device for heating freshly spun filaments produced by the dry spinning process. The spun filament is drawn off in a direction parallel to the axis of a tube having a vertical axis and heated by means of horizontal radiation. In one embodiment the tube is ellitical in cross section and the inner wall of the tube has good reflecting properties. To achieve good focusing of the rays, the source of heat radiation is situated at one principal focus of the ellipse while the filament is at the other principal focus. It is stated that the heating of the spun filaments thus obtained proved to be advantageous also in melt spinning polyamides. In this manner the filaments are maintained in a plastic or semi-plastic state so that drawing is facilitated. The device described in the aforesaid patent is, however, very large and difficult to handle.
According to German Offenlegungsschrift No. 1,435.5 l 2 a long, heated, cylindrical or rectangular tube serves as heating zone which surrounds for a considerable distance the freshly spun filaments below the spinneret. In this specification the minimum temperature T around the filaments is given by the equation where:
7, stands for the temperature of the spinneret D represents the distance in feet from the spinneret F indicates the denier value of the filaments V is the winding speed in feet per second and r, a r,,+ 100C In this process the degree of pre-orientation could be kept low in multifilament yarns.
French Pat. No. 1,347,986 provides a process according to which the freshly spun polyester or polyamide filaments pass through a cylindrical heated tube the gas temperature around the filaments being determined according to the following condition T gas temperature directly on the spinneret in C with 270 C s T 700 C T gas temperature in C at distance L vertically below the spinneret T temperature of spinneret in C D distance from the spinneret in meters V draw-off speed of the spun filaments in m/sec After having left the cylinder the filaments are rapidly cooled by a horizontal air current. Subsequently,
they are treated with a preparation, hot steam is blown on to them for warming, they are drawn and wound off.
In the known processes heating devices are used which heat the filaments over a long distance after they have left the spinneret. In this manner cooling and solidification of the filaments takes place very slowly so that their pre-orientation is reduced. It has been found, however, that this method does not give filaments of optimum quality. The regularity of the filaments obtained is not satisfactory and the blowing step carried out after the filaments have passed the radiator involves sticking together of the capillaries because with the construction of the heating radiator used the blowing air gets into the heating zone where it whirls together the still. plastic filaments. A further drawback resulting from the irregularity is the reduction of the tensile strength.
It is an object of the present invention to provide a heater which permits the production of spun filaments having a low degree of pre-orientation and having satisfactory uniformity, which filaments are suitable for the manufacture of threads of high tensile strength.
The invention provides a heater for use in the manufacture of spun plastics filaments which comprises two portions each of which has a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the perimeters of the larger ends of the'internal surfaces being congruent and the two portions meeting at their larger ends with the perimeters of the larger ends of the internal surfaces in register with one another, wherein the internal surface of one of the portions is heated and the internal surface of the other portion is thermally reflective.
Advantageously, there is provided at the smaller end of the said one portion a screen arranged to reduce the effective area of the said smaller opening. The internal surface of each of the said portions is, preferably, a truncated right conical surface.
One form of heater constructed in accordance with the invention will now be described in detail by way of example with reference to the accompanying drawings in which:
FIG. 1 is a perspective view of the heater;
FIG. 2 is an axial cross-section of the heater shown in FIG. 1; and
FIG. 3 illustrates the variation in temperature along the axis of the heater.
Referring to the accompanying drawings, a heater comprises two parts 1 and 2, each of which has the shape of a hollow truncated cone, which are attached to each other at their larger circular openings. The lower part 2 is heated while the inside wall of the upper part 1 reflects the heat emitted by the lower part. Hence, part 1 has the function of a reflector while part 2 has the function of a radiator. The lower opening 3 of the heater is protected by an annular screen 4 preventing air blown onto filaments after they have left the heater entering the space below the spinneret and disturbing the course of the capillaries while they are still plastic. The diameter d, of the opening in the screen is larger by only 5 to 30 millimeters than the diameter dp of a bundle of capillaries, that is to say,
The diameter d, of the upper opening of upper part 1 is larger than the diameter of the bundle of capillaries. The height L of the radiator is in the range of from 1.0 to 2.5 times the diameter d, of the opening of the upper part. That is to say:
1.0d, s L 2.5 :1
Between the bundle of capillaries and the walls of the heater air streams upward and replaces the air entrained by the bundle of capillaries. The cross sectional area of flow should be as large as possible so that the compensation of air can take place at a low speed. The largest cross sectional area of the heater should be at least twice the cross sectional area of the bundle of capillaries, that is to say,
The side line H of the heated part 2 of the heater and the cone angle 4) should be chosen in such a manner that the said perpendicular 5 drawn on the wall of part 2 points to the opposite wall of part I; and arcsin H/2d, l2 arcsin (H/Z s/(d, +d /2 L,) arccot d,+d /2 L The biconical shape of the heating radiator allows concentric thermal radiation. The reason why this shape was chosen is that only a minor part of the thermal rays hits the spinneret while the major part is reflected by the conical reflector into the space below the spinneret. In a preferred embodiment of the radiator according to the invention the reflector I is, therefore, provided with a highly polished surface or coated with a reflecting foil. The heating elements of radiator 2 preferably consist of ceramic plates with inserted heating spirals.
The device according to the invention can be used in melt spinning, preferably spinning of high molecular weight polyesters, more preferably polyethylene terephthalate, and copolyesters, the acid components of which preponderantly consist of terephthalic acid. With the use of the radiator of the invention spun filaments of a very low degree of pre-orientation can be obtained, which permit the production of high strength threads. It is likewise possible to increase the throughput of molten polyester since the higher pre-orientation resulting from a higher draw-off speed of the spun filaments can be compensated for in the heater. The device according to the invention is also suitable for the continuous spin drawing of filaments from highly viscous material.
With the aid of the short biconical heating radiator according to the invention a narrow temperature variation with respect to time and space as indicated in FIG. 3 can be obtained below the spinneret in the solidification zone of the filaments, whereby the solidification is very favourably influenced. The temperature is within the indicated limits ll0- 1.7 X 10 l BIL-0.4 T T,, 2 X10 (D/L 0.5)
at a distance 0 D/L l where:
L height of the heating radiator, measured in the same units of length as the vertical distance D from the spinneret T the gas (air) temperature and T, the temperature of the spinneret in the direct vicinity of the spun filaments from the spinneret in downward direction the air temperature first increases, it passes a maximum and then decreases rapidly with a growing distance from the spinneret. Owing to the fact that a screen narrows the lower opening of the heating radiator to such an extent that it has just the size necessary for an undisturbed running of the filaments, the air blown onto the filaments for cooling them does not enter the space below the spinneret, this being extremely important for obtaining an optimum filament quality. The still soft and very sensitive capillaries could otherwise be entangled by air whirls so that they would stick together and uniform cooling would 7 EXAMPLE 1 Polyethylene terephthalate having an intrinsic viscosity of 1.23, measured at 25 C in a mixture of phenol and tetrachloroethane in a ratio of 3 2, was spun at 304 C at a rate of 220 glminute through a spinneret with 200 orifices each having a diameter of 0.5 mm and the filaments were wound off with a speed of 320 rn/minute. Directly below the spinneret a biconical heater was mounted having the following dimensions:
It had an installed filament power of 2,000 watts at 220 volts and was operated with ISO volts. Immediately after having left the heater, the filaments passed an air blowing zone having a length of about 2 meters with a blowing speed of the air of 0.8 m/sec.
As measurement for the molecule orientation the spun filaments produced in this manner have a double refraction DR of (1.6 2.0). 10', measured according to the compensation method of Ehringhous with quartz or calcite compensators. The DR value is calcu-' lated from the ratio of the path difference and the capillary diameter.
The filaments had a very good uniformity over their length. For the variation of titer of the spun filament composed of 200 capillaries there is given as measurement of non-uniformity U 'the average linear deviation of the titer T from the means titer value T:
U=f T Tuzf Tdz For this purpose the titer T is measured as a function of the filament length l. L is the total filament length measured. The mean titer value is With the use of the heating radiator according to the invention filaments were produced having a titer nonuniformity U of 0.8%. The spun filaments did not stick together.
The spun filaments obtained in this manner could be drawn in a ratio of l 6.5, their strength then being 82 g/tex.
COMPA RATlVE EXAMPLE Double refraction DR l.6 2.0).I"
uniformit of titer U 1.6%
possible raw ratio l 6.4
strength obtained 79 g/tex EXAMPLE 2 A heater according to the invention was used in the spinning process of high strength filaments from a material having an intrinsic viscosity of 0.73. In this case it can be used either for reducing the molecule orientation with the same draw-off speed of the spun filaments or for maintaining the degree of molecule orientation with an increased draw-off speed. The present example is intended to illustrate the former possibility. The positions of the heater and spinning chamber were the same as in Example 1.
Spinning temperature 290C Spinning rate 325 grams/minute number of orifices in spinncret 200 diameter of orifice 0.35 millimeter winding speed 500 meters/minute heating radiator (2,000 watts with 220 volts) 150 volts blowing length 2 meters speed of sir current 0.8 meter/second non-uniformity of titer 0.7% double refraction 1.2-10" COMPARATIVE EXAMPLE The same material as used in Example 2 was spun 6 under the conditions of Example 2, with the exception that no heating radiator according to the invention was used. The filaments obtained had the same degree of titer non-uniformity but a higher degree of preorientation characterized by a double refraction of 1.6 10".
What is claimed is:
1. A heater for use in the manufacture of spun plastics filaments which comprises two portions each of which has a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the perimeters of the larger ends of the internal surfaces being congruent and the two portions meeting at their larger ends with the perimeters of the larger ends of the internal surfaces in register with one another, wherein the internal surface of one of the portions is heated and the internal surface of the other portion is thermally reflective.
2. A heater as claimed in claim 1, wherein there is provided at the smaller end of the said one portion a screen arranged to reduce the effective area of the said smaller opening.
3. A heater as claimed in claim I, wherein the internal surface of each of the said portions is a truncated right conical surface.
4. A heater as claimed in claim 1, wherein the largest cross sectional area is at least twice the cross sectional area of the bundle of filaments.
5. A heater as claimed in claim 1, wherein the diameter d of the smaller opening in the said other portion is in the range of from 0.4 to 1.0 times the total height L, of the heater.
6. A heater as claimed in claim 1, wherein the length H of the internal surface of the said one portion and the apex angle d: are such that a perpendicular drawn from the said point of the internal surface of the said one portion meets the internal surface of the said other portion, and arcsin H/2d, I2 arcsin (H12 {(11, +d,/2)' L,') +arccot d,+d /2L, where:
L, is the total height of the heater,
d, is the largest diameter of the heater taken at right angles to the axis, and
d, is the diameter of the smaller opening in the said other portion.
7. A heater as claimed in claim I, wherein the internal surface of the said other portion is highly polished or coated with a reflective foil.
0 i 0 l i
Claims (7)
1. A heater for use in the manufacture of spun plastics filaments which comprises two portions each of which has a truncated right polygonal pyramidal or truncated right conical internal surface that is open ended, the perimeters of the larger ends of the internal surfaces being congruent and the two portions meeting at their larger ends with the perimeters of the larger ends of the internal surfaces in register with one another, wherein the internal surface of one of the portions is heated and the internal surface of the other portion is thermally reflective.
2. A heater as claimed in claim 1, wherein there is provided at the smaller end of the said one portion a screen arranged to reduce the effective area of the said smaller opening.
3. A heater as claimed in claim 1, wherein the internal surface of each of the said portions is a truncated right conical surface.
4. A heater as claimed in claim 1, wherein the largest cross sectional area is at least twice the cross sectional area of the bundle of filaments.
5. A heater as claimed in claim 1, wherein the diameter d4 of the smaller opening in the said other portion is in the range of from 0.4 to 1.0 times the total height L, of the heater.
6. A heater as claimed in claim 1, wherein the length H of the internal surface of the said one portion and the apex angle phi are such that a perpendicular drawn from the said point of the internal surface of the said one portion meets the internal surface of the said other portion, and arcsin H/2d3 < phi /2 <arcsin (H/2 Cube Root (d3 + d4/2)2 + L12) + arccot d3+d4/2L1 where: L1 is the total height of the heater, d3 is the largest diameter of the heater taken at right angles to the axis, and d4 is the diameter of the smaller opening in the said other portion.
7. A heater as claimed in claim 1, wherein the internal surface of the said other portion is highly polished or coated with a reflective foil.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2115312A DE2115312C3 (en) | 1971-03-30 | 1971-03-30 | Heatable spinning shaft |
Publications (1)
Publication Number | Publication Date |
---|---|
US3741716A true US3741716A (en) | 1973-06-26 |
Family
ID=5803215
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00238846A Expired - Lifetime US3741716A (en) | 1971-03-30 | 1972-03-28 | Heater for use in the manufacture of plastics filaments |
Country Status (11)
Country | Link |
---|---|
US (1) | US3741716A (en) |
BE (1) | BE781488A (en) |
CA (1) | CA964422A (en) |
CH (1) | CH539691A (en) |
DD (1) | DD95903A5 (en) |
DE (1) | DE2115312C3 (en) |
FR (1) | FR2132171B1 (en) |
GB (1) | GB1391471A (en) |
IT (1) | IT950854B (en) |
NL (1) | NL7203995A (en) |
RO (1) | RO64788A (en) |
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003024882A2 (en) | 2001-09-17 | 2003-03-27 | Rhodianyl | Material comprising an inorganic matrix such as cement, mortar, gypsum plaster or concrete, reinforced with microfibres |
US10089516B2 (en) | 2013-07-31 | 2018-10-02 | Digilens, Inc. | Method and apparatus for contact image sensing |
US10145533B2 (en) | 2005-11-11 | 2018-12-04 | Digilens, Inc. | Compact holographic illumination device |
US10156681B2 (en) | 2015-02-12 | 2018-12-18 | Digilens Inc. | Waveguide grating device |
US10185154B2 (en) | 2011-04-07 | 2019-01-22 | Digilens, Inc. | Laser despeckler based on angular diversity |
US10209517B2 (en) | 2013-05-20 | 2019-02-19 | Digilens, Inc. | Holographic waveguide eye tracker |
US10216061B2 (en) | 2012-01-06 | 2019-02-26 | Digilens, Inc. | Contact image sensor using switchable bragg gratings |
US10234696B2 (en) | 2007-07-26 | 2019-03-19 | Digilens, Inc. | Optical apparatus for recording a holographic device and method of recording |
US10241330B2 (en) | 2014-09-19 | 2019-03-26 | Digilens, Inc. | Method and apparatus for generating input images for holographic waveguide displays |
US10330777B2 (en) | 2015-01-20 | 2019-06-25 | Digilens Inc. | Holographic waveguide lidar |
US10359736B2 (en) | 2014-08-08 | 2019-07-23 | Digilens Inc. | Method for holographic mastering and replication |
US10423222B2 (en) | 2014-09-26 | 2019-09-24 | Digilens Inc. | Holographic waveguide optical tracker |
US10437064B2 (en) | 2015-01-12 | 2019-10-08 | Digilens Inc. | Environmentally isolated waveguide display |
US10437051B2 (en) | 2012-05-11 | 2019-10-08 | Digilens Inc. | Apparatus for eye tracking |
US10459145B2 (en) | 2015-03-16 | 2019-10-29 | Digilens Inc. | Waveguide device incorporating a light pipe |
US10545346B2 (en) | 2017-01-05 | 2020-01-28 | Digilens Inc. | Wearable heads up displays |
US10591756B2 (en) | 2015-03-31 | 2020-03-17 | Digilens Inc. | Method and apparatus for contact image sensing |
US10642058B2 (en) | 2011-08-24 | 2020-05-05 | Digilens Inc. | Wearable data display |
US10670876B2 (en) | 2011-08-24 | 2020-06-02 | Digilens Inc. | Waveguide laser illuminator incorporating a despeckler |
US10678053B2 (en) | 2009-04-27 | 2020-06-09 | Digilens Inc. | Diffractive projection apparatus |
US10690916B2 (en) | 2015-10-05 | 2020-06-23 | Digilens Inc. | Apparatus for providing waveguide displays with two-dimensional pupil expansion |
US10690851B2 (en) | 2018-03-16 | 2020-06-23 | Digilens Inc. | Holographic waveguides incorporating birefringence control and methods for their fabrication |
US10732569B2 (en) | 2018-01-08 | 2020-08-04 | Digilens Inc. | Systems and methods for high-throughput recording of holographic gratings in waveguide cells |
US10859768B2 (en) | 2016-03-24 | 2020-12-08 | Digilens Inc. | Method and apparatus for providing a polarization selective holographic waveguide device |
US10890707B2 (en) | 2016-04-11 | 2021-01-12 | Digilens Inc. | Holographic waveguide apparatus for structured light projection |
US10914950B2 (en) | 2018-01-08 | 2021-02-09 | Digilens Inc. | Waveguide architectures and related methods of manufacturing |
US10942430B2 (en) | 2017-10-16 | 2021-03-09 | Digilens Inc. | Systems and methods for multiplying the image resolution of a pixelated display |
US10983340B2 (en) | 2016-02-04 | 2021-04-20 | Digilens Inc. | Holographic waveguide optical tracker |
US11307432B2 (en) | 2014-08-08 | 2022-04-19 | Digilens Inc. | Waveguide laser illuminator incorporating a Despeckler |
US11378732B2 (en) | 2019-03-12 | 2022-07-05 | DigLens Inc. | Holographic waveguide backlight and related methods of manufacturing |
US11402801B2 (en) | 2018-07-25 | 2022-08-02 | Digilens Inc. | Systems and methods for fabricating a multilayer optical structure |
US11442222B2 (en) | 2019-08-29 | 2022-09-13 | Digilens Inc. | Evacuated gratings and methods of manufacturing |
US11448937B2 (en) | 2012-11-16 | 2022-09-20 | Digilens Inc. | Transparent waveguide display for tiling a display having plural optical powers using overlapping and offset FOV tiles |
US11460621B2 (en) | 2012-04-25 | 2022-10-04 | Rockwell Collins, Inc. | Holographic wide angle display |
US11480788B2 (en) | 2015-01-12 | 2022-10-25 | Digilens Inc. | Light field displays incorporating holographic waveguides |
US11513350B2 (en) | 2016-12-02 | 2022-11-29 | Digilens Inc. | Waveguide device with uniform output illumination |
US11543594B2 (en) | 2019-02-15 | 2023-01-03 | Digilens Inc. | Methods and apparatuses for providing a holographic waveguide display using integrated gratings |
US11681143B2 (en) | 2019-07-29 | 2023-06-20 | Digilens Inc. | Methods and apparatus for multiplying the image resolution and field-of-view of a pixelated display |
US11726332B2 (en) | 2009-04-27 | 2023-08-15 | Digilens Inc. | Diffractive projection apparatus |
US11747568B2 (en) | 2019-06-07 | 2023-09-05 | Digilens Inc. | Waveguides incorporating transmissive and reflective gratings and related methods of manufacturing |
US12092914B2 (en) | 2018-01-08 | 2024-09-17 | Digilens Inc. | Systems and methods for manufacturing waveguide cells |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4036070A1 (en) * | 1990-11-13 | 1992-05-14 | Hoechst Ag | HEATING DEVICE AND METHOD FOR THE PRODUCTION OF QUICKLY SPONSED FILAMENTS |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1881331A (en) * | 1930-12-24 | 1932-10-04 | Smith Wiloughby Statham | Apparatus for the continuous heat treatment of metals or alloys |
US3174537A (en) * | 1959-06-30 | 1965-03-23 | Thompson Ramo Wooldridge Inc | Electromagnetic radiant energy response apparatus |
US3285333A (en) * | 1962-10-17 | 1966-11-15 | Garrett Corp | Geometrically-spectrally selective radiator |
-
1971
- 1971-03-30 DE DE2115312A patent/DE2115312C3/en not_active Expired
-
1972
- 1972-03-24 NL NL7203995A patent/NL7203995A/xx not_active Application Discontinuation
- 1972-03-28 IT IT22525/72A patent/IT950854B/en active
- 1972-03-28 RO RO7270299A patent/RO64788A/en unknown
- 1972-03-28 US US00238846A patent/US3741716A/en not_active Expired - Lifetime
- 1972-03-28 CH CH459372A patent/CH539691A/en not_active IP Right Cessation
- 1972-03-29 CA CA138,412A patent/CA964422A/en not_active Expired
- 1972-03-29 FR FR7211001A patent/FR2132171B1/fr not_active Expired
- 1972-03-30 GB GB1517872A patent/GB1391471A/en not_active Expired
- 1972-03-30 DD DD161933A patent/DD95903A5/xx unknown
- 1972-03-30 BE BE781488A patent/BE781488A/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1881331A (en) * | 1930-12-24 | 1932-10-04 | Smith Wiloughby Statham | Apparatus for the continuous heat treatment of metals or alloys |
US3174537A (en) * | 1959-06-30 | 1965-03-23 | Thompson Ramo Wooldridge Inc | Electromagnetic radiant energy response apparatus |
US3285333A (en) * | 1962-10-17 | 1966-11-15 | Garrett Corp | Geometrically-spectrally selective radiator |
Cited By (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003024882A2 (en) | 2001-09-17 | 2003-03-27 | Rhodianyl | Material comprising an inorganic matrix such as cement, mortar, gypsum plaster or concrete, reinforced with microfibres |
US10145533B2 (en) | 2005-11-11 | 2018-12-04 | Digilens, Inc. | Compact holographic illumination device |
US10234696B2 (en) | 2007-07-26 | 2019-03-19 | Digilens, Inc. | Optical apparatus for recording a holographic device and method of recording |
US10725312B2 (en) | 2007-07-26 | 2020-07-28 | Digilens Inc. | Laser illumination device |
US11175512B2 (en) | 2009-04-27 | 2021-11-16 | Digilens Inc. | Diffractive projection apparatus |
US10678053B2 (en) | 2009-04-27 | 2020-06-09 | Digilens Inc. | Diffractive projection apparatus |
US11726332B2 (en) | 2009-04-27 | 2023-08-15 | Digilens Inc. | Diffractive projection apparatus |
US10185154B2 (en) | 2011-04-07 | 2019-01-22 | Digilens, Inc. | Laser despeckler based on angular diversity |
US11487131B2 (en) | 2011-04-07 | 2022-11-01 | Digilens Inc. | Laser despeckler based on angular diversity |
US11287666B2 (en) | 2011-08-24 | 2022-03-29 | Digilens, Inc. | Wearable data display |
US10670876B2 (en) | 2011-08-24 | 2020-06-02 | Digilens Inc. | Waveguide laser illuminator incorporating a despeckler |
US10642058B2 (en) | 2011-08-24 | 2020-05-05 | Digilens Inc. | Wearable data display |
US10459311B2 (en) | 2012-01-06 | 2019-10-29 | Digilens Inc. | Contact image sensor using switchable Bragg gratings |
US10216061B2 (en) | 2012-01-06 | 2019-02-26 | Digilens, Inc. | Contact image sensor using switchable bragg gratings |
US11460621B2 (en) | 2012-04-25 | 2022-10-04 | Rockwell Collins, Inc. | Holographic wide angle display |
US10437051B2 (en) | 2012-05-11 | 2019-10-08 | Digilens Inc. | Apparatus for eye tracking |
US11994674B2 (en) | 2012-05-11 | 2024-05-28 | Digilens Inc. | Apparatus for eye tracking |
US11815781B2 (en) * | 2012-11-16 | 2023-11-14 | Rockwell Collins, Inc. | Transparent waveguide display |
US11448937B2 (en) | 2012-11-16 | 2022-09-20 | Digilens Inc. | Transparent waveguide display for tiling a display having plural optical powers using overlapping and offset FOV tiles |
US20230114549A1 (en) * | 2012-11-16 | 2023-04-13 | Rockwell Collins, Inc. | Transparent waveguide display |
US10209517B2 (en) | 2013-05-20 | 2019-02-19 | Digilens, Inc. | Holographic waveguide eye tracker |
US11662590B2 (en) | 2013-05-20 | 2023-05-30 | Digilens Inc. | Holographic waveguide eye tracker |
US10423813B2 (en) | 2013-07-31 | 2019-09-24 | Digilens Inc. | Method and apparatus for contact image sensing |
US10089516B2 (en) | 2013-07-31 | 2018-10-02 | Digilens, Inc. | Method and apparatus for contact image sensing |
US10359736B2 (en) | 2014-08-08 | 2019-07-23 | Digilens Inc. | Method for holographic mastering and replication |
US11709373B2 (en) | 2014-08-08 | 2023-07-25 | Digilens Inc. | Waveguide laser illuminator incorporating a despeckler |
US11307432B2 (en) | 2014-08-08 | 2022-04-19 | Digilens Inc. | Waveguide laser illuminator incorporating a Despeckler |
US10241330B2 (en) | 2014-09-19 | 2019-03-26 | Digilens, Inc. | Method and apparatus for generating input images for holographic waveguide displays |
US11726323B2 (en) | 2014-09-19 | 2023-08-15 | Digilens Inc. | Method and apparatus for generating input images for holographic waveguide displays |
US10423222B2 (en) | 2014-09-26 | 2019-09-24 | Digilens Inc. | Holographic waveguide optical tracker |
US11726329B2 (en) | 2015-01-12 | 2023-08-15 | Digilens Inc. | Environmentally isolated waveguide display |
US11740472B2 (en) | 2015-01-12 | 2023-08-29 | Digilens Inc. | Environmentally isolated waveguide display |
US11480788B2 (en) | 2015-01-12 | 2022-10-25 | Digilens Inc. | Light field displays incorporating holographic waveguides |
US10437064B2 (en) | 2015-01-12 | 2019-10-08 | Digilens Inc. | Environmentally isolated waveguide display |
US10330777B2 (en) | 2015-01-20 | 2019-06-25 | Digilens Inc. | Holographic waveguide lidar |
US10156681B2 (en) | 2015-02-12 | 2018-12-18 | Digilens Inc. | Waveguide grating device |
US11703645B2 (en) | 2015-02-12 | 2023-07-18 | Digilens Inc. | Waveguide grating device |
US10527797B2 (en) | 2015-02-12 | 2020-01-07 | Digilens Inc. | Waveguide grating device |
US10459145B2 (en) | 2015-03-16 | 2019-10-29 | Digilens Inc. | Waveguide device incorporating a light pipe |
US12013561B2 (en) | 2015-03-16 | 2024-06-18 | Digilens Inc. | Waveguide device incorporating a light pipe |
US10591756B2 (en) | 2015-03-31 | 2020-03-17 | Digilens Inc. | Method and apparatus for contact image sensing |
US11281013B2 (en) | 2015-10-05 | 2022-03-22 | Digilens Inc. | Apparatus for providing waveguide displays with two-dimensional pupil expansion |
US10690916B2 (en) | 2015-10-05 | 2020-06-23 | Digilens Inc. | Apparatus for providing waveguide displays with two-dimensional pupil expansion |
US11754842B2 (en) | 2015-10-05 | 2023-09-12 | Digilens Inc. | Apparatus for providing waveguide displays with two-dimensional pupil expansion |
US10983340B2 (en) | 2016-02-04 | 2021-04-20 | Digilens Inc. | Holographic waveguide optical tracker |
US10859768B2 (en) | 2016-03-24 | 2020-12-08 | Digilens Inc. | Method and apparatus for providing a polarization selective holographic waveguide device |
US11604314B2 (en) | 2016-03-24 | 2023-03-14 | Digilens Inc. | Method and apparatus for providing a polarization selective holographic waveguide device |
US10890707B2 (en) | 2016-04-11 | 2021-01-12 | Digilens Inc. | Holographic waveguide apparatus for structured light projection |
US11513350B2 (en) | 2016-12-02 | 2022-11-29 | Digilens Inc. | Waveguide device with uniform output illumination |
US11586046B2 (en) | 2017-01-05 | 2023-02-21 | Digilens Inc. | Wearable heads up displays |
US10545346B2 (en) | 2017-01-05 | 2020-01-28 | Digilens Inc. | Wearable heads up displays |
US11194162B2 (en) | 2017-01-05 | 2021-12-07 | Digilens Inc. | Wearable heads up displays |
US10942430B2 (en) | 2017-10-16 | 2021-03-09 | Digilens Inc. | Systems and methods for multiplying the image resolution of a pixelated display |
US12092914B2 (en) | 2018-01-08 | 2024-09-17 | Digilens Inc. | Systems and methods for manufacturing waveguide cells |
US10914950B2 (en) | 2018-01-08 | 2021-02-09 | Digilens Inc. | Waveguide architectures and related methods of manufacturing |
US10732569B2 (en) | 2018-01-08 | 2020-08-04 | Digilens Inc. | Systems and methods for high-throughput recording of holographic gratings in waveguide cells |
US11726261B2 (en) | 2018-03-16 | 2023-08-15 | Digilens Inc. | Holographic waveguides incorporating birefringence control and methods for their fabrication |
US11150408B2 (en) | 2018-03-16 | 2021-10-19 | Digilens Inc. | Holographic waveguides incorporating birefringence control and methods for their fabrication |
US10690851B2 (en) | 2018-03-16 | 2020-06-23 | Digilens Inc. | Holographic waveguides incorporating birefringence control and methods for their fabrication |
US11402801B2 (en) | 2018-07-25 | 2022-08-02 | Digilens Inc. | Systems and methods for fabricating a multilayer optical structure |
US11543594B2 (en) | 2019-02-15 | 2023-01-03 | Digilens Inc. | Methods and apparatuses for providing a holographic waveguide display using integrated gratings |
US11378732B2 (en) | 2019-03-12 | 2022-07-05 | DigLens Inc. | Holographic waveguide backlight and related methods of manufacturing |
US11747568B2 (en) | 2019-06-07 | 2023-09-05 | Digilens Inc. | Waveguides incorporating transmissive and reflective gratings and related methods of manufacturing |
US11681143B2 (en) | 2019-07-29 | 2023-06-20 | Digilens Inc. | Methods and apparatus for multiplying the image resolution and field-of-view of a pixelated display |
US11899238B2 (en) | 2019-08-29 | 2024-02-13 | Digilens Inc. | Evacuated gratings and methods of manufacturing |
US11442222B2 (en) | 2019-08-29 | 2022-09-13 | Digilens Inc. | Evacuated gratings and methods of manufacturing |
US11592614B2 (en) | 2019-08-29 | 2023-02-28 | Digilens Inc. | Evacuated gratings and methods of manufacturing |
Also Published As
Publication number | Publication date |
---|---|
DD95903A5 (en) | 1973-02-20 |
IT950854B (en) | 1973-06-20 |
DE2115312B2 (en) | 1974-10-31 |
BE781488A (en) | 1972-10-02 |
CA964422A (en) | 1975-03-18 |
FR2132171B1 (en) | 1975-10-24 |
DE2115312A1 (en) | 1972-10-19 |
GB1391471A (en) | 1975-04-23 |
NL7203995A (en) | 1972-10-03 |
DE2115312C3 (en) | 1975-06-26 |
RO64788A (en) | 1982-02-26 |
FR2132171A1 (en) | 1972-11-17 |
CH539691A (en) | 1973-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3741716A (en) | Heater for use in the manufacture of plastics filaments | |
RU2111294C1 (en) | Method of production of cellulose bodies by forming and device for its embodiment | |
US3053611A (en) | Process for spinning of synthetic fibers | |
US5866055A (en) | Process for the production of a polyester multifilament yarn | |
CN1131207A (en) | Apparatus and method for heat treatment of fibre | |
US5186879A (en) | Spinning process for producing high strength, high modulus, low shrinkage yarns | |
US4176150A (en) | Process for textured yarn | |
KR890000097B1 (en) | Partially oriented nylon yarn and process | |
FI75556C (en) | Apparatus for producing mineral fibers from a thermoplastic material. | |
US3366722A (en) | Yarn manufacture | |
US5238740A (en) | Drawn polyester yarn having a high tenacity and high modulus and a low shrinkage | |
US6015616A (en) | Drawn polyester yarn having a high tenacity, a high modulus and a low shrinkage | |
US5137670A (en) | Polyester fiber and process for manufacture | |
US3061874A (en) | Melt spinning apparatus | |
US4522773A (en) | Process for producing self-crimping polyester yarn | |
KR100738518B1 (en) | Polyester fiber and manufacturing method thereof | |
US4956446A (en) | Polyester fiber with low heat shrinkage | |
US3832435A (en) | Process for the manufacture of crimped fibers and filaments of linear high molecular weight polymers | |
AU643641B2 (en) | A spinning process for producing high strength, high modulus, low shrinkage synthetic yarns | |
US3551550A (en) | Process for preheating and drawing filaments of synthetic linear polyesters | |
PT97732B (en) | ROTARY FUSING PROCESS OF A FIBER FORMER PILIMER | |
EP0456495A2 (en) | A drawn polyester yarn having a high tenacity, a high initial modulus and a low shrinkage | |
US4287713A (en) | Process for low-torque textured yarn | |
KR920008537B1 (en) | A spinning nozzle for shaped synthetic fiber | |
EP0456494A2 (en) | An as-spun polyester yarn having small crystals and high orientation |