US3717460A - A method of imaging using interdigitated electrodes, a photoconductive layer and a magnetic imaging layer - Google Patents

A method of imaging using interdigitated electrodes, a photoconductive layer and a magnetic imaging layer Download PDF

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US3717460A
US3717460A US00029584A US3717460DA US3717460A US 3717460 A US3717460 A US 3717460A US 00029584 A US00029584 A US 00029584A US 3717460D A US3717460D A US 3717460DA US 3717460 A US3717460 A US 3717460A
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electrodes
image
interdigitated
recording layer
layer
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S Duck
F Jeffers
J Lemke
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Bell and Howell Co
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G19/00Processes using magnetic patterns; Apparatus therefor, i.e. magnetography

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  • a composite recording medium comprises a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to the photoconductive layer, and-a magnetic recording layer in heat-transfer relationship with and contiguous to the photoconductive layer. Methods and apparatus for magnetically recording an image with the assistance of this composite recording medium are also disclosed.
  • the subject invention relates to magnetic recording and, more particularly, to the magnetic recording of images with the assistance of thermal gradients.
  • magnetic imaging offers the prospect of an avoidance of tim-consuming and delicate chemical processing steps now required in customary photography.
  • Magnetic imaging also ofiers the prospect of an avoidance of expensive and potentially dangerous highvoltage equipment now required in electrostatic xerography and related techniques.
  • the subject invention overcomes or materially alleviates the above mentioned disadvantages and, from one aspect thereof, resides in a method of magnetically recording an image, comprising in combination the steps of providing a plurality of interdigitated first and second electrodes, providing a photoconductive layer in electrical contact with and contiguous to the interdigitated first and second electrodes, and providing in heat-transfer relationship with and contiguous to said photoconductive layer a magnetic image recording layer susceptible to an imagewise change of magnetization in response to a thermal image pattern.
  • This method further includes the steps of connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy and applying electrical energy from said source to the interdigitated first and second electrodes by way of said opposite terminals and exposing the photoconductive layer to the image to provide a thermal pattern corresponding to theimage and constituting the thermal image pattern, and magnetically recording the image by changing the state of magnetization of the recording layer in response to the thermal pattern.
  • the interdigitated first and second electrodes may be located between the photoconductive layer and the magnetic recording layer.
  • This arrangement has the advantage that the electrode structure does not obscure the image-exposed top surface of the photoconductive layer, and
  • At least part of the photoconductive layer may be located between the'interdigitated first and second electrodes and the magnetic recording layer.
  • a preferred embodiment of the invention in accordance with this alternative solution has the photoconductive layer provided with a first side located at the. plurality of interdigitated first and second electrodes, and with a second side opposite such first side.
  • the magnetic recording layer is then provided in heat-transfer relationship with the photoconductive layer through the latter second side of the photoconductive layer.
  • the subject invention resides in a method of magnetically recording an image on a composite recording medium, which medium includes a photoconductive layer, a plurality of inter- I digitated first and second electrodes in'electrical contact with and contiguous to the photoconductive layer, and, contiguous to the photoconductive layer a magnetic image recording layer susceptible to an imagewise change of magnetization in response to a thermal image pattern.
  • This method comprises in combination the steps of applying electrical energy from said source to the interdigitated first and second electrodes by way of said opposite terminals and progressively exposing the photoconductive layer to the image in a direction progressing parallel to the interdigitated electrodes to produce a thermal pattern corresponding to the image and constituting said thermal image pattern, and mag- I netically recording said image by changing the state of magnetization of the recording layer in response to the thermal pattern.
  • the subject invention also resides in apparatus for magnetically recording an image, comprising in combination a plurality of interdigitated first and second electrodes, a photoconductive layer in electrical contact with the interdigitated first and second electrodes, and a magnetic recording layer in heat-transfer relationship with the photoconductive layer.
  • This apparatus further includes means connected to the first and second electrodes for electrically energizing the photoconductive layer, means for exposing the electrically energized photoconductive layer to the image to produce a thermal pattern corresponding to the image, and means operatively associated with said magnetic recording layer for changing the state of magnetization of the recording layer in response to the thermal pat- I tern whereby a magnetic record of the image is established.
  • theinterdigitated first and second electrodes may, for example, be located between the photoconductive layer and the magnetic recording layer or, alternatively, at least part of the photoconductive layer may be located between
  • the subject invention further resides in a composite recording medium operable with a source of electric energy having opposite terminals, comprising in combination a plurality of interdigitated first and second electrodes means for connecting said interdigitated first and second electrodes to opposite terminals, respectively, of said source of electric energy, a photoconductive layer in electrical contact with and contiguous to the interdigitated first and second electrodes, and a thermally responsive magnetic image recording layer in heat-transfer relationship with and contiguous to the photoconductive layer.
  • the photoconductive layer mentioned in the preceding paragraph has a first side located at the named plurality of interdigitated first and second electrodes, and has a second side opposite such first side.
  • the magnetic recording layer is in this embodiment in heat-transfer relationship with the photoconductive layer through the latter second side of the photoconductive layer.
  • the interdigitated electrode structure acts in the manner of a halftone plate which materially improves image resolution and quality.
  • the interdigitated electrode structure greatly facilitates the premagnetization of the magnetic recording layer, which is important where information is recorded by a selective demagnetization of premagnetized material.
  • thermomagnetic imaging effect requires that the transparent top electrode in sandwich-type arrangements has to have a considerable thickness, which can lead to severe transmission losses in the incoming image.
  • our interdigitated electrode structure does not impair light transmission in the areas between the conductors. This feature alone permits an increase in sensitivity by a factor of two or more, despite the fact that sity required for the operation of the recording medium is accomplished, and a superior rheology is still preserved, since every light-exposed point is serviced by two adjacent electrodes.
  • FIG. 1 is a perspective view of an imaging apparatus in accordance with a preferred embodiment of the subject invention
  • FIG. 2 illustrates a first phase in the operation of the apparatus of FIG. 1;
  • FIG. 3 illustrates further phases in the operation of the apparatus of FIG. 1.
  • the apparatus 10 of FIG. 1 includes a composite photoelectromagnetic recording medium 12 which embodies-key features of the subject invention.
  • the composite recording medium 12 includes a transparent substrate 13 which may be a sheet of glass or an organic equivalent thereof, such as a transparent high-temperature polyimide or polybenzamidazole.
  • An interdigitated electrode structure 14 including interdigitated first and second electrodes 15 and 16 is preferably located on the transparent substrate 13, although the electrodes may alternatively be located on the photoconductive layer presently to be described.
  • the deposition of electrode structures on a transparent substrate is a well-established art and does not as such form part of the subject invention. Suffice to say therefore, that the electrode structure 14 may be deposited on the substrate 13 by evaporation, painting or sputtering, and that preferred electrode materials include gold, indium, chromium, and aluminum.
  • a photoconductive layer 18 is deposited on the substrate 13 and electrode structure 14.
  • Suitable photoconductive materials include cadmium sulfide, cadmium selenide, alloys of cadmium sulfide or cadmium selenide, and sensitized zinc sulfide.
  • High-gain photoconductor materials are presently preferred, since they provide for the large currents needed for heating of the magnetic material but require only moderate input light levels.
  • the thickness of the layer 18 is not generally critical, but a layer thickness of about 3 to 10 microns is presently preferred for resolutions of more than about ten line pairs per millimeter.
  • the composite recording medium 12 further includes a magnetic recording layer 20 which ispressed against, coated on, or deposited on the photoconductive layer 18, to be in heat-transfer relationship therewith.
  • a magnetic recording layer 20 which ispressed against, coated on, or deposited on the photoconductive layer 18, to be in heat-transfer relationship therewith.
  • Several materials and types of materials are suitable as a magnetic recording medium in the layer 20.
  • Presently preferred materials for the magnetic recording layer 20 include low-Curie point media of the type described in U.S. Pat. No. 3,176,278, by L]. Mayer, issued Mar. 30, 1965, U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966, U.S. Pat. No. 3,368,209, by McGlauchlin et al., issued Feb. 6, 1968, U.S. Pat. No.
  • a magnetic recording medium 20 that has an acute temperature-dependent transition between the ferromagnetic and paramagnetic states at the Curie point.
  • the preferred acuity may, according to the allowed'U.S. Pat. application, Ser. No. 649,540, Magnetic Information Recording, filed June 28, 1967, by James U. Lemke, and assigned to the subject assignee, now US. Pat. No. 3,541,577, be realized by providing the low- Curie point magnetic particles with a shape anisotropy that dominates their crystal anisotropy.
  • Two preferred magnetic recording techniques include information-selective thermal demagnetization and information-selective thermoremanent magnetization.
  • selective demagnetization the recording medium 20 is typically premagnetized and is thereupon demagnetized by above-Curie point heating until the remaining magnetized areas present a record of the input image.
  • thermoremanent magnetization a thermal pattern which represents the input image is imposed upon the typically unmagnetized recording medium 20 so that selected portions of that medium are heated above Curie point. These portions are thereupon cooled in the presence of a magnetic field whereby a thermoremanent magnetization of the type described by CD.
  • the apparatus further includes a source of light 22, such as an incandescent lamp or a fluorescent tube, which is energized from an electric power source 23 and which is combined with a reflector and shade 24 that defines a narrow longitudinal slit 25 for the emission of a sheet of light 26.
  • the light sheet is reflected by a mirror 28 which is tiltable about a longitudinal axis 29 and which reflects the impinging light in the form of a light sheet 30 onto a master record 31 that may, for instance, be supported on a sheet of glass (not shown).
  • the light 32 reflected by the master record 31 is imaged by a lens 34 onto the interdigitated electrode structure 14 and photoconductive layer 18.
  • the first and second electrodes 15 and 16 of the interdigitated electrode structure 14 are connected to opposite terminals of a source of electric energy 36.
  • a switch 37 and a variable resistor 38 are connected in this circuit to control timing and intensity of the current flow to the electrode structure 14 and through the photoconductor layer 18.
  • the apparatus 10 requires means for magnetizing portions of the magnetic recording layer 20 that, after an image-wise thermal exposure, cool down through the Curie point of the magnetic recording medium. If the magnetic record is to be established by selective demagnetization, then the apparatus 10 requires means for premagnetizing the magnetic recording layer 20 prior to its image-wise thermal exposure.
  • the same elongated magnetizing head 40 may be employed for both methods with the difference that the magnetic field provided by the head 40 is applied to the magnetic recording layer 20 prior to image exposure if the record is to be established by selective demagnetization, and is applied after thermal I exposure during the subsequent cooling step if the record is to be established by thermoremanent magnetization.
  • the illustrated apparatus 10 operates with a combination of the two methods by imposing a premagnetization through the agency of thermoremanent magnetization and by establishing the magnetic record by an image-wise selective demagnetization.
  • the magnetizing head 40 has an air gap 42, as well as an energizing winding 43 which is connected to a source of electric energy 44 through a switch 45 and a 1 variable resistor 46 which serve to control the timing and intensity of the magnetic field 48 provided at the air gap 42.
  • the photocon ductive layer 18 and interdigitated electrode structure 14 are subjected to a uniform exposure.
  • a flood lamp (not shown) which uniformly irradiates the electrode structure 14 and photoconductive layer 18 may be provided for this purpose.
  • a light exposure which operates within a narrow exposure band 50 that extends across the, alternating electrodes 15 and 16 and that progresses in the direction of an arrow 51 parallel to the electrode 15 and 16 is, however, preferred for two reasons. First, if the exposure is at any instant limited to a narrow exposure band, then the intensity of electric current flow is very substantially reduced relative to intensities that would occur if the entire composite medium were exposed at that instant.
  • a light-reflecting element 53 is initially substituted for the master record 31.
  • the reflecting element 53 may, for
  • the exposure band 50 is then swept across the composite recording medium 20 in the direction of the arrow 51 by a tilting of the mirror 28 about its axis 29.
  • This tilting motion is effected by a drive 54 which is coupled to the mirror 28 and also to the magnetizing head 40 so as to move this head in the direction of an arrow 56 and in proportion to the tilting motion of the mirror 28, in such mutual synchronism that the magnetic field 48, which extends across the magnetic recording layer 20, follows the exposure band 50 in the direction of the arrow 51.
  • the switch 37 is closed and the variable resistor 38 is adjusted to supply sufficient electrical energy to the interdigitated electrode structure 14 so that successive portions of the magnetic recording layer are heated above the Curie point of the magnetic recording medium, and do thereupon cool through the Curie point as the exposure band 50 travels along the arrow 51.
  • the position of the traveling magnetizing head 40 relative to the moving exposure band 50 is selected such that the magnetic field 48, which extends in parallel to the exposure band 50, trails this exposure band at such a distance that the magnetic field 48 is successively present at all the magnetic layer portions that cool back through their Curie point.
  • thermoremanent magnetization In preparation of this thermoremanent magnetization, the switch 45 is closed and the variable resistor 46 is adjusted so that the magnetic field 48 has an intensity which is insufficient to magnetize the layer 20 while the same remains at a temperature below its Curie point, but which is sufficient to magnetize portions of the layer 20 that cool through their Curie point.
  • thermoremanent magnetization has the highest'efficiency and linearity for all forms of magnetization.
  • the source which energizes the magnetizing head 40 may be a source of direct current, in which case the thermoremanent premagnetization produces in the layer 20 a pattern of magnetized lines that extend in parallel to the electrodes and'l6 and occupy regions mal diffusion from adjacent regions, but a diffusion effeet can easily-be overcome by decreasing the light intensity of. the source 22 or by increasing the travelingspeed of the exposure region 50, or by a combination of
  • a line-pattern premagnetization provides a multitude of sharp magnetic gra'dien ts which promote large-area fill-in, increased contrast and increased resolution.
  • the reflecting element 53 may be provided with a pattern of alternatinglight-reflecting and light-absorbing areas, or the source 44 may be a source of current pulses, whereby every line 58 is only magnetized along spaced points, as shown at 60. Point-patterns are sometimes preferred toline-patterns as is well known in the book and newspaper printing arts.
  • each of the premagnetization lines 58 possesses a pattern of alternating magnetizations as shown in FIG. 2 at 62. In practice, this corresponds to a point-pattem magnetization, since no magnetizing effect takes place at and adjacent the zero crossovers of the alternating current. A strong toner attraction may result in this type of pattern from the alternating polarity of the magnetized points.
  • the reflecting element 53 is replaced by an information master record 31 that may, for instance, be a drawing, a writing or a printed text.
  • an information master record 31 may, for instance, be a drawing, a writing or a printed text.
  • the master record 31 is a white sheet of paper on which a black character 65 has been printed.
  • the switch 45 is opened and the magnetizing head 40 is decoupled from the drive 54 so that no magnetic field 48 follows the exposure band 50.
  • the mirror 28 is, however, coupled to the drive 54 so that the light sheet 30 is moved across the master record 31 whereby successive portions of the master record are illuminated within a traveling narrow band 64.
  • the lens 34 images the band 64 onto the composite recording medium 12 whereby the latter is exposed within an exposure band 50 that travels in the direction of the arrow 51.
  • the switch 37 is again closed and the variable resistor 38 adjusted so thatelectric currents in the photoconductive layer 18 heat the magnetic recording layer 20 above its Curie point at locations at which light reflected by the white background of the master record 31 impinges on the photoconductive layer 18.
  • This above-Curie point heating causes a demagnetization of the recording layer 20 or of its premagnetized line or point pattern.
  • An application of magnetic fields to the recording layer 20 is avoided at this stage to preclude an undesired remagnetization of demagnetized areas through the agency of thermoremanent magnetization.
  • a further substantial advantage of the apparatus, methods and media of the subject invention may be considered at this juncture.
  • Information recording methods that rely on a selective demagnetization of a premagnetized medium are frequently hampered by the fact that areas which have been demagnetized are remagnetized by the magnetic information record itself -when the recording medium cools back through its 18 located midway between adjacent electrodes and 16 tend to acquire a higher temperature than areas corresponding to points located more closely to the electrodes.
  • the reason for this resides in the fact that the photoconductive layer portions below the electrodes 16 remain dark and do thus not produce heat-generating electric currents, and that the electrodes themselves provide a heat-sink effect.
  • the premagnetization lines 58, 60 or 62 can easily be made narrow and spaced from each other whereby a thermoremanent remagnetization efiect brought about by the information record during cooling will limit itself to a broadeningof the premagnetization lines or points until the same have dimensions desired for a printout of the magnetic image.
  • This broadening is very beneficial since the thermoremanent magnetization effect under discussion typically provides magnetized fringes that have a polarity opposite to the magnetic polarity of the adjacent regions whereby strong magnetic gradients provide a sharp outline of the details of the magnetic image.
  • the magnetic image 68 may be stored in the magnetic recording medium and'printed out as often as desired.
  • a magnetic toner 70 may be applied to the magnetic image 68 to render the same visible or printable.
  • Magnetic toners typically comprise magnetically attractable particles 72 in powdered form or liquid suspension.
  • Suitable materials for the toner particles 72' include iron, nickel, cobalt'or ferromagnetic alloys.
  • preferred materials for the toner particles72 include submicron particles of iron, carbonyl iron, and magnetite (Fe O Magnetic toners, toning techniques, and toning apparatus are disclosed in U.S. Pat. No. 2,932,278, by .l.C. Sims, issued Apr. 12, 1960; U.S. Pat. No. 3,052,564, by F.W. Kulesza, issued Sept. 4, 1962; and U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966.
  • the toner image 74 resulting from a toning of the magnetic image 68 may be printed out on a sheet of paper, on a film, or on another material having similar surface qualities.
  • a sheet of paper 75 may be provided with an adhesive coating 76 to assure a transfer and retention of the toner image 74 in the form of a copy 78 of the original character 65.
  • the adhesive paper 75 is pressed onto the magnetic recording layer 20 and is thereupon removed whereby the toner image 74 adheres to and is pulled off together with the paper 75.
  • the toner 70 may be present in the form of a magnetic ink that is absorbed by the paper 75, or the toner particles may be provided with shells of a thermoplastic or other fusible material that may be fused to the paper 75 by a combination of pressure and heat. No adhesive coating 76 is provided if a magnetic ink or a fusible material is employed.
  • the magnetic image 68 may be erased by such conventional methods as an exposure of the magnetic recording layer 20 to anhysteretic magnetic erasing fields, or to above-Curie point heating. The latter may be efiected by a sweeping of the light sheet 32 across the interdigitated electrode structure 14 and photoconductive layer 18, while the electrodes are connected to the electric energy source 36 and the reflective element 53 is substituted for the information record 31.
  • any exposed point of the photoconductive layer is serviced by two current supply electrodes. If a light exposure shifts in the direction of the arrow 51, then an increase in electrical resistance along an electrode 15 is automatically compensated by a corresponding decrease in electrical resistance along an adjacent electrode l6. Electrode sheets, on the other hand, do not provide a similar favorable rheology so that contrast, resolution and quality of image points tend to be dependent on the location of the particular point relative to the edges of the recording medium.
  • said photoconductive layer is provided with a first side located at said plurality of interdigitated first and second electrodes, and with a second side opposite said first side; and 1 said magnetic recording layer is provided in heattransfer relationship with said photoconductive to said pattern so as to demagnetize said portions of said recording layer.
  • said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
  • thermoremanent magnetization including a heating of said recording layer with the assistance of an electrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
  • said photoconductive layer is progressively exposed to said image in a direction progressing in parallel to said interdigitated electrodes.
  • said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes.
  • a method of magnetically recording an image on a composite recording medium which medium includes a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to said photoconductive layer, and, in heat-transfer relationship with and contiguous to said photoconductive layer, a magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern, comprising in combination the steps of:
  • said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes.
  • the state of magnetization of said recording layer is changed by premagnetizing said recording layer and heating with said thermal pattern portions of said premagnetized recording layer corresponding to said pattern so as to demagnetize said portions of said recording layer.
  • said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
  • thermoremanent agnetiza io including a heatin of said recording ayer wit t e assistance of an e ectrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
  • a composite photoelectric recording medium operable with a source of electric energy having opposite terminals comprising in combination:
  • a transparent substrate carrying said interdigitated first and second electrodes and said photoconductive layer.
  • said photoconductive layer has a first side located at said plurality of interdigitated first and second electrodes, and a second side opposite said first side;
  • said magnetic recording layer is in heat-transfer relationship with said photoconductive layer through said second side of said photoconductive layer.

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Abstract

A composite recording medium comprises a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to the photoconductive layer, and a magnetic recording layer in heat-transfer relationship with and contiguous to the photoconductive layer. Methods and apparatus for magnetically recording an image with the assistance of this composite recording medium are also disclosed.

Description

United States Patent 1191 Duck et a1.
[54] METHOD OF IMAGING USING INTERDIGITATED ELECTRODES, A PHOTOCONDUCTIVE LAYER AND A MAGNETIC IMAGING LAYER [75] Inventors: Sherman W. Duck, Alhambra;
Frederick J. Jeffers, Altadena; James U. Lemke, Del Mar, all of Calif.
[73] Assignee: Bell & Howell Company, Chicago,
Ill.
[22] Filed: April 17, 1970 21 Appl. Nb; 29,584
[52] US. Cl, ..96/l R, 96/1.5, 96/1 E, 346/74 M, 346/74 MT, 117/211, 117/212, 117/215,117/217,l17/21,8
' s11 lnt.Cl. ..o03 13/14,o03 13/22 [58] Field of Search ..96/11.5, 1, l E; 346/74 MT 51 Feb. 20, 1973 [56] References Cited Y UNITED STATES PATENTS 3,485,621 12/1969 Kazan ..96/1
3,288,602 1 1/1966 Snelling et a1. ..96/l 2,836,766 5/1958 Halstead 96/1.5 X 2,798,959 7/1957 Moucrieff-Yeates.... ..96/l E Primary Examiner-George F. Lesmes Assistant Examiner-Roland E. Martin, Jr. Attorney-Luc P. Benoit [57] ABSTRACT A composite recording medium comprises a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to the photoconductive layer, and-a magnetic recording layer in heat-transfer relationship with and contiguous to the photoconductive layer. Methods and apparatus for magnetically recording an image with the assistance of this composite recording medium are also disclosed.
15 Claims, 3 Drawing Figures I PATfiNTEflr azbl'sis I IN VENTORS SHERMAN w. DUCK FREDERICK J. JEFFERS JAMES u. LEMKE Arne v5)",
METHOD OF IMAGING USING INTERDIGITATED ELECTRODES, A PI-IOTOCONDUCTIVE LAYER AND A MAGNETIC IMAGING LAYER BACKGROUND OF THE INVENTION 1. Field of the Invention The subject invention relates to magnetic recording and, more particularly, to the magnetic recording of images with the assistance of thermal gradients.
2. Description of the Prior Art Magnetic imaging has been the subject of serious investigation in. recent years, since it has several advantages over more conventional imaging techniques.
For instance, magnetic imaging offers the prospect of an avoidance of tim-consuming and delicate chemical processing steps now required in customary photography. Magnetic imaging also ofiers the prospect of an avoidance of expensive and potentially dangerous highvoltage equipment now required in electrostatic xerography and related techniques.
Unfortunately, magnetic imaging techniques which have become publically known to date cannot compete in terms of light sensitivity and exposure speed with photographic methods or even with electrostatic xerography.
SUMMARY OF INVENTION The subject invention overcomes or materially alleviates the above mentioned disadvantages and, from one aspect thereof, resides in a method of magnetically recording an image, comprising in combination the steps of providing a plurality of interdigitated first and second electrodes, providing a photoconductive layer in electrical contact with and contiguous to the interdigitated first and second electrodes, and providing in heat-transfer relationship with and contiguous to said photoconductive layer a magnetic image recording layer susceptible to an imagewise change of magnetization in response to a thermal image pattern. This method further includes the steps of connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy and applying electrical energy from said source to the interdigitated first and second electrodes by way of said opposite terminals and exposing the photoconductive layer to the image to provide a thermal pattern corresponding to theimage and constituting the thermal image pattern, and magnetically recording the image by changing the state of magnetization of the recording layer in response to the thermal pattern.
By way of example, the interdigitated first and second electrodes may be located between the photoconductive layer and the magnetic recording layer. This arrangement has the advantage that the electrode structure does not obscure the image-exposed top surface of the photoconductive layer, and
that heat imparted to the electrodes is readily transferred to the magnetic recording layer.
Alternatively, at least part of the photoconductive layer may be located between the'interdigitated first and second electrodes and the magnetic recording layer. A preferred embodiment of the invention in accordance with this alternative solution has the photoconductive layer provided with a first side located at the. plurality of interdigitated first and second electrodes, and with a second side opposite such first side. The magnetic recording layer is then provided in heat-transfer relationship with the photoconductive layer through the latter second side of the photoconductive layer.
The latter alternative solution is presently preferred because available techniques favor the provision of an electrode structure on a substrate over the provision of an electrode structure on a photoconductive layer, and because problems of light absorption by the photoconductive layer are alleviated if the electrodes are at the image-exposed side of the photo-conductive layer.
From another aspect thereof, the subject invention resides in a method of magnetically recording an image on a composite recording medium, which medium includes a photoconductive layer, a plurality of inter- I digitated first and second electrodes in'electrical contact with and contiguous to the photoconductive layer, and, contiguous to the photoconductive layer a magnetic image recording layer susceptible to an imagewise change of magnetization in response to a thermal image pattern. This method comprises in combination the steps of applying electrical energy from said source to the interdigitated first and second electrodes by way of said opposite terminals and progressively exposing the photoconductive layer to the image in a direction progressing parallel to the interdigitated electrodes to produce a thermal pattern corresponding to the image and constituting said thermal image pattern, and mag- I netically recording said image by changing the state of magnetization of the recording layer in response to the thermal pattern.
The subject invention also resides in apparatus for magnetically recording an image, comprising in combination a plurality of interdigitated first and second electrodes, a photoconductive layer in electrical contact with the interdigitated first and second electrodes, and a magnetic recording layer in heat-transfer relationship with the photoconductive layer. This apparatus further includes means connected to the first and second electrodes for electrically energizing the photoconductive layer, means for exposing the electrically energized photoconductive layer to the image to produce a thermal pattern corresponding to the image, and means operatively associated with said magnetic recording layer for changing the state of magnetization of the recording layer in response to the thermal pat- I tern whereby a magnetic record of the image is established.
As already indicated above in connection with a method aspect of the subject invention, theinterdigitated first and second electrodes may, for example, be located between the photoconductive layer and the magnetic recording layer or, alternatively, at least part of the photoconductive layer may be located between The subject invention further resides in a composite recording medium operable with a source of electric energy having opposite terminals, comprising in combination a plurality of interdigitated first and second electrodes means for connecting said interdigitated first and second electrodes to opposite terminals, respectively, of said source of electric energy, a photoconductive layer in electrical contact with and contiguous to the interdigitated first and second electrodes, and a thermally responsive magnetic image recording layer in heat-transfer relationship with and contiguous to the photoconductive layer.
In accordance with a presently preferred embodiment of the subject invention, the photoconductive layer mentioned in the preceding paragraph has a first side located at the named plurality of interdigitated first and second electrodes, and has a second side opposite such first side. The magnetic recording layer is in this embodiment in heat-transfer relationship with the photoconductive layer through the latter second side of the photoconductive layer.
The above mentioned combination of photoconductive layer, interdigitated electrodes, and magnetic recording medium constitutes an important feature of the subject invention, either by itself or in combination with other features.
To be sure, the use of interdigitated electrodes on photoconductors is old in the art of photoelectric devices. In the field of electrophotography, however, to a subgroup of which the subject invention belongs, the use of interdigitated electrodes on one side of the photoconductive layer has so far been generally rejected, and emphasis has been placed on the use of sandwich configurations in which thephotoconductive layer is located between a pair of sheet-like electrodes.
In the course of intensive investigations into magnetic imaging we have, however, been able to reach the conclusion that the prior-art bias is unfounded and that an interdigitated electrode approach presents, indeed, the best overall solution as far as the particular field of magnetic imaging is concerned.
In particular, we have found that the interdigitated electrode structure acts in the manner of a halftone plate which materially improves image resolution and quality. We have also found that the interdigitated electrode structure greatly facilitates the premagnetization of the magnetic recording layer, which is important where information is recorded by a selective demagnetization of premagnetized material.
We have also found in the course of extensive tests that composite magnetic recording media of the type herein disclosed with interdigitated electrode structures display less sensitivity to pin holes and lumps in the photoconductor. In sandwich-type photoconductive media, these-irregularities lead to very annoying ef-, fects in the printed-out image.
We have further come to the conclusion that the heavy electric currents required for the thermomagnetic imaging effect require that the transparent top electrode in sandwich-type arrangements has to have a considerable thickness, which can lead to severe transmission losses in the incoming image. In contrast thereto, our interdigitated electrode structure does not impair light transmission in the areas between the conductors. This feature alone permits an increase in sensitivity by a factor of two or more, despite the fact that sity required for the operation of the recording medium is accomplished, and a superior rheology is still preserved, since every light-exposed point is serviced by two adjacent electrodes.
BRIEF DESCRIPTION OF THE DRAWINGS The invention will become more readily apparent from the following detailed description of preferred embodiments thereof, illustrated by way of example in the accompanying drawings, in which:
FIG. 1 is a perspective view of an imaging apparatus in accordance with a preferred embodiment of the subject invention;
FIG. 2 illustrates a first phase in the operation of the apparatus of FIG. 1; and
FIG. 3 illustrates further phases in the operation of the apparatus of FIG. 1.
DESCRIPTION OF PREFERRED EMBODIMENTS The apparatus 10 of FIG. 1 includes a composite photoelectromagnetic recording medium 12 which embodies-key features of the subject invention. The composite recording medium 12 includes a transparent substrate 13 which may be a sheet of glass or an organic equivalent thereof, such as a transparent high-temperature polyimide or polybenzamidazole.
An interdigitated electrode structure 14 including interdigitated first and second electrodes 15 and 16 is preferably located on the transparent substrate 13, although the electrodes may alternatively be located on the photoconductive layer presently to be described. The deposition of electrode structures on a transparent substrate is a well-established art and does not as such form part of the subject invention. Suffice to say therefore, that the electrode structure 14 may be deposited on the substrate 13 by evaporation, painting or sputtering, and that preferred electrode materials include gold, indium, chromium, and aluminum.
A photoconductive layer 18 is deposited on the substrate 13 and electrode structure 14. Suitable photoconductive materials include cadmium sulfide, cadmium selenide, alloys of cadmium sulfide or cadmium selenide, and sensitized zinc sulfide. High-gain photoconductor materials are presently preferred, since they provide for the large currents needed for heating of the magnetic material but require only moderate input light levels. The thickness of the layer 18 is not generally critical, but a layer thickness of about 3 to 10 microns is presently preferred for resolutions of more than about ten line pairs per millimeter.
The composite recording medium 12 further includes a magnetic recording layer 20 which ispressed against, coated on, or deposited on the photoconductive layer 18, to be in heat-transfer relationship therewith. Several materials and types of materials are suitable as a magnetic recording medium in the layer 20. Presently preferred materials for the magnetic recording layer 20 include low-Curie point media of the type described in U.S. Pat. No. 3,176,278, by L]. Mayer, issued Mar. 30, 1965, U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966, U.S. Pat. No. 3,368,209, by McGlauchlin et al., issued Feb. 6, 1968, U.S. Pat. No. 3,364,496, by Greiner et al., issued Jan. 16, 1968, and British Pat. Specification No. 1,139,232, filed Apr. 27, 1966 by E.l. du Pont de Nemours and Company. Presently preferred media include MnAs films and ferromagnetic chromium dioxide.
In the composite recording medium 12 we prefer the use of a magnetic recording medium 20 that has an acute temperature-dependent transition between the ferromagnetic and paramagnetic states at the Curie point. Where this is not inherent in the material, the preferred acuity may, according to the allowed'U.S. Pat. application, Ser. No. 649,540, Magnetic Information Recording, filed June 28, 1967, by James U. Lemke, and assigned to the subject assignee, now US. Pat. No. 3,541,577, be realized by providing the low- Curie point magnetic particles with a shape anisotropy that dominates their crystal anisotropy. v
Two preferred magnetic recording techniques include information-selective thermal demagnetization and information-selective thermoremanent magnetization. In selective demagnetization the recording medium 20 is typically premagnetized and is thereupon demagnetized by above-Curie point heating until the remaining magnetized areas present a record of the input image. In thermoremanent magnetization a thermal pattern which represents the input image is imposed upon the typically unmagnetized recording medium 20 so that selected portions of that medium are heated above Curie point. These portions are thereupon cooled in the presence of a magnetic field whereby a thermoremanent magnetization of the type described by CD. Mee, The Physics of Magnetic Recording (North-Holland Publishing Company, 1964), pp. 80-84, and in the above mentioned Greiner et al'. U.S. Patent and British du Pont Patent Specification takes place. If desired, strong positive magnetic records may be produced in the manner disclosed in Patent application, Ser. Nos. 821,232 and 821,432, filed by Luc P. Benoit on May 2, 1969, and assigned to the subject assignee, now U.S. Pat. Nos. 3,61 1,420 and 3,582,877 respectively. As will become apparent in the further course of this disclosure, either of these magnetic recording techniques, or acombination of these techniques to be more fully described below may be employed for recording the magnetic image.
The apparatus further includes a source of light 22, such as an incandescent lamp or a fluorescent tube, which is energized from an electric power source 23 and which is combined with a reflector and shade 24 that defines a narrow longitudinal slit 25 for the emission of a sheet of light 26. The light sheet is reflected by a mirror 28 which is tiltable about a longitudinal axis 29 and which reflects the impinging light in the form of a light sheet 30 onto a master record 31 that may, for instance, be supported on a sheet of glass (not shown).
The light 32 reflected by the master record 31 is imaged by a lens 34 onto the interdigitated electrode structure 14 and photoconductive layer 18.
The first and second electrodes 15 and 16 of the interdigitated electrode structure 14 are connected to opposite terminals of a source of electric energy 36. A switch 37 and a variable resistor 38 are connected in this circuit to control timing and intensity of the current flow to the electrode structure 14 and through the photoconductor layer 18.
If the magnetic record is to be established by thermoremanent magnetization, then the apparatus 10 requires means for magnetizing portions of the magnetic recording layer 20 that, after an image-wise thermal exposure, cool down through the Curie point of the magnetic recording medium. If the magnetic record is to be established by selective demagnetization, then the apparatus 10 requires means for premagnetizing the magnetic recording layer 20 prior to its image-wise thermal exposure. The same elongated magnetizing head 40 may be employed for both methods with the difference that the magnetic field provided by the head 40 is applied to the magnetic recording layer 20 prior to image exposure if the record is to be established by selective demagnetization, and is applied after thermal I exposure during the subsequent cooling step if the record is to be established by thermoremanent magnetization. v
By way of example, it is assumed that the illustrated apparatus 10 operates with a combination of the two methods by imposing a premagnetization through the agency of thermoremanent magnetization and by establishing the magnetic record by an image-wise selective demagnetization.
The magnetizing head 40 has an air gap 42, as well as an energizing winding 43 which is connected to a source of electric energy 44 through a switch 45 and a 1 variable resistor 46 which serve to control the timing and intensity of the magnetic field 48 provided at the air gap 42.
To provide for a premagnetization, the photocon ductive layer 18 and interdigitated electrode structure 14 are subjected to a uniform exposure. A flood lamp (not shown) which uniformly irradiates the electrode structure 14 and photoconductive layer 18 may be provided for this purpose. A light exposure which operates within a narrow exposure band 50 that extends across the, alternating electrodes 15 and 16 and that progresses in the direction of an arrow 51 parallel to the electrode 15 and 16 is, however, preferred for two reasons. First, if the exposure is at any instant limited to a narrow exposure band, then the intensity of electric current flow is very substantially reduced relative to intensities that would occur if the entire composite medium were exposed at that instant. Secondly, it is easier to impose a premagnetization that has the requisite uniformity over the recording layer if such premagnetization takes place successively along a progressing band, rather than over the entire recording layer at once. Also, the total electric current flow is distributed over the electrodes if the exposure band extends across the electrodes rather. than parallel thereto.
Accordingly, a light-reflecting element 53, only part of which has been shown, is initially substituted for the master record 31. The reflecting element 53, may, for
these measures.
instance, include a white sheet of paper or a mirror. The exposure band 50 is then swept across the composite recording medium 20 in the direction of the arrow 51 by a tilting of the mirror 28 about its axis 29. This tilting motion is effected by a drive 54 which is coupled to the mirror 28 and also to the magnetizing head 40 so as to move this head in the direction of an arrow 56 and in proportion to the tilting motion of the mirror 28, in such mutual synchronism that the magnetic field 48, which extends across the magnetic recording layer 20, follows the exposure band 50 in the direction of the arrow 51.
The switch 37 is closed and the variable resistor 38 is adjusted to supply sufficient electrical energy to the interdigitated electrode structure 14 so that successive portions of the magnetic recording layer are heated above the Curie point of the magnetic recording medium, and do thereupon cool through the Curie point as the exposure band 50 travels along the arrow 51. The position of the traveling magnetizing head 40 relative to the moving exposure band 50 is selected such that the magnetic field 48, which extends in parallel to the exposure band 50, trails this exposure band at such a distance that the magnetic field 48 is successively present at all the magnetic layer portions that cool back through their Curie point.
In preparation of this thermoremanent magnetization, the switch 45 is closed and the variable resistor 46 is adjusted so that the magnetic field 48 has an intensity which is insufficient to magnetize the layer 20 while the same remains at a temperature below its Curie point, but which is sufficient to magnetize portions of the layer 20 that cool through their Curie point. As is known in magnetics, thermoremanent magnetization has the highest'efficiency and linearity for all forms of magnetization.
The source which energizes the magnetizing head 40 may be a source of direct current, in which case the thermoremanent premagnetization produces in the layer 20 a pattern of magnetized lines that extend in parallel to the electrodes and'l6 and occupy regions mal diffusion from adjacent regions, but a diffusion effeet can easily-be overcome by decreasing the light intensity of. the source 22 or by increasing the travelingspeed of the exposure region 50, or by a combination of In contrast to a uniform premagnetization, a line-pattern premagnetization provides a multitude of sharp magnetic gra'dien ts which promote large-area fill-in, increased contrast and increased resolution.
If a point-pattern, rather than a line-pattem, is desired, then the reflecting element 53 may be provided with a pattern of alternatinglight-reflecting and light-absorbing areas, or the source 44 may be a source of current pulses, whereby every line 58 is only magnetized along spaced points, as shown at 60. Point-patterns are sometimes preferred toline-patterns as is well known in the book and newspaper printing arts.
If the source 44 is a source of alternating current, each of the premagnetization lines 58 possesses a pattern of alternating magnetizations as shown in FIG. 2 at 62. In practice, this corresponds to a point-pattem magnetization, since no magnetizing effect takes place at and adjacent the zero crossovers of the alternating current. A strong toner attraction may result in this type of pattern from the alternating polarity of the magnetized points.
After the premagnetization step has been completed the reflecting element 53 is replaced by an information master record 31 that may, for instance, be a drawing, a writing or a printed text. By way of example, it is assumed in FIG. 1, that the master record 31 is a white sheet of paper on which a black character 65 has been printed.
For imaging according to the embodiment shown in FIG. 1, the switch 45 is opened and the magnetizing head 40 is decoupled from the drive 54 so that no magnetic field 48 follows the exposure band 50. The mirror 28 is, however, coupled to the drive 54 so that the light sheet 30 is moved across the master record 31 whereby successive portions of the master record are illuminated within a traveling narrow band 64. As before, the lens 34 images the band 64 onto the composite recording medium 12 whereby the latter is exposed within an exposure band 50 that travels in the direction of the arrow 51. The switch 37 is again closed and the variable resistor 38 adjusted so thatelectric currents in the photoconductive layer 18 heat the magnetic recording layer 20 above its Curie point at locations at which light reflected by the white background of the master record 31 impinges on the photoconductive layer 18. This above-Curie point heating causes a demagnetization of the recording layer 20 or of its premagnetized line or point pattern. An application of magnetic fields to the recording layer 20 is avoided at this stage to preclude an undesired remagnetization of demagnetized areas through the agency of thermoremanent magnetization.
No significant light is reflected by the black character65, whereby portions of the photoconductive layer that correspond to that character remain dark. Since no electric currents are caused to flow at those corresponding portions, the temperature of the magnetic recording layer 20 remains below its Curie point within an outline occupied by an image of the character 65. The resulting lack of demagnetization of the premagnetized line or point-pattern leads to a magnetic record 68 of the character 65 as shown in FIG. 3.
A further substantial advantage of the apparatus, methods and media of the subject invention may be considered at this juncture. Information recording methods that rely on a selective demagnetization of a premagnetized medium are frequently hampered by the fact that areas which have been demagnetized are remagnetized by the magnetic information record itself -when the recording medium cools back through its 18 located midway between adjacent electrodes and 16 tend to acquire a higher temperature than areas corresponding to points located more closely to the electrodes. The reason for this resides in the fact that the photoconductive layer portions below the electrodes 16 remain dark and do thus not produce heat-generating electric currents, and that the electrodes themselves provide a heat-sink effect. Accordingly, the premagnetization lines 58, 60 or 62 can easily be made narrow and spaced from each other whereby a thermoremanent remagnetization efiect brought about by the information record during cooling will limit itself to a broadeningof the premagnetization lines or points until the same have dimensions desired for a printout of the magnetic image. This broadening is very beneficial since the thermoremanent magnetization effect under discussion typically provides magnetized fringes that have a polarity opposite to the magnetic polarity of the adjacent regions whereby strong magnetic gradients provide a sharp outline of the details of the magnetic image.
The magnetic image 68 may be stored in the magnetic recording medium and'printed out as often as desired. A magnetic toner 70 may be applied to the magnetic image 68 to render the same visible or printable. Magnetic toners typically comprise magnetically attractable particles 72 in powdered form or liquid suspension. Suitable materials for the toner particles 72' include iron, nickel, cobalt'or ferromagnetic alloys. By way of example and not by way of limitation, preferred materials for the toner particles72 include submicron particles of iron, carbonyl iron, and magnetite (Fe O Magnetic toners, toning techniques, and toning apparatus are disclosed in U.S. Pat. No. 2,932,278, by .l.C. Sims, issued Apr. 12, 1960; U.S. Pat. No. 3,052,564, by F.W. Kulesza, issued Sept. 4, 1962; and U.S. Pat. No. 3,250,636, by R.A. Wilferth, issued May 10, 1966.
The toner image 74 resulting from a toning of the magnetic image 68 may be printed out on a sheet of paper, on a film, or on another material having similar surface qualities. If desired, a sheet of paper 75 may be provided with an adhesive coating 76 to assure a transfer and retention of the toner image 74 in the form of a copy 78 of the original character 65. To effectsuch a transfer, the adhesive paper 75 is pressed onto the magnetic recording layer 20 and is thereupon removed whereby the toner image 74 adheres to and is pulled off together with the paper 75. As is known in the art of magnetic printing, the toner 70may be present in the form of a magnetic ink that is absorbed by the paper 75, or the toner particles may be provided with shells of a thermoplastic or other fusible material that may be fused to the paper 75 by a combination of pressure and heat. No adhesive coating 76 is provided if a magnetic ink or a fusible material is employed.
If no further printout or storage is desired, the magnetic image 68 may be erased by such conventional methods as an exposure of the magnetic recording layer 20 to anhysteretic magnetic erasing fields, or to above-Curie point heating. The latter may be efiected by a sweeping of the light sheet 32 across the interdigitated electrode structure 14 and photoconductive layer 18, while the electrodes are connected to the electric energy source 36 and the reflective element 53 is substituted for the information record 31.
tact with, and removable from, the photoconductive layer 18.
Reverting to the interdigitated electrode structure 14 it should be noted that the same affords a much better management of current supply than systems in which the photoconductive layer is sandwiched between sheet electrodes. In the interdigitated structure shown in FIG. 1, any exposed point of the photoconductive layer is serviced by two current supply electrodes. If a light exposure shifts in the direction of the arrow 51, then an increase in electrical resistance along an electrode 15 is automatically compensated by a corresponding decrease in electrical resistance along an adjacent electrode l6. Electrode sheets, on the other hand, do not provide a similar favorable rheology so that contrast, resolution and quality of image points tend to be dependent on the location of the particular point relative to the edges of the recording medium.
We claim:
comprising in combination the steps of:
providing a plurality of interdigitated first an second electrodes;
providing a photoconductive layer in electrical contact with and contiguous to said interdigitated first and second electrodes; providing in heat-transfer relationship with and contiguous to said photoconductive layer a magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern; connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy; applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals and exposing said photoconductive layer to said image to produce a thermal pattern corresponding to said image and constituting said thermal image pattern; and magnetically recording said image by changing the state of magnetization of said recording layer in response to said thermal pattern. 2. A method as claimed in claim 1, wherein: said photoconductive layer is provided with a first side located at said plurality of interdigitated first and second electrodes, and with a second side opposite said first side; and 1 said magnetic recording layer is provided in heattransfer relationship with said photoconductive to said pattern so as to demagnetize said portions of said recording layer. 4. A method as claimed in claim 3, wherein:
said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
5. A method as claimed in claim 3, wherein:
said recording layer is premagnetized by thermoremanent magnetization including a heating of said recording layer with the assistance of an electrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
6. A method as claimed in claim 1, wherein:
said photoconductive layer is progressively exposed to said image in a direction progressing in parallel to said interdigitated electrodes.
7. A method as claimed in claim 1, wherein:
said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes.
8. A method of magnetically recording an image on a composite recording medium, which medium includes a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to said photoconductive layer, and, in heat-transfer relationship with and contiguous to said photoconductive layer, a magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern, comprising in combination the steps of:
connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy;
applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals and progressively exposing said photoconductive layer to said image in .a direction progressing parallel to said interdigitated electrodes to produce a thermal pattern corresponding to said image and constituting said thermal image pattern; and
magnetically recording said image by changing the state of magnetization of said recording layer in response to said thermal pattern.
9. A method as claimed in claim 8, wherein:
said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes. 10. A method as claimed in claim 8, wherein:
the state of magnetization of said recording layer is changed by premagnetizing said recording layer and heating with said thermal pattern portions of said premagnetized recording layer corresponding to said pattern so as to demagnetize said portions of said recording layer.
11. A method as claimed in claim 10, wherein:
said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
12. A method as claimed in claim 10, wherein:
said recording layer is premagnetized by thermoremanent agnetiza io including a heatin of said recording ayer wit t e assistance of an e ectrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
13. A composite photoelectric recording medium operable with a source of electric energy having opposite terminals, comprising in combination:
a thermally responsive magnetic image recording layer contiguous to said photoconductive layer. 14. A composite recording medium as claimed in claim 13, including:
a transparent substrate carrying said interdigitated first and second electrodes and said photoconductive layer.
15. A composite recording medium as claimed in claim 13, wherein:
said photoconductive layer has a first side located at said plurality of interdigitated first and second electrodes, and a second side opposite said first side; and
said magnetic recording layer is in heat-transfer relationship with said photoconductive layer through said second side of said photoconductive layer.
U l 0 i -+zg g STATQESYPATENT OFFICE CERTIFICATE OF CORRECTION I Patent No. 3,717, 460 Dated 973 Duck Frederick J.Je r
Inventofls) Sherman W.
Ir 1s certified that error appears in the above-identified patent 1 and that: said Letters Patent are hereby corrected as shown below:
!" Column 2, line 19, in heat-tiafisfer relationship with and. should. be inserted after "and".- f v Column 3, line 5, insert comma. after "electrodes" Signed and sealed this 26th dy of November 1974.
I (SEAL) -Attest: M coY M. GIBS ON'JR. c. MARSHALL DAN-N A ttestingfi ffieer Y 7 Commissioner of Patents mg UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3 ,717,460 Dated 2 973 Inventofls) Sherman W.Duck, Frederick JJefi'egg, lgmgg n l gmkg It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
I'" Column 2, line 19, in heat-trazisfer relatibnship with and should be inserted after "and". v Column 3, line 5, insert comma. after "electrodes" Signed and sealed this 26th dy of Ndvefnber 1974.
(SEAL) Attest: v
McoY M. snsson JR. 0. MARSHALL DAN-N Attesting Officer Commissioner of Patents

Claims (14)

1. A method of magnetically recording an image, comprising in combination the steps of: providing a plurality of interdigitated first and second electrodes; providing a photoconductive layer in electrical contact with and contiguous to said interdigitated first and second electrodes; providing in heat-transfer relationship with and contiguous to said photoconductive layer a magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal image pattern; connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy; applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals and exposing said photoconductive layer to said image to produce a thermal pattern corresponding to said image and constituting said thermal image pattern; and magnetically recording said image by changing the state of magnetization of said recording layer in response to said thermal pattern.
2. A method as claimed in claim 1, wherein: said photoconductive layer is provided with a first side located at said plurality of interdigitated first and second electrodes, and with a second side opposite said first side; and said magnetic recording layer is provided in heat-transfer relationship with said photoconductive layer through said second side of said photoconductive layer.
3. A method as claimed in claim 1, wherein: the state of magnetization of said recording layer is changed by premagnetizing said recording layer and heating with said thermal pattern portions of said premagnetized recording layer corresponding to said pattern so as to demagnetize said portions of said recording layer.
4. A method as claimed in claim 3, wherein: said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
5. A method as claimed in claim 3, wherein: said recording layer is premagnetized by thermoremanent magnetization including a heating of said recording layer with the assistance of an electrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
6. A method as claimed in claim 1, wherein: said photoconductive layer is progressively exposed to said image in a direction progressing in parallel to said interdigitated electrodes.
7. A method as claimed in claim 1, wherein: said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes.
8. A method of magnetically recording an image on a composite recording medium, which medium includes a photoconductive layer, a plurality of interdigitated first and second electrodes in electrical contact with and contiguous to said photoconductive layer, and, in heat-transfer relationship with and contiguous to said photoconductive layer, a magnetic image recording layer susceptible to an image-wise change of magnetization in response to a thermal Image pattern, comprising in combination the steps of: connecting said interdigitated first and second electrodes to opposite terminals, respectively, of a source of electric energy; applying electrical energy from said source to said interdigitated first and second electrodes by way of said opposite terminals and progressively exposing said photoconductive layer to said image in a direction progressing parallel to said interdigitated electrodes to produce a thermal pattern corresponding to said image and constituting said thermal image pattern; and magnetically recording said image by changing the state of magnetization of said recording layer in response to said thermal pattern.
9. A method as claimed in claim 8, wherein: said photoconductive layer is exposed to said image within a band of exposure extending substantially across said interdigitated first and second electrodes and progressing in a direction parallel to said interdigitated electrodes.
10. A method as claimed in claim 8, wherein: the state of magnetization of said recording layer is changed by premagnetizing said recording layer and heating with said thermal pattern portions of said premagnetized recording layer corresponding to said pattern so as to demagnetize said portions of said recording layer.
11. A method as claimed in claim 10, wherein: said recording layer is premagnetized by cooling said recording layer through its Curie temperature in the presence of a magnetic field.
12. A method as claimed in claim 10, wherein: said recording layer is premagnetized by thermoremanent magnetization including a heating of said recording layer with the assistance of an electrical energization and a progressive exposure of said photoconductive layer in a direction progressing in parallel to said electrodes, and a subsequent cooling of said recording layer in the presence of a magnetic field.
13. A composite photoelectric recording medium operable with a source of electric energy having opposite terminals, comprising in combination: a plurality of interdigitated first and second electrodes; said interdigitated first and second electrodes connected to opposite terminals, respectively, of said source of electric energy; a photoconductive layer in electrical contact with and contiguous to said interdigitated first and second electrodes; and a thermally responsive magnetic image recording layer contiguous to said photoconductive layer.
14. A composite recording medium as claimed in claim 13, including: a transparent substrate carrying said interdigitated first and second electrodes and said photoconductive layer.
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US4439504A (en) * 1980-09-18 1984-03-27 Canon Kabushiki Kaisha Electrophotographic photosensitive member and color electrophotographic process

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DE2118561B2 (en) 1975-12-04
DE2118561A1 (en) 1971-11-18
FR2089813A5 (en) 1972-01-07
GB1323973A (en) 1973-07-18

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