US3728115A - Photographic dry copying material - Google Patents

Photographic dry copying material Download PDF

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US3728115A
US3728115A US00143226A US3728115DA US3728115A US 3728115 A US3728115 A US 3728115A US 00143226 A US00143226 A US 00143226A US 3728115D A US3728115D A US 3728115DA US 3728115 A US3728115 A US 3728115A
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image
light
sensitive
compounds
layer
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A Poot
Besauw J Van
A Koenig
H Kampfer
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Agfa Gevaert AG
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Agfa Gevaert AG
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/695—Compositions containing azides as the photosensitive substances
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
    • G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/56—Processes using photosensitive compositions covered by the groups G03C1/64 - G03C1/72 or agents therefor

Definitions

  • Photographic copies are produced by image-wise exposing a light-sensitive layer which contains a light-sensitive photo-oxidizing compound and an image-producing pyrazolin-S-one capable of being transferred to an imagereceiving layer, the image-producing compound in the exposed areas being converted into a non-transferable compound by reaction with the light-sensitive compound, bringing the exposed layer into contact with an imagereceiving layer which contains compounds which react with the image-producing compound to form colored compounds and heating of the layers while in contact with each other to a temperature of between 80 and 200 C. at which the image-producing compound is transferred from the unexposed areas of the light-sensitive layer to the image-receiving layer.
  • the invention relates to a photographic dry copying process and to a light-sensitive material for carrying out this process.
  • Dry photographic processes for producing copies of an original are already known.
  • the materials used for these processes consist mainly of layers which are sensitive to light or heat and which are either exposed to light or are heated. A color-forming reaction is thus initiated which leads to the formation of the image.
  • the known light-sensitive materials of this kind which can be used for producing negative copies have, however, several disadvantages. Their sensitivity to light is unsatisfactory, especially in the visible region of the spectrum, so that the copying times required are too long and the reproduction of colored original copies gives rise to difiiculties. Moreover, the finished copies remain sensitive to light and their stabilisation against daylight can generally only be achieved by a very complicated aftertreatment.
  • These processes include e.g. the so-called heat development processes in which the light-sensitive materials used include a silver halide emulsion layer which contains a photographic developing agent. After exposure, the photographic material is developed by heating it in contact with an image-receiving layer which contains substances which react with the developing agent to yield colored compounds. The developing agent is transferred by the heat from the unexposed areas of the light-sensi- 3,728,115 Patented Apr. 17, 1973 "ice tive layer to the image-receiving layer so that a colored lmage is produced in the corresponding areas of the receiving layer.
  • One disadvantage of this known heat development or developer-sublimation process is that the silver halide emulsion layers which contain developing agents are not sufliciently stable on storage. This is because they contain substances which increase the residual moisture content of the layers, e.g. salts which form hydrates, or glycols, and because of the increased sensitivity to oxidation of most developing agents in these unhardened or only slightly hardened emulsion layers which have a high residual moisture content.
  • the process described in US. Pat. No. 3,094,417 belongs to this type of copying process.
  • the light-sensitive layers used in this process contain a volatile compound and a dye.
  • the volatile compound (4methoxy-l-naphthol) is converted into a non-volatile product.
  • This compound can be transferred by subsequent heating from the unexposed areas into an image-receiving layer where it reacts with a silver salt (silver behenate) to produce a colored positive image.
  • a dry copying process including the steps of imagewise exposing a supported light-sensitive layer containing as light-sensitive compound a photooxidizing agent and an image-producing compound capable of being transferred to an image-receiving layer whereby the image-producing compound in the exposed areas is converted into a non-transferable compound, contacting the exposed layer with an image-receiving layer which contains compounds which react with the image-producing compound to form colored compounds and heating of the layers while in contact with each other to a temperature at which the image-produced compound is transferred from the unexposed areas of the light-sensitive layer to the image-receiving layer; wherein the light-sensitive layer which contains a photooxidans contains, as image-producing, transferable compound, a pyrazolin-S-one which is transferable at a temperature of between C. and 200 C.
  • a particular advantage of the pyrazolin-S-ones according to the present invention is their very low sensitivity to atmospheric oxygen.
  • the pyrazolin-S-ones preferably used are those pyrazolin-S-one derivatives which contain at least one hydrogen or a 4-aminophenylamino group in the 4-position.
  • R is either 1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group which preferablycontains up to 6 carbon atoms and may be substituted, e.g. with phenyl as in the benzyl group with nitrile, halogen such as fluorine, with amino, in which case the amino group may in turn be substituted, e.g. alkylated amino groups and especially dialkylarnino, the alkyl groups on the amino group preferably containing up to 3 carbon atoms,
  • aryl especially a group of the phenyl series; the aryl ring may in turn be substituted, e.g. with alkyl or alkoxy, preferably containing up to 3 carbon atoms, nitro, halogen such as fluorine, chlorine or bromine, amino or substituted amino group, e.g. alkylated amino groups,
  • a cycloalkyl group such as cyclohexyl or cyclopentyl
  • R represents (1) hydrogen
  • a saturated or an olefinically unsaturated aliphatic group which preferably contains up to 6 carbon atoms and may itself be substituted e.g. with phenyl, as in the case of a benzyl or phenylethyl group with halogen such as fluorine, with alkoxy carbonyl, hydroxyl or alkoxy,
  • aryl especially a group of the phenyl series
  • the aryl ring may be substituted e.g. with alkyl or alkoxy, preferably containing up to 3 carbon atoms or with nitro or halogen such as chlorine or bromine,
  • cycloalkyl such as cyclohexyl or cyclopentyl
  • R stands for (1) hydrogen
  • a saturated or an olefinically unsaturated aliphatic group which preferably contains up to 6 carbon atoms and which may be substituted e.g. with phenyl as in the case of benzyl or phenylethyl groups, with halogen such as chlorine or bromine, with nitrite, alkoxy having preferably up to 3 carbon atoms, alkoxy carbonyl or anilinocarbonyl,
  • aryl especially a group of the phenyl series
  • the aryl ring may be in turn substituted e.g. with alkyl or alkoxy preferably containing up to 3 carbon atoms, nitro or nitrile,
  • alkyl preferably containinng up to 3 carbon atoms, cycloalkyl, phenyl or acyl, especially acyl groups of short-chained aliphatic carboxylic acids, or
  • alkoxy preferably containing up to 3 carbon atoms
  • R represents hydrogen, a 4-aminophenylamino group, a
  • R and R may together represent the 3 ring members required to complete a S-membered or TABLE I H R: I R; l
  • R2 RI N H H OH; H 5 0 H3 H Cyclohexyl CH H 5 P- yl OH; H 6 m-Chlorophenyl CH, H 7 2, E-dichlorophenyl CH H 8 B-nitrophenyl C H; H 9 4-nltrophenyl OH; H 10.
  • the light-sensitive photo-oxidizing compounds suitable for the material according to the present invention cannot be classified according to any particular chemical groups. They must simply be adequately light-sensitive and they must react with the image-producing pyrazolin- 5-ones on exposure to light in such a manner that the image-producing compounds are converted into nonvolatile reaction products.
  • R R and R represent an aromatic carbocyclic or heterocyclic group, e.g. a group of the phenyl or naphthyl series, thienyl or the like; the aromatic rings may carry further substituents, e.g. (1) halogen such as fluorine, chlorine or bromine, (2) cyano, (3) alkyl groups which may be substituted e.g.
  • halogen such as fluorine, chlorine or bromine, nitril, alkoxy or phenyl, (4) alkoxy or alkylthio preferably containing up to 5 carbon atoms, (5) aryloxy or arylthio, especially phenoXy or naphthoxy, (6) alkyl sulfonyl preferably containing up to 5 carbon atoms, (7) aryl sulfonyl, especially phenyl sulfonyl, (8) acyloxy and acylamino groups, e.g. those derived from aromatic or aliphatic carboxylic acids, e.g.
  • R R and R may be the same or different and are preferably compounds in which R is an ortho-substituted phenyl group.
  • Phenyl Phenyl. dn Do. ..do D0. fin D0. p-Ohlorophenyl D0. 3,4-dichlorophenyl Do. m-PentyloxyphenyL... Do.
  • dn m-Pentyloxyphenyl 25 do p-Proplonyloxyphenyl Phenyl. 26 2-chloro-4-phenyl Phenyl Do. 27 o-Cyanophenyl Do. 28 do p-tert.-Butylphenyl Do. do p-Cyanophenyl p-Cyanophenyl. an dn p-Methoxyphenyl. p-Methoxyphenyl. 31 Q-phenanthry Pheny henyl. 32.. 2,3-dibromophenyldo Do. 33-. 2,4dibromophenyl. dn Do. 34 2,6-dibutylphenyL.
  • 2,4-d1ethoxyphen Do. o-Dlethylsulfamoylph Do. 2,6-difiuorophenyL- Do. 2,3-dim Do. Do. alleged o-Ohlorophenyl. o-Methoxyphenyl- Phen 1. p-MethoxyphenyL Do. do m-Phenylthiom-Phenylthio. Dimethylaminopheny Phenyl Phenyl. do d-Dipent-ylaminopheny Do. do o-Dipropylsulfamoylpheny Do. imeth ylcarbamoylphenyl Phenyl Do. 2,4-dinaphthylthiophenyl. do Do. 2,4dipentylpheny1 2,4'dipenty1phenyl 2,4-dipentylpheny1.
  • the most advantageous method is the oxidative dimerization of monoimidazolyl compounds in an alkaline organic medium by means of hexacyano ferrate- (III) compounds, e.g. potassium hexacyano ferrate.
  • This process predominantly leads to the formation of bis-imidazolyl compounds in which the two imidazole rings are connected via a CN bridge (1,2'-bis-imidazoles or CN isomers), but bis-imidazoles which are connected via a CC bridge, e.g. 4,4'-bis-imidazoles or other CC isomers, may also be formed in this process.
  • Organic azides are also suitable for use as light-sensitive photo-oxidizing compounds for the material according to the invention, especially light-sensitive aryl azides Heterocyclic azides of the following general formula have proved to be particularly suitable:
  • Yb-N3 In the above formula Z represents the ring members required to complete a S-membered or 6-membered heterocyclic ring which contains nitrogen, e.g. an oxazole, thiazole, selenazole, imidazole, pyridine, pyrrole or pyrimidine ring, or the condensed heterocyclic rings resulting from condensation of the above with an aromatic ring system;
  • Y is an arylene group, preferably phenylene or a phenylene-carbonyl methylene group in which the phenylene rings may contain further substituents such as alkyl or alkoxy, both of which preferably contain up to 3 carbon atoms, hydroxyl, halogen such as fluorine, chlorine or bromine or the like;
  • R R can be the same or difierent and stand for 1) hydrogen, (2) saturated or olefinically unsaturated aliphatic groups having preferably up to carbon atoms, (3) aryl, especially phenyl, (4) amino which may be substituted with alkyl or acyl, (5) halogen such as chlorine or bromine, (6) hydroxyl, (7) alkoxy preferably having up to 5 carbon atoms, (8) carboxyl, (9) esterified carboxyl, especially with aliphatic alcohols, (l0) carbamoyl, (ll) sulfo, (12) sulfamoyl or (13) cyano;
  • R and R also represent the ring members required to complete a condensed benzene or naphthalene ring;
  • n 0 or 1.
  • Light-sensitive compounds of the 9-azido-2,3-benzacridine, 4-azidoquinoline or 9-azidoacridine series are preferred.
  • the compounds have the same basic structure. They dilfer from each other merely by a condensed benzene ring. Substitution products of these basic compounds may also be used, e.g.
  • alkyl preferably containing up to 6 carbon atoms such as methyl, ethyl, propyl or butyl, or alkoxy which also preferably contains up to 6 carbon atoms, amino or monoor di-alkyl-amino also preferably containing up to 6 carbon atoms in the alkyl group, halogen such as chlorine or bromine, nitro, cyano, carboxyl or esterified carboxyl group.
  • Phenyl azides, naphthyl azides, phenyl carbonyl azides, naphthyl carbonyl azides, phenyl sulfonyl azides and naphthyl sulfonyl azides are also suitable.
  • Aryl azides in which two phenyl or naphthyl rings are conjugated to each other by one or more vinylene groups have been found to be particularly suitable, e.g. stilbenazides.
  • the chain consisting of vinylene groups may be interrupted by carbonyl groups.
  • Suitable azides are shown in Table HI below.
  • azides mentioned above are prepared by known methods, for example compounds (1) to (25), (39) and (40) by reacting the corresponding halogen compounds with sodium azide (as described, for example, in German Oifenlegungsschrift No. 1,547,774) and compounds (26) to (38) by the condensation of aldehydes with ac: tive methylene compounds. Another suitable process for their preparation is the Sandmeyer reaction.
  • the materials according to the invention preferably contain the image-producing pyrazolin-S-one compounds and the light-sensitive compounds in a molar ratio of about 1:1 to 6.
  • the light-sensitive layers contain the light-sensitive compounds, e.g. at least one of the light-sensitive azides, in quantities of 0.1 to 1.5 g. /m. and one or more imageproducing pyrazolin-S-one compounds in quantities of 0.03 to 0.6 g./m. or at least one of the light-sensitive bis-imidazoles in quantities of 0.5 to 8 g./m. and one or more image-producing pyrazolin-S-one compounds in quantities of 0.1 to 1.5 g./m.
  • concentrations have been found to be suitable, although concentrations outside these ranges may, of course, be employed.
  • the concentration depends mainly on the requirements of the particular reproduction process.
  • the light-sensitive compound and the image-producing compound may be dissolved or suspended in solvents, mixed with a binder and applied to the layer support.
  • Suitable binders for the light-sensitive layer are the usual natural or synthetic film-forming polymers, e.g. proteins, especially gelatine, cellulose derivatives, especially cellulose ethers, cellulose esters or carboxymethyl cellulose, alginic acid and its derivatives, starch ether or galactomannan, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl chloride, copolymers of vinyl chloride and vinyl acetate, polyvinyl acetate or partly saponified polyvinyl acetate or copolymers of vinyl acetate, copolymers of acrylonitrile and acrylamide, polyacrylic acid esters, polymethacrylic acid esters, polyethylene, etc.
  • proteins e.g. proteins, especially gelatine, cellulose derivatives, especially cellulose ethers, cellulose esters or carboxymethyl cellulose, alginic acid and its derivatives, starch ether or galactomannan
  • polyvinyl alcohol polyvinyl pyr
  • the light-sensitive layers may either be used as self-supporting layers or applied to a layer support.
  • Suitable layer supports are e.g. paper, especially baryta paper or backed paper, cellulose esters, e.g. cellulose triacetate, polyesters, especially those based on ethylene terephthalate, glass, etc.
  • the image-receiving material preferably consists of an image-receiving layer applied to a suitable layer support. Substantially the same substances as those described above for the light-sensitive materials may be used both as binder for the image-receiving layer and as layer support.
  • the image-receiving layer contains compounds which should be substantially insensitive to visible light under the conditions of the process of the invention and which must react with transferred image-producing compounds to form colored products. Numerous compounds have been found to be suitable for this purpose. Chemically, these compounds belong to many difierent classes so that they cannot be definitely classified on a chemical basis, but suitable compounds and suitable combinations of an image-producing compound for use in the light-sensitive layer and of its reactant which is used in the image-receiving layer to produce the reaction which yields the image dye can easily be identified by a few simple laboratory tests. Thus the two reactants must react to produce a stable image dye when heated for a few seconds to a temperature of between about 80 C. and 200 C. A second test is then necessary to choose suitable imageproducing compounds.
  • This test should indicate whether the image-producing compound reacts sufiiciently rapidly with the light-sensitive azide or bis-imidazole on exposure to light so that when the exposed mixture is heated in the presence of the reactant in the image-receiving layer it will no longer yield a colored compound.
  • Noble metal compounds e.g. compounds of silver, gold or platinum. Suitable examples are the salts of these metals with long-chain aliphatic carboxylic acids, having preferably between 6 and 30 carbon atoms. Silver compounds which are largely insensitive to light under the conditions of the copying process carried out according to the invention have been found to be particularly suitable, e.g. the silver salts of aliphatic carboxylic acids having a thioether group as described in British Pat. No. 1,111,492 or silver salts of long-chain fatty acids, such as silver behenate, silver palmitate, silver stearate, etc.
  • the copies obtained are generally brown to black.
  • the image consists of the metal and/or a reaction product of the transferred image-producing compound.
  • Diazonium salts which react with the transferred pyrazolin-S-one compound via the hydrogen atom in the 12 4-position of the pyrazoline ring to form a colored product. This reaction is similar in principle to the reaction employed in the known diazo-type photographic process.
  • Suitable reactants are e.g. the oxidation products of p-phenylene diamines or their derivatives which react with the pyrazolin-S-one compounds to form azomethine dyes of the type known in color photography.
  • the image-receiving layers may also contain additives which have an advantageous influence on the color tone, contrast, stability, etc. of the copy.
  • Image-receiving layers of this type are already known and have been described for example in German Pats. Nos. 895,101 and 1,003,577 and in Belgian Pats. Nos. 614,064 and 609,057.
  • the image-receiving layers may also contain white pigments such as zinc oxide, silicon dioxide or titanium dioxide as fillers for improving the whites and to control the tendency of the layers to stick, and they may contain terpene resins and organic acids to improve the stability in storage.
  • Image-receiving layers of this type have been described in U.S. Pats. Nos. 3,074,809 and 3,107,174.
  • the color tone of the resulting images may be improved e.g. by addition of compounds of the 1-(2H)- phthalazinone series. Toners of this type have been described in U.S. Pats. Nos. 3,080,254 and 3,446,648. Additives which accelerate the reduction reaction in the. image-receiving layer have also been found to be advantageous. Sterically hindered phenols, e.g. 2,6-di-tertbutyl p cresol, are suitable for this purpose, for example. Compounds of this type have been described in U.S. Pat. No. 3,218,166. The image tone and density can also be improved by certain metal salts, e.g. copper-II stearate. Ionic metal compounds of this type which in tensity the image and their use have been described in German Auslegeschrift No. 1,572,209.
  • the light-sensitive layers according to the invention may be exposed to the usual sources of light used in reproduction work, e.g. mercury vapour lamps, iodine quartz lamps or incandescent lamps.
  • the spectral sensitivity of the light-sensitive material depends on the nature of the azides and bis-imidazoles used.
  • Exposure may be carried out either in contact or optically or in reflex position.
  • Transfer of the image-producing compounds from the unexposed areas of the light-sensitive layers to the imagereceiving layer is carried out in the heat at temperatures of between C. and 200 C.
  • the layers may be heated e.g. by passing the exposed light-sensitive layer over hot plates or rollers in contact with the image-receiving layer or by irradiation with infra-red light.
  • the best temperature and heating time depend, of course, on the nature of the compound which is to be produced, and can easily be determined by a few simple tests.
  • the spectral sensitivity of the light-sensitive materials depends on the nature of these materials.
  • the bis imidazole compounds used according to the invention are generally sensitive to wavelengths below 300 nm. of the ultraviolet portion of the spectrum.
  • the organic azido compounds are generally also sensitive to the ultraviolet part of the spectrum, whereas the 9-azidoacridines are already sensitive to the part of the spectrum ranging from blue to green, in the region of about 350 to 540 nm.
  • a special advantage of the light-sensitive system for use according to the invention which consists of the hisimidazole or organic azide and the image-producing compound, is that the system can be optically sensitized.
  • any compounds used for the optical sensitization of silver halide emulsions aresuitable for use as sensitisers for the material according to the invention; this means especially cyanine dyes, merocyanines, oxonoles, rhodacyanines or various types of styrly com- 3 pounds, e.g. as described in the book by M. Hamer, The Cyanine Dyes and Related Compounds (1964).
  • the technique used for sensitizing is also similar to that commonly used in silver halide photography.
  • the sensitizers are dissolved in a suitable solvent such as shortchain aliphatic alcohols or aqueous systems and added to the layers before casting.
  • the concentration of optical sensitizers may vary within wide limits. Quantities of between 1 and 10 g. per mol of light-sensitive compounds have generally been found to be sufficient but larger quantities may in some cases be necessary, e.g. in the case of dyes which have a low extinction.
  • sensitizers for any given system can easily be determined by the usual sensitometric tests which are commonly used in silver halide photography.
  • sensitizers results not only in an increase in the range of spectral sensitivity but also in a considerable increase in the overall sensitivity, which is especially desirable for obtaining short copying times. Owing to the possibility of sensitizing the layers according to the invention, perfect copies of colored originals can be obtained.
  • the image-receiving layer and the light-sensitive layer may be combined on one support.
  • a transparent layer support must be used, and the image-receiving layer, e.g. a layer containing silver behenate and behenic acid (molar ratio 1:1) dispersed in a copolymer of styrene and isobutylene, is applied first to the support and the light-sensitive layer, e.g. a layer of ethyl cellulose containing the light-sensitive compound and the pyrazolin-S-one, is then applied to the image-receiving layer.
  • the image-receiving layer e.g. a layer containing silver behenate and behenic acid (molar ratio 1:1) dispersed in a copolymer of styrene and isobutylene
  • the light-sensitive layer e.g. a layer of ethyl cellulose containing the light-sensitive compound and the pyrazolin-S-one
  • EXAMPLE 1 Light-sensitive material The following casting solution is applied in a quantity of 35 g./m. to a layer support of pergamin paper:
  • the layer is dried in the usual manner.
  • the image-receiving material is prepared by grinding 2.1 g. of a mixture of silver behenate and behenic acid (molar ratio 1:1),
  • the dried layer contains about 0.2 g. of silver per m. in the form of the above silver salt.
  • the light-sensitive material is exposed to a 1000 watt source of UV light from a distance of cm. through a positive transparent original for 3 seconds.
  • the exposed layer is then brought into contact with the image-receiving layer and heated to a temperature of 125 C. for 5 seconds.
  • the imagewise exposure may be carried out with an ordinary incandescent lamp (tungsten filament).
  • the tungsten filament lamp has a power of 1500 watt, the exposure time at the same distance between light-sensitive material and source of light is 30 seconds. Subsequent processing is identical. A deep black copy of equally good quality is obtained.
  • a text printed on ordinary paper may be used as original copy. Exposure must in this case be carried out in reflex position. The exposure times are between 15 to 25 seconds under otherwise the same conditions.
  • EXAMPLE 2 Light-sensitive material
  • the light-sensitive material used is the same as in Example 1 except that the pyrazolin-S-one compound contained in it is 1-phenyl-3-methyl-pyrazolin-5-one used in the same quantity.
  • Image-receiving layer The following casting solution is applied to a layer support of baryta paper:
  • Example 1 Processing The material is processed as described in Example 1. A red positive image of the original is obtained on a grey background.
  • Processing The material is exposed for 30 seconds to the reflected light of an ordinary 1500 watt incandescent lamp.
  • the image-receiving material described in Example 1 is used. Processing is carried out in the same way. A sharp dark brown image of the original is obtained.
  • a light-sensitive layer is prepared by dissolving one of the combinations of an azido compound with a pyrazolin- 5-one mentioned in Table IV below in the given proportions in 10 ml. of butanone-2, adding 5 ml. of 5% ethyl cellulose in butanone-2, and applying the solution to a support and drying.
  • the light-sensitive layer is exposed to a 75 watt mercury vapour lamp at a distance of 20 cm. through an original copy for 2;,minutes and then heated to a temperature of 125 C. to 140 C. for 5 to seconds in contact with the image-receiving material of Example 1. Brown to brownish-black copies of the original are obtained.
  • iodine quartz lamps or incandescent lamps may be used as the sources of light.
  • a process for the production of copies including the steps of image-wise exposing a light-sensitive layer which contains a light-sensitive photooxidizing compound and an image-producing compound capable of being transferred to an image-receiving layer, the image-producing compound in the exposed areas being converted into a non-transferable compound by reaction with the light-sensitive compound, bringing the exposed layer into contact with an image-receiving layer which contains compounds which react with the image-producing compound to form colored compounds and heating of the layers while in contact with each other to a temperature at which the image-producing compound is transferred from the unexposed areas of the light-sensitive layer to the image-receiving layer, the improvement consisting of exposing a light-sensitive layer which contains a lightsensitive photooxidizing compound selected from the group consisting of heterocyclic azide, aryl azide, carbonyl azide, sulfonyl azide, and bis-imidazole of the following formula:
  • R R or R represent a group of the naphthyl or phenyl series
  • a pyrazolin-S-one which contains at least one hydrogen atom or a 4-aminopheny1amino group in the 4-position of the pyrazolone ring, said pyrazolin-5-one compound being transferable at a temperature of between 80 C. and 200 C.
  • a light-sensitive photographic composition containing a light-sensitive photooxidans as an oxidizing agent and an image-producing compound that is transferable at least one hydrogen atom or one 4-amino-phenylamino composition is heated, the light-sensitive compound in the exposed areas being capable of reacting with the imageproducing compound to form a non-transferable reaction product
  • the light-sensitive photooxidans is selected from the group consisting of heterocyclic azide, aryl azide, carbonyl azide, sulfonyl azide, and bis-imidazole of the following formula:
  • R R or R represent a group or the naphthyl or phenyl series, and a pyrazolin-S-one being transferable at a temperature of between C. and 200 C.
  • the light-sensitive material contains, as image-producing, transferable compound, a pyrazolin-S-one derivative of the following formula:
  • R is 1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) a heterocyclic group, or (5) cycloalkyl;
  • R is (1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) a heterocyclic group, (5) cycloalkyl, (6) hydroxyl, (7) alkoxy, (8) an amino group, or (9) an alkoxy carbonyl group;
  • R is (1) hydrogen, 2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) an amino group, or (5) alkoxy;
  • R is hydrogen or a 4-aminophenylamino group
  • R and R may also represent the ring members required to complete a 5- or 6-membered carbocyclic or heterocyclic ring.
  • the light-sensitive azide is an azide of the 9azidoacridine, 9-azido-2,3-benzacridine or 4-azidoquinoline series.
  • the light-sensitive material contains, as light-sensitive compounds, a heterocyclic azide of the following formula:
  • the light-sensitive layer contains a merocyanine, a styryl dye or another polymethine sensitizer.
  • the image-receiving layer contains silver salts of a long-chain aliphatic carboxylic acid having 8 to 24 carbon atoms.
  • the image-receiving layer contains a silver salt of an aliphatic carboxylic acid which is substituted with a thioether group.
  • R is (1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) a heterocyclic group, or (5) cycloalkyl;
  • R is (1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) a heterocyclic group, (5) cycloalkyl, (6) hydroxyl, (7) alkoxy, (8) an amino group, or (9) alkoxy carbonyl;
  • R is (1) hydrogen, (2) a saturated or an olefinically unsaturated aliphatic group, (3) aryl, (4) an amino group, or (5) alkoxy;
  • R is hydrogen or a 4-aminophenylamino group
  • R and R may also represent the ring members required to complete a 5- or 6-membered carbocyclic or heterocyclic ring.
  • the light-sensitive material of claim 2 which contains an azide of the 9-azidoacridine, 9-azido-2,3-benzacridine or 4-azidoquinoline series.
  • Z represents the ring members required to complete a S-membered or 6-membered heterocyclic ring which contains nitrogen;
  • Y is an arylene group
  • R or R stand for hydrogon, a saturated or an olefinically unsaturated aliphatic group, aryl, an amino group, halogen, hydroxyl, alkoxy, carboxyl, esterified carboxyl, carbamoyl, sulfo, sulfamoyl or cyano;
  • R and R may be ring members required to complete a condensed benzene or naphthalene ring;
  • n 0 or 1
  • n 0 or 1.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
US00143226A 1970-05-14 1971-05-13 Photographic dry copying material Expired - Lifetime US3728115A (en)

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DE19702023629 DE2023629A1 (de) 1970-05-14 1970-05-14 Photographisches Trockenkopierverfahren

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DE (1) DE2023629A1 (enExample)
FR (1) FR2093503A5 (enExample)
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4040835A (en) * 1974-06-27 1977-08-09 Fuji Photo Film Co., Ltd. Two-equivalent magenta couplers with amido coupling-off groups
US4191573A (en) * 1974-10-09 1980-03-04 Fuji Photo Film Co., Ltd. Photosensitive positive image forming process with two photo-sensitive layers
EP0451561A1 (de) * 1990-03-27 1991-10-16 Morton International, Inc. Photopolymerisierbares Gemisch und daraus hergestelltes Aufzeichnungsmaterial
US20050234020A1 (en) * 2002-06-06 2005-10-20 Smithkline Beecham Corp. Thrombopoietin mimetics
US20190136396A1 (en) * 2017-11-08 2019-05-09 Rohm And Haas Electronic Materials Llc Copper electroplating compositions and methods of electroplating copper on substrates

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4040835A (en) * 1974-06-27 1977-08-09 Fuji Photo Film Co., Ltd. Two-equivalent magenta couplers with amido coupling-off groups
US4191573A (en) * 1974-10-09 1980-03-04 Fuji Photo Film Co., Ltd. Photosensitive positive image forming process with two photo-sensitive layers
EP0451561A1 (de) * 1990-03-27 1991-10-16 Morton International, Inc. Photopolymerisierbares Gemisch und daraus hergestelltes Aufzeichnungsmaterial
AU641486B2 (en) * 1990-03-27 1993-09-23 Hoechst Aktiengesellschaft Photopolymerizable mixture and recording material prepared therefrom
US20050234020A1 (en) * 2002-06-06 2005-10-20 Smithkline Beecham Corp. Thrombopoietin mimetics
US7414040B2 (en) * 2002-06-06 2008-08-19 Smithkline Beecham Corporation Thrombopoietin mimetics
US20190136396A1 (en) * 2017-11-08 2019-05-09 Rohm And Haas Electronic Materials Llc Copper electroplating compositions and methods of electroplating copper on substrates
US10612148B2 (en) * 2017-11-08 2020-04-07 Rohm And Haas Electronic Materials Llc Copper electroplating compositions and methods of electroplating copper on substrates

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Publication number Publication date
FR2093503A5 (enExample) 1972-01-28
DE2023629A1 (de) 1971-12-02
BE766836A (nl) 1971-11-08
CA976800A (en) 1975-10-28
GB1341092A (en) 1973-12-19

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