US3725130A - Method of making tubular battery electrode - Google Patents

Method of making tubular battery electrode Download PDF

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Publication number
US3725130A
US3725130A US00132978A US3725130DA US3725130A US 3725130 A US3725130 A US 3725130A US 00132978 A US00132978 A US 00132978A US 3725130D A US3725130D A US 3725130DA US 3725130 A US3725130 A US 3725130A
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US
United States
Prior art keywords
sheath
yarns
electrode
tube
glass fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00132978A
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English (en)
Inventor
J Andersson
K Lindbergh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tudor AB
Original Assignee
Tudor AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tudor AB filed Critical Tudor AB
Application granted granted Critical
Publication of US3725130A publication Critical patent/US3725130A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/76—Containers for holding the active material, e.g. tubes, capsules
    • H01M4/765—Tubular type or pencil type electrodes; tubular or multitubular sheaths or covers of insulating material for said tubular-type electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/10—Battery-grid making
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making

Definitions

  • the present invention relates to a storage battery electrode of the so-'called tube type, intended primarily for lead batteries, and it relates especially to the sheath that encloses the active material of the electrode. The sheath is necessary to prevent the active material of the electrode from getting loose under the operating conditions of the electrodes.
  • the particular characteristic of the invention is that the material in the electrode sheath is resistant to chemicals and to physical attack that oc curs during charging and discharging of the battery, and at the same time, it is suiciently porous so that the electrolyte can, practically speaking, be unhindered in penetration of the active material.
  • Glass fiber sheaths encased in plastic foil are relatively expensive to manufacture and are relatively thick walled with the resultant disadvantage that with sheaths having equal external diameters, less active material can be accommodated in the electrode, thereby reducing the capacity of the battery.
  • the active material is enclosed in a glass fiber material that is combined with a meltable thermoplastic material in a new way.
  • Meltable plastic or thermoplastic mateirals that are electrolyte resistant can be utilized.
  • Polyoletins, and particularly polyethylene, are preferred materials. In spite of the fact that the good properties of the glass liber material are well known, this material could not be utilized because of the characteristics mentioned above.
  • the suitable properties of polyethylene or other polyoletins in this connection were also well known, but since these materials only hold their shape in relatively large dimensions at the temperatures prevailing in a working battery, they have not been deemed effective for practical use in a sheath for a battery electrode.
  • the principal object of the present invention resides in providing a novel electrode sheath and method wherein the combination yof materials have the requisite properties with respect to chemical resistance and mechanical strength, which could not be anticipated, and also, quite surprisingly, a porosity that is nearly comparable to the porosity of the glass liber hose that is a component of the sheath.
  • the active material of the electrode is surrounded by one or more sheaths which in turn are constituted of a glass ber hose or tube on which powdered polyoleiin has been applied and sintered to provide islands or dots of plastic material which adheres to the yarns to thereby prevent relative movement between different yarns at their points of attachment to the same island of plastic material. It has been found that when the islands of plastic material are concentrated mainly at the crossing points of the yarns of the fabric, there is sufficient rigidity to provide a sheath having good mechanical strength.
  • FIG. l is a view in section of an electrode sheath of the present invention.
  • FIG. 2 is a view similar to FIG. 1 on a larger scale to illustrate how the plastic material during sintering is essentially collected along the yarns and concentrated at the intersections of the yarns;
  • FIG. 3 is a diagrammatic view of an apparatus for production of the electrode sheath of IFIGS. 1 and 2;
  • FIG. 4 is an elevation, in partial section, showing a tube-type plate electrode of the type with which the sheath of FIGS. 1 and 2 is adapted to be used;
  • FIG. 5 is a side view of the electrode of FIG. 4;
  • FIG. 6 shows a circular sheath in the form of a braid which may embody the present invention
  • FIG. 7 shows a circular sheath in the form of a woven material which may embody the present invention.
  • FIG. 8 shows a multiple layer belt which may be sewed to form suitable electrode sheaths which may embody the present invention.
  • the glass Ifiber yarns 1 are shown in the form of a braid. Small islands 2 ⁇ of sintered plastic material are shown mainly at the regions where the yarns 1 cross each other. The plastic material adheres to the yarns rather than bridging over the spaces, which is important in providing the desired porosity. The fact that concentrations of the plastic material occur in the form of islands mainly at the cross-over points serves to prevent slippage or movement of the yarns relative to each other.
  • FIG. 3 shows a means for production of the electrode sheath of the invention.
  • a spool 3 contains a continuous glass ber sleeve or hose 4 that is threaded onto a metallic mandrel 5 which rests on a roll 6, rotating in the direction indicated by the arrow, which roll is covered at its periphery with friction material suitable for causing the glass ber sleeve 4 to be fed onto mandrel 5.
  • the other end of mandrel 5 is borne between the pair of rollers 7, 8 which likewise continuously remove the processed glass ber sleeve.
  • a container 9 is provided which holds pulverized plastic material in the form of a powder 10 which is iluidized by air blown in via blower openings 11.
  • the plastic material is thermoplastic and may be a polyoletin, such as polyethylene.
  • the glass fiber sleeve ⁇ 4 is carried on mandrel 5 through the iluidized powder zone while the sleeve 4 is heated to the melting temperature of the plastic material.
  • the heating means illustrated is a high frequency coil 12 around mandrel 5, which extends on both sides of container 9. As the powder particles are blown upwardly from the blower openings
  • vMandrel 5 passes through a cooling chamber 13. As the glass fiber sleeve passes through chamber 13, the relatively soft, small drops of plastic material harden. Cold air may be used as coolant.
  • the sheath as it is removed from the end of mandrel 5 after passing rollers 7 and 8, is essentially ready for use in a fabrication of the battery electrode, as illustrated for example in FIGS. 4 and 5.
  • the glass fiber tubing is produced in a continuous length and available to be cut to suitable lengths according to the particular battery size in which it will be used.
  • the electrode for a known type of lead-acid storage battery conventionally comprises a plurality of conducting grid rods 14 surrounded by active material 15 and enclosed in a sheath 16.
  • the grid rods 14, after being inserted in a sheath 16 and the active material packed in the space between the outer surface of the rod 14 and the inner surface of sheath 16, are joined at top and bottom by cross strips 17 and 18, of which generally only the upper strip A17 is made of conductive material.
  • a contact lug 18 connects the upper crosspiece
  • the sheath as described in connection with FIGS. l-3 may be used as sheath 16.
  • FIG. 6 ⁇ illustrates a length of sheath where the fibrous material comprises a braid
  • FIG. 7 shows a length of sheath using a woven material.
  • Either type of sheath can be used with the present invention, though with single-ply sheaths, the braiding method is preferable.
  • the electrode sheath is to be made as a multiple-ply sheath with so-called cartridge belt material, as illustrated 4 in FIG. 8, the weaving method would be the most advantageous.
  • Woven fabrics can be sewed together to form suitable electrode sheaths, as is well known, and such sheaths then treated according to the invention.
  • thermoplastic material is a polyolen.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inert Electrodes (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Cell Separators (AREA)
US00132978A 1970-04-16 1971-04-12 Method of making tubular battery electrode Expired - Lifetime US3725130A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE5182/70A SE343433B (xx) 1970-04-16 1970-04-16

Publications (1)

Publication Number Publication Date
US3725130A true US3725130A (en) 1973-04-03

Family

ID=20265882

Family Applications (1)

Application Number Title Priority Date Filing Date
US00132978A Expired - Lifetime US3725130A (en) 1970-04-16 1971-04-12 Method of making tubular battery electrode

Country Status (15)

Country Link
US (1) US3725130A (xx)
JP (1) JPS5815903B1 (xx)
AT (1) AT303854B (xx)
BE (1) BE765891A (xx)
CH (1) CH524254A (xx)
DE (1) DE2113337C3 (xx)
DK (1) DK129886B (xx)
ES (2) ES390166A1 (xx)
FR (1) FR2086126B1 (xx)
GB (1) GB1308096A (xx)
IL (1) IL36540A0 (xx)
NL (1) NL7105193A (xx)
NO (1) NO133821C (xx)
SE (1) SE343433B (xx)
ZA (1) ZA711969B (xx)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3920479A (en) * 1972-12-04 1975-11-18 Tudor Ab Electrodes for storage batteries
US3972728A (en) * 1973-12-17 1976-08-03 Aktiebolaget Tudor Sheath for tubular storage, battery electrodes and method for their production
US4008100A (en) * 1973-12-17 1977-02-15 Aktiebolaget Tudor Sheath for tubular storage battery electrodes and method for their production
US4054402A (en) * 1976-03-01 1977-10-18 Aktiebolaget Tudor Apparatus for producing tubular sheath-like coverings for electrodes
US4161503A (en) * 1976-03-04 1979-07-17 Chloride Group Limited Method of making multitubular sheaths

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT377387B (de) * 1982-10-05 1985-03-11 Akkumulator Es Szarazelemgyar Vorrichtung zur fertigstellung von akkumulatoren -panzerplattentaschen bzw. taschenreihen durch thermofixieren
WO1995008195A1 (en) * 1993-09-13 1995-03-23 Daramic, Inc. Composite gauntet/separator

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL96482C (xx) * 1949-11-23 1900-01-01
GB679514A (en) * 1950-05-25 1952-09-17 Young Accumulator Company Ltd Improvements in or relating to the manufacture of electric battery separators
US2904611A (en) * 1955-12-01 1959-09-15 Electric Storage Battery Co Glass fiber tubing

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3920479A (en) * 1972-12-04 1975-11-18 Tudor Ab Electrodes for storage batteries
US3972728A (en) * 1973-12-17 1976-08-03 Aktiebolaget Tudor Sheath for tubular storage, battery electrodes and method for their production
US4008100A (en) * 1973-12-17 1977-02-15 Aktiebolaget Tudor Sheath for tubular storage battery electrodes and method for their production
US4054402A (en) * 1976-03-01 1977-10-18 Aktiebolaget Tudor Apparatus for producing tubular sheath-like coverings for electrodes
US4161503A (en) * 1976-03-04 1979-07-17 Chloride Group Limited Method of making multitubular sheaths

Also Published As

Publication number Publication date
GB1308096A (en) 1973-02-21
NL7105193A (xx) 1971-10-19
DK129886B (da) 1974-11-25
FR2086126B1 (xx) 1976-03-19
JPS5815903B1 (xx) 1983-03-28
NO133821C (xx) 1976-06-30
IL36540A0 (en) 1971-06-23
FR2086126A1 (xx) 1971-12-31
ZA711969B (en) 1972-01-26
NO133821B (xx) 1976-03-22
ES396548A1 (es) 1974-04-16
DK129886C (xx) 1975-05-05
DE2113337A1 (de) 1971-11-18
DE2113337B2 (de) 1973-11-22
SE343433B (xx) 1972-03-06
CH524254A (de) 1972-06-15
ES390166A1 (es) 1974-05-16
DE2113337C3 (de) 1974-06-27
AT303854B (de) 1972-12-11
BE765891A (fr) 1971-09-16

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