Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
  • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
  • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
  • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C7/00—Purification; Separation; Use of additives
  • C07C7/20—Use of additives, e.g. for stabilisation
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/04—Oxygen-containing compounds
  • C08K5/13—Phenols; Phenolates
  • C08K5/134—Phenols containing ester groups
  • C08K5/1345—Carboxylic esters of phenolcarboxylic acids

Definitions

• ABSTRACT Esters of 3-hydroxy-2,Z-dimethylpropyl 3-hydroxy- 2,2-dimethylpropionate with 3,5-dialkyl-4-hydroxyphenylalkanoic acids are stabilizers of organic material.
• each of R and R is a (lower)alkyl group of from one to four carbon atoms;
• n 1. or 2.
• each of R and R is the same or different (lower)alkyl groups of from one to four carbon atoms, namely, methyl, ethyl, n-propyl, isopropyl, n-butyl, secondary-butyl, isobutyl or tertiary butyl.
• the compounds in this invention can be prepared through esterification of 3-hydroxy-2,2-dimethylpropyl 3-hydroxy-2,Z-dimethylpropionate with a dialkyl-4- hydroxyphenylalkanoic acid derivative of the formula R Il wherein R and R are as previously defined.
• This derivative can be either the free acid, an acid halide thereof such as the acid chloride or acid bromide, or an acid anhydride thereof.
• the esterification is preferably conducted in an inert non-aqueous organic solvent in the presence of an acid catalyst.
• An inert, non-aqueous organic solvent is also preferably employed when the acid halide or anhydride is utilized, together with an acid acceptor such as pyridine or triethylamine.
• 3,5-dialkyl-4-hydroxyphenylalkanoic acid derivatives of 3-hydroxy-2,2-dimethylpropyl 3-hydroxy-2,2-dimethylpropionate are useful as stabilizers or organic materials normally subject to oxidative and thermal deterioration.
• Such organic materials include: synthetic organic polymeric substances such as vinyl resins formed from the polymerization of vinyl halides or from the copolymerization of vinyl halides with unsaturated polymerizable compounds, e.g., vinylesters, a,fi-unsaturated ketones, a,,8-unsaturated aldehydes and unsaturated hydrocarbons such as butadienes and styrene; poly-a-olefins such as polyethylene, polypropylene, polybutylene, polyisoprene, and the like, including copolymers of poly-a-olefins; polyurethanes and polyamides such as polyhexamethylene adipamide and polycaprolactam; polyesters such as polyethylene terephthalates; polycarbonates; polyacetals; polystyrene; polyethyleneoxide; and copolymers such as those of high impact polystyrene containing copolymers of butadiene and styrene
• lubricating oil of the aliphatic ester type i.e., di (2-ethylhexyl) azelate, pentaerythritol tetracaproate, and the like
• animal and vegetable derived oils e.g., linseed oil, fat, tallow, lard, peanut oil, cod liver oil, castor oil, palm oil, corn oil, cottonseed oil, and the like
• hydrocarbon materials such as gasoline, mineral oil, fuel oil, drying oil, cutting fluids, waxes, resins, and the like, salts of fatty acids such as soaps and the like.
• the stabilizers of this invention are employed from about 0.005 percent to about 10 percent by weight of the stabilized composition, although this data... l
• An advantageous range is from about 0.05 percent to about 5 percent and especially 0.05 percent to about 2 percent.
• These compounds are particularly useful for the stabilization of polyolefins such as polypropylene and polyethylene. They can. be blended before polymerization or after polymerization during the usual processing operations, for example, by hot-milling the composition then being extruded, pressed, or the like into films, fibers, filaments, hollowspheres and the like.
• the heat stabilizing properties of these compounds advantageously stabilize the polymer against degradation during such processing at the high temperatures generally encountered.
• the stabilizers can also be dissolved in suitable solvents and sprayed on the surface of films, fabrics, filaments or the like to provide effective stabilization.
• antioxidants sulfur-containing esters such as distearyl-B-thiodipropionate (DSTDP) dilauryl-B-thiodipropionate (DLTDP) in an amount of from 0.01 to 2 percent by weight of the organic material, and the like, pourpoint depressants, corrosion and rust inhibitors, dispersing agents, demulsifiers, antifoaming agents, carbon black, accelerators and other chemicals used in rubber compounding, plasticizers, color stabilizers, diand tri-alkyland -alkylphenylphosphites, heat stabilizers, ultraviolet light stabilizers, dyes, pigments, metal chelating agents, dyesites and the like. Often combinations such as these, particularly the sulfur containing esters, the phosphites and/or the ultraviolet light stabilizers will produce superior results in certain applications to those expected by the properties of the individual components.
• DSTDP distearyl-B-thiodipropionate
• DLTDP dilauryl-B-thi
• EXAMPLE 2 Unstabilized polypropylene powder (Hercules Profax 6501) was thoroughly blended with 0.20 percent by weight of 3-hydroxy-2,2-dimethylpropyl-(3- hydroxy-2,2-dimethylpropionate)-bis[ 3-( 3 ',5 '-di-tbutyl-4'-hydroxyphenyl)propionate]. Also prepared was samples of polypropylene containing 0.1 percent by weight of. the same stabilizer and 0.3 percent by weight of distearylthiodipropionate (DSTDP). bThe blended materials were then milled on a two-roll mill at 182C for minutes, after which time the stabilizer polypropylene was sheeted from the mill and allowed to cool.
• DSTDP distearylthiodipropionate
• Stabilized polypropylene compositions are also obtained when 0.5 percent of 3-hydroxy-2,2-dimethylpropyl-(3-hydroxy-2,2-dimethylpropionate)-bis[3- (3',5'4'-hydroxyphenyl)-propionate] or 0.5 percent of 3-hydroxy-2,2-dimethylpropyl-(3-hydroxy- 2,2-dimethylpropionate)-bis[3-(3'-methyl-5'-t-butyl- 4'-hydroxyphenyl)propionate] are employed alone or in combination with DSTDP.
• EXAMPLE 4 A water-white, refined (U.S.P. grade) mineral oil (Esso PRIMOL D) is stabilized and tested under the following test conditions.
• a sample of the mineral oil (10 g) containing 0.1 percent by weight of 3-hydroxy-2,2-dimethylpropyl-(3- hydroxy-2,Z-dimethyl-propionate)-bis( 3 -methyl-5 '-tbutyl-4-hydroxyphenyl)-acetate] is placed in a Sligh type oxidation flask filled with oxygen at room temperature (25C) and atmospheric pressure. Thereafter, the'flask is sealed to form a system having a mercury manometer which measures the pressure changes as oxygen is absorbed by the sample in the flask. The sample is then heated at 150C until the manometer registers a decrease of 300 mm Hg pressure within the flasks with reference to the maximum pressure obtained at 150C. Results of this test show the increase oxidation resistance for the sample containing the stabilizer.
• High impact polystyrene resin containing elastomer i.e., butadiene-styrene
• elastomer i.e., butadiene-styrene
• the stabilized resin retains a higher percentage of its original elongation properties, whereas the unstabilized resin retains less elongation properties.
• a substantial improvement in stability is also noted when only 0.05 percent of the stabilizer is employed.
• the unstabilized resin is dissolved in chloroform and the stabilizer then added, after which the mixture is cast on a glass plate and the solvent evaporated to yield a uniform film which, upon drying, is removed and cut up, and then pressed for 7 minutes at a temperature of 163C and a pressure of 2,000 pounds per square inch into a sheet of uniform thickness (25 mil).
• the sheets are then cut into strips, approximately 4 X 0.5 inches. A portion of these strips is then measured for length of elongation in the lnstron Tensile tester (Instron Engineering Corporation, Quincy Mass). The remaining portion of the strips is aged in a forced draft oven for 6 weeks at C and thereafter tested for elongation.
• the stabilized polystyrene resin has retained its elongation property much better than the unstabilized resin.
• EXAMPLE 6 A quantity of SBR emulsion containing 100 g of rubber (500 ml of SBR obtained from Texas U.S., Synpol 1500) previously stored under nitrogen, is place in a beaker and stirred vigorously. The pH of the emulsion is adjusted to 10.5 with a 0.5N NaOH solution.
• the coagulated rubber is isolated by filtration through cheese cloth, and rinsed with distilled water. After three subsequent washings with fresh distilled water, the coagulated rubber is dried, first at 25 mm Hg and finally to constant weight under high vacuum 1 mm) at -45C.
• the dried rubber (25 g) is heated under nitrogen at 125C in a Brabender mixer and to this is added with mixing 1.25 g (0.5%)of 3-hydroxy-2,2-dimethylpropyl- (3-hydroxy-2,2-dimethylpropionate)-bis[3-(3',5-di-tbutyl-4hydroxyphenyl)-propoinate].
• the composition is mixed for 5 minutes after which it is cooled and compression molded at 125C into 5 X 5 X 0.025 inch plaques.
• the plaques are placed on aluminum sheets and heated in a circulating air oven at 100C for up to 96 hours.
• the viscosity of a 0.5 percent toluene solution of aged and unaged rubber samples are determined at 25C.
• Stabilizer effectiveness is judged by the percent retention of specific viscosity, color formation and gel content after oven aging.
• the stabilized rubber has better viscosity, color retention, and less gel content than the rubber which is unstabilized after oven aging.
• EXAMPLE 7 To g of polyacetal resin containing 0.1 percent of an acid scavenger dicyandiamide is added 0.5 percent of 3-hydroxy-2,2-dimethylpropyl-(3-hydroxy-2,2- dimethylpropionate )-bis[ 3-( 3 ',5 '-di-t-butyl-4 '-hydroxyphenyl)propionate]. The resin containing this additive is milled for 7 minutes at resistence 200C in a Brabender Plasti-recorder. The milled formulation is subsequently pressed into a 40 mil sheet at 215C at 350 psi for seconds then cooled quickly in a cold press at 350 psi.
• composition 15 prepared comprising linear polyethylene and 1.0 percent by weight of 3-hydroxy- 2,2-dimethylpropyl-(3-hydroxy-2,2-dimethylpropionate)-bis( 3 '-methyl-5 -t-butyl-4 '-hydroxyphenyl)acetate].
• composition is injected molded into 0 tensile bars which are placed in a circulating air oven at 120C.
• tensile bars molded from'the instant composition retained its tensile strength for a substantially longer period.
• Cyclohexene, freshly distilled is stabilized by the addition thereto of 0.05 percent by weight of 3-hydroxy- 2,2-dimethylpropyl-(3-hydroxy-2,2-dimethyl- 20 propionate )-bis[ 3-( 3 '-methyl-5 -t-butyl-4 '-hydroxyphenyl)propionate].
• the effectiveness of this stabilizer in cyclohexene is tested by the ASTM D 525-55 oxidation test.
• the unstabilized cyclohexene fails in shorter time as compared to the stabilized cyclohexene.
• a stabilized high temperature lubricating oil is prepared by incorporating 2 percent by weight of 3- hydroxy-2,2-dimethylpropyl-(3-hydroxy-2,2-dimethyl- 30 propionate)-bis[3-(3',5'-di-t-butyl-4'-hydroxyphen- 35 to the test method described in Military Specification Mil-l-808c. After 72 hours, the blank containing no stabilizer contains more sludge and has a greater viscosity than the stabilized lubricant.
• a compound of the formula 0 (EH: (1) CH: I0 I wherein each of R and R is a (lower)alkyl group of from one to four carbon atoms; m is 1 or 2.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Medicinal Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Materials Engineering (AREA)
• Polymers & Plastics (AREA)
• Analytical Chemistry (AREA)
• Oil, Petroleum & Natural Gas (AREA)
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• Compositions Of Macromolecular Compounds (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

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Citations (1)

• 1971
  • 1971-07-01 US US00159021A patent/US3723503A/en not_active Expired - Lifetime
• 1972
  • 1972-06-12 CA CA144,425A patent/CA973196A/en not_active Expired
  • 1972-06-28 DE DE2231672A patent/DE2231672A1/de active Pending
  • 1972-06-29 GB GB3053172A patent/GB1360164A/en not_active Expired
  • 1972-06-30 IT IT26454/72A patent/IT968196B/it active
  • 1972-06-30 NL NL7209230A patent/NL7209230A/xx unknown
  • 1972-07-03 FR FR727223990A patent/FR2143964B1/fr not_active Expired

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